695results about How to "High thermodynamic stability" patented technology

A method of producing a material capable of electrochemically storing and releasing a large amount of lithium ions is provided. The material is used as an electrode material for a negative electrode, and includes silicon or tin primary particles composed of crystal particles each having a specific diameter and an amorphous surface layer formed of at least a metal oxide, having a specific thickness. Gibbs free energy when the metal oxide is produced by oxidation of a metal is smaller than Gibbs free energy when silicon or tin is oxidized, and the metal oxide has higher thermodynamic stability than silicon oxide or tin oxide. The method of producing the electrode material includes reacting silicon or tin with a metal oxide, reacting a silicon oxide or a tin oxide with a metal, or reacting a silicon compound or a tin compound with a metal compound to react with each other.

The invention provides a metal organic framework/carbon nanofiber composite membrane material and a preparation method thereof. The metal organic framework/carbon nanofiber composite membrane material is characterized by comprising a carbon nanofiber membrane, wherein a metal organic framework layer is grown on the nanofiber surface of the carbon nanofiber membrane. The preparation method comprises the following steps: first preparing a flexible carbon nanofiber membrane, oxidizing the flexible carbon nanofiber membrane by using nitric acid to form a carboxyl group-containing flexible carbon nanofiber membrane, putting the carboxyl group-containing flexible carbon nanofiber membrane into a precursor solution of a metal organic framework to grow the metal organic framework to obtain the metal organic framework/carbon nanofiber composite membrane material. The metal organic framework/carbon nanofiber composite membrane material prepared according to the preparation method provided by the invention has a great application potential in the fields of gas adsorption and separation, catalysts, sensors, electrode materials and the like.

The invention relates to a lithium ion solid electrolyte and a preparation method application thereof, and belongs to the technical field of a lithium ion battery. The lithium ion solid electrolyte has the chemical formula shown as follows: Li<3+a>M

A<m>B<n>Y<1-b>, wherein a is more than or equal to -0.25 but less than or equal to 0.25, b is more than or equal to 0 but less than or equal to 0.5, m is more than or equal to 0 but less than or equal to 1.25, n is more than or equal to 0 but less than or equal to 1.25, M is one of Ca, Ba, Mg, Al and Ti, A and B are separately selected from one of O, S, Se, Te, N, P, Si, C, Sb, Bi, F, Cl, Br and I, and Y is one of halogen, minus monovalent ionic group or vacancy. The lithium ion solid electrolyte has a stable structure and favorable lithium ion transmission performance and has favorable electrochemical performance and safety performance when used as a solid electrolyte of the lithium ion battery.

The present invention provides a powdered lithium transition metal oxide useful as a major component for cathode active material of rechargeable lithium batteries, comprising a lithium transition metal oxide particle, a doped interface layer formed near the surface of the particle, and a thermodynamically and mechanically stable outer layer, and a method of preparing the same.

The invention provides a lithium-ion battery electrolyte, which is composed of an organic solvent, lithium salt, a novel additive and other conventional additives. The novel additive is a dicyclophosphimide lithium salt or lithium dicyclothiophosphimide lithium salt compound shown in a structural formula 1. The compound shown in structural formula 1 of the invention has a high reduction potentialwhen used as an electrolyte additive, so that the novel additive can participate in the formation of a solid electrolyte film on the surface of a negative electrode in preference to the conventional additives and improve the composition of the interfacial film. Because the additive has a cyclic phosphate structure, the phosphorus-oxygen bond is easy to break under high voltage, and the additive can participate in the formation of a positive electrolyte film and improve the interface stability of the positive electrode material. Therefore, the introduction of the additive can improve the high temperature performance, low temperature performance and cycle performance of lithium-ion batteries.

