2625results about "Hydrocarbon preparation" patented technology

The invention provides a method for synthesizing 1, 2-bis (4-vinyl phenyl) ethane, which comprises the following steps: adding a first solvent, methyl triphenyl phosphine halide and strong alkali into a reaction flask, and uniformly stirring to obtain a first mixed solution; heating the first mixed solution and carrying out reflux reaction for 1 hour; dropwise adding a 1, 2-bis (p-formaldehyde phenyl) ethane solution until the reflux reaction is finished to obtain a second mixed solution; reducing the temperature of the second mixed solution to room temperature, and adjusting the pH value of the second mixed solution to obtain a first solution; layering the first solution, and taking an organic layer; adding a polymerization inhibitor into the organic layer to obtain a second solution; concentrating the second solution to obtain a 1, 2-bis (4-vinyl phenyl) ethane crude product; adding a poor solvent into the crude product, stirring and crystallizing; filtering the crystal to obtain a filter cake, adding a second solvent into the filter cake, and washing and drying the filter cake to obtain 1, 2-bis (4-vinyl phenyl) ethane; the method for synthesizing the BVPE is simple and low in raw material cost, and the synthesized BVPE is high in purity and free of product isomeride.

The invention discloses a catalyst for preparing propylene through propane dehydrogenation as well as preparation and application of the catalyst. The catalyst comprises a tin-containing spherical alumina carrier and noble metal Pt, and a preparation method of the tin-containing spherical alumina carrier comprises the following steps: mixing aluminum hydroxide sol with acidic silica sol, dropwise adding the obtained mixture into an oil-ammonia water-oil-water four-layer mixed column, molding, drying and roasting to obtain the tin-containing spherical alumina carrier; the oil-ammonia water-oil-water four-layer mixing column is sequentially provided with four layers from top to bottom, the first layer is a first oil layer, the second layer is an ammonia water layer, the third layer is a second oil layer, and the fourth layer is a tin-containing water layer. When the catalyst is applied to propane dehydrogenation propylene preparation reaction, the activity of the catalyst can be remarkably improved.

A device for preparing chemicals through waste plastic and crude oil mixed feeding grading gas-phase dehydrogenation cracking is composed of a waste plastic self-hot-melting dechlorination pretreatment subsystem, a waste plastic melting liquid and crude oil selective vaporization dehydrogenation cracking subsystem, a high-temperature cracked oil gas gas-phase catalytic cracking subsystem and a cracked oil gas fractionation and refining subsystem. A recycle oil pipeline and a cracking dry gas pipeline of the cracking oil-gas fractionation and refining subsystem are respectively connected to a high-temperature molten oil inlet and a feeding carrying gas inlet of the waste plastic self-heating melting dechlorination pretreatment subsystem, and a waste plastic molten liquid delivery pipeline of the waste plastic self-heating melting dechlorination pretreatment subsystem is connected to a crude oil feeding pipeline; a waste plastic and crude oil mixed feeding pipeline is connected into the waste plastic molten liquid and crude oil selective vaporization dehydrogenation cracking subsystem through an atomizing nozzle, selective vaporization dehydrogenation cracking and gas-phase catalytic cracking are sequentially completed in a grading mode, and then the cracked oil gas fractionation and refining subsystem produces triene tribenzene, high-temperature recycle oil and cracked dry gas.

Processes for preparing Compound I, and pharmaceutically acceptable salts and solvates thereof, pharmaceutically acceptable solid (e.g., crystalline or amorphous) forms of Compound I, pharmaceutical compositions comprising the same, methods of treating pain using the same, and methods for making the same are disclosed.

The invention belongs to the field of catalyst regeneration, and provides a regeneration method of a platinum-based low-carbon alkane dehydrogenation catalyst, which specifically comprises the following steps of: simultaneously carrying out charking and oxychlorination operations before a deactivated catalyst reaches the highest roasting temperature, and adding agent pouring treatment in the regeneration process, and measures for protecting the dispersity of platinum on the catalyst are added in the reaction heating process of the catalyst and after the application is finished, so that the service life of the catalyst is prolonged. According to the regeneration method, the regeneration step of the deactivated catalyst is simplified, chlorine injection, water injection, vulcanization and other operations are not needed, charking, oxychlorination and different reduction depths caused by different positions of the catalyst are avoided, the performance uniformity of the catalyst and the redispersity of platinum are improved, and the regeneration efficiency is improved. The problems that in an existing regeneration method, the dispersity of active components is low, the number of repeated regeneration times is small, and the performance of the catalyst is reduced are solved, the regenerated catalyst obtained through the regeneration method is not lower than that of a fresh catalyst in the aspects of catalyst conversion rate, selectivity and stability, and the regeneration effect is remarkable.

