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165results about How to "Reduce the lighting voltage" patented technology

Organic compound and electroluminescent material and applications thereof

The invention provides an organic compound and an electroluminescent material and applications thereof; the organic compound has a structure represented by a formula I, by designing a spiro parent nucleus structure and introducing a specific substituent, material stacking can be prevented, and the crystallinity of molecules can be reduced; due to the design of the spiro structure and a substituentgroup, the organic compound has a high triplet state energy level T1, and due to a nitrogen heterocyclic ring and a connecting group thereof, the organic compound has relatively good electron transport and hole transport characteristics; HOMO and LUMO energy levels are appropriate, so that energy level matching with adjacent layers is facilitated; the glass transition temperature is high, and themolecular thermal stability is good; the light-emitting efficiency and the service life of the device can be effectively improved. The organic compound can be used as an electroluminescent material for a light-emitting layer, a hole blocking layer or an electron blocking layer of an OLED device, is especially suitable for being used as a phosphorescent host material to be applied in the light-emitting layer, and can significantly improve the light-emitting performance of the device and prolong the service life of the device.
Owner:WUHAN TIANMA MICRO ELECTRONICS CO LTD

Organic electroluminescent material and preparation method thereof and organic electroluminescent device

The invention relates to an organic electroluminescent material and a preparation method thereof and an organic electroluminescent device. According to the organic electroluminescent material, a benzo[g] bending structure is adopted as the center, a first benzene ring is introduced into the site g of the benzo[g] bending structure, then a second benzene ring is used for replacing hydrogen groups on the first benzene ring, a nitrogen heterocyclic ring is used for replacing hydrogen groups on the second benzene ring, and the following structure shown in the description is achieved, wherein Ar is a nitrogen heterocyclic ring with the electron transport function. Compared with the prior art, the organic electroluminescent material has a very proper triplet state energy level, high glass-transition temperature, good heat stability and high carrier transport capacity, the preparation method is simple, operation is easy, the yield is high, and cost is low; the organic electroluminescent material serves as a main material to replace CBP to manufacture the organic electroluminescent device, lower turn-on voltage and higher maximum current efficiency are achieved, the turn-on voltage can be reduced by 0.5-1.1 V, and the maximum current efficiency can be improved by 18% to 24%.
Owner:VALIANT CO LTD

Multi-functional modified phenyl ether single phosphine oxide main material, synthetic method and application thereof

The invention discloses a multi-functional modified phenyl ether single phosphine oxide main material, a synthetic method and an application thereof, relates to an organic electroluminescence material, preparation and application thereof and solves the problems of low luminous efficiency and brightness of existing organic electroluminescence materials and contradiction between high triplet state excited state energy level and good carrier injection/transmitting capacity. The preparing method of parent structure of the multi-functional modified phenyl ether single phosphine oxide main material includes adding N-bromo-succinimide in 2-diphenyl phosphine oxide phenylate to perform bromination reaction; and introducing a functional group with a carrier transmission characteristic to perform a substitution reaction, and extraction, drying and column chromatography are performed to obtain the multi-functional modified phenyl ether single phosphine oxide main material. The multi-functional modified phenyl ether single phosphine oxide main material has the advantages that the voltage of lightening an electrophosphorescent device is reduced, the luminous efficiency and brightness of the organic electroluminescence material are improved, and the material is mainly used for an organic electrophosphorescent diode device.
Owner:HEILONGJIANG UNIV

Preparation method for chalcogenide semiconductor/carboxylation PPV (polyphenylene vinylene) electroluminescence composite material

The invention discloses a preparation method for a chalcogenide semiconductor/carboxylation PPV (polyphenylene vinylene) electroluminescence composite material. The electroluminescence composite material is prepared by means of complexation between semiconductor metal salt and carboxylation PPV firstly and then by means of hydrothermal reaction, the semiconductor metal salt is selected from soluble nitrate or halide of Zn, Cd, Pb or Bi, and the carboxylation PPV refers to poly[2-methoxy-5-(5'-carboxypentyloxy) p-phenyl acetylene]. The carboxylation PPV serving as an organic phase to be doped and composited with an inorganic semiconductor, and the carboxylation PPV is connected with the inorganic semiconductor by means of coordination bonds, so that inorganic particles are uniformly dispersed, the two phases form a uniform system, energy and charge transfer on the two phase interfaces is improved, the composite material has processibility of polymer and photoelectric property of semiconductor materials, and the novel electroluminescence material high in stability and luminous efficiency is provided for the fields such as large-area flexible display and solid-state luminescence and the like.
Owner:HEFEI UNIV OF TECH

