7220 results about "Carboxylic group" patented technology

The invention discloses rubber powder grafted nano material composite modifier modified asphalt, a preparation method thereof and an asphalt mixture, and belongs to the technical field of modified asphalt. The modified asphalt is prepared by modifying a carboxylated nano material grafted with aminated rubber powder. According to the invention, the rubber powder and the nano material are grafted, so that the advantages of the rubber powder and the nano material can be fully played, the high temperature, low temperature, water stability and other properties of asphalt and asphalt mixtures are remarkably improved, and a new solution is provided for high performance and sustainable development of asphalt pavements; therefore, the method has good application prospect and value in the field of road engineering.

The invention relates to a high / low-temperature-resistant wear-resistant tear-resistant fluorosilicone rubber compound and a preparation method thereof, and belongs to the technical field of special rubber materials, the high / low-temperature-resistant wear-resistant tear-resistant fluorosilicone rubber compound comprises the following components: raw fluorosilicone rubber, a reactive liquid rubber compatibilizer, a reinforcing filler, a tear-resistant aid, a high-temperature-resistant aid, a vulcanizing agent, an accelerant, an anti-aging agent and an anti-attrition filler, the provided reaction type liquid rubber compatibilizer contains vinyl carboxyl liquid fluorosilicone rubber, the tear-resistant auxiliary agent contains zinc polymethacrylate, the high-temperature auxiliary agent contains vinyl fluorosilane modified carbon nanotubes, and the anti-friction filler contains molybdenum disulfide and layered nano zirconium phosphate which are treated by oxygen plasma. The high and low temperature resistance stability, oil resistance, wear resistance and tear strength of the fluorosilicone rubber are synergistically improved by regulating and controlling the multi-cross-linked network structure of the fluorosilicone rubber, strengthening the interface action of the rubber and the filler and optimizing the composite vulcanization system, meanwhile, structuralization of a rubber compound is prevented by optimizing the preparation process, and the requirement for adaptability to severe working conditions is met.

The invention relates to the field of membrane materials, and discloses an epoxy modified starch-based degradable membrane and a preparation method thereof, the epoxy modified starch-based degradable membrane comprises epoxidized starch, modified nanocellulose and a plasticizer; the modified nano cellulose is prepared by mixing a modified composite filler, a nano cellulose dispersion liquid and a zinc acetate dihydrate aqueous solution; the nano-cellulose dispersion liquid is prepared by adhering polytannic acid formed by oxidation and self-polymerization of tannic acid to the surface of nano-cellulose; the modified composite filler is prepared by performing carboxylation modification on nano titanium dioxide coated fumed silica nanoparticles by using succinic anhydride and gamma-aminopropyltriethoxysilane, then reacting with polyethyleneimine to obtain an aminated composite filler, and finally grafting glycidyl dodecyl dimethyl ammonium chloride to the surface of the aminated composite filler. The prepared film material is high in tensile strength, has certain hydrophobicity, and has good heat resistance, antibacterial property and flame retardant property.

A solid electrolyte includes: LiaAbEc(SO4)dJeXfHh, A is selected from alkaline earth metals and alkali metals other than Li, E is selected from Al, Ga, In, Sc, Y, Ti, Zr, Hf, and lanthanides, J is selected from OH, BO2, BO3, BO4, B3O6, B4O7, CO3, NO3, AlO2, SiO3, SiO4, Si2O7, Si3O9, Si4O11, Si6O18, PO3, PO4, P2O7, P3O10, SO3, SO5, S2O3, S2O4, S2O5, S2O6, S2O7, S2O8, BF4, PF6, BOB, (COO)2, N, AlCl4, CF3SO3, CH3COO, CF3COO, OOC—(CH2)2—COO, OOC—CH2—COO, OOC—CH(OH)—CH(OH)—COO, OOC—CH(OH)—CH2—COO, C6H5SO3, OOC—CH═CH—COO, OOC—CH═CH—COO, C(OH)(CH2COOH)2COO, AsO4, BiO4, CrO4, MnO4, PtF6, PtCl6, PtBr6, PtI6, SbO4, SeO4, TeO4, HCOO, and O, X is selected from F, Cl, Br, and I, 0.5≤a<6, 0≤b<6,0<c<2,0.1<d≤6.0, 0<e≤6.0, 0<f≤6.1, and 0≤h≤0.2, and a peak is observed at a diffraction angle 2θ=22.3°±1.0° in an X-ray diffraction pattern in which Cu-Kα is used as a line source.

