44results about How to "Facilitate crossing" patented technology

The invention discloses an organic electroluminescent device. A light-emitting layer comprises a host material and a guest material. The host material is an exciplex formed by an electron donor material and an electron acceptor material, and the guest material is a thermally activated delayed fluorescent material. The singlet-state energy level of the host material is lower than the singlet-stateenergy level of the guest material. Since the singlet-state energy level of the exciplex as the host material in the light-emitting layer is lower than the singlet-state energy level of the thermallyactivated delayed fluorescent material, the generation of high-energy excitons is prevented, and molecular bond breakage due to high excitation energy is effectively suppressed. The singlet-state energy level of the exciplex is low, which is beneficial to reduce the excitation energy of the excitons in the device, and suppress the triplet state-triplet state annihilation, the triplet state-polaronquenching and the singlet state-triplet annihilation phenomena in the device, thereby reducing the efficiency roll-off of the device and prolonging the service life of the device.

The invention discloses a cuprous complex orange red phosphorescent material based on benzoxazolyl quinoline and a preparation method of the orange red phosphorescent material. A phosphorescent complex is prepared by complexing cuprous salt with a ligand and has a following molecular structure: [Cu(2-QBO)(o-anisyl3P)2]PF6, wherein o-anisyl3P and 2-QBO are respectively an electroneutral phosphine ligand, namely tris(o-methoxyphenyl)phosphine and a neutral heterocyclic ligand, namely 2-(2-benzoxazolyl)quinoline. The phosphorescent complex has the advantages that small molecules are easily purified, the light emitting efficiency is high, and furthermore, the thermal stability is high. The orange red phosphorescent material is prepared by directly mixing and reacting Cu(CH3CN)4PF6 with a dichloromethane solution of the ligands and has the advantages that the process is simple and convenient, equipment is simple, the raw materials are easily available, and the cost is low. The orange red phosphorescent material can be used as a photoluminescent orange red light material and also can be used as a luminescent layer phosphorescent material in an electroluminescent device consisting of multiple layers of organic materials.

The invention discloses a red phosphorescence CuIN2P-type light emitting material with cuprous complexes and a method for manufacturing the red phosphorescence CuIN2P-type light emitting material. Cuprous iodide and ligands carry out coordination reaction to obtain the phosphorescence complexes of the red phosphorescence CuIN2P-type light emitting material. A molecular structural formula of the red phosphorescence CuIN2P-type light emitting material is CuI(2-PBO)(TXP-2, 5), and the 2-PBO and the TXP-2, 5 in the formula respectively represent electrically neutral ligand 2-(2-benzoxazole) pyridine and (2, 5-xylyl) triphosphine. The red phosphorescence CuIN2P-type light emitting material and the method have the advantages that small molecules of the complexes are easy to purify, and the complexes are high in light emitting efficiency and can be easily dissolved by organic solvents; liquor of the cuprous iodine and liquor of the ligands directly carry out mixed reaction to obtain the red phosphorescence CuIN2P-type light emitting material, accordingly processes are simple and convenient, equipment is simple, raw materials are easily available, and the red phosphorescence CuIN2P-type light emitting material is low in cost; the ed phosphorescence CuIN2P-type light emitting material not only can be used as a photoluminescence red light material, but also can be used as a phosphorescence material for a light emitting layer in an electroluminescence device with multiple layers of organic materials, and the like.

The invention provides a star-shaped thermal activation delayed fluorescence material, an electronic device and an application thereof, which belong to the technical field of organic electroluminescence. The thermal activation delayed fluorescence material has the following structure: a star-shaped triphenylbenzene derivative compound disclosed by the invention has the property of thermal activation delayed fluorescence; a nitrogen-containing heterocyclic ring is used as an electron donor (Donor); the compound is connected with an electron-deficient receptor group, and the D-A type molecules with intramolecular charge transfer are formed; meanwhile, a large torsion angle between D and A is used for reducing molecular front line orbit overlapping, so that the singlet state-triplet state energy level is reduced, triplet state excitons can return to the singlet state through reverse intersystem crossing and finally return to the ground state in a radiation transition mode to emit fluorescence, the exciton utilization rate is increased, and finally the purpose of improving the device efficiency is achieved.