The present invention provides a
flame-retardant aqueous
polyurethane microfiber based on
silicon and a manufacturing process thereof, and belongs to the technical field of
polymer materials. In the present invention, a
silicon source is first hydrolyzed under alkaline conditions to obtain a
silicon dioxide nanosphere, and then the
silicon dioxide nanosphere is subjected to
silane modification and coupled and modified with various
phosphorus-containing compounds to obtain a
phosphorus-hybridized silicon-based
flame retardant.It is then mixed with
isophorone diisocyanate, polytetrahydrofurandiol,
dibutyltin dilaurate,
dimethylolpropionic acid, and the silicon-based
flame retardant to obtain a
prepolymer. The
prepolymer is emulsified in a dispersant to obtain a silicon-based flame retardant /
polyurethane emulsion, and then a specific amount of thickener,
defoamer, leveling agent, and color paste, etc., is added. Subsequently, the
coating is bonded to the base fabric, cured, and peeled to obtain the silicon-based flame-retardant aqueous
polyurethane microfiber. The silicon-based flame-retardant aqueous polyurethane of the present invention achieves excellent mechanical and flame-retardant properties and also exhibits excellent
smoke suppression and
low toxicity.