This invention discloses a method for preparing polycrystalline
fluoride composites through template-based slow-release in-situ molding, belonging to the field of inorganic luminescent functional materials technology. The method includes: providing raw materials, including at least one bulk material as a template, with the raw materials collectively providing A, B, and M ions; mixing the raw materials in a
solvent and maintaining the
reaction temperature for a specified time, allowing the template to slowly dissolve and release ions; the ions provided by the raw materials react with
fluoride ions provided by the
solvent and / or the raw materials to grow
fluoride crystals in situ on the template surface, with the crystals interpenetrating and fusing to form a polycrystalline composite; after the reaction, the product is obtained by washing and
drying. This invention eliminates the need for
tableting, high-temperature
sintering, and organic binders, and can generate polycrystalline fluorescent fluoride composites of predetermined sizes in a single self-stacking process, avoiding the defects of
powder breakage and high-temperature degradation of luminescent ions in traditional two-step methods. It features high
luminescence quantum efficiency, a simple process, and ease of industrial production.