113results about How to "Reduced efficiency roll-off" patented technology

The invention provides an organic electroluminescent device and a display device. The organic electroluminescent device comprises an organic luminescent layer; the organic luminescent layer comprisesa main body material, a sensitizing agent material and a resonance thermally activated delayed fluorescence (TADF) material; the main body material is a broad-band gap material; the sensitizing agentmaterial is a thermally activated delayed fluorescence material; a singlet-state energy level of the thermally activated delayed fluorescence material is located between a singlet-state energy level of the broad-band gap material and a singlet-state energy level of the resonance thermally activated delayed fluorescence material; and a triplet-state energy level of the thermally activated delayed fluorescence material is located between a triplet-state energy level of the broad-band gap material and a triplet-state energy level of the resonance thermally activated delayed fluorescence material.With the organic electroluminescent device and the display device, the defects of short life time and wide spectrum of the device caused by a condition that the traditional TADF material is adopted to emit light at the present stage can be overcome.

The invention discloses a dimethylanthracene-containing compound and an application of the dimethylanthracene-containing compound on an organic electroluminescent device. A structural general formula of the organic compound is shown as a general formula (1). The compound has high glass transition temperature and molecular thermal stability, and appropriate HOMO and LUMO energy level and high Eg, by optimizing a device structure, the photoelectric property of the OLED device and the life of the OLED device are effectively increased.

The invention discloses an organic compound containing spirofluorene dibenzocycloheptene and an application of the organic compound. The compound with spirofluorene dibenzocycloheptene as a core is connected with a nitrogen-containing branched chain through phenyl, biphenyl or naphthyl. The compound is not prone to crystallization, has good film-forming property and heat stability and has higher glass transition temperature and proper HOMO and LUMO energy levels; by means of optimization of device structure, photoelectric property of an OLED (organic light emission diode) device can be effectively improved, and the service life of the OLED device can be effectively prolonged, so that application requirements of a panel manufacturing enterprise can be met better.

The invention provides an organic electroluminescent device and a display device. The organic light-emitting device comprises a first light-emitting layer and a second light-emitting layer, wherein the material of the first light-emitting layer comprises a first main body material, a first sensitizer and a first dye, and the material of the second light-emitting layer comprises a second main bodymaterial, a third main body material, a second sensitizer and a second dye; the first main body material can form an exciplex with the second main body material or the third main body material, and the second main body material can form an exciplex with the third main body material; the first sensitizer and the second sensitizer are both thermally activated delayed fluorescent materials; the firstdye and the second dye are both resonance type thermal activation delayed fluorescence materials. According to the light-emitting layer of the organic light-emitting device provided by the invention,the interface exciplex and the bulk phase exciplex are used as main body materials, and the TADF material is used as a sensitizer to sensitize the resonant TADF material, so that the efficiency roll-off is remarkably reduced, and the device efficiency and stability are remarkably improved.

The invention discloses a compound taking fluorene as a core, and a preparation method and an application thereof, and belongs to the technical field of semiconductors. The compound provided by the invention has the structure represented by a general formula (I). The invention also discloses the preparation method and the application of the compound taking fluorene as the core. The compound provided by the invention contains fluorene derivatives and six-membered ring derivative structures, has relatively high glass transition temperature and molecular thermal stability, proper HOMO and LUMO energy levels and relatively high Eg, and can effectively improve the photoelectric property of an OLED device and prolong the service life of the OLED device through device structure optimization.

The invention discloses a compound based on bis(dimethyl)fluorene, and a preparation method and application thereof, and belongs to the technical field of semiconductors. The structure of the compoundis represented by general formula (I). The compound with a bis(dimethyl)fluorene structure has high glass transition temperature and molecular thermal stability, suitable HOMO (highest occupied molecular orbital) and LUMO (lowest unoccupied molecular orbital) energy levels and high Eg; through device structure optimization, the photoelectric performance of an OLED (organic light emitting diode) device can be effectively improved, and the service life of the OLED device can be effectively prolonged.

The invention relates to a nitrogen-containing heterocyclic compound. The heterocyclic compound has a structure shown in the following formula (1). The nitrogen-containing heterocyclic compound comprises asymmetric carboline groups and carbazole groups, so that molecules have excellent hole and electron transmission performance at the same time; meanwhile, bridged N heterocyclic rings and electron-withdrawing groups such as triazine, phenylcyano, pyrazine, pyridylcyano and the like are introduced into the molecular structure, so that improvement of the molecular electron transmission capability is facilitated. The nitrogen-containing heterocyclic compound has excellent bipolar transmission capacity, and can widen a charge composite area and reduce efficiency roll-off. Through introductionof different carboline groups and through change of relative substitution positions of carbazole groups and / or carboline groups, the energy level of the compound can be regulated and controlled, so that materials with different energy levels are screened, and selection and collocation of device materials are facilitated.

