The invention discloses a
solid optical material and a preparation method and application thereof, the
solid optical material comprises a
salicylaldehyde derivative, a high-molecular
polymer and a curing agent, the catalyst is selected from at least one of 2, 5-di-tert-butyl
salicylaldehyde aniline, 3-
trifluoromethyl salicylaldehyde aniline, 3-
trifluoromethyl salicylaldehyde triphenylmethylamine, 3-
trifluoromethyl salicylaldehyde triphenylmethylamine, 3-trifluoromethyl salicylaldehyde 2-amino-3-methylpyridine, 3-trifluoromethyl salicylaldehyde 2-amino-5-methylthiazole and 3-trifluoromethyl salicylaldehyde alpha-methylbenzylamine. The catalyst is prepared from at least one of 2, 5-di-tert-butyl salicylaldehyde
aniline, 3-trifluoromethyl salicylaldehyde aniline, 3-trifluoromethyl salicylaldehyde triphenylmethylamine, 3-trifluoromethyl salicylaldehyde triphenylmethylamine, 3-trifluoromethyl salicylaldehyde 2-amino-3-methylpyridine, 3-trifluoromethyl salicylaldehyde The
solid optical material has a photochromic property, is high in transparency, is relatively weak in
fluorescence emission under the excitation of visible light, and can be subjected to a
proton transfer process after being irradiated by
ultraviolet light to generate
photochromism; visible light with specific
wavelength is used for irradiating a sample, and
photoluminescence emission can be generated at the overlapping position of the visible light and a color changing area of the sample; therefore, a stable space in-vivo three-dimensional image is formed in the material, and the image is clear and does not diffuse.