The invention relates to the technical field of adhesives, particularly an adhesive composition for veneer sheets and a preparation technique thereof. The adhesive composition is composed of the following substances in parts by mass: 120-150 parts of water, 25-35 parts of polyvinyl alcohol, 100-120 parts of 42% urea solution, 10-16 parts of bentonite, 10-20 parts of thickener, 10-15 parts of preservative, 0.3-0.6 part of moldproof bactericide, 3.5-6.8 parts of iodine weed, 20-30 parts of melamine urea-formaldehyde resin, 5-10 parts of foaming agent and 20-30 parts of filler. The pH value of the adhesive composition is 3-5. The adhesive composition for veneer sheets avoids using formaldehyde, benzene, toluene and other toxic substances, can satisfy the demands of people for green construction materials and high-grade furniture in home decoration, and is suitable for demands of people. The artificial sheet produced by using the product can completely implement no toxicity, no harm and environment friendliness. The adhesive composition has the advantages of no environmental pollution in the production process, short curing time and long effective service life.