The invention belongs to the technical field of petrochemical engineering, and particularly relates to a thermal auxiliary material for promoting alkane dehydrogenation reaction efficiency and a preparation method and application thereof. The auxiliary material is composed of a heating main body, a heat storage carrier, a stabilizing auxiliary agent and a carrier auxiliary agent. Wherein the component of the heating main body is CuO; the component of the heat storage carrier is CaO-Al2O3 composite oxide; the stabilizing auxiliary agent is one or more of Cr2O3, La2O3, CeO2 and ZrO2; and the carrier auxiliary agent is one or more of MgO, BaO, NiO and Fe2O3. The thermal auxiliary material with high mechanical strength, high heat transfer performance and high stability is synthesized through the steps of coprecipitation reaction, high-temperature hydrothermal reaction, high-temperature calcination, vacuum impregnation, ultrasonic oscillation and the like; when the material is applied to an alkane dehydrogenation olefin preparation device, alkane conversion rate and olefin selectivity can be improved, the service life of a catalyst can be prolonged, and energy consumption of the device can be reduced.

The invention relates to the technical field of catalyst carriers, and discloses reticular porous spherical aluminum oxide as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) mixing an aluminum source, acid, a pore-forming agent, a surfactant and water to obtain pseudo sol; (2) performing ultrasonic treatment and oil ammonia column forming treatment on the pseudo sol obtained in the step (1) to obtain gamma-Al2O3 spherical gel beads; and (3) aging, washing, drying and calcining the gamma-Al2O3 spherical gel beads obtained in the step (2) to obtain the reticular porous spherical alumina. The spherical aluminum oxide prepared by the method has abundant communicated reticular pore channels, is obviously distributed in mesopore and macropore ranges, is beneficial to obviously improving dispersion and loading of a catalyst in an aluminum oxide carrier and improving the performance of petroleum reforming and propane dehydrogenation, and has industrial production utilization value and commercial value.

A Liquid Organic Hydrogen Carrier (LOHC) dehydrogenation system is described, capable of meeting time-variable hydrogen demands with short dynamics while always ensuring a high degree of dehydrogenation under all operating conditions. The system comprises one or more reactors comprising an LOHC vessel and a recirculation circuit comprising a recirculation pump, a preheater capable of supplying the reaction heat as sensible heat, and a cartridge containing the solid catalyst.

The invention relates to the field of plastic degradation, in particular to a polystyrene hydrocracking method. Comprising the following steps: respectively adding a metal sulfide catalyst and polystyrene into a suspended bed reactor, sealing the suspended bed reactor, introducing hydrogen with a certain pressure, and starting a reaction; the polystyrene hydrocracking method provided by the invention adopts the non-noble metal catalyst, and is more economical. The problem that polystyrene is easy to generate hydrogen by self-cyclization and polycyclic aromatic hydrocarbon is formed is solved; meanwhile, the problems of benzene ring hydrogenation and aromatic hydrocarbon selectivity reduction are solved, and the yield of monocyclic aromatic hydrocarbon is up to 90%. The method can realize complete cracking of waste polystyrene, and has good economic benefits.

The invention discloses a catalyst for catalyzing ethane to prepare ethylene or an oxygen-containing compound as well as a preparation method and application of the catalyst, and belongs to the field of catalysts. On the basis of ERB-1 and MCM-22, a large number of hydroxyl structures are formed through post-treatment of nitric acid or ammonium nitrate; a titanium source and molecular sieve silicon hydroxyl are subjected to a dehydrohalogenation reaction in a titanium halide gas form to form a Ti-O-Si bond, so that titanium successfully enters a molecular sieve framework and is uniformly distributed. Au or Pd is anchored by a framework Ti, Au or Pd is loaded by using a deposition-precipitation method, and the introduced Ti species can provide a better environment for further dispersing Au or Pd by changing isoelectric points on the surface of a molecular sieve carrier, so that the size of Au or Pd nanoparticles is controlled; secondly, due to the high specific surface area of the MWW molecular sieve, the gold precursor can be effectively dispersed, and agglomeration is inhibited; compared with an MWW molecular sieve of pure Si, Au or Pd nanoparticles can be dispersed and anchored by introducing a framework Ti, so that an Au and Pd-based catalyst which is about 2nm in size and good in dispersion is prepared.

