150 results about "Anthranil" patented technology

A method for marking a liquid petroleum hydrocarbon. The method comprises adding to the liquid petroleum hydrocarbon at least one substituted anthraquinone dry having formula (I) wherein X is O or S; Y is O, NR<7 >or S; R<1 >and R<2 >independently are hydrogen, alkyl, aryl, aralkyl, heteroalkyl, heterocyclic or alkanoyl; R<3 >and R<5 >independently are alkyl, aryl, aralkyl, heteroalkyl or heterocyclic; R<4 >and R<6 >independently are hydrogen or alkyl; R<7 >is hydrogen or alkyl; and wherein the substituted anthraquinone dye(s) has an absorption maximum in the range from 600 nm to 750 nm.

The invention belongs to the technical field of crossing of chemical engineering, materials engineering and environmental engineering, particularly relates to an improvement technology of cellulose membrane materials and a chemical grafting and fixing technology for treating anthraquinones compound carriers of wastewater containing nitrogen, and particularly relates to a method for preparing an anthraquinone functional cellulose membrane by fixing an anthraquinone compound on microcrystalline cellulose by chemical grafting. According to the method, the microcrystalline cellulose is used as a raw material; firstly, ionic liquid is used as a solvent for dissolving the microcrystalline cellulose; thionyl chloride modified cellulose is used for preparing cellulose chloride and then the cellulose chloride is reacted with amino anthraquinone in dimethylformamide to prepare an anthraquinone functional cellulose membrane material; the substitution degree of the prepared cellulose chloride can reach 1.89 and the anthraquinone grafting rate of the anthraquinone functional cellulose membrane reaches 82%; the anthraquinone functional cellulose is prepared by the two-step reaction; the content of anthraquinonyl is high and the grafting rate is high; the fixing effect is stable; finally, the anthraquinone functional cellulose is changed into the membrane by a phase transferring method; the membrane material can be used for accelerating and strengthening the biological degradation process in the treatment of the wastewater containing the nitrogen.

A carried non-crystal Pd alloy catalyst for hydrogenating anthraquinone to prepare H2O2 is prepared from the carrier which is one or two of gamma-Al2O3, alpha-Al2O3, MgO, activated carbon, molecular sieve and mullite, non-crystal PdB alloy and RE element through immersing the carrier in the solution of RE metal's nitrate under ultrasonic condition, calcining at 400-700 deg.C for 2-5 hr, immersing in PdCl2 solution, dropping KBH4 solution in ice water bath, and washing. Its advantages are high catalytic activity and low cost.

The invention discloses a preparation method of a porous inorganic filling materials-fixed quinone compound, belonging to the technical field of water treatment in environmental engineering. The method comprises the following steps of: selecting porous inorganic filling materials such as ceramsites, volcanics and the like; plating gamma-aluminum oxide on the surface of the materials; aminating, so that the surfaces of the porous inorganic filling materials contain a certain quantity of primary amidogen; putting the aminated materials into hydrochloric solution to have reaction for protecting the primary amidogen; and putting the reacted porous inorganic filling materials into sodium hydroxide solution, adding sulfonyl chloride group-containing anthraquinone compound which is dissolved in dichloromethane, and reacting for 6-10h under the room temperature to fix the water-soluble quinone compound. The quinone compound-containing macroporous polymer is applied to an anaerobic reactor to be capable of improving the biotransformation speed of an organic matter which is hardly degraded. The method covalently fixes the quinone compound on the macroporous polymer of a biologic carrier, so that the redox medium is easily contacted with the microbe, thereby overcoming the problem of the secondary pollution since the water-soluble quinone compound flows out with the water.

The present invention belongs to the field of chemical technology and is especially one catalyst for anthraquinone hydrogenation process of preparing hydrogen peroxide and its preparation. The catalyst is obtained with some alloy and through active treatment with alkali solution and the alloy consists of Ni, Al and metal additive including one or several of Cr, Mo, W, Fe, Co, Cu and Zn. The catalyst is one kind of amorphous skeleton alloy catalyst prepared through high temperature melting of metal components, quenching stress to obtain alloy strip or scaly alloy, grinding, sieving and activation in alkali solution. Compared with traditional Raney Ni catalyst, the said catalyst has high anthraquinone hydrogenation activity and high selectivity.