The invention belongs to the technical field of OLED, and provides a compound used as a host material. The compound has a structure as shown in a formula (I) which is described in the specification. In the formula (I), X is selected from the group consisting of C, O, S, Se, Si and Te atoms; a and b respectively represent the number of an electron donor D and an electron acceptor A and are respectively selected from the group consisting of 1, 2 and 3; c and d are respectively selected from the group consisting of 0, 1 and 2; L1, L2 and the electron donor D are respectively and independently selected from the group consisting of an alkyl group, a cycloalkyl group, a heterocyclic group, an aryl group, a heteroaryl group, a fused aryl group and a fused heteroaryl group; and the electrozxn acceptor A is selected from the group consisting of an azacycle-containing substituent, a cyano-containing substituent, a phosphoxy-containing substituent and a triaryl boron substituent. The compound provided by the invention has a D-(pi)-sigma-(pi)-A structure with bipolarity, and a sigma bond can effectively interrupt the intramolecular charge transfer between the electron donor D and the electronacceptor A, and limits an excited state to be a local excited state in a segment of D or A, so the compound has a dipole moment with a small excited state; and when the compound is used as the host material of a luminescent layer, the compound can effectively reduce the efficiency roll-off of a blue light material and improves luminescent brightness and luminescent efficiency.

The invention relates to a novel iridium complex taking heterocyclic nitrogen as a main ligand and taking a thiobis diaryl / aromatic heterophosphamide compound as an auxiliary ligand. The heterocyclicnitrogen and phosphorus-sulfur groups in iridium complex molecules are helpful for increasing the electron mobility of a material and regulating the luminescence color, injection and transmission of cavity and electrons can be balanced, a composite area of a carrier is widened, the equipment efficiency is increased, and the efficiency roll-off is reduced. The iridium complex has the advantages ofsimple synthesis, stable chemical properties, easy sublimation purification, and excellent equipment performance, and provides convenience for acquiring a high-efficiency organic electroluminescent device and an application of the high-efficiency organic electroluminescent device in the fields of illumination and display.

The invention discloses an organic dual-functional device and a preparation method thereof. The device comprises a transparent substrate, an anode layer, a hole transport layer, an organic active layer, an electron transport layer and a cathode layer. Under the drive of an applied forward voltage, the organic dual-functional device can achieve an electroluminescence function; and under the drive of an applied backward voltage, the device can achieve an ultraviolet detection function. The organic dual-functional device simultaneously has electroluminescence and ultraviolet detection dual-functions, has the characteristics of being high in efficiency, ultra-thin and integrated, and is simple in preparation technology, short in preparation time and low in cost.

The invention discloses an organic light-emitting display device. The organic light-emitting display device includes a first conducting layer, a second conducting layer, a hole transport part and an electron transport part which are formed between the first conducting layer and the second conducting layer and a luminous layer formed between the hole transport part and the electron transport part, and is characterized in that the luminous layer includes n+1 layers of luminous sublayers and intermediate barrier layers formed between two adjacent luminous sublayers, and at least one of the luminous sublayers is formed by doping a metal auxiliary delayed fluorescent sensitizer, a host material and a fluorescent guest material, wherein n is a natural number larger than or equal to 1. The organic light-emitting display device provided by the invention can transfer 100% of exciton energy to the fluorescent guest material to perform fluorescence radiation, thereby improving the luminous efficiency.

The invention requests and protects a dual-light emitting layer structure blue-light OLED device and a manufacturing process thereof. The device comprises a positive electrode substrate, a hole injection layer, a hole transmission layer, a first light-emitting layer, a second light-emitting layer, an electronic transmission layer, an electronic injection layer and a negative electrode, wherein the first light-emitting layer and the second light-emitting layer employ the same main body materials, same object material and same thickness, and the object doping concentration of the first light-emitting layer is not higher than 50% of the object doping concentration of the second light-emitting layer. The dual-light emitting layer structure provided by the technical scheme is simple, the exciton utilization rate and the composite region can be expanded, and the efficiency roll-off of the device is effectively improved.