Dibenzofuranyl aromatic phosporic-oxygenic compound and preparation method and application thereof

The invention discloses a dibenzofuranyl aromatic phosporic-oxygenic compound and a preparation method and application thereof, relating to the dibenzofuranyl aromatic phosporic-oxygenic compound and the preparation method and the application thereof. The problems of low luminous efficiency and brightness and poor stability of an electrophosphorescent device, caused by serious concentration quenching and a triplet annihilation effect existing in the traditional electrophosphorescent material, are solved. In a general structural formula of the compound, X represents H or diphenyl phosporic-oxygenic group. The preparation method comprises the following steps of: preparing a derivative by using dibenzofuran, butyl lithium, tetramethylethylenediamine and diphenylphosphine chloride; dissolving the derivative in CH2CI2; adding H2O2; reacting; and thus obtaining the compound. In the application of an organic electrophosphorescent device, the compound is used as a main material of a luminescent layer. The diphenyl phosporic-oxygenic group is modified on a chromophore patent body through a C-P saturated bond to prepare electro blue/electro white/electro green main materials which are high in triplet excited state energy level and have good carrier injection and transmission capacity, and the prepared device has extremely low driving voltage, excellent brightness and stable efficiency.
Owner:HEILONGJIANG UNIV

Organic electroluminescence device and preparing method thereof

The invention discloses an organic electroluminescence device. The organic electroluminescence device comprises a substrate, a first electrode, a hole injection layer, a hole transmission layer, an organic light emitting layer, an electron transmission layer, an electron injection layer and a second electrode, wherein the substrate, the first electrode, the hole injection layer, the hole transmission layer, the organic light emitting layer, the electron transmission layer, the electron injection layer and the second electrode are sequentially stacked. The hole injection layer comprises two thin inorganic nano-rod films which are vertically stacked. The inclination angles of inorganic nano-rods of the thin inorganic nano-rod film at the side close to the substrate are smaller than the inclination angles of inorganic nano-rods of the thin inorganic nano-rod film at the side far away from the substrate. The thin inorganic nano-rod film with the smaller inclination angles is beneficial to the increase of the effective contact area between the hole injection layer and an adjacent electrode layer, the barrier height, from an anode to the hole injection layer, of a hole is effectively reduced, and the starting voltage and the working voltage are reduced. The thin inorganic nano-rod film with the larger inclination angles can effectively adjust the balance of electrons and the hole, the gap scattering property of the inclined nano-rods is used, so that on the premise that power efficiency is not sacrificed, the luminous efficiency is improved. The invention further discloses a preparing method of the organic electroluminescence device.
Owner:SICHUAN CCO DISPLAY TECH

Naphtho-five-membered ring-benzofused heterocyclic organic compounds and application thereof

The invention belongs to the technical field of organic photoelectric materials, and particularly relates to naphtha-five-membered ring-benzofused heterocycle organic compounds and application thereof. The organic compounds disclosed by the invention have a parent structure of naphtho-five-membered ring-benzofused heterocycle, are high in interatomic bond energy, present good thermal stability, are beneficial for intermolecular solid accumulation, and can be used as luminescent layer materials to effectively prolong the service life of materials. The compounds provided by the invention are derivatives of large conjugated fused heterocycles, are applied to light emitting layers, have proper energy levels matched with adjacent layers, facilitate injection of holes and electrons, can effectively reduce turn-on voltage, and can realize good light emitting efficiency in a device due to a relatively high exciton migration rate. The compounds disclosed by the invention have relatively large conjugate planes, are beneficial for molecular accumulation, show good thermodynamic stability and present long service life in devices. A preparation process of the derivatives is simple and feasible,raw materials are easy to obtain, and the derivatives are suitable for large-scale production.
Owner:YANTAI XIANHUA CHEM TECH CO LTD

Multifunctional modified tert-butyl carbazole phosphine oxide main material and synthesis method and application thereof