The invention belongs to the technical field of chemical catalysis and chemical engineering, and discloses an oxygen carrier for preparing ethylene through oxidative dehydrogenation of chemical chain ethane as well as a preparation method and application of the oxygen carrier. Comprising a main component CeO2 and loading components V and Ru, specifically, the V and the Ru are loaded on the CeO2 in a step-by-step impregnation mode, and according to the mass percent of the CeO2, the Ru accounts for 2.00%, and the V accounts for 1.00%-5.00%. The key problems that a traditional ethane dehydrogenation technology is high in dependence on precious metal, prone to sintering at high temperature, frequent in regeneration and the like are solved, and an innovative solution is provided for low-carbon efficient ethylene production.

Transalkylation processes using catalysts comprising three dimensional 12 membered ring zeolites with a combination of small and large pores are described. These catalysts have increased conversion of alkylphenols to phenol, cresols, and alkylbenzenes from coal-derived liquid streams compared to catalysts consisting of HZSM-5 zeolite.

The invention belongs to the technical field of catalysis, and discloses a high-density long-chain alkane dehydrogenation catalyst and a preparation method thereof. The invention relates to a high-density long-chain alkane dehydrogenation catalyst, which is a composition of Pt, Sn, Ni, Fe and alkali metal or oxide thereof loaded by using mesoporous and microporous alumina as a carrier. The catalyst is mainly applied to the reaction process of preparing monoolefine through dehydrogenation of long-chain n-alkanes (C10-C13), the catalyst uses a ball-forming high-density carrier, the preparation process is safer and more environment-friendly, the dehydrogenation service life of the catalyst is prolonged, and the dehydrogenation stability is improved by 15-30%.

The invention discloses a metal self-dispersed low-carbon alkane dehydrogenation catalyst as well as a preparation method and application thereof. The catalyst is composed of a molecular sieve carrier, metal particles of main active components Ru, Rh, Pd, Ir, Pt and Au, auxiliary components Fe, Co, Ni, Cu, Zn, Ga, In, Ge, Sn, Mn, Zr, V, Cr, Ti, Nb, Mo, Y, W, Pb, Sc, Bi, Sb, La and Ce, and alkali metal components Na, Mg, K, Ca and Cs. Firstly, the synthesized molecular sieve is subjected to high-temperature activation heat treatment, so that rich defect sites are generated; and mixing the activated molecular sieve with metal particles, and finally carrying out high-temperature treatment on the mixture in an oxygen atmosphere to prepare the stable molecular sieve loaded metal cluster. The obtained catalyst shows excellent catalytic activity and regeneration performance. The active metal particles are used as raw materials, the step of converting metal particle powder into salt is reduced, a physical mixing method is adopted, the preparation process of the catalyst is simpler, and the economic cost is lower.

A method for producing hydrocarbons includes subjecting a first feed stream to steam cracking to obtain a first product stream, and subjecting an ethane-containing second feed stream to oxidative dehydrogenation to obtain a second product stream. A portion of the first product stream is subjected to a deethanization or a depropanization separately from the second product to obtain a lighter fraction and a heavier fraction. A demethanization feed stream is formed by combining at least a portion of the lighter fraction and at least a portion of the second product stream and is subjected at least in part to demethanization. Partial oxygen removal is carried out during the formation of the demethanization feed stream. The oxygen removal is carried out downstream of the combining step.

The invention belongs to the technical field of solid waste utilization, and particularly relates to a modified ZSM-5 molecular sieve catalyst and a preparation method and application thereof. The catalyst comprises a ZSM-5 molecular sieve and an active component, wherein the active component is loaded on the internal pore channel and the surface of the ZSM-5 molecular sieve; the active component comprises one or more of Zn, Fe, Ni, Co, Mo and Zr. By adjusting the loading capacity of the active components and the acidity of the catalyst and adjusting the interaction among the components of the catalyst, the high-density polyethylene plastic is used as a raw material, and the catalyst is simple in structure, single in element, free of oxygen element and low in by-product content; the modified ZSM-5 molecular sieve catalyst is simple in preparation process and low in production cost, and the catalyst takes high-density polyethylene plastic as a raw material, so that the yield of MAHs prepared by directional pyrolysis of the high-density polyethylene plastic as the raw material and the stability of the catalyst are effectively improved.