The invention provides a thermal activation delayed fluorescent material and application of the thermal activation delayed fluorescent material to organic light emitting diodes. The chemical structureof the thermal activation delayed fluorescent material is shown as a formula (1). A group R in the formula (1) is a chemical group, and triphenylamine derivatives and carbazole derivatives are linkedwith one another to form the chemical group; the R is selectively a type of the certain carbazole derivatives, and the numbers of annular carbon atoms of the certain carbazole derivatives are 18. Thethermal activation delayed fluorescent material and the application have the advantages that donor groups of organic light emitting materials are modified, accordingly, the current carrier transportperformance of the donor groups can be greatly improved, and the organic light emitting materials are good in device performance when applied to blue light, deep blue light or white light; the thermalactivation delayed fluorescent material not only can be used as blue light dye, but also can be used as a host material for yellow light or green light dye; the problem of efficiency roll-off under the condition of high brightness can be solved when the thermal activation delayed fluorescent material is applied to the organic light emitting diodes with single light emitting layers, the structuresof white organic light emitting diode devices can be simplified, and the industrial production cost can be reduced.

The invention belongs to the field of display technologies and particularly discloses an organic electroluminescent device. The organic electroluminescent device comprises a light-emitting layer, wherein the light-emitting layer comprises an exciplex consisting of donor molecules and receptor molecules and a broad-band-gap material used for increasing the spacing between the donor molecules and the receptor molecules. Through the organic electroluminescent device, the HOMO and LUMO track overlapping degree of the formed exciplex can be lowered, singlet-triplet energy level difference is reduced, the reverse intersystem crossing rate (kRISC) of an exciplex body is increased, energy transmission to guest molecules is enhanced, and the efficiency of the device is improved; and meanwhile, by introducing the broad-band-gap material, the concentration of triplet excitons in the light-emitting layer can be effectively lowered, triplet-triplet annihilation (TTA) and triplet-polaron annihilation (TPA) are suppressed, efficiency roll-off is lowered, and the life of the device is prolonged.

The invention relates to a novel iridium complex with a nitrogen heterocyclic ring as a main ligand and a thiocarboxylic acid compound as an auxiliary ligand. The nitrogen heterocyclic ring and a carbon-sulfur group in an iridium complex molecule help to improve the electron mobility of the material and control a luminescence color, so the injection and transmission of holes and electrons are balanced, the current carrier recombination region is broadened, the device efficiency is improved and the efficiency roll-off is reduced. The iridium complex has the advantages of simple synthesis, stable chemical property, easy sublimation and purification, and excellent device performance, and provides convenience for the acquisition of high-efficiency organic electroluminescent devices and application in the technical fields of lighting and display.

The invention relates to a novel iridium complex taking heterocyclic nitrogen as a main ligand and taking a dithiolyl ring / aromatic heterocyclic phosphate compound as an auxiliary ligand. The heterocyclic nitrogen and phosphorus-sulfur groups in iridium complex molecules are helpful for increasing the electron mobility of a material and regulating the luminescence color, injection and transmissionof cavity and electrons can be balanced, a composite area of a carrier is widened, the equipment efficiency is increased, and the efficiency roll-off is reduced. The iridium complex has the advantages of simple synthesis, stable chemical properties, easy sublimation purification, and excellent equipment performance, and provides convenience for acquiring a high-efficiency organic electroluminescent device and an application of the high-efficiency organic electroluminescent device in the fields of illumination and display.

The invention discloses a compound taking diphenyl cycloheptene as a core and an application thereof in an organic light-emitting device. The diphenyl cycloheptene is used as a mother core of the organic compound and is connected with a triarylamine group or a nitrogenous poly-heterocyclic aromatic base through a phenyl group, a biphenyl group or a naphthyl group. The compound disclosed by the invention has higher glass transition temperature and molecular thermal stability, is suitable for HOMO and LUMO energy levels and is higher in Eg. Through the optimization for the device structure, the photoelectric property of an OLED device can be effectively promoted, and the service life of the OLED device can be effectively prolonged.

The invention discloses an organic compound and an application thereof to an OLED (organic light emission diode) device. The organic compound contains dibenzo six-membered rings, and oxygen atoms, sulfur atoms, C1-10 linear or branched alkyl substituted alkylidene, aryl substituted alkylidene and alkyl or aryl substituted tertiary amide are contained between the two dibenzo six-membered rings. Thecompound has higher glass transition temperature and molecular thermal stability and appropriate HOMO and LUMO energy level, and photoelectric property of the OLED device can be effectively improvedand the service life of the OLED device can be effectively prolonged through structural optimization of the device.

