The invention belongs to the technical field of
lithium ion batteries, and particularly relates to a composite positive
electrode material for a
lithium ion battery and a preparation method of the composite positive
electrode material. The composite positive
electrode material is composed of a positive electrode base material, a
lithium supplementing material and a catalytic material. The preparation method comprises the following steps: (1) preparing a
composite material of the positive electrode base material and the lithium supplementing material in situ; and (2) dispersing the catalytic material on the surface of the
composite material of the positive electrode base material and the lithium supplementing material, and forming a stable
interface layer between the catalytic material and the lithium supplementing material. According to the method disclosed by the invention, the lithium supplementing material has double functions of
surface modification of a positive electrode base material and lithium supplementing of a negative electrode, and meanwhile, the first effect and the
cycling stability of the battery are improved; a catalytic material is introduced to the surface of the lithium supplementing material, free O generated by the lithium supplementing material Li is fixed in situ, the bag expansion phenomenon of the battery is relieved, and the
cycling stability and safety of the battery are further improved; the preparation process is simple, raw materials are cheap and easy to obtain, the production cost is low, and industrial production and popularization are easy.