The invention relates to a sort of cerium-based block amorphous alloy, which is formed primarily from the cerium and contains at least 50% amorphous phase percentage by volume, and can be represented by the formula: CeaAlbNicCudMe, wherein 50<=a<=80, 5<=b<=20, 5<=c<=20, 5<=d<=20, 0<=e<=10, and a+b+c+d+e=100, and said transition metal elements M is Sc, Nb, Ti, V, Cr, Mn, Fe, Co, Y, Zr, Mo, La, Pr , Nd or Hf. The preparation of the alloy is in the electric arc furnace of argon atmosphere absorbed with the titanium and the steps is: smelting each group according to needed atomic matching, mixing them evenly, and getting the key metal ingoting after cooling, smelting the ingoting again by normal chill casting method, inhaling the flux to the water-cooled copper mould through the suction apparatus in the furnace, then getting the alloy.