A shaped Pd catalyst is used to prepare hydrogen peroxide through dissolving alkyl anthrauinone in the mixed solvent of ester and arylhydrocarbon to obtain the working liquid, catalytic hydrogenating reaction on said alkyl anthraquinone in working liquid, and oxidizing by O2-enriched air or O2. Said catalyst is prepared through carrying palladium chloride by the salt of alkali metal, alkali-earth metal, or transition metal for modifying it, and extruding out.

The invention discloses a preparation method of a porous inorganic filling materials-fixed quinone compound, belonging to the technical field of water treatment in environmental engineering. The method comprises the following steps of: selecting porous inorganic filling materials such as ceramsites, volcanics and the like; plating gamma-aluminum oxide on the surface of the materials; aminating, so that the surfaces of the porous inorganic filling materials contain a certain quantity of primary amidogen; putting the aminated materials into hydrochloric solution to have reaction for protecting the primary amidogen; and putting the reacted porous inorganic filling materials into sodium hydroxide solution, adding sulfonyl chloride group-containing anthraquinone compound which is dissolved in dichloromethane, and reacting for 6-10h under the room temperature to fix the water-soluble quinone compound. The quinone compound-containing macroporous polymer is applied to an anaerobic reactor to be capable of improving the biotransformation speed of an organic matter which is hardly degraded. The method covalently fixes the quinone compound on the macroporous polymer of a biologic carrier, sothat the redox medium is easily contacted with the microbe, thereby overcoming the problem of the secondary pollution since the water-soluble quinone compound flows out with the water.

The invention discloses a novel catalyst and process of preparation for anthraquinone hydrogenation in hydrogen dioxide solution preparation, wherein the catalyst comprises nickel, boron, metallic additive M and carrying agent S, the specific surface is 200-1200 m2g-1, the active specific surface is 0.1-50 m2g-1. The catalyst preparing process comprises the steps of charging surface activator in the nickel-boron alloy preparation, producing mixture of mesopore or micropore molecular sieve and nickel-boron alloy, the conventional immersion or reducing agent immersion method can be employed to load the nickel-boron alloy onto the common carrying agent or mesopore and microporous molecular sieve.

A sphingomonas xenophaga QYY (CGMCC No.1172) is disclosed, which features that the bromamino acid as the intermediate of anthraquinone dye is the unique carbon and nitrogen sources for its growth, so its cells can destroy the anthraquinone rings. As a result, it has strong decolor capacity and can be used to decolor the sewage of anthraquinone dye.

The invention belongs to the field of water treatment, and relates to the field of treatment of pollutant-containing wastewater, in particular to a preparation method and application of an anthraquinone compound modified hydrophilic carrier. Inorganic filler, plastic and other carriers subjected to hydrophilic treatment react with an epoxy silane coupling agent to obtain an epoxy modified carrier,then an epoxy group and an amino-containing anthraquinone compound are used for reacting with an amino-terminated polyethylene glycol, and an anthraquinone compound and polyethylene glycol modified carrier is obtained, wherein the anthraquinone compound accelerates biodegradation of azo dyes, nitrate and the like, and the hydrophilicity of the polyethylene glycol can improve the compatibility ofthe carrier and the water containing the azo dyes, the nitrate and the like, so that the performance of the anthraquinone compound is further improved. The obtained anthraquinone compound modified hydrophilic carrier can be widely applied to sewage treatment.

The invention discloses a method for detecting copper ions with the 1,4-dyhydroxy-9,10-anthraquinone salicylic hydrazide compound as a fluorescence probe and belongs to the technical field of optical analysis detection. According to the method, the recognition action of the 1,4-dyhydroxy-9,10-anthraquinone salicylic hydrazide and 15 types of metal ions is observed and researched through experiments, it is found out that the probe molecule EXZ has a good selective recognition action on the copper ions, the probe molecule can achieve fluorescent recognition of the copper ions in a water solution through the solubleness of hydroxide radical and water, and a good result can be achieved under the physiological pH value condition. The method is environmentally friendly, the selectivity of the copper ions is concentrated, sensitivity is high, a fluorescence quenching function is achieved within a short reaction time, and the probe molecule can be successfully applied to detection of the copper ions in creature living cells.

