2900 results about "Carboxylic group" patented technology

The present invention relates to the field of polyurethane materials and particularly to a temperature-induced color-changing vehicle film and a preparation method therefor. The method of the present invention comprises: firstly, using polyurethane to wrap vanadium dioxide powder to obtain color-changing microcapsules; then using 1,1,1,3,5,5,5-heptamethyltrisiloxane and 3-allyloxy-1,2-propanediol as raw materials to synthesize an organosilicon-modified diol, and enabling trimellitic anhydride to react with toluene diisocyanate to synthesize a dicarboximide compound; enabling the organosilicon-modified diol and the dicarboximide compound to undergo an esterification reaction and a polymerization reaction to obtain an organosilicon-modified imide polyester diol; then mixing the organosilicon-modified imide polyester diol with polytetrahydrofuran ether glycol 2000, and then enabling the mixture to react with toluene diisocyanate to obtain a polyurethane elastomer; and mixing the polyurethane elastomer, the color-changing microcapsules, a silane coupling agent, a plasticizer, an antioxidant, and an ultraviolet light absorber, followed by melt extrusion and blow molding into a film, so as to obtain the temperature-induced color-changing vehicle film.

The invention relates to the technical field of fuels and additives thereof, in particular to an alcohol fuel with a catalytic effect and an additive thereof.The alcohol fuel with the catalytic effect comprises C1-C7 alcohol and hydrocarbon, and a rare earth compound catalytic material is used in the fuel; the rare earth compound comprises a hydroxyl group or a phenyl group or a C5-C25 group or a carboxyl group or an amino group or a metal, the alcohol fuel is high in formula calorific value adjustable calorific value, can well adapt to an internal combustion engine or an engine for testing the alcohol fuel, is a novel alternative energy with potential, and can be used for preparing the alcohol fuel. The environmental protection problem of fossil fuel is solved, and the fuel efficiency is accelerated.

The invention belongs to the field of functional composite materials, and particularly relates to low-viscosity and high-dispersity aluminum oxide slurry and a preparation method thereof.The low-viscosity and high-dispersity aluminum oxide slurry is prepared from a newly-designed phosphono-carboxyl block copolymer and biquaternary ammonium salt polyether silane as composite modifiers; and efficient anchoring and stable dispersion of the surfaces of alumina particles are realized through the synergistic effect of molecular structures. The phosphono-carboxyl block copolymer is prepared through controllable polymerization and deprotection reaction, and strong chemical bonding is formed between a phosphono group and the surface of aluminum oxide; the biquaternary ammonium salt polyether silane is subjected to click chemical synthesis, and electrostatic adsorption of quaternary ammonium salt and the steric hindrance effect of a polyether chain are combined. When the slurry is prepared, the two modifiers are sequentially added into water, the aluminum oxide powder is added after the pH value is adjusted, finally, the isobutylene maleic anhydride copolymer and the defoaming agent are introduced, and the slurry is obtained through vacuum defoaming and filtering. The slurry prepared by the method has the characteristics of high solid content, low viscosity and good dispersion stability.

Provided is a heat-curable acrylic resin composition which is capable of suppressing the generation of ultra-fine bubbles when cured under heat and pressure, and which has excellent adhesiveness. A thermosetting acrylic resin composition which contains (A) an acrylic copolymer having a carboxyl group and (B) a phenolic resin, and which is characterized in that: when the acrylic copolymer (A) is an acrylic copolymer (A-1) having a glass transition temperature of-35 DEG C or less, the phenolic resin (B) is a phenolic resin; the thermosetting acrylic resin composition contains a specific content of an epoxy curing agent (C-1), contains a specific content of a novolac phenolic resin (B-1) or a self-crosslinking phenolic resin (B-2) as the phenolic resin (B), and contains a specific content of a novolac phenolic resin (B-1) or a self-crosslinking phenolic resin (B-2) when the novolac phenolic resin (B-1) is contained as the phenolic resin (B). The thermosetting acrylic resin composition also contains a specific content of an amine curing agent (C-2).