The invention relates to a novel organic compound, especially relates to a perimidine derivative, and further discloses an application of the perimidine derivative in the production of an organic electroluminescence device. The perimidine derivative has a good carrier transfer property, and can be used in the OLED as an electron transportation material and a phosphorescence host material. Device test data shows that the derivative is used as the electron transportation material in the OLED, and the derivative has an excellent electron injectivity, a high mobility and a high triplet state energy level, so the derivative can significantly reduce the lighting and working voltages of the device, and can improve the efficiency of the device; and the derivative is used as the phosphorescence host material in the OLED, has balanced hole and electron transporting performances, has an appropriate band gap to facilitate the significant reduction of the lighting and working voltages of the device, and has the high triplet state energy level to facilitate the effective transportation of exciton energy to a phosphorescence dye in order to improve the efficiency of the device.

The invention discloses an anthraquinone general formula compound and application thereof. The general formula compound is shown in a formula in the specification, in the formula, Y represents an oxygen atom or a sulfur atom, X1 to X8 represent C, CR or N, when any one or any two of X1 to X8 represent C, the C atom is connected with L, R is selected from a hydrogen atom, alkyls of C1 to C10, substituted or unsubstituted aryls of C6 to C30, or substituted or unsubstituted heteroaryl groups of C3 to C30, adjacent R can form a ring, L is selected from substituted or unsubstituted heterocyclic arylenes of C3 to C12, Ar is selected from substituted or unsubstituted aryls of C6 to C30 or substituted or unsubstituted heteroaryl groups of C3 to C30, n is an integer of 1 to 2, and when n is 2, twoL groups in the formula are the same or different, and two Ar groups are the same or different. When serving as a light-emitting material in an organic light-emitting device (OLED), the compound showsexcellent device performance and stability; and meanwhile, the OLED made of the general formula compound is within the scope of patent right.

The invention provides a compound and application thereof, and an organic electroluminescent device comprising the same, the compound has a structure of formula (I), and the compound is used as a material of a luminescent layer in the organic electroluminescent device; and the organic electroluminescent device comprises a first electrode, a second electrode and an organic layer between the first electrode and the second electrode, and the organic layer contains any one or a combination of at least two of the compounds. The compound provided by the invention can further reduce the efficiency roll-off of the device and prolong the service life of the device on the premise of ensuring proper driving voltage.

The invention discloses a thickened triphenyl compound as well as a preparation method and application thereof. The thickened triphenyl compound has a structure shown as a formula (I). The parent nucleus of the thickened triphenyl compound is thickened triphenyl. Since the three benzene rings are non-coplanar, the thermal stability of molecules is improved. In addition, the non-coplanar structureof the thickened triphenyl can avoid molecular stacking, exciton generation is facilitated, and the luminous efficiency of the material is improved. By setting R1 and R2 substituent groups, the compound shown as the formula (I) has high overall structural rigidity, the thermal stability of the molecules can be improved, and the service life of the material is prolonged. The invention furthermore discloses an organic electroluminescence device. At least one functional layer contains the previous thickened triphenyl compound. The thickened triphenyl compound serves as a host material or a guestmaterial of the luminescent layer, the stability is high, and the luminous efficiency of the device is high.

The invention provides a B / N organic electroluminescent material as well as a preparation method and application thereof, and further relates to an organic electroluminescent device. The novel B / N organic electroluminescent materials DBTN-1 and DBTN-2 provided by the invention have extremely high fluorescence quantum yield and efficient narrow-band green light emitting property of thermally activated delayed fluorescence in a solution and in a film-doped state. Particularly, the organic electroluminescent device prepared from the fluorescent dye has the advantages of high efficiency, high color purity and ultra-pure green light emission, and can be applied to an ultra-high-definition display technology and the like.

The invention relates to a novel organic compound having a structure represented by formula (1), wherein: the dashed line represents a single bond connection or a non-connection, L1 and L2 are each independently selected from a single bond, a substituted or unsubstituted C6-C30 arylene group, or a substituted or unsubstituted C3-C30 heteroarylene group, and X1-X40 is independently selected from CH, C, or N, R1-R10 is respectively and independently selected from one or more of H, halogen, cyano, alkyl or cycloalkyl of C1-C10, alkenyl of C2-C6, alkoxy or thioalkoxy of C1-C6, substituted or unsubstituted aryl of C6-C30 and substituted or unsubstituted heteroaryl of C3-C30. When the compound provided by the invention is used as a luminescent dye in an OLED device, excellent device performanceand stability are shown.The invention also discloses an organic light-emitting device adopting the compound with the general formula.

