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235 results about "Deep blue" patented technology

Preparation method of bismuth vanadate visible light photocatalysis material

The invention discloses a method for synthesizing a Eu<3+>-doped BiVO4 visible light photocatalysis material by using a citric acid complexed sol-gel method. The preparation method is simple, and the visible light activity of the obtained photocatalyst is high. According to the invention, Bi(NO3)3.5H2O (97%) and NH4VO3 (98.5%) are adopted as source materials; citric acid (99.5%) is adopted as a chelating agent; Eu(NO3)3 is adopted as a doping source material; the pH value is regulated by using ammonia water, and a deep blue sol is prepared; the sol is dried by baking, and is calcined for 5h under the temperature of 500 DEG C, such that the Eu<3+>-doped bismuth vanadate photocatalysis material is obtained. Compared with non-doped bismuth vanadate, oxygen vacancies and V<4+> with catalytic activities in the Eu<3+>-doped bismuth vanadate crystals are increased. After doping, red shift occurs in the light absorption performance of the sample, the band gap can be narrowed, such that the visible light photocatalytic activity is substantially improved. The method provided by the invention is advantaged in simple process, mild condition, and good repeatability. The method can be widely applied in photocatalytic degradation of organic pollutants, and has a good application prospect in environment treatment.
Owner:SHENYANG LIGONG UNIV

Preparation method of montmorillonite-modified crosslinked acrylate-hybridized core-shell emulsion

InactiveCN102702419AAvoid the organic processGood dispersionCoatingsBuffering agentChemistry
The invention discloses a preparation method of a montmorillonite-modified crosslinked acrylate-hybridized core-shell emulsion. The preparation method of the montmorillonite-modified crosslinked acrylate-hybridized core-shell emulsion comprises the following steps: dispersing sodium-based montmorillonite, an emulsifying agent and a buffering agent into water; stirring to obtain a sodium-based montmorillonite suspension; adding a core monomer mixture and an initiating agent solution into the sodium-based montmorillonite suspension, and preserving heat for 0.5 hours to obtain a seed emulsion; dripping the remaining core monomer mixture into the seed emulsion, and preserving heat for 1 hour to obtain a deep blue core emulsion; and adding the initiating agent solution and a shell monomer mixture into core emulsion, preserving heat for 2 hours and regulating pH value to obtain the opalescent bluish montmorillonite-modified crosslinked acrylate-hybridized core-shell emulsion. The prepared montmorillonite-modified crosslinked acrylate-hybridized core-shell emulsion is good in water resistance and heat resistance of a coating, adjustable in gloss of a latex film, free of organic solvent, environment-friendly, relatively high in solid content (32 to 45%), relatively small in particle size, bluish, high in stability (storage stability is more than six months) and good in a film-forming property at room temperature.
Owner:GUANGZHOU CHEM CO LTD CHINESE ACADEMY OF SCI

PEDOT (poly(3,4-ethylenedioxythiophene)):PSS (poly(sodium-p-styrenesulfonate)) water dispersion and preparation method thereof

The invention relates to the technical field of organic semiconductors and in particular relates to a PEDOT (poly(3,4-ethylenedioxythiophene)):PSS (poly(sodium-p-styrenesulfonate)) water dispersion prepared by using sulfonic acid type conjugated polyelectrolyte as the template and a preparation method thereof. The preparation method comprises the following steps: adding a sulfonic acid type anionic conjugated polymer, EDOT, PSS and deionized water to a reaction flask under the condition of room temperature and dissolving the materials by stirring the materials; then adding isopropanol, an initiator, a ferric iron catalyst and deionized water to react for 12-24 hours under the conditions of heating at 30-45 DEG C and stirring, thus obtaining a water dispersion; removing the supernatant after centrifuging the water dispersion, after repeating the operations three times, diluting the deionized water for precipitation and then carrying out ultrasonic dispersion for one hour, thus obtaining the PEDOT:PSS deep blue water dispersion with PFSO3H as the template. The PEDOT:PSS water dispersion prepared by the preparation method is simple and reliable in preparation method and has good repeatability. Films of the water dispersion have better transparency and higher electrical conductivity.
Owner:CHANGZHOU XIAOGUO INFORMATION SERVICES

*derivatives, materials containing the same and organic electroluminescent devices

The invention discloses a type of (the formula is shown in the formula) derivative, material comprising this (the formula is shown in the formula) derivative and organic electroluminescent device. The(the formula is shown in the formula) structural formula of the derivative is shown in the following formula I: (the formula is shown in the formula) The derivative (the formula is shown in the formula) provided by the derivatives, materials containing the same and organic electroluminescent devices as shown by the formula I, has the deep blue fluorescent property, which overcomes the fluorescentaggregation quenching effect of the fluorescent material, and has higher glass transition temperature, high thermal stability and excellent luminescence performance. The properties such as simple synthesis process, simple purification method suitable for large-scale production, and the properties such as product luminescence performance and thermal stability adjustable by connecting different groups, make the derivative an ideal choice for the organic light-emitting layer material of the organic electroluminescent device. The light-emitting layer of the OLED device using the fluorescent material has high fluorescence efficiency and good stability, so that the light-emitting efficiency and the service life of the device can reach the practical requirements.
Owner:SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIALS CO LTD
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