The invention provides polyacrylic acid-carboxylated chitosan interpenetrating network hydrophobic modified hydrogel as well as a preparation method and application thereof, and belongs to the technical field of wastewater treatment. The preparation method comprises the following steps: mixing an acrylic monomer, a hydrophilic acrylate monomer, an etherification type acrylamide monomer, an allyl quaternary ammonium salt type hydrophobic monomer, a crosslinking monomer and water, then mixing with a chitosan compound, and adjusting the pH value to obtain a reaction solution; and mixing the reaction liquid and a photoinitiator, then carrying out polymerization reaction, and sequentially pre-freezing and freeze-drying the obtained polymer hydrogel. Through multiple synergistic effects of photo-initiated rapid polymerization, amphiphilic hydrophobic modification, etherification auxiliary crosslinking and a chitosan compound interpenetrating network, the structural stability, complexing efficiency, industrial applicability and heavy metal adsorption performance are comprehensively improved; the adsorption rate and capacity of the hydrogel disclosed by the invention are obviously superior to those of the existing similar polyacrylic acid-based or chitosan-based hydrogel.

The invention provides LED-UV (Light Emitting Diode-Ultraviolet) curing ink as well as a preparation method and application thereof, and the LED-UV curing ink is prepared from the following components in parts by weight: 30 to 50 parts of modified polyurethane acrylate resin, 15 to 30 parts of modified epoxy acrylate resin, 10 to 15 parts of amino resin, 15 to 30 parts of acrylate monomer, 6 to 10 parts of photoinitiator, 1 to 3 parts of adhesion promoter, 2 to 4 parts of coupling agent, 0.5 to 1 part of defoaming agent and 1 to 2 parts of flatting agent. The modified polyurethane acrylate resin is hydroxyl and / or carboxyl modified polyurethane acrylate resin; the modified epoxy acrylate resin is polyurethane modified epoxy acrylate resin. After the ink is photo-cured, a paint film has good flexibility, adhesive force and chemical resistance; the hardness, the curing speed and the chemical resistance of a paint film can be improved; the adhesive force to a base material can be promoted; and the water resistance and the wine soaking resistance of a paint film are enhanced.

The invention belongs to the technical field of waterproof and moisture permeable membrane materials, and particularly relates to a bio-based microporous membrane based on a template and a preparation method and application thereof, and the preparation method comprises the following steps: dispersing one of polybenzimidazole, aminated PI and carboxylated PBO and modified CNF into a DMF / water system; performing electrostatic spinning on the high-viscosity spinning solution; carrying out low-temperature vacuum drying treatment on the modified nanofiber self-supporting framework; coating and filling the bio-based polyurethane resin into the bio-based microporous membrane template, and carrying out negative pressure adsorption until the filling is uniform; and carrying out gradient drying on the bio-based wet membrane to obtain the bio-based microporous membrane. Compared with the prior art, the problems that in the prior art, the mechanical property or stability of bio-based polyurethane is insufficient, and a nanofiber reinforcing technology is difficult to combine with the bio-based polyurethane are solved. A nanofiber self-supporting framework with a stable structure is prepared through an electrostatic spinning technology, and then the nanofiber self-supporting framework is compounded with bio-based polyurethane to form a microporous membrane layer with waterproof and moisture permeable functions.

The application relates to the technical field of packaging films, and discloses an antistatic plastic packaging film and a preparation process.The antistatic plastic packaging film comprises 100 parts by weight of polyethylene, 1-6 parts by weight of phenolic resin polyaniline antistatic agent and 0.2-0.3 parts by weight of an antioxidant.The dodecyl succinic anhydride esterified phenolic resin contains carboxyl groups, can be used as a protonic acid, is doped into polyaniline through an in-situ polymerization reaction, makes imine nitrogen atoms of the polyaniline protonate, forms a charged excited state polaron, and thus the conductivity of the polyaniline is improved, the resistance of the polyethylene is reduced, and the antistatic performance of the packaging film is improved.The dodecyl succinic anhydride esterified phenolic resin and the doped polyaniline have good compatibility with the polyethylene, have a certain reinforcing effect on the polyethylene, and make the film material have higher tensile strength and elongation at break.

