8983 results about "Carboxylic group" patented technology

The invention belongs to the field of catalysts, and particularly relates to an alumina carrier as well as a preparation method and application thereof. The surface of the alumina carrier has oxygen-containing groups, and the density of the oxygen-containing groups on the surface of the alumina carrier is 0.15-5mmol / m < 2 >. Wherein the oxygen-containing group is at least one of hydroxyl, carboxyl and lactone group; the specific surface area of the alumina carrier is 10-150m < 2 > / g. The types, the number and the density of oxygen-containing groups on the surface of the obtained carrier are improved, and various index requirements of various supported catalysts on dispersion forms and dispersion degrees of different metal active components in the field of petrochemical engineering can be well met; and the carrier also has the characteristics of low bulk density, high water absorption rate, large pore volume and large average pore size, has a gain effect on uniform distribution of active metal components in the catalyst loading process, and has extremely high application value.

The invention discloses rubber powder grafted nano material composite modifier modified asphalt, a preparation method thereof and an asphalt mixture, and belongs to the technical field of modified asphalt. The modified asphalt is prepared by modifying a carboxylated nano material grafted with aminated rubber powder. According to the invention, the rubber powder and the nano material are grafted, so that the advantages of the rubber powder and the nano material can be fully played, the high temperature, low temperature, water stability and other properties of asphalt and asphalt mixtures are remarkably improved, and a new solution is provided for high performance and sustainable development of asphalt pavements; therefore, the method has good application prospect and value in the field of road engineering.

The invention relates to a high / low-temperature-resistant wear-resistant tear-resistant fluorosilicone rubber compound and a preparation method thereof, and belongs to the technical field of special rubber materials, the high / low-temperature-resistant wear-resistant tear-resistant fluorosilicone rubber compound comprises the following components: raw fluorosilicone rubber, a reactive liquid rubber compatibilizer, a reinforcing filler, a tear-resistant aid, a high-temperature-resistant aid, a vulcanizing agent, an accelerant, an anti-aging agent and an anti-attrition filler, the provided reaction type liquid rubber compatibilizer contains vinyl carboxyl liquid fluorosilicone rubber, the tear-resistant auxiliary agent contains zinc polymethacrylate, the high-temperature auxiliary agent contains vinyl fluorosilane modified carbon nanotubes, and the anti-friction filler contains molybdenum disulfide and layered nano zirconium phosphate which are treated by oxygen plasma. The high and low temperature resistance stability, oil resistance, wear resistance and tear strength of the fluorosilicone rubber are synergistically improved by regulating and controlling the multi-cross-linked network structure of the fluorosilicone rubber, strengthening the interface action of the rubber and the filler and optimizing the composite vulcanization system, meanwhile, structuralization of a rubber compound is prevented by optimizing the preparation process, and the requirement for adaptability to severe working conditions is met.

Methods, systems and devices for removing iodide from an aqueous solution including submerging an iodophilic electrode in an aqueous solution containing iodide, applying a current to the electrode, and electrochemically oxidizing the iodide to iodine within the electrode. The electrode may include an iodophilic material and an electrically conductive material. It may also include a binder. The iodophilic material may be a starch, chitosan, carboxycellulose, cationic polymer, or an anion exchange membrane material, for example. After oxidizing the iodide to iodine within the electrode, the electrode may be submerged in a second solution and a current may be applied to reduce the iodine and release it from the electrode in the form of iodide into the second solution.

The invention relates to the field of membrane materials, and discloses an epoxy modified starch-based degradable membrane and a preparation method thereof, the epoxy modified starch-based degradable membrane comprises epoxidized starch, modified nanocellulose and a plasticizer; the modified nano cellulose is prepared by mixing a modified composite filler, a nano cellulose dispersion liquid and a zinc acetate dihydrate aqueous solution; the nano-cellulose dispersion liquid is prepared by adhering polytannic acid formed by oxidation and self-polymerization of tannic acid to the surface of nano-cellulose; the modified composite filler is prepared by performing carboxylation modification on nano titanium dioxide coated fumed silica nanoparticles by using succinic anhydride and gamma-aminopropyltriethoxysilane, then reacting with polyethyleneimine to obtain an aminated composite filler, and finally grafting glycidyl dodecyl dimethyl ammonium chloride to the surface of the aminated composite filler. The prepared film material is high in tensile strength, has certain hydrophobicity, and has good heat resistance, antibacterial property and flame retardant property.

A solid electrolyte includes: LiaAbEc(SO4)dJeXfHh, A is selected from alkaline earth metals and alkali metals other than Li, E is selected from Al, Ga, In, Sc, Y, Ti, Zr, Hf, and lanthanides, J is selected from OH, BO2, BO3, BO4, B3O6, B4O7, CO3, NO3, AlO2, SiO3, SiO4, Si2O7, Si3O9, Si4O11, Si6O18, PO3, PO4, P2O7, P3O10, SO3, SO5, S2O3, S2O4, S2O5, S2O6, S2O7, S2O8, BF4, PF6, BOB, (COO)2, N, AlCl4, CF3SO3, CH3COO, CF3COO, OOC—(CH2)2—COO, OOC—CH2—COO, OOC—CH(OH)—CH(OH)—COO, OOC—CH(OH)—CH2—COO, C6H5SO3, OOC—CH═CH—COO, OOC—CH═CH—COO, C(OH)(CH2COOH)2COO, AsO4, BiO4, CrO4, MnO4, PtF6, PtCl6, PtBr6, PtI6, SbO4, SeO4, TeO4, HCOO, and O, X is selected from F, Cl, Br, and I, 0.5≤a<6, 0≤b<6,0<c<2,0.1<d≤6.0, 0<e≤6.0, 0<f≤6.1, and 0≤h≤0.2, and a peak is observed at a diffraction angle 2θ=22.3°±1.0° in an X-ray diffraction pattern in which Cu-Kα is used as a line source.

The invention relates to the technical field of PVC pipe production and processing, and particularly discloses a PVC pipe composition and a preparation method of a PVC pipe. PVC resin and PE resin are compounded, the problem of PVC decomposition caused by high temperature in the processing process is reduced, meanwhile, the PE resin has good flexibility, and by compounding the PVC resin and the PE resin, the PVC resin and the PE resin have good flexibility, so