The invention relates to a LiMnPO4 clad lithium-rich layered oxide Li[Li(1-2x)/3MxMn(2-x)/3]O2 (M is at least one of Ni or Co, wherein x is more than 0 and not less than 0.33) and a preparation method thereof. The Li[Li(1-2x)/3MxMn(2-x)/3]O2 is dipped in water solution containing Li, Mn and PO43- (the mol ratio is 1: 1: 1), is continuously stirred for 3-8 hours in an opening container at the temperature of 60-90 DEG C to prepare solid powder, then is dried for 2-24 hours at the temperature of 100 DEG C, and is roasted for 5-10 hours at the temperature of 300-600 DEG C to prepare the LiMnPO4 clad lithium-rich layered oxide Li[Li(1-2x)/3MxMn(2-x)/3]O2 cathode material, wherein the mass ratio of the LiMnPO4 to the Li[Li(1-2x)/3MxMn(2-x)/3]O2 is 3-10 wt%. The electrode material prepared by the method has the characteristics of high electrochemical capacity, good circulating stability, excellent rate capacity and the like, and has the advantages of simple preparation process, low cost and good reproducibility.

The invention relates to a surface coating type reinforced concrete corrosion inhibitor. The surface coating type reinforced concrete corrosion inhibitor comprises the components as follows: 15 to 40 wt% of a non-ionic surface active agent with HLB (Hydrophile Lipophile Balance) value more than 10, 5 to 30 wt% of a cosurfactant, 1 to 20 wt% of water insoluble organic inhibitor, and 20 to 50 wt% of water, wherein the cosurfactant is selected from organic alcohol or organic amine. The preparation method comprises the steps of mixing the non-ionic surface active agent, the cosurfactant and the water insoluble organic inhibitor, and agitating along with heating unit the mixture is completely molten, and then agitating along with water adding until the mixed liquid is turned into a clear state from a muddy state, thus obtaining the product. The preparation method provided by the invention is simple; the prepared product can be applied to surface treatment of the constructed concrete structure; and the prepared product has superior infiltration capacity, can effectively prevent the reinforcement surface from being eroded by chloride salt and sulfate, and has no adverse effect to the performance of the concrete.

The present invention relates to novel polymorphic and amorphous forms of a phosphate salt of 8-fluoro-2-{4-[(methylamino)methyl]phenyl}-1,3,4,5-tetrahydro-6H-azepino[5,4,3-cd]indol-6-one, and to processes for their preparation. Such polymorphic forms may be a component of a pharmaceutical composition and may be used to treat a mammalian disease condition mediated by poly(ADP-ribose) polymerase activity including the disease condition such as cancer.

The invention provides a nano hard alloy material containing spherical face-centered cubic structure cobalt powder and a preparation process thereof and belongs to the technical field of hard alloy preparation. The method comprises the steps of using 12-14 wt.% of the spherical face-centered cubic structure cobalt powder with the average grain diameter in a range of 200-300nm, 65-70 wt.% of tungsten carbide with the average grain diameter in a range of 200-300nm, 16-23 wt.% of tungsten carbide-titanium carbide-vanadium carbide-tantalum carbide-chromium carbide solid solution powder with the average grain diameter in a range of 300-400nm and a proper amount of an active and surface dispersing agent, and combining with airtight inert gases to protect high-speed ball milling, spray drying and overpressure sintering, so that sintering bodies are compact to the maximum extent, grain growth is restrained, the high-temperature performance of an alloy is optimized, and finally the high-hardness high-strength hard alloy material is obtained. The process is optimal in technology, easy to operate and applicable to industrial production.

The invention provides a novel polyaniline/carbon nano tube/nanometer silver particle conductive composite material which belongs to the technical field of composite materials. The novel polyaniline/ carbon nano tube/nanometer silver particle conductive composite material uses a two-phase composite material of carbon nano tube/nanometer silver particle as conductive filling and effectively utilizes the supersonic technology to lead the nanometer silver particle to uniformly disperse into polyaniline; the polyaniline grows on the surface of the carbon nano tube and completely covers the carbon nano tube. The invention solves the glomeration problem in aniline polymerization, can lead the nanometer silver particle to uniformly disperse into a polyaniline structure, effectively improves the conductive property and the thermodynamics stability of the polyaniline, and has simple process, convenient operation, mild reaction conditions, low production cost, high production efficiency, and better industrial production prospect.