The invention relates to the technical field of polypropylene, and discloses a high-strength polypropylene composite material as well as a preparation method and application thereof in an automobile bumper. The high-strength polypropylene composite material comprises the following components in parts by weight: 70-90 parts of polypropylene resin, 10-30 parts of polycarbonate resin, 25-40 parts of glass fibers, 3-10 parts of an allyl carbonate grafted polypropylene compatilizer and the like. The compatilizer contains carbonate groups similar to polycarbonate, so that the compatibility between polypropylene resin and polycarbonate resin is improved, and the compatilizer has higher mechanical properties. Moreover, the compatilizer contains carboxyl and can form interaction with the surface of the glass fiber, so that the compatibility between the glass fiber and the polypropylene resin is improved, the glass fiber has a better reinforcing effect, the tensile strength, the impact strength and the bending strength of the composite material are remarkably improved, and the compatilizer has good practical application in the aspects of automobile bumpers and the like.

The invention relates to the technical field of environmental materials and water treatment, in particular to a graphene amino silica gel composite adsorbent for heavy metal wastewater treatment and a preparation method thereof.The graphene amino silica gel composite adsorbent is prepared from # imgabs0 nanoparticles, an amino-functionalized silicon dioxide coating layer, carboxylated reduced graphene oxide, a polydopamine modification layer and tetraethyl orthosilicate; the coating is prepared from the following raw materials: 3-aminopropyltriethoxysilane, 3-mercaptopropyltrimethoxysilane, N-((4-vinyl benzyl) amino) diacetic acid, chitosan, beta-cyclodextrin, hexadecyl trimethyl ammonium bromide, polyethylene glycol, L-ascorbic acid, 1-ethyl-3-(3-dimethyl aminopropyl) carbodiimide hydrochloride and N-hydroxysuccinimide. The composite adsorbent shows excellent adsorption performance on various heavy metal ions, and the adsorption performance is far higher than that of traditional adsorption materials and existing composite adsorbents.

The invention discloses a bamboo powder-containing biodegradable plastic for food contact and a preparation method thereof, and relates to the technical field of bio-based materials. The bamboo powder-containing biodegradable plastic for food contact comprises chitosan starch and modified bamboo powder, the chitosan starch is prepared by adding composite chitosan and amino-terminated polyethylene glycol into oxidized corn starch, and the composite chitosan is prepared by grafting chlorogenic acid on the surface of chitosan and then coating succinic anhydride derivatives. The succinic anhydride derivative is prepared from dodecenyl succinic anhydride and 1, 4-butanediamine through a reaction, so that the plastic has the antibacterial property, and meanwhile, the mechanical property is enhanced; the modified bamboo powder is prepared by reacting bamboo powder with a carboxyl-terminated composition, and the carboxyl-terminated composition comprises carboxyl-terminated polylactic acid and carboxyl-terminated polyamide. The toughness of the plastic is enhanced, and the mechanical property of the plastic is further enhanced.

The present invention uses commercially available 3-aminopropylsilane coupling agent, diallylamino polyether acrylate, and an alkylating agent, or γ-propanesultone, or γ-butyrolactone as raw materials, and through an aza-Michael addition reaction and a quaternization reaction, a multifunctional silane coupling agent containing one or more quaternary ammonium cations, or sulfobetaine, or carboxybetaine in its molecular structure is prepared, which is used for the surface modification of bioactive glass, and the bioactivity, antibacterial and antifungal properties, and hydrophilicity enhancement effects after the surface modification of bioactive glass are obtained.