The invention belongs to the technical field of OLED and provides a compound used as a main body material. The compound has a structure shown as formula (I) (the formula is shown in description), wherein a and b respectively represent the number of electron donors D and the number of electron acceptors A and are respectively selected from 1, 2 or 3; c and d are respectively selected from 0, 1 or 2; L1 and L2 and the electron donors D are respectively independently selected from alkyl, cycloalkylene, heterocyclyl, aryl, heteroaryl, fused aryl or fused heteroaryl; the electron acceptors A are selected from substituent groups containing nitrogen heterocyclic ring, cyan and phosphoxyl or triaryl boron substituent groups. A D-(pi)-sigma-(pi)-A structure in the compound has bipolarity; the sigmabond is capable of effectively breaking intramolecular charge transfer between the electron donors D and the electron acceptors A, so that excitation state is limited into local-area excitation statein fragments of D or A, so that the compound is enabled to have small excitation state dipole moments; when the compound is used as a main body material of a light-emitting layer, the efficiency roll-off of a blue-light material can be effectively reduced; the light-emitting brightness and the light-emitting efficiency are improved.

The invention discloses a compound taking ketone and fluorene as cores, and a preparation method and an application thereof, and belongs to the technical field of semiconductors. The compound providedby the invention has the structure represented by a general formula (I) defined in the specification. The invention also discloses the preparation method and the application of the compound. The structure of the compound is formed by connecting ketone and fluorene structures, and the compound has a high triplet state energy level (T1); the chemical stability is improved, and the compound has relatively high glass transition temperature and molecular thermal stability. In addition, HOMO and LUMO distribution positions of the compound are separated from each other, so that the compound has appropriate HOMO and LUMO energy levels. Therefore, after the compound is applied to an OLED device, the luminous efficiency of the device can be effectively improved, and the service life of the device can be effectively prolonged.

The invention discloses an organic compound containing dimethylanthracene and application thereof in an organic light-emitting device (OLED). A structure general formula of the organic compound is represented as the formula (I). The compound has high glass transition temperature and molecular thermostability, appropriate HOMO and LUMO energy level and high Eg. Through structural optimization of the device, photoelectric performance and service life of the OLED can be effectively improved.

The invention relates to a novel iridium complex taking heterocyclic nitrogen as a main ligand and taking a sulfo aromatic ring / aromatic heterocyclic phosphate compound as an auxiliary ligand. The heterocyclic nitrogen and phosphorus-sulfur groups in iridium complex molecules are helpful for increasing the electron mobility of a material and regulating the luminescence color, injection and transmission of cavity and electrons can be balanced, a composite area of a carrier is widened, the equipment efficiency is increased, and the efficiency roll-off is reduced. The iridium complex has the advantages of simple synthesis, stable chemical properties, easy sublimation purification, and excellent equipment performance, and provides convenience for acquiring a high-efficiency organic electroluminescent device and an application of the high-efficiency organic electroluminescent device in the fields of illumination and display.

The invention discloses organic blue light micromolecule materials based on anthracene-tetraphenylethylene and application of organic blue light micromulecule materials to preparation of a non-doped organic electroluminescence device, and belongs to the technical field of organic photoelectric materials. An organic electroluminescence material is an anthracene-tetraphenylethylene derivative basedon asymmetry, anthracene groups having the feature of triplet state-triplet state annihilation (TTA) and tetraphenylethylene groups with high solid-state light-emitting efficiency are reasonably connected, the high solid-state light-emitting efficiency can be realized, and the utilization rate of excitons can be increased based on the TTA principle. The prepared non-doped blue light organic electroluminescence device with the organic blue light micromolecule materials being a light-emitting layer can obtain high efficiency under high brightness, and the problem is solved that the efficiency ofa traditional fluorescent material is low, and a device made from a phosphor material or thermal activation delay fluorescent material has severe roll-off of efficiency under high brightness.

The invention discloses an aromatic amine derivative containing a benzophenone groupand a preparation method and application thereof. The aromatic amine derivative containing the benzophenone group provided by the invention has a unique triphenylamine group and the benzophenone group, has TICT and AIE effects, high luminous intensity and good hole transport ability, and can be used as a novel soluble light-emitting molecule which is good in performance, low in cost and highly distorted in space structure. The aromatic amine derivative can be widely applied to the fields of color display and solid-state lighting, and is used for preparing a luminescent material, a luminescent device or an intelligent material; when thearomatic amine derivative is used as OLED, the aromatic amine derivative containing the benzophenone group is taken as a host material and a phosphorescent material is taken as a guest material, so that the concentration quenching of the phosphorescent material can be reduced, the external quantum efficiency of the device is improved, and efficiency roll-off is reduced.