The invention belongs to the field of separation membranes, and particularly relates to an anti-pollution and washable reverse osmosis membrane and a preparation method thereof. The reverse osmosis membrane provided by the invention is prepared according to the following steps: soaking a nascent state polyamide reverse osmosis membrane in a first treatment solution, taking out and cleaning, then soaking in a second treatment solution, taking out and draining to obtain the anti-pollution and washing-resistant reverse osmosis membrane, the nascent state polyamide reverse osmosis membrane comprises a non-woven fabric layer, a porous support layer and a polyamide separation layer which are in contact in sequence; the first treating fluid contains double-end amino polyethylene glycol and triethylamine; the second treatment liquid contains polyvinyl alcohol and alpha-aldehyde group-omega-carboxyl polyethylene glycol. Experimental results show that the reverse osmosis membrane provided by the invention has relatively high anti-pollution capacity, desalting rate and acid and alkali cleaning resistance.

The present invention is a resist composition containing a hypervalent iodine compound, a carboxy-group-containing polymer, and a solvent, where the carboxy-group-containing polymer includes a repeating unit of a carboxylic acid derivative, represented by the following formula (1), and the polymer has a dispersity Mw / Mn of 1.30 or less, where Mw is a weight-average molecular weight and Mn is a number-average molecular weight measured by gel permeation chromatography. This can provide: a non-chemically amplified resist composition excellent in sensitivity and limiting resolution in photolithography using a high-energy beam; a laminate including the resist composition; a patterning process using the resist composition; and a method for manufacturing the resist composition.

The application discloses a kind of high-performance coiled material powder coating and preparation method thereof, belong to powder coating technical field, the application is by the compounding of organosilicon modified epoxy resin and carboxyl-terminated polyester resin, after organosilicon modification, the segment of introduction-Si-O-Si in system has high flexibility, and synergistic effect with nano calcium carbonate, it is helpful to balance the adhesion and flexibility of coating, grafting modification graphene oxide, active chromium oxide is added again, can obviously improve the mechanical strength of coating;After then, phosphite group is grafted onto graphene oxide, and is applied in the present powder coating system, can form three-dimensional network structure in system, chemical bond effect, not only can improve its crosslinking stability in system, and the sheet structure of graphene oxide, also can play certain barrier property, can also give coating longer weather resistance, and active chromium oxide synergistic effect is further improved, and the weather resistance and corrosion resistance of coating.

The invention belongs to the technical field of ceramic slurry, and particularly relates to ceramic slurry and a preparation method and application thereof.The ceramic slurry comprises inorganic components and organic components, the inorganic components comprise inorganic additives and glass powder, the inorganic additives comprise Al2O3, ZrO2 and Y2O3, and the organic components comprise modified acrylic resin, organic solvent and auxiliaries. By controlling the relative content of carboxyl and ester groups in the modified acrylic resin and utilizing the polarity difference of functional groups, selective adsorption of inorganic powder is realized, so that the dispersion uniformity of the powder in the ceramic slurry is remarkably improved, segregation of yttrium oxide is effectively inhibited, and the service life of the ceramic slurry is prolonged. Therefore, monoclinic-phase zirconium oxide, tetragonal-phase zirconium oxide and cubic-phase zirconium oxide with a proper proportion can be formed in the sintered ceramic substrate, further the bending strength of the ceramic substrate is remarkably improved, and the ceramic substrate is particularly suitable for manufacturing miniaturized and thin electronic components.

The invention discloses a dual-response dual-network fracturing fluid thickening agent and a preparation method thereof, and relates to the technical field of oilfield chemistry and fine chemistry, a nonionic monomer and a cross-linking agent are subjected to cross-linking polymerization under the action of an initiator to form a first network structure, and a carboxyl-containing polymer filled in the first network structure is utilized to form a second network structure. Wherein the nonionic monomer is at least one of acrylamide and modified acrylamide. According to the dual-network fracturing fluid thickening agent, carboxyl and high-valence cations are subjected to ionic crosslinking under high salinity to form an egg box structure, so that molecular chain aggregation and gelation are caused. Under the acidic condition, the charge density of carboxyl protonated molecular chains is reduced, the electrostatic repulsive force is weakened, and inter-chain aggregation and precipitation are caused. In addition, protonated carboxyl and hydroxyl form intramolecular and intermolecular hydrogen bonds, so that interchain aggregation is further promoted. Therefore, the prepared dual-network thickening agent has the characteristics of high density, salt resistance and acid resistance, and the yield increase and transformation effect of an unconventional oil and gas reservoir is remarkably improved.