The invention discloses a polytetrafluoroethylene film with high tensile strength and a preparation process thereof, and relates to the technical field of polytetrafluoroethylene films. The preparation method comprises the following steps: step 1, preparing a composite raw material: S1-1, sequentially putting a tetrafluoroethylene copolymer into acetone and methanol to be soaked, washed and dried; dispersing in a glycidyl methacrylate-methanol solution, and carrying out irradiation grafting in a nitrogen atmosphere; filtering, washing and drying to obtain an epoxy tetrafluoroethylene copolymer; s1-2, sequentially putting an epoxy tetrafluoroethylene copolymer and a composite filler into tetrahydrofuran, stirring for 24-48 hours at the temperature of 70-75 DEG C in a nitrogen atmosphere, filtering, washing and drying to obtain a composite raw material; 2, mixing polytetrafluoroethylene, the composite raw material and carboxylated polyphenylene sulfide to obtain a mixture; performing cold press molding and temperature-controlled sintering to obtain a basic film; 3, the basic film is subjected to turning forming and continuous rolling, and the polytetrafluoroethylene film is obtained.

The invention relates to the technical field of friction materials, and particularly discloses an electromagnetic brake friction material prepared from granules and a preparation process of the electromagnetic brake friction material in order to solve the problem that an existing electromagnetic brake friction plate is difficult to prepare or insufficient in performance. The reinforcing material comprises plasma modified aramid pulp, coupling modified composite mineral fibers, SiO2 coated tetrapod-like zinc oxide whiskers and carbon fiber-aluminum silicon whiskers; the filler comprises modified needle-like wollastonite and organic modified precipitated barium sulfate; the adhesive comprises boron-silicon synergistic modified phenolic resin and modified carboxy nitrile rubber. The raw materials are improved, and granules are prepared by adopting a mixing and crushing process, so that the content of an adhesive can be greatly reduced, meanwhile, the die filling efficiency can be improved, the die thickness and the high-temperature heat fading of the friction material can be reduced, a cold press molding process can be omitted, and the qualification rate of finished friction materials can be improved.

The invention belongs to the technical field of lithium ion batteries, and particularly relates to a self-repairing type lithium ion battery positive electrode adhesive, a preparation method, positive electrode slurry and a positive electrode plate. The adhesive comprises a mixed solvent, and a first copolymer serving as a main component and a second copolymer serving as a cross-linking agent are dissolved in the mixed solvent; the first copolymer is an acrylate-based multipolymer containing carboxyl or hydroxyl; the second copolymer is isocyanate terminated UPy functional polyurethane; the adhesive is in a liquid state at room temperature, when the adhesive is subjected to vacuum heat treatment at 60-180 DEG C, carboxyl or hydroxyl in main components of the adhesive reacts with isocyanate groups of a cross-linking agent to form amido bonds along with volatilization of a mixed solvent, and UPy groups are associated through quadruple hydrogen bonds to form dual dynamic cross-linking points. The method can effectively adapt to the volume change of the positive electrode material in the lithium removal / insertion process, and maintains the integrity of the electrode structure, thereby improving the cycling stability and rate capability of the lithium ion battery.

The invention belongs to the technical field of thin film capacitors, and particularly relates to a chemical grafting modified polypropylene capacitor film material and a preparation method and application thereof. According to the preparation method of the chemical grafting modified polypropylene capacitor film material, provided by the invention, diethylenetriamine ethyl acrylate with a plurality of specific groups such as amino groups and carboxyl groups and unsaturated double bonds is synthesized through esterification reaction, and the diethylenetriamine ethyl acrylate is introduced into a polypropylene material through chemical grafting to obtain chemical grafting modified polypropylene; the prepared polypropylene capacitor film material has the excellent properties of good compatibility, difficulty in film breakage, capability of adsorbing and removing residual moisture, difficulty in oxidation corrosion, excellent breakdown resistance and the like, and the preparation method is a preparation method of the high-performance polypropylene capacitor film material; therefore, the technical problem that a polypropylene capacitor film material prepared in the prior art is low in performance is solved.

