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Glycidyl ether modified urea formaldehyde resin and preparation method thereof

The invention discloses a glycidyl ether modified urea formaldehyde resin and a preparation method thereof. The glycidyl ether modified urea formaldehyde resin is prepared from formaldehyde, urea, long-chain multifunctional glycidyl ether and a modifying agent according to the technological line of weak alkali-weak acid-weak alkali. According to the method, the long-chain multifunctional glycidylether is introduced as a crosslinking agent of the urea formaldehyde resin; a plurality of epoxy groups on the end group of glycidyl ether are used for enhancing the curing crosslinking degree of urea formaldehyde resin with a low aldehyde to urea (F/U) molar ratio; and meanwhile, a long chain is used for enhancing the flexibility of the resin and reducing internal stress generated in the curing process of the resin so as to enhance the cementing strength and the water resistance of the resin. The urea formaldehyde resin prepared by the method has the advantages of low content of free formaldehyde, simple technology and excellent cementing strength; meanwhile, the use period of the resin is prolonged greatly; the construction performance of an adhesive is improved; and the average value of the release amount of platy formaldehyde prepared by the adhesive is smaller than or equal to 0.3mg/L.
Owner:BEIJING UNIV OF CHEM TECH
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