Provided are chemically modified silk fibroin and a use thereof in cell and organoid culture. The chemically modified silk fibroin is a product obtained by sequentially carboxylating silk fibroin and modifying same by an organic amine having a phenol group. Also provided is a hydrogel based on the chemically modified silk fibroin. A hydrogel system has a hierarchical structure and mechanical properties similar to those of an extracellular matrix, and exhibits characteristics such as definite composition, controllable physicochemical properties, low cytotoxicity, good biocompatibility, and biodegradability, can support the growth and differentiation of cells and organoids, and is suitable as a matrigel for cell and organoid culture.

The invention provides a Lewis acid metal ion-piperazine modified nanocellulose film as well as a preparation method and application thereof, and belongs to the technical field of battery materials. The preparation method comprises the following steps: mixing carboxylated nanocellulose with Lewis acidic metal salt in a solution, and carrying out pre-crosslinking reaction to obtain Lewis acidic metal ion modified carboxylated nanocellulose; a piperazine ligand compound and dopamine hydrochloride are added into the Lewis acidic metal ion modified carboxylated nano-cellulose, a cross-linking reaction is carried out with Lewis acidic metal ions as the center, suction filtration is carried out, and a film is formed. The metal in the Lewis acid metal salt is metal cations with the valence of more than bivalent. The carboxylated nanocellulose, the Lewis acid metal ion-piperazine complex and the solid polymer electrolyte are organically combined together for the first time and are applied to the lithium metal battery, the unique advantages of the lithium metal battery in the field of batteries are shown, and the rate capability and the cycling stability are greatly improved.

The invention discloses a carboxyl-functionalized porous organic polymer, a preparation method thereof and application of the carboxyl-functionalized porous organic polymer in ammonia gas adsorption separation and sensing. The polymer is obtained by free radical polymerization, hydrolysis and acidification of monomers containing vinyl and ester groups, and has a mesoporous structure and a skeleton carboxyl functional group. The preparation method is simple and mild in condition. The polymer has excellent adsorption selectivity and high adsorption capacity on ammonia gas, the static adsorption capacity on the ammonia gas under the conditions of 298 K and 1 bar is not lower than 6.5 mmol / g, the ammonia gas can be efficiently separated from NH / N / H and NH / COs mixed gas, and the cycling stability is good. An ammonia gas sensor prepared by taking the graphene oxide as a sensitive material has linear or piecewise linear response to ammonia gas with the concentration of 1-100 ppm at room temperature, the detection limit is lower than 30 ppb, and the selectivity is excellent. The invention overcomes the defects of the existing ammonia gas adsorption separation material and sensor, has important significance for optimizing the ammonia production process and reducing pollution, and has wide application prospects.

The invention relates to the technical field of concrete, and provides ultra-high performance concrete and a preparation method thereof. The ultra-high performance concrete is prepared from the following raw materials in parts by weight: 70 to 80 parts of Portland cement, 15 to 25 parts of silica fume, 5 to 10 parts of limestone, 2 to 5 parts of metakaolin, 100 to 120 parts of quartz sand, 24 to 42 parts of hydroxylated steel fiber, 6 to 24 parts of carboxylic butadiene-acrylonitrile latex, 2.0 to 3.5 parts of a water reducing agent and 15 to 22 parts of water. Through the technical scheme, the problem of poor chloride ion permeability resistance of the ultra-high performance concrete in the prior art is solved.

The preparation method comprises the following steps: by taking natural chitosan, epsilon-polylysine and polyphenol as raw materials, firstly, respectively preparing polyphenol modified chitosan and carboxyphenylboronic acid modified polylysine through a carbodiimide coupling method, then, mixing single-component solutions of the polyphenol modified chitosan and the carboxyphenylboronic acid modified polylysine, and then, preparing the antibacterial and antioxidant glycopeptide hydrogel based on the polyphenol. And the antibacterial and antioxidant glycopeptide hydrogel is obtained by virtue of the synergistic effect of the phenolic hydroxyl group-boric acid group dynamic bond and the amino group-carboxyl group. The hydrogel disclosed by the invention has broad-spectrum antibacterial property and glucose response oxidation resistance, has self-healing capability and strong wound adhesion, is excellent in biocompatibility and can be naturally degraded; and the process is simple, convenient and controllable, large-scale production is easy to realize, the hydrogel can be used as a wound dressing for treating chronic difficult-to-heal wounds such as diabetes mellitus in a targeting manner, and integrated nursing of antibiosis, antioxidation, wound adhesion and self-repairing is realized.