The invention relates to the technical field of papermaking, and particularly provides high-strength tipping base paper for cigarettes and a preparation process of the high-strength tipping base paper. The tipping paper base paper for the cigarettes comprises a fiber raw material; functionalizing the nano cellulose; a cellulase; a dry strength agent; a wet strength agent; and a sizing agent. Nano cellulose is functionalized and a synergistic stepped enhancement mechanism is constructed, so that the synergistic breakthrough of the high-strength raw tipping paper for cigarettes in the aspects of strength, wet strength and air permeability is realized; after the functionalized nanocellulose is subjected to carboxylation treatment, the hydrogen bond and electrostatic adsorption between the functionalized nanocellulose and the fiber are enhanced, and the bonding strength in a dry state and a wet state is remarkably improved; meanwhile, the wet strength agent is added in stages, and the adsorption sequence of the dry strength agent is optimized, so that the reinforcing agent constructs a stable three-dimensional network framework in the paper sheet, and the end breaking risk under high-speed winding is effectively reduced.

The invention discloses nano-porous aerogel based on carboxymethyl chitosan as well as a preparation method and application of the nano-porous aerogel, and belongs to the technical field of biomass-based aerogel. The aerogel is prepared from the following raw materials in parts by weight: 2.5 parts of deionized water, 0.075 part of carboxymethyl chitosan (CMC), 0.0075 to 0.0225 part of carboxylated multi-walled carbon nanotubes (C-CNT), 0.01125 part of glutaraldehyde (GA), 0.01 part of poly (3, 4-ethylenedioxythiophene)-poly (styrene sulfonic acid) (PEDOT: PSS) and 10 parts of dimethyl sulfoxide (DMSO). According to the preparation method, CM C is used as a matrix, C-CNT is used as an internal conductive material and a strength enhancing material, hydrogel is formed under the action of a cross-linking agent GA, and CMC / C-CNT aerogel is prepared through directional freeze drying; cMC / C-CNT is taken as a substrate, then PEDOT: PSS is dip-coated to obtain CMC / C-CNT / PEDOT: PSS, the CMC / C-CNT / PEDOT: PSS is taken as an external conductive substance, the CMC / C-CNT / PEDOT: PSS and internal C-CNT form a double-conductive network, aerogel with excellent conductive performance and mechanical performance is prepared, the prepared aerogel is used for preparing an aerogel sensor, and the prepared sensor has high mechanical performance and high electrical performance.

The invention discloses a shielding protection adhesive tape for semiconductor integrated circuit packaging and a preparation method thereof, and relates to the technical field of semiconductor integrated circuit packaging. The shielding protective adhesive tape for packaging the semiconductor integrated circuit is prepared by taking polyimide as a base material and coating a coating, and the coating comprises the following raw materials in parts by weight: 3-5 parts of modified nano silicon dioxide, 30-40 parts of N, N-dimethylformamide, 1-3 parts of a curing agent and 1-3 parts of a curing agent. The invention discloses a high-temperature-resistant epoxy resin coating which is prepared from the following components in parts by weight: 25-30 parts of N, N-dimethylformamide, 25-30 parts of a modified acrylate copolymer, 17-26 parts of ethyl acetate, 12-15 parts of epoxy resin, 1-2 parts of a silane coupling agent KH-550, 0.5-1 part of an antioxidant 1010, 0.3-0.8 part of an ultraviolet absorbent UV-327, 1-2 parts of carboxyl-terminated nitrile rubber, 2-4 parts of decabromodiphenyl ether, 0.1-0.3 part of an organic siloxane defoaming agent, 0.2-0.5 part of an acrylate flatting agent and 10-11 parts of diaminodiphenyl sulfone. The adhesive tape contains the modified nano silicon dioxide, the modified acrylate copolymer and other components, so that the performance of the adhesive tape is guaranteed; pretreatment is meticulous, preparation steps are standard, and mass production is easy; a finished product can be effectively shielded, and the packaging yield and the product stability can be improved.