The invention discloses a supported platinum-nickel alloy catalyst and a preparation method and application thereof, and belongs to the technical field of catalysis. The preparation method of the supported platinum-nickel alloy catalyst comprises the following steps: mixing a platinum source, a nickel source and an organic ligand in an organic solvent, stirring, filtering, washing and drying to obtain a platinum-nickel complex; dispersing the platinum-nickel complex and the nitrogen-doped porous carbon in an organic solvent, and performing ultrasonic treatment, centrifugation and drying to obtain a supported platinum-nickel catalyst precursor; and carrying out reduction annealing treatment on the supported platinum-nickel catalyst precursor in an argon atmosphere, and cooling to obtain the platinum-nickel alloy catalyst. The supported platinum-nickel alloy catalyst provided by the invention can be applied to deuteration reaction of polycyclic aromatic hydrocarbon compounds, is high in catalytic activity and few in side reaction, and has a good industrial application prospect.

The invention belongs to the technical field of alkane processing, and particularly relates to a process for preparing isopentene by dehydrogenation of isopentane, a catalyst and a tert-amyl alcohol preparation process. The process for preparing isopentene by dehydrogenation of isopentane comprises an isopentane dehydrogenation device and an isopentene separation device, in the isopentane dehydrogenation device, a dehydrogenation reactor is a fixed bed adiabatic reactor and is filled with a Pt-Sn-K / alumina type alkane dehydrogenation catalyst, the catalyst has hydromethanation performance under the CO2-containing dehydrogenation reaction condition, and the arrangement and operation of a dehydrogenation reactor group comprise a mode A, a mode B or a mode C; the isopentene separation device comprises a cooling separation system, a pressure swing adsorption separation system and an optional rectification system. The tert-amyl alcohol is further prepared from isoamylene under the conditions of a fixed bed hydration reactor, ethylene glycol monobutyl ether and other solvents, and the tert-amyl alcohol product is obtained through separation. The process is superior to the prior art on the whole, and has certain application prospects.

The invention discloses a continuous method for preparing 4-methyl-1-pentene through propylene dimerization and the obtained 4-methyl-1-pentene. The continuous method for preparing the 4-methyl-1-pentene through propylene dimerization comprises the steps that components containing propylene and a catalyst react in a reactor in the presence of a solvent, the product obtained after the reaction is separated, and then the 4-methyl-1-pentene is obtained, and the reactor comprises a first solid-liquid reaction kettle and a second solid-liquid reaction kettle. According to the invention, the continuous propylene dimerization reaction is realized, the blank of the domestic production technology for preparing 4-methyl-1-pentene by propylene dimerization is hopefully filled, sufficient raw materials are provided for the production of PMP, the current situation that the PMP completely depends on import in China is broken through, and the method has great significance.

The invention provides an all-silicon molecular sieve confined Pt-based bimetallic catalyst and application thereof in preparation of propylene through propane dehydrogenation. The preparation method comprises the following steps: mixing a silicon source, a template agent, a Pt precursor, an auxiliary element Cu precursor and the like by adopting an in-situ synthesis method, synthesizing under a hydrothermal condition, washing, drying, roasting and reducing to obtain the Pt-based bimetallic molecular sieve catalyst. According to the present invention, the pure silicon molecular sieve Silicalite-1 (S-1) is adopted as the carrier, such that the good carrier characteristics of high thermal stability, low acidity, rich pore structure and the like are provided, and the silicon hydroxyl group (Si-OH) in the S-1 pore channel can further provide the metal species anchoring effect so as to easily disperse and limit the active site; and the Cu auxiliary agent improves the metallicity of Pt. The synergy of the two significantly improves the performance of propylene preparation by direct dehydrogenation of propane. The synthesized PtCu-coated S-1 catalyst is low in Pt loading capacity, Pt and Cu are highly dispersed, side reactions such as deep dehydrogenation of propylene can be inhibited, and good stability is achieved.