The invention relates to the technical field of biological medicines, and discloses a polypeptide for treating osteoarthritis by aiming at AHR (Aryl Hydrocarbon Receptor), the amino acid sequence of the polypeptide is GFQQSDVIHQSVYELISINHTEDRA, and the amino acid sequence of the polypeptide is GFQQSDVIHQSVYELISINHTEDRA, and the amino acid sequence of the polypeptide is GFQQSDVIHQSVYELISINHTEDRA. The polypeptide is prepared by a solid-phase polypeptide synthesis method; the solid-phase polypeptide synthesis method specifically comprises the following steps: synthesizing from a C end to an N end, connecting a carboxyl group of a first amino acid to insoluble resin, then adding other amino acids one by one to form a peptide chain, and carrying out protection and deprotection reactions of a side chain in each step. The polypeptide is composed of natural amino acids and has good biocompatibility and degradability, and experimental results show that no obvious toxic reaction occurs in the cell level and the animal level, so that the polypeptide has conditions for further development of pharmacokinetic research and preclinical tests, and a feasible basis is provided for conversion to clinical application.

The invention relates to a lead-free and halogen-free soldering paste and a preparation process thereof, and belongs to the technical field of soldering paste production, through the combination of nano-silver-loaded carbon nanotubes, organically coated solder alloy powder and soldering flux, the surface tension of the lead-free and halogen-free soldering paste can be reduced by carbon nanotube surface carboxyl in the nano-silver-loaded carbon nanotubes, so that the lead-free and halogen-free soldering paste is obtained. Nano-silver and tin form an Ag3Sn strengthening phase which synergistically promotes wetting and spreading of the solder on a substrate, meanwhile, the carbon nanotubes loaded with the nano-silver are uniformly dispersed in the soldering paste to play a dispersion strengthening role, and the brittleness caused by bismuth segregation is effectively inhibited in cooperation with the grain refinement effect of copper and indium in the solder alloy powder; and the organic coating layer hydrogenated rosin-terpene resin and the soldering flux alcohol ether solvent form a slight dissolution-fusion effect, so that the welding flux alloy powder is prevented from being oxidized, an organic acid active agent can be released to remove a substrate oxidation film, the metallurgical bonding quality of a welding interface is further guaranteed, and the defects of pseudo soldering, cavities and the like are reduced.

The invention relates to the technical field of organic-inorganic hybrid materials, in particular to an antifouling organic-inorganic hybrid material, a preparation method, a photocuring antifouling material and a product. The organic-inorganic hybrid material is prepared by carrying out a ring-opening addition reaction on an epoxy group of epoxy polyhedral oligomeric silsesquioxane and polydimethylsiloxane with an amino group or perfluoropolyether with a carboxyl group. According to the scheme provided by the invention, the coating has high thermal stability and structural rigidity endowed by epoxy polyhedral oligomeric silsesquioxane and excellent low surface energy antifouling property endowed by amino-containing polydimethylsiloxane or carboxyl-containing perfluoropolyether, and the defect that a pure epoxy polyhedral oligomeric silsesquioxane coating does not have antifouling property is effectively overcome.

The present invention is a method for manufacturing a non-chemically amplified resist composition, including, in the following order, the steps of: (i) placing a carboxy-group-containing polymer, a hypervalent iodine compound, and a solvent in a container and mixing together to prepare a fundamental resist composition; (ii) collecting part of the fundamental resist composition, forming a resist film on a test substrate by using the collected fundamental resist composition, and evaluating a film physical property of the resist film; and (iii) adding an additional material to the fundamental resist composition and mixing together to achieve a target film physical property based on an evaluation result of the step (ii). This can provide: a method for manufacturing a non-chemically amplified resist composition whose quality is controlled to be constant; and a patterning process.