The invention relates to the technical field of PET geothermal films, and discloses a high-temperature-resistant geothermal film and a preparation method thereof.The high-temperature-resistant geothermal film is obtained through blending extrusion and blow molding of polyethylene glycol terephthalate, carboxyl polyetherimide and modified graphene. The carboxyl polyetherimide contains a benzoate structural unit similar to PET, the carboxyl polyetherimide and the benzoate structural unit form an alloy-like system with good compatibility, the modified graphene is good in dispersity and excellent in compatibility with PET, meanwhile, the modified graphene contains more carboxyl groups, and the carboxyl groups and carboxyl groups of side chains of the carboxyl polyetherimide interact with each other to form hydrogen bonds and the like; the graphene can be uniformly dispersed in a composite system of PET and carboxyl polyetherimide, so that a better reinforcing effect is achieved, and the tensile strength and the elongation at break of the PET composite geothermal film are remarkably improved. After high-temperature thermal aging, the geothermal film is high in retention rate of tensile strength and elongation at break and good in high-temperature resistance.

The invention discloses an active oxygen scavenging drug-loaded targeted nano delivery platform based on diselenide bond bridging as well as a preparation method and application thereof, and belongs to the technical field of biological medicines. According to the invention, tetra (4-carboxyphenyl) porphyrin (TCPP) and manganese porphyrin (Mn-TCPP) are used as raw materials to synthesize an organic metal framework MOFs, a target drug is loaded on the MOFs through electrostatic adsorption / blending, and amino and diselenide bonds are linked on the MOFs to realize combination with a specific peptide ligand and promote release of a drug oxidative stress microenvironment. The nano delivery platform with specific targeting and ROS response performance is obtained. The specific treatment effect of different diseases is achieved through different selections of the loaded drugs and the specific peptide ligands.

The present invention discloses a pH-responsive pesticide slow-release hydrogel sphere and a preparation method thereof, belonging to the technical field of slow-release pesticides. The present invention uses carboxylated nanocrystalline cellulose modified by polyethyleneimine as a raw material, which is self-assembled with modified montmorillonite through electrostatic binding, and then loaded with pesticides in an organic solvent. Then, sodium alginate is used as a coating material and anhydrous calcium chloride is used as a cross-linking agent to prepare a pH-responsive pesticide slow-release hydrogel sphere of nanocrystalline cellulose composite montmorillonite by dropping, which is used for the slow release of pesticides in the soil environment. Under the optimal conditions, the encapsulation rate of fipronil in the organic solvent by the hydrogel sphere of the present invention is above 64.1 wt%, and the loading rate is above 67.3 wt%. In the soil environment with different pH values, the highest release rate of pesticides after 120 h is above 59.7%, and the pesticide release rate increases with the increase of pH until the hydrogel skeleton completely breaks, and the purpose of adjusting the pesticide release rate can be achieved by adjusting the pH.

The invention discloses a fluorescent composite nano material as well as a preparation method and application thereof, and belongs to the technical field of fluorescent materials. The fluorescent composite nano-material provided by the invention comprises carbon quantum dots with carboxyl modified surfaces and fluorescent nano-particles with amino modified surfaces, wherein the mass ratio of the carbon quantum dots to the fluorescent nano-particles is (0.8-3): 1; the carbon quantum dots of which the surfaces are modified with carboxyl groups are connected with the fluorescent nanoparticles of which the surfaces are modified with amino groups through amido bonds formed by dehydration condensation of carboxyl groups and amino groups; the molecular formula of the fluorescent nanoparticles is Cs2NaYCl6: Yb < 3 + > / Eu < 3 + >, the molar concentration of doped Yb < 3 + > is 15-25%, and the molar concentration of doped Eu < 3 + > is 8-12%. The fluorescent composite nanomaterial provided by the invention has the advantages of uniform particle size and high fluorescence emission intensity, has good fluorescence stability, and can be applied to the fields of humidity detection, fluorescence imaging and the like.