The invention discloses a multifunctional modified tert-butyl carbazole phosphine oxide main material and a synthesis method and an application thereof, and relates to an organic electroluminescent material and a synthesis method and an application thereof, which are used for solving the problem that the turn-on voltage of an electroluminescent device applied to an organic electroluminescent main material is on the high side. Six kinds of main materials are available; in 2 kinds of main materials, one or two phosphine oxide functional groups with carrier transmission characteristic are introduced to a tert-butyl carbazole parent respectively; and in the other 4 kinds of main materials, one, two or three phosphine oxide functional groups with carrier transmission characteristic are introduced to a 9-phenyl tert-butyl carbazole parent respectively. The tert-butyl carbazole is used as the parent of the main material; since the diphenylphosphine oxide matrix structure has the conjugation breaking effect of the P=O group, the parent has relatively high triple-stage energy level, as well as certain electron injection and transmission capacity, and the luminous efficiency and brightness of a luminous device are improved after the parent is applied to the luminous device; and meanwhile, the turn-on voltage can be reduced to 2.4V.
Owner:HEILONGJIANG UNIV

Fluorinated triphenylamine electro-material and application thereof

InactiveCN102875390AImprove thermal stabilityThe glass transition temperature range varies widelyAmino preparation from aminesSolid-state devicesFull width at half maximumAniline
The invention discloses a fluorinated triphenylamine electro-material and an application thereof; according to the material, through the change of the positions and the numbers of hole transporting moieties of strong electron-withdrawing groups of fluorine or trifluoromethyl at periphery of triphenylamine, the energy of the highest occupied molecular orbital, the energy of the lowest unoccupied molecular orbital, the charge transport capacity, photophysical properties and thermal properties of the material are adjusted; thus balance between the injection and transport of holes and electrons is reached; most holes and electrons of the injected device are combined in a luminescent layer; therefore, the device structure is greatly simplified, and the device performance is improved. Meanwhile, through the modification of fluorine or trifluoromethyl, the luminescence property for blue and violet light of the material quite approaches the blue light chromaticity coordinate (CIE=(0.14, 0.08)) of the International Commission of Illumination (NTSC) the material also has a narrow spectrum full width at half maximum (FWHM); devices prepared by the material can not only effectively reduce device energy consumption, but also adjust the illuminant color of the device through radiation or energy transfer between a subject and an object.
Owner:XI AN JIAOTONG UNIV

Fluorine-substituted 9,9'-dianthracene blue light emitting host material and its application

The invention discloses a fluorine-substituted 9,9'-dianthracene blue light emitting host material and its application. The position and the number of a peripheral strong electrophilic group fluoro or trifluoromethyl are changed to realize a high fluorescence quantum efficiency and a good luminescence peak blue shift, and realize dark blue light emission by cooperating with an appropriate host (CBP); and the position and the number of the peripheral strong electrophilic group fluoro or trifluoromethyl are changed to make the material have an appropriate highest occupied molecular orbital and a lowest unoccupied orbital energy and realize good overlapping of the emission spectrum and the absorption spectrum of an object DPAVBi, so energy can be effectively absorbed and transferred to the object, thereby the luminescence of the object is caused, and the performances of a device are improved. The material has the advantages of good heat stability, good luminescence performance, easy synthesis and convenient purification, and can be widely used in the fields of organic field effect transistors, organic electroluminescent devices, the organic lasers and organic photovoltaic solar batteries.
Owner:西安极光新材料科技有限公司

Green light diode with interpenetration interaction structure and method of manufacturing the same

This invention is related to a green light diode with interpenetrating alternate structure and manufacturing method. The diode adopts the design of interpenetrating alternate structure. A conductive glass anode layer is a dual-plane layer. A cavity transmission layer is a single plane+ a convex groove layer. A luminous layer is a recess+ a convex groove layer. A cathode is a single plane+ a convex groove layer. Each convex groove is correspondingly matched with the recess and interpenetrated and alternated so that a structure of plane+ convex layer+ plane layer is formed. The interpenetrating alternate structure is capable of extending a current carrier complex interface and a contact interface of metal cathode layer, improving the electronic injection, reducing the generation of positive ion and increasing the complex ratio of the current carrier. A convex-concave film is film-formed by mutually displacing main and secondary mask plates. An evaporation material is converted into a film layer from a solidity-gaseity-solidity in a vacuum evaporation furnace under the condition that the vacuum degree is not greater than 0.002 Pa and the temperature is 50 degrees Celsius. This method has short technical process, and the luminous efficiency of the component can be improved about 70%; the low voltage for lightening is 2.7V; the good color purity of green light is 0.4829; the color coordinate is that X is 0.2707 and Y is 0.5267. This invention supplies a gap of scientific research of this structure, such as the light emitting diode.
Owner:TAIYUAN UNIV OF TECH
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