A combustion turbine component (10) includes a combustion turbine component substrate (16) and an alloy coating (14) on the combustion turbine component substrate. The alloy coating (14) includes a first amount, by weight percent, of cobalt (Co) and a second amount, by weight percent, of nickel (Ni), the first amount being greater than the second amount. The alloy coating further includes chromium (Cr), aluminum (Al), at least one rare earth element, and an oxide of the at least one rare earth element.

The invention relates to a monodisperse nano-polymer carrier with biological compatibility and a method for preparation and carrying drug thereof. Firstly, a reversible addition fragmentation chain transfer (RAFT) polymerization method is used for preparing amphiphilic block copolymers with smaller polydispersity index, wherein the hydrophilic segment is methylacryoyloxyethyl phosphorylcholine (MPC) and the hydrophobic segment is n-butyl methacrylate (BMA). Then through the method of solvent evaporation, the amphiphilic block copolymers are used for preparing nano-polymer micelle, drugs are encapsulated in the micelle through physical action, thus obtaining the monodisperse nano-polymer carrier system with good biological compatibility.

The invention relates to a hot rolled steel used for a stirrer in an automotive stirring tank with tensile intensity of 750 MPa and a production method thereof. The hot rolled steel comprises the following chemical components by weight: 0.13-0.18% of C, not more than 0.15% of Si, 1.20-1.70% of Mn, 0.016-0.025% of P, not more than 0.008% of S, 0.035-0.070% of Als, 0.07-0.10% of Ti, 0.035-0.055% of Nb and 0.20-0.33% of Cu. The process comprises the following steps: smelting in a converter; treating in an LF furnace (ladle furnace); continuously casting to a blank and heating the cast blank; rolling in a segmental manner; cooling at variable speed and carrying out laminar flow cooling; coiling; and finishing and carrying out an after treatment process. According to the invention, an Rm average value is 780-800 MPa, elongation A is not less than 14%, the surface hardness HV10 reaches 260-300, in comparison with the conventional intensity steel with the same level, the surface hardness is at least improved for 20%, a plate form is easy to control, the surface quality is high, copper is particularly added, and the wear resistance and the anti-corrosion performance of a steel product are greatly improved.

The invention provides a superfine oil-base drilling fluid used for a high temperature high pressure superdeep well, the superfine oil-base drilling fluid contains the following raw materials by weight: 20-40 parts of water, 250-500 parts of diesel, 2-10 parts of an emulsifier, 3-15 parts of a wetting agent, 2-8 parts of organic soil, 15-25 parts of a filtrate loss agent, 5-10 parts of calcium chloride, 5-10 parts of calcium oxide, 450-800 parts of API barite, and 350-660 parts of an ultra aggravating material. The oil-base drilling fluid is weighted by compounding superfine mineral powder and ordinary barite, the superfine high density oil-base drilling fluid density can reach 2.8g / cm<3>, has better settling stability and high temperature and high pressure filtration loss compared with that of ordinary barite weighted drilling fluid, and can meet drilling of deep wells, superdeep wells and composite salt formations.

The invention relates grain refiner used for synthesizing aluminum alloy by laser firing and preparing method. The grain refiner comprises Al, Ti and B. The method comprises the following steps: mixing the Al, Ti, B and TiH2 powers with blending attachment, adding the powders into die and pressing them to preformed sample, after evacuating and filling argon gas, utilizing the laser to carry out self-propagating reaction of preformed sample and get grain refiner. The grain refiner possesses good refining effect and decline-resistant capability. The invention suits for aluminum alloy handling field.