The invention discloses an amphiphilic chitosan and plant nanocellulose composite coating fresh-keeping material, which is prepared from the following ingredients in percentage by mass: 0.5 to 20 percent of amphiphilic chitosan, 0.1 to 5.0 percent of plant nanocellulose, 0.5 to 10.0 percent of coalescing agents, 0.1 to 3.0 percent of antioxidants and the balance deionized water. Wherein the amphiphilic chitosan is prepared from chitosan, quaternary phosphonium salt and sorbic acid. Amphipathic chitosan of the material has hydrophilic groups such as amino and carboxyl and a sorbate hydrophobic group, has hydrophilicity and hydrophobicity at the same time, and is extremely easy to combine with substances such as a coalescing agent, plant nanocellulose and an antioxidant to form a stable polymeric membrane layer, so that the mechanical property after membrane formation is remarkably improved, and the material has a good application prospect. Meanwhile, the plant nanocellulose particles can be stably coated in the polymeric membrane material layer, so that the mechanical property of the material is enhanced, and lasting and efficient antibacterial and antioxidant effects are realized. The invention further discloses a preparation method and application of the amphiphilic chitosan and plant nanocellulose composite coating fresh-keeping material.

The invention relates to a dispersing agent for garnet type solid electrolyte and a preparation method thereof, a special powder dispersing agent for dispersing garnet type solid electrolyte (LLZO, Li7La3Zr2O12) in an ethanol or isopropanol system is a polycarboxylic acid-polyether colorless transparent viscous liquid copolymer, and the copolymer is anchored on the surface of powder particles through the strong adsorption effect of carboxyl, so that the dispersing agent can be used for dispersing the garnet type solid electrolyte (LLZO, Li7La3Zr2O12) in an ethanol or isopropanol system. Meanwhile, the polyether chain segment realizes solvent compatibility and steric hindrance effect, the preparation method for the dispersing agent is a controllable free radical polymerization method and specifically comprises dozens of specific steps and conditions, and the dispersing agent has the advantages that the grinding particle size of the garnet type solid electrolyte can be effectively reduced, stable dispersion of powder in slurry is realized, and the dispersing effect is good. Powder agglomeration is inhibited, and the grinding efficiency is improved, so that the mass production requirement of the high-safety solid-state lithium ion battery is met.

The invention discloses a UiO-66-(COOH) 2-Glu composite material for efficient recovery of lithium ions and application of the UiO-66-(COOH) 2-Glu composite material. A preparation method of the UiO-66-(COOH) 2 composite material comprises four steps of preparation of UiO-66-(COOH) 2, drying treatment, amino acid modification and separation and purification. The preparation process comprises the following steps: preparing a precursor UiO-66-(COOH) 2-Glu in an aqueous solution system under mild conditions, carrying out functional modification by introducing glutamic acid, and introducing amino groups and carboxyl groups in amino acid to enhance the selective adsorption performance of the UiO-66-(COOH) 2-Glu composite material on lithium ions, thereby obtaining the UiO-66-(COOH) 2-Glu composite material. The preparation process is green, environment-friendly and low in cost, traditional high-temperature and high-pressure conditions are avoided, the practicability of the material is remarkably improved, and the prepared material shows excellent lithium ion selective adsorption performance and shows excellent performance in the field of rapid recovery of lithium ions.

The invention relates to the technical field of electronic materials, in particular to a preparation method of low-halogen alkali-soluble photosensitive resin and solder resist ink. Comprising the following steps: adding amino resin, alcohol olefin and a catalyst A into a solvent, mixing, and carrying out an ether exchange reaction to obtain an initial etherified product; adding peroxide into the initial etherification product, and carrying out epoxidation reaction to obtain an epoxy resin intermediate; adding an olefine acid compound, a catalyst B and a polymerization inhibitor into the epoxy resin intermediate, and carrying out ring-opening esterification reaction to obtain an epoxy acrylate intermediate; and adding acid anhydride into the epoxy acrylate intermediate, and carrying out carboxylation reaction to obtain the low-halogen alkali-soluble photosensitive resin. The problem of high halogen content of the existing alkali-soluble photosensitive resin is solved, and the solder resist ink prepared from the alkali-soluble photosensitive resin has high sensitivity, high resolution, high heat resistance, high acid and alkali resistance and high electrical insulation property.