The invention discloses a palladium-based catalyst. The palladium-based catalyst is characterized in that composite oxide prepared by zirconium dioxide and activated aluminum oxide and modified by lithium is used as a supporter, palladium is used as a main active component, one or more of magnesium, calcium, lanthanum, cerium, ferrum, cobalt, nickel and zinc is selected as an assistant active component, the mass ratio of zirconium dioxide ZrO2 and activated aluminum oxide AlO2O3 is 1: (1-40), the mass content of lithium in the supporter is 0.1-20%, the mass content of palladium in the catalyst is 0.02-10%, and the mass content of the assistant active component in the catalyst is 0-8%. Compared with the prior art, the catalyst is obviously improved in the aspects of activity, wearing resistance and anti-hydration performance.

A (meth)acrylate ester includes a (meth)acrylate monomer moiety having an ester oxygen, an anthraquinone moiety having a transmittance spectrum producing red light, and a linking group covalently coupled to the ester oxygen and the anthraquinone moiety, the linking group including phenyl, naphthyl, a linear alkyl group having from 2 to about 10 carbons, a branched alkyl group having from 3 to about 10 carbons, a cycloalkyl group having from about 3 to about 20 carbons, or a substituted aromatic group.

The invention discloses a noble metal / TiO2-C catalyst for removing p-carboxybenzaldehyde, 2,6-dicarboxyl anthraquinone, 2,6-dicarboxyl fluorenone, and other colored impurities from crude p-phthalic acid. The noble metal / TiO2-C catalyst of the present invention can be used for the hydrogenation refinement process of the crude p-phthalic acid. With the noble metal / TiO2-C catalyst of the present invention, the contents of the p-carboxybenzaldehyde, the 2,6-dicarboxyl anthraquinone, the 2,6-dicarboxyl fluorenone, and other colored impurities can be significantly reduced.

The process for chemically modifying metal-free, colored anthraquinone or condensed anthraquinone compounds or the compounds prepared by said process for improving one or more properties thereof such as water dispersibility, compatibility with other organics, or increased chemical reactivity, wherein the process includes providing material with from 1-6 sulfonylhalide groups or sulfonate ester groups or mixtures thereof, and contacting the material under sulfonamido forming conditions with one or more reactants containing one or more poly(oxyalkylene) moieties, each of the reactants having from 1 to 4 functional amino groups, and each of the poly(oxyalkylene) moieties being comprised of from about 4 to about 200 epoxide reactant residues at least about 50 mole percent of which residues contain 2-4 carbons and wherein the total of said epoxide reactant residues is from about 4 to about 600.

Red colorants comprising a chromophore having at least one poly(oxyalkylene) chain attached to the 1-position, as well as at least one poly(oxyalkylene) chain attached to either the 5-position or the 8-position of an anthraquinone backbone are provided. Such colorants exhibit excellent base stability, effective colorations, excellent low extraction rates, and high lightfastness levels, particularly when incorporated within certain media and / or on the surface of certain substrates, particularly polyesters. The poly(oxyalkylene) chains also increase the solubility in different solvents or resins thereby permitting the introduction of such excellent coloring chromophores within diverse media and / or diverse substrates as well as provides a liquid colorant which facilitates handling. Compositions and articles comprising such colorants are provided as well as methods for producing such inventive colorants are also provided.

The invention relates to a nanometer palladium catalyst for hydrogenation of anthraquinone and a preparation method thereof, relating to a palladium catalyst. The invention provides the nanometer palladium catalyst for the hydrogenation of anthraquinone and the preparation method thereof, wherein natural plants are taken as a reducing agent and a carrier. The nanometer palladium catalyst is prepared by dispersing nanometer palladium granules on a Cape jasmine carrier, and based on weight percent, the loaded palladium accounts for 1.2-3.6 percent of Cape jasmine, and the size of the nanometer palladium granules is 3-10 nm. Cape jasmine lixivium is prepared by dipping Cape jasmine in water, and the nanometer palladium catalyst is prepared by preparing palladium chloride into palladium chloride and Cape jasmine mixing solution by using the Cape jasmine lixivium, reducing and drying to obtain the nanometer palladium catalyst loaded on the Cape jasmine, i.e. the nanometer palladium catalyst for the hydrogenation of anthraquinone.

