The polycomponent lead-free piezoelectric ceramic composition with excellent performance is one perovskite type environment consistency piezoelectric ceramic composition. The composition has the general expression of (1-e-f-g)(Bi1-uLu)1-w(Na1-x-yKxLiy)wTiO3+eBaTiO3+fSrTiO3+gCaTiO3+aMalphaObeta, where x is 0-1, y 0-0.5, u 0-0.12, (x+y) 0-1, e 0-1, f 0-1, g 0-1, (e+f+g) 0-1, w 0.3-0.7, L is RE elements La, Ce, Pr, Nd, Sm, etc.; MalphaObeta is doping oxide(s) in the content an of 0-10 %; M is +1~+6 valent element capable of forming solid oxide, such as Na, K, Li, Zn, Cr, etc. with alpha and beta being atom number. The piezoelectric ceramic composition has d33 up to 200 pC/N, kp up to 36.0 % and stable technological process, may be produced via traditional piezoelectric ceramic preparation process and industrial material, and is practical.