The invention discloses a series organic electrophosphorescent material. A structural general formula of the electrophosphorescent material is shown as a formula I. The complex electrophosphorescent luminescent material takes 4,5-disubstituted phenanthrene and 4,5-disubstituted 9, 10-dihydrophenanthrene as a main body. Due to influence of electron donating group with 4,5-two large steric hindrance, fixing effect of phenanthrene and 9,10- dihydrophenanthrene hydrocarbon chain, the capture capability to exciton is greatly increased, phosphorescence life can be effectively shortened, the luminescence efficiency is increased, and the luminescent device performance is increased. The compound has excellent film forming ability and high luminescence efficiency.