The invention aims at providing a novel azaaromatic compound having an azafluoranthene skeleton which is useful as the constituent of organic EL devices and at realizing a long lifetime, high-efficiency and practical organic EL device by using the compound in at least one of the organic compound layers. The invention provides azaaromatic compounds having azafluoranthene skeletons as represented by the general formula (1): wherein R1 to R12 are each independently hydrogen, substituted or unsubstituted alkyl having 1 to 30 carbon atoms, substituted or unsubstituted alkoxy having 1 to 30 carbon atoms, substituted or unsubstituted aryl having 6 to 40 carbon atoms, trialkylsilyl (wherein each alkyl has 1 to 20 carbon atoms and may be substituted), aryloxy (wherein the aryl has 6 to 40 carbon atoms and may be substituted), halogen atom, or cyano group, with the proviso that at least two of R1 to R12 are each cyano group, trifluoromethyl group, or fluorine atom and adjacent two of R1 to R12 may be linked together to form a ring structure.

A colored composition includes: (A) a dye that is selected from the group consisting of a methine dye, an anthraquinone dye and an azomethine dye, and that is a mixture of stereoisomers; and (B) a non-polar solvent.

The invention is a type of red dispersive dye containing two anthraquinone rings, using 1-amino-2-bromo-4- hydroxyl (or alkoxy) anthraquinone as raw material to make condensation reaction with diphenol A, quinol, diphenol S, etc, respectively, in a high-boiling point inert solvent so as to make it. It has not only simple synthetic process and fewer steps but also better sublimating fastness and higher molar extinction coefficient.

The invention relates to a process for the production of hydrogen peroxide by the anthraquinone process, comprising a hydrogenation stage, an oxidation stage and an extraction stage. According to the invention, catalytic hydrogenation of anthraquinone derivatives dissolved in a working solution is carried out in the presence of added molecular oxygen. Per mol hydrogen, 0.1 to 10 mmol oxygen is preferably introduced into the hydrogenation stage with the hydrogenating gas, in mixture with an inert gas and / or dissolved and / or dispersed in the working solution. This increases the residence time of the catalyst.

The present disclosure relates to a catalyst. The catalyst comprises a carrier and an active component supported on the carrier, and the active component comprises 0.00001-30 wt% of an alkali metal element, 0.0001-60 wt% of an alkaline-earth metal element and 0.00001-30 wt% of a fourth periodic transition-metal element. The present invention also provides a preparation method of the catalyst, an application of the catalyst for catalyzing regeneration of effective anthraquinone from an anthraquinone degradation product, a regeneration method of a circulating working fluid in the process of producing hydrogen peroxide by an anthraquinone method and a method for producing the hydrogen peroxide. The catalyst provided by the present invention effectively improves the regeneration effect of thecatalyst on the anthraquinone degradation product, significantly reduces accumulation of the anthraquinone degradation product in the working fluid, and improves the content of the effective anthraquinone in the working fluid, thereby facilitating reduction of the production costs and improvement of the production efficiency.

The invention relates to two novel substances, specifically (1R,2S,3S,4R)-3-acetoxy-1,2,4,5-tetrahydroxy-y-methoxy-2-methyl-1,2,3,4-tetrahydroanthracene-9,10-dione (3-O-acetyl-altersolanol M) (I) and 8-(4,5,6-trihydroxy-7-methyl-2-methoxy-9,10-dioxo-9H,10H-anthracene-1-yl)-(1S,2S,3R,4S)-1,2,3,4,5-pentahydroxy-7-methoxy-2-methyl-1,2,3,4-tetrahydro-9H,10H-anthracene-9,10-dione (atropisomeric alterporriol I und J), (II) to the use thereof as anti-infective agents or anti-cancer agents, and to a production method therefor.