The invention relates to the technical field of metal amino acid chelate preparation, and discloses high-bioavailability magnesium glycinate and a preparation method thereof.The method comprises the steps that a glycine solution and a magnesium salt solution are mixed, the initial pH value is adjusted to be within the alkaline range, and a low-polarity organic phase is added to construct a two-phase solvent system; dynamically adjusting the pH value of the reaction system by stages, and sequentially inducing amino and carboxyl of glycine to chelate magnesium ions step by step to form a chelate; and blending the chelated product with a chitosan-sodium alginate composite carrier, and carrying out spray drying to obtain magnesium glycinate particles. The molar ratio of magnesium ions to glycine in the chelating structure of magnesium glycinate is 1: 3. Through the synergistic effect of dynamic pH regulation and a two-phase solvent system, directional synthesis of the magnesium glycinate 1: 3 high-coordination chelate is achieved, the bioavailability and the targeted slow release performance are remarkably improved by combining a composite carrier nano embedding technology, and meanwhile, the process is efficient and environmentally friendly.

The invention relates to a preparation method of a nanofiltration membrane, the nanofiltration membrane prepared by the preparation method and application of the nanofiltration membrane. The method comprises: treating a base membrane having a polyamide layer thereon to convert acyl chloride groups in the polyamide layer into carboxyl groups, the base membrane comprising a reinforcing material layer and a polymer layer; activating the carboxyl group, wherein the activating treatment is carried out by using a solution containing a carboxyl group activating agent; contacting with a solution containing amino polyethylene glycol substances; contacting with a solution comprising a cross-linking agent; contacting with a solution comprising at least one of a polyhydroxy polymer and a polyhydroxy compound. The method is simple and easy to operate, reaction parameters are easy to regulate and control, and continuous industrial production can be achieved. The nanofiltration membrane prepared by the invention has stable and excellent comprehensive performance (permeability, separation performance, pollution resistance, scratch resistance and thick net bruise resistance). The nanofiltration membranes of the invention can be advantageously used for filtration, separation, and / or concentration.

The invention provides a self-repairing hydrated salt phase change microcapsule as well as a preparation method and application thereof, and belongs to the field of phase change materials. The preparation method comprises the following steps: preparing a hydrated salt phase change material and sorbitol into eutectic melt by adopting a melting method; strontium carbonate, sorbitol grafted nano titanium dioxide, SiO2-coated silicone rubber microspheres, hollow Al2O3 microspheres, tannic acid microcapsules, alpha-zirconium phosphate, melamine polyphosphate, diethyl aluminum hypophosphite, carboxylated multi-walled carbon nanotubes, polydopamine modified boron nitride nanosheets and hydrophilic fumed silica are added into the eutectic melt, and blending is performed to obtain a core material; The preparation method comprises the following steps: adding strontium carbonate, sorbitol grafted nano titanium dioxide, SiO2-coated silicone rubber microspheres, hollow Al2O3 microspheres, tannic acid microcapsules, alpha-zirconium phosphate, melamine polyphosphate, diethyl aluminum hypophosphite, carboxylated multi-walled carbon nanotubes, polydopamine modified boron nitride nanosheets and hydrophilic fumed silica into the eutectic melt; bio-based polyurethane-polyurea is used as a shell material, the core material is coated in the shell to prepare the microcapsule, and the temperature of the coating operation is not higher than the phase change temperature of the hydrated salt phase change material; the surface is coated with a super-hydrophobic coating. According to the invention, a solid filler system is constructed, and a low-temperature preparation process is combined, so that the phase-change microcapsule with high performance, high reliability and high safety is developed.