The present invention relates to bio-based bisphenol monomer of formula I and process of preparation thereof. Specifically, the present invention relates to bio-based bisphenol monomers of formula I containing multiple alkoxyl groups, and polyphenols. The bisphenol monomers of formula I contain built-in methoxyl groups, which represent latent phenolic hydroxyl groups and could conveniently be de-blocked to phenolic hydroxyl groups leading to formation of polyphenols containing catechol / phloroglucinol units with anti-oxidant properties and are potentially useful in various applications like cosmetics, polymer additives and so on. Further, the present invention relates to process of preparation of polymers using bisphenol monomer of formula I as valuable building blocks wherein the high performance thermoplastics are poly(ether sulfone)s, poly(ether ether ketone)s, polyesters, polycarbonates, polyphosphonates, etc. and thermosetting resins are epoxies, cyanate esters, phthalonitriles, propargyl ethers, etc.

The invention discloses a nickel-based catalyst as well as a preparation method and application thereof, and belongs to the technical field of catalyst synthesis. The nickel-based catalyst is prepared by an equivalent-volume impregnation method, a mechanochemical method and a deposition-precipitation method, the operation is simple, the cost is low, and the used raw materials are few; the method for regulating and controlling the selectivity of the prepared nickel-based catalyst to C4 olefin is simple and easy to implement, and the waterproof performance is good. According to the nickel-based catalyst, niobium oxide is used as a carrier, nickel is loaded on the niobium oxide carrier to catalyze heterogeneous ethylene oligomerization reaction, no co-catalyst is needed, the dispersity of loaded metal is effectively increased, carbon deposition and blockage are not prone to occurring in the reaction process, and the catalytic stability of the nickel-based catalyst for catalyzing the ethylene oligomerization reaction is improved.

To provide a manufacturing method that enables efficient production of metal carbide by allowing the reaction to proceed quickly at relatively low temperatures without requiring the use of combustible raw materials, a method for producing carbohydrates from the obtained metal carbide, and a metal inclusion component supported by the metal carbide.SOLUTION: A manufacturing method for a metal carbide, comprises preparing a molten salt containing a carbonate ion, preparing an electrode containing a first metal, and applying a voltage to the molten salt using the electrode to obtain a metal carbide composition containing a carbide of the first metal.SELECTED DRAWING: Figure 1

The utility model discloses a heat energy utilization system of a C3 and C4 mixed dehydrogenation device, and relates to the technical field of heat energy utilization. According to the utility model, heat generated by a heat pump compressor is respectively used as a heat source of materials extracted from the side lines of a propane tower reboiler and a C3 and C4 separation tower A, heat of an aromatic solvent pipe system is used as a heat source of the reboiler of the C3 and C4 separation tower A, and heat of materials at the bottom of a C3 and C4 separation tower B is used as a heat source to exchange heat with materials at the inlet of the C3 and C4 separation tower A; surplus heat of the dehydrogenation device is fully utilized, steam consumption is reduced, and the purpose of saving energy is achieved.

The present invention relates to the technical field of ethylene oligomerization catalysts, and discloses a ligand compound, a selective ethylene oligomerization catalytic composition and application thereof, and a selective ethylene oligomerization reaction method, the ligand compound has a structure represented by a formula (1) # imgabs0 #, Ar and Ar'are independently selected from substituted or unsubstituted aryl or heteroaryl; 1, 2-positions are substituted or unsubstituted cyclic substituents. The ligand compound is applied to a selective ethylene oligomerization catalytic composition, high ethylene trimerization and tetramerization catalytic activity can be obtained, hexene-1 and octylene-1 selectivity is high, the high-molecular polymer content is low, the risk of scaling and blocking of a reaction pipeline in a continuous reaction can be greatly reduced, and the selectivity of ethylene oligomerization is high. Good industrial application prospects and economic values are realized.