The loaded noble metal catalyst for hydrogenating alkyl anthraquinone has gamma-Al2O3 carrier, and contains Pt 0.2-0.4 wt%, and one of K2O, Cs2O, MgO, BaO, La2O3 and CeO2 0.3-1.2 wt%. The catalyst isprepared through soaking process and has high activity and high selectivity. The catalyst has a hydrogenating efficiency of 7.5-12g (H2O2) / L and a selectivity over 97 % at the conditions of 0.2 MPa pressure, 45 deg.c temperature and working liquid space velocity of 11.4 to the minus first / hr.

The invention discloses a preparation method of a supported nickel catalyst. The method comprises the following steps: making a mixed solution containing soluble nickel salt and aluminium nitrate or a mixed solution containing soluble nickel salt, magnesium nitrate, and aluminium nitrate react with a precipitant so as to obtain a green precipitate, washing the precipitate with distilled water, then carrying out a supercritical drying treatment or an azeotropic distillation drying treatment so as to obtain a precursor of the supported nickel catalyst; calcining the precursor for 2 to 5 hours in the atmosphere of N2 and at a temperature of 200 to 600 DEG C; and then switching to an atmosphere of H2 to carry out reduction reactions for 2 to 4 hours at a temperature of 300 to 550 DEG C so as to obtain the supported high active nickel catalyst. The supported nickel catalyst has a specific surface area of 250 to 450 m<2> / g, an average pore diameter of 9 to 30 nm, and a pore volume of 1.0 to 1.9 cm<3> / g. The surface area of the active metal nickel loaded on the catalyst is 40 to 70 m<2> / g. The supported nickel catalyst is applied to the hydrogen peroxide production through an anthraquinone hydrogenation method.

The invention relates to a colorimetric fluorescence probe for high selectivity multiple biological thiol and a preparation method thereof, particularly to the colorimetric fluorescence probe which uses selenazole ring as an identification receptor, takes an anthraquinone derivant as an information report functional group, can high selectively distinguish and identify cysteine, homocysteine and glutathione and the preparation method thereof, belonging to the technical field of life science. The colorimetric fluorescence probe has the following structure formula as shown in the specification. The colorimetric fluorescence probe is prepared by grinding and reacting a diamine compound corresponding to the colorimetric fluorescence probe for the high selectivity multiple biological thiol and selenium dioxide in an agate mortar for 15-90 min at the grinding temperature of 10-35 DEG C, the mole ratio of the corresponding diamine compound to the selenium dioxide is 1:1-5, and the reaction formula is shown in the specification. The invention can directly distinguish and identify the cysteine, the homocysteine and the glutathione by eyes, and carry out imaging analysis on biological thiol in living cells. The invention has the advantages of simple method, environmental protection and industrial production.

The invention relates to a preparation method for a 2-alkyl anthracene derivative. The preparation method comprises the following steps that zinc powder is taken as a reducing agent, and crystallized copper sulphate is taken as a catalyst; 2-alkyl substituted anthraquinone reacts inside strong aqua ammonia at a temperature of between 70 and 80 DEG C for 2 to 6 hours; the reaction solution is cooled down to room temperature, and is filtered; the filtrate is extracted 2 to 4 times by diethyl ether, and a filter cake undergoes Soxhlet extraction for 2 to 4 hours by means of diethyl ether; a diethyl ether phase is combined; and finally, the 2-alkyl anthracene derivative can be obtained through silica gel column chromatography. The zinc powder adopted by the preparation method has low price and abundant raw material sources; moreover, the preparation method has the advantages of moderate reaction conditions, simple and easy column chromatography separation, high yield and low cost, and has enormous application value and economic value.

The invention relates to a treatment technology of wastewater generated in the preparation of hydrogen peroxide from anthraquinone. The technology comprises the following steps: adding a flocculating agent and an antifoaming agent to wastewater obtained in the preparation of hydrogen peroxide from anthraquinone, and stirring for 12-24h to complete the wastewater treatment. Compared with the prior art, the technology makes the COD of water discharged from a water discharge end decrease from original 250ppm to below 20-30ppm and SS decrease to about 20-30mg / l after long time wastewater treatment, meets wastewater emission indexes, has a very stable effect, and has no untoward effects on the whole wastewater treatment system.

Thermoplastic resin compositions are described in which amine salts of anthraquinone dyes and monoazo complex dyes are added. These compositions show superior performance in laser welding applications.