The invention relates to an organic electroluminescence device with high electronic filling efficiency and a preparation method of the organic electroluminescence device. The organic electroluminescence device comprises a glass base plate, an anode, a hole filling layer, a hole transmitting layer, a luminescence layer, an electronic transmitting layer, an electronic filling layer and a cathode, wherein the anode, the hole filling layer, the hole transmitting layer, the luminescence layer, the electronic transmitting layer, the electronic filling layer and the cathode are sequentially stacked on the glass base plate from bottom to top, the electronic transmitting layer is divided into an upper electronic transmitting layer and a lower electronic transmitting layer, an Al membrane electrode layer with a lattice structure is arranged between the upper electronic transmitting layer and the lower electronic transmitting layer, voltage U1 is connected in parallel between the cathode and the Al membrane electrode layer with the lattice structure, and voltage U2 is connected in parallel between the anode and the Al membrane electrode layer with the lattice structure. Through the addition of the Al membrane electrode layer with the lattice structure, the electronic filling efficiency and the luminescence efficiency of the organic electroluminescence device can be effectively improved. Because the Al membrane electrode layer with the lattice structure is in a hollow structure, the electronic transmitting layer is still a whole, the interface potential barrier cannot be increased, and in addition, the voltage exerted on the electronic transmitting layer can be changed. The electronic transmitting capability is enhanced for reaching the current carrier filling balance.