The invention relates to the technical field of plastic material preparation, and discloses a modified bamboo fiber, a PBAT composite material and a plastic object. The modified bamboo fiber comprises bamboo fiber subjected to hot pressing treatment in water and a closed aziridine cross-linking agent loaded on the bamboo fiber, and the mass ratio of the bamboo fiber subjected to hot pressing treatment in water to the closed aziridine cross-linking agent is 100: (1-10). The PBAT composite material comprises the following components in parts by weight: PBAT and modified bamboo fibers, and the mass ratio of the PBAT to the modified bamboo fibers is 100: (20-40). The modified bamboo fiber is subjected to hot pressing treatment in water, so that the generation of volatile gas caused by high-temperature processing can be avoided when the modified bamboo fiber is applied to the plastic material, and the interface interaction with the plastic material can be improved; the closed aziridine cross-linking agent can release active groups at high temperature, and can react with active functional groups such as hydroxyl and carboxyl on the surfaces of the bamboo fibers and the surfaces of the plastic materials, so that the interface interaction between the bamboo fibers and the plastic matrix is improved, and the tensile strength of the composite material is improved.

The invention discloses a self-repairing nylon elastomer material as well as a preparation method and application thereof. The preparation method comprises the following steps: S1, polymerizing a nylon monomer in the presence of an amine end-capping reagent to prepare a double-amino-terminated nylon hard segment; s2, adding the double-amino-terminated nylon hard segment, the double-carboxyl-terminated polyether and / or polyester soft segment and a disulfide bond-containing chain extender into a reactor, adjusting the proportion of the raw materials, and polymerizing under an optional auxiliary A to obtain a double-amino-terminated pre-polymerized nylon elastomer; and S3, adding the double-amino-terminated pre-polymerized nylon elastomer and a dialdehyde chain extender into the reactor, and carrying out a reaction in the presence of an optional auxiliary agent B to obtain the self-repairing nylon elastomer material. According to the self-repairing nylon elastomer material provided by the invention, the nylon elastomer can be self-repaired in various environments through the synergistic effect of various dynamic covalent bonds, and the polymerization efficiency is remarkably improved.

The invention relates to the technical field of research and development of BIB liquid packaging materials, and discloses a PE-PA-based composite film, a manufacturing process and an application in BIB liquid packaging, and specifically comprises the following steps: synthesizing a PE-PA compatilizer; the preparation method comprises the following steps: carrying out ring-opening reaction on an epoxy functional group of a PE-PA compatilizer and an amino functional group or a carboxyl functional group at a PA resin molecular chain end to prepare PE-PA compatilizer grafted nylon resin, and carrying out physical anchoring action on a long-chain alkane structure on the PE-PA compatilizer grafted nylon resin and a PE resin molecular chain to prepare the PE-PA alloy master batch; low-density polyethylene resin is used as a raw material of a supporting layer, PE-PA alloy master batch is used as a raw material of a functional layer, metallocene polyethylene resin is used as a raw material of a heat sealing layer, a three-layer co-extrusion blow molding film forming technology is adopted, the PE-PA composite film is prepared, and the film product is excellent in comprehensive performance and can be used for manufacturing a BIB bag body.

The invention relates to the technical field of polyester fibers, and discloses a preparation method of antibacterial modified polyester hollow fibers, which comprises the following steps: by taking nitrilotriacetic acid, thionyl chloride, epoxy chloropropane, eugenol and the like as raw materials, carrying out acylating chlorination reaction, quaternization reaction and esterification reaction to obtain eugenol epoxy quaternary ammonium salt. The preparation method comprises the following steps: carrying out ring-opening reaction on carboxyl groups in graphene oxide and epoxy groups in eugenol epoxy quaternary ammonium salt to obtain modified graphene, uniformly mixing the modified graphene with polyethylene glycol terephthalate, and carrying out a series of steps to finally obtain the antibacterial modified polyester hollow fiber. Eugenol and quaternary ammonium salt are utilized to improve the antibacterial property of the polyester hollow fiber, and graphene is utilized to improve the mechanical property of the polyester hollow fiber. The polyester hollow fiber prepared by the invention has excellent mechanical properties and antibacterial properties.