Perimidine derivative and application thereof
A technology of metadiazepines and derivatives, which is applied in the field of new organic compounds, can solve the problems of low current density and current efficiency, and achieve the effects of good conjugation, high electron affinity and excellent carrier transport.
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[0052] Hereinafter, the organic electroluminescent compound of the present invention, its preparation method, and the preparation method and light-emitting properties of a light-emitting device comprising the compound are described in detail with reference to the following examples.
[0053] Various chemicals used in the present invention such as petroleum ether, ethyl acetate, tetrahydrofuran, n-hexane, toluene, acetic acid, methylene chloride, DMF, 1,8-dinaphthylamine, N,N'-carbonyldiimidazole, 4 -Bromo-2-iodonitrobenzene, sodium tert-butoxide, tris(dibenzylideneacetone) dipalladium, tetrakistriphenylphosphine palladium, tri-tert-butylphosphine toluene solution, palladium acetate, isoamyl nitrite, Zinc powder, sodium sulfate, etc. can be bought in the domestic chemical product market.
[0054] Synthesis of main intermediates
[0055] Synthesis Example 1. Synthesis of Intermediate M1:
[0056]
[0057] Add 1,8-dinaphthylamine (50 g, 0.316 mol) and 500 ml of dichlorometha...
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