The invention discloses a renewable alkane dehydrogenation catalyst as well as a preparation method and application thereof. The preparation method of the catalyst comprises the following steps: activating the molecular sieve carrier by adopting high-temperature heat treatment, mechanically and uniformly mixing the activated carrier with the active metal salt, the auxiliary metal salt and the alkali metal salt, and finally carrying out high-temperature oxidation treatment. And through high-temperature activation heat treatment, the pore structure of the molecular sieve is reconstructed, oxygen vacancies are introduced, rich defect sites are formed, then active metal is effectively anchored, and the metal-carrier interaction is optimized. Meanwhile, auxiliary metal and alkali metal are added to achieve a synergistic effect, sintering agglomeration of active metal is further inhibited, and the high-temperature stability and the recyclability of the catalyst are remarkably improved. The method is simple in process route, less in wastewater discharge and low in investment cost, the obtained catalyst is not inactivated after 50 times of circulation in propane dehydrogenation high-temperature reaction-regeneration, long-time sustainable use and recycling can be realized, and a new technical reference is provided for synthesis of novel industrial catalysts.

The invention relates to a heterogeneous catalysis technology, and aims to provide a method for improving the yield of components of aviation kerosene prepared by ethylene oligomerization through combination of a fixed bed and a slurry bed. Comprising a fixed bed reactor and a slurry bed reactor which are sequentially connected in series, the fixed bed reactor is filled with a metal modified mesoporous zeolite molecular sieve catalyst, and the slurry bed reactor is filled with a mesoporous zeolite molecular sieve catalyst. The method comprises the following steps: firstly, carrying out ethylene oligomerization reaction in a fixed bed reactor to generate a product containing C4-C8 olefin; the reaction product is directly introduced into the fixed bed reactors connected in series for secondary reaction, and the final product comprises C5-C16 + liquid phase olefin as an aviation fuel component. By adopting a fixed bed-slurry bed reactor combined method, the ethylene conversion rate can be greatly improved; secondary oligomerization is carried out by using an acidic mesoporous zeolite molecular sieve catalyst, so that the selectivity of aviation kerosene components is improved; the mesoporous catalyst prepared by an alkali treatment method has a good diffusion effect and keeps high activity for a long time.

A method may include operating a dehydrogenation process whereby a hydrocarbon-containing feed is converted to light olefins, wherein the dehydrogenation process utilizes a fluidized process catalyst that circulates between a reactor and a combustor. The method may comprise withdrawing the process catalyst from the dehydrogenation process, modifying the process catalyst to form a modified catalyst, and adding the modified catalyst back to the dehydrogenation process. The process catalyst may include from 0.1 wt. % to 10 wt. % of one or more metals chosen from gallium, indium, thallium, or combinations thereof, from 1 ppmw to 1000 ppmw of one or more metals chosen from platinum, palladium, rhodium, iridium, ruthenium, osmium, or combinations thereof, and at least 85 wt. % support. Modifying the process catalyst may include adding one or more of manganese, iron, chromium, or vanadium.

A machine learning model predicts a K value for a new iron ethylene oligomerization catalyst structure, where the K value has not yet been experimentally determined. The system utilizes a device comprising memory coupled to at least one processor, the memory having instructions that cause the at least one processor to: input a set of reaction conditions and a new iron ethylene oligomerization catalyst structure comprising a ligand to a random forest machine learning regressor model, wherein the random forest machine learning regressor model is trained on a data set comprising multi-dimensional features for tested iron ethylene oligomerization catalyst structures, wherein the multi-dimensional features comprise experimental K values, physical features, molecular features, and connective steric factors for each of the tested iron ethylene oligomerization catalyst structures

The invention discloses an ethylene dimerization catalyst composition and application thereof, the catalyst composition mainly comprises a cocatalyst and a main catalyst, the cocatalyst comprises the following raw materials by mole: 41%-90% of an aluminum-based compound, 9%-41% of a polymerization inhibitor A1, and 0.9%-16% of a dispersant B1; the main catalyst comprises the following raw materials: 13%-50% of a titanium-based compound, 50%-78% of a polymerization inhibitor A2 and 0%-7.9% of a dispersing agent B2, and the ethylene dimerization catalyst composition comprises a co-catalyst mainly composed of an aluminum-based compound, a polymerization inhibitor A1 and a dispersing agent B1 and a main catalyst mainly composed of the titanium-based compound, the polymerization inhibitor A2 and the dispersing agent B2. The polymerization inhibitor A1, the polymerization inhibitor A2, the dispersing agent B1 and the dispersing agent B2 are introduced, so that the catalyst has higher catalyst activity, generation of scaling polymers is effectively reduced, the catalyst can be used for producing 1-butene through ethylene dimerization, and the problem that a large number of polymers are produced as by-products in current industrial production can be effectively solved.