This invention discloses a blue thermally activated delayed
fluorescence (TADF) material, its preparation method, and its applications, belonging to the field of luminescent materials technology. Using a
triazine unit as an
electron acceptor and an organophosphorus-modified diphenyl
acridine as an
electron donor, a blue TADF
luminescent material, TRz-POAc, was synthesized. Organophosphorus modification can effectively regulate the molecular twist angle, intermolecular interactions, and photophysical properties. The prepared TRz-POAc exhibits a molecular twist angle of 83.7°, with no significant π-π stacking between molecules, and a singlet-triplet bandgap (ΔEST) as low as 0.02 eV, enabling efficient reverse
system crossing (RISC) processes. In doped devices, the maximum EQE reaches 22.26% with 20 wt%
doping; in undoped devices, the maximum EQE is still as high as 21.00%, demonstrating excellent
deep blue light emission performance and its application potential in undoped devices.