The invention discloses a high-CTI (comparative tracking index) halogen-free flame-retardant PA66 (polyamide 66) composite material and a preparation method thereof, and belongs to the technical field of high polymer materials. The composite material comprises the following components in parts by weight: 52-64 parts of PA66 resin, 20-30 parts of glass fibers, 12-15 parts of a phosphorus-based flame retardant, 0.5-1.5 parts of a flame-retardant synergist, 0.3-0.7 part of a lubricant and 0.1-0.5 part of an antioxidant, and the flame-retardant synergist is aliphatic dicarboxylic acid with the carbon atom number greater than or equal to 8. The material surface energy is reduced and electrolyte is repelled through long-carbon-chain hydrophobic groups, and meanwhile, the CTI value is increased to 600 V or above while it is guaranteed that the material reaches the UL94 V0 flame retardant grade (1.6 mm) by utilizing interaction of carboxyl and a PA66 matrix and cooperating with a phosphorus flame retardant. The invention also provides a preparation method of the material, the process is simple, the material is suitable for industrial production, and the product can be widely applied to electronic and electrical components with high safety requirements.

The invention provides a rubidium and cesium adsorbent and a preparation method and application thereof. The preparation method comprises the following steps: providing a doped and modified Prussian blue analogue, wherein the Prussian blue analogue comprises a Prussian blue matrix material and a transition metal doping element doped in the Prussian blue matrix material; granulating a mixed material containing the doped and modified prussian blue analogue and a granulating agent to obtain a rubidium and cesium adsorbent precursor; a mixed reaction system containing the rubidium and cesium adsorbent precursor and a surface modifier are subjected to a reaction, the surface modifier contains one or more functional structures of an amino group, a sulfonic group, a carboxyl group, a sulfydryl group, an acryloyloxy group, an epoxy group, a crown ether structure and a calixarene structure, and therefore the rubidium and cesium adsorbent is obtained. Through a multi-aspect synergistic strategy of transition metal doping, granulation and surface modification, the prepared rubidium and cesium adsorbent has good stability and high adsorption capacity, and has strong selectivity to Cs < + > / Rb < + >.

The invention discloses a high-dispersion cobalt-based catalyst and a preparation method and application thereof, and belongs to the technical field of cobalt-based catalysts.The preparation method comprises the steps that tetracarboxyl cobalt phthalocyanine and nitrogen-defect carbon nanotubes serve as raw materials, a pre-assembled compound is formed in an organic solvent through molecular self-assembly, then programmed microwave heating is conducted on the pre-assembled compound, and the high-dispersion cobalt-based catalyst is obtained. According to the high-dispersion cobalt-based catalyst and the preparation method thereof disclosed by the invention, a means of combining a specific molecular precursor and carrier defect engineering is utilized, a'molecular anchor-anchor positioning 'pre-connection system is constructed through liquid-phase pre-assembly, and a programmed microwave energy accurate input principle is supplemented, so that the high-dispersion cobalt-based catalyst is obtained. The key technical problems that when the cobalt-based catalyst is prepared through an existing microwave method, metal atoms are prone to agglomeration, the active site structure is uncontrollable, and the catalytic performance is ordinary are successfully solved.

The invention relates to the technical field of biomedical material modification, in particular to a sulfhydrylation biocompatible polymer derivative, a preparation method thereof, extracellular matrix imitating injectable in-situ cross-linked hydrogel and application thereof. According to the invention, a pre-acylation strategy is firstly carried out on the biocompatible polymer containing both amino and carboxyl, so that a three-dimensional cross-linked byproduct formed by coupling of self amido bonds is avoided, meanwhile, the number of side chain carboxyl for sulfhydrylation modification is increased, and the accurate and adjustable pre-acylation rate can optimize the physical and chemical properties of the derivative; meanwhile, a disulfide bond is used as a protective precursor, active sulfydryl is introduced through amido bond coupling, self-oxidation of the active sulfydryl in the reaction process is avoided, sulfydryl activity is guaranteed, hydrazine-containing reagents are avoided, safety is further improved, virus residues and immunological rejection risks are avoided, universality is high, and the application prospect is wide; and in combination with a high-concentration preparation method, the method has the advantage of large-scale production, and further widens the industrial application potential.

The invention discloses functionalized graphene for removing tritium from radioactive waste liquid and a preparation method and application of a graphene film, the functionalized graphene is a flaky substance formed by stacking lamellar structures, and the distance between the stacked lamellar structures is 7.5-8.7. The preparation method comprises the following steps: preparing graphene oxide powder; performing sulfonation on the graphene oxide powder to obtain sulfonated graphene aerogel; performing carboxylation on the graphene oxide powder to obtain carboxylated graphene; and mixing and stirring the sulfonated graphene aerogel and carboxylated graphene to obtain the functionalized graphene. The tritium in the tritium-containing liquid is separated by utilizing the membrane formed by the functionalized graphene, and the tritium removal technology has the advantages of mild reaction conditions, low energy consumption, easiness in large-scale production and the like.

The invention discloses a fireproof flame-retardant battery diaphragm, a preparation method thereof and a fireproof flame-retardant battery, and relates to the technical field of battery diaphragms. When the fireproof flame-retardant battery diaphragm is prepared, boric acid diglyceride and chlorinated trimellitic anhydride mixed liquor react to prepare a flame-retardant monomer; the preparation method comprises the following steps: polymerizing 4, 4 '-diaminodiphenyl ether and a flame-retardant monomer, and carrying out electrostatic spraying to prepare polyamide acid microspheres; dehydrating and drying the polyamide acid microspheres to obtain polyimide microspheres; performing etching-acidification on the polyimide microspheres to prepare carboxylated polyimide microspheres; allyl phosphoric acid and acrylic acid are copolymerized and grafted on the surface of a polyethylene film to prepare a modified polyethylene film; and coating the surface of the modified polyethylene film with the carboxylated polyimide microspheres to prepare the fireproof flame-retardant battery diaphragm. The prepared fireproof flame-retardant battery diaphragm has excellent flame retardance, wetting performance and thermal stability.

The invention relates to a silicon-based negative electrode material with a composite coating layer, the silicon-based negative electrode material is of a core-shell structure and comprises a silicon-based material core and the composite coating layer, and the composite coating layer sequentially comprises a carboxyl-containing ionic conductive polymer layer and an electronic conductive polymer layer from inside to outside; wherein the carboxyl group-containing ionic conductive polymer layer is formed by carrying out surface modification on a silicon-based material by using an alkenyl silane coupling agent to form a precursor A, and then carrying out in-situ copolymerization on the precursor A, unsaturated carboxylic acid and an ionic group-containing olefin monomer under the action of an initiator; the precursor A and the carboxyl-containing ionic conductive polymer layer jointly form a precursor B; and the electronic conductive polymer layer is formed by carrying out chemical oxidation polymerization on an electronic conductive polymer monomer on the surface of the precursor B under the action of an oxidizing agent. Strong interface bonding force exists between the composite coating layer and the silicon-based core and between the composite coating layer and the silicon-based core, so that silicon expansion is effectively relieved, the cycling stability is improved, and meanwhile the ion transmission and electron transmission capacity is improved.

The invention relates to the field of separation and purification, in particular to an anti-pollution nanofiltration membrane for magnesium-lithium separation, the anti-pollution nanofiltration membrane comprises a base membrane and a functional layer, and the functional layer is prepared from the following raw materials in parts by weight: a water phase: 1.5-2.5 parts of piperazine, 0.1-1 part of lauryl sodium sulfate, 0.5-2 parts of glycerol, 1-2 parts of triethylamine, 0.6-2 parts of ionic polymer, and the balance of water for supplementing the total amount of the water phase to 100 parts; the ionic polymer comprises at least one of sulfobetaine metacrylic acid ester, sulfobetaine and carboxyl betaine metacrylic acid ester; and an oil phase: 0.1-1 part of trimesoyl chloride, and the total amount of the oil phase is supplemented to 100 parts by normal hexane or isoparaffin. The ionic polymer is added, and a compact hydration layer is formed on the surface of the membrane by using a betaine group of the ionic polymer, so that the membrane pollution probability is reduced, and common inorganic scaling and organic pollution in the high-salt brine are remarkably inhibited; in addition, the ionic polymer enables the membrane surface to have strong negative electricity, and the magnesium ion rejection rate is improved; and the ionic polymer can also reduce the lithium ion transmission energy barrier and reduce the rejection rate.