The invention discloses a thermally activated delayed fluorescent material, a preparation method thereof and a luminescent device, and relates to the technical field of organic luminescent materials. The
structural formula of the thermal activation delayed
fluorescence material is shown in the specification, wherein R1 is H, tert-butyl or methyl, and R1 is located at any connectable position on a
benzene ring; r < 2 >, R < 3 >, R < 4 > and R < 5 > are each independently H, tert-butyl or phenyl; a is an m-cyanophenyl group, a p-cyanophenyl group, a cyano group, or; representing a connection site; r6 is H or
alkyl, R6 is located at any connectable position on a
benzene ring, and M is O or N. The thermally activated delayed
fluorescence material provided by the invention has relatively high
fluorescence quantum yield and rapid reverse
intersystem crossing rate, emits dark
blue light, has the emission
wavelength of 444-457 nm, is matched with a dark
blue light MR material with a narrow-band emission characteristic, and has a wide application prospect. Therefore, the thermal activation delayed fluorescence material provided by the invention can be used as a sensitizer to realize preparation of a
deep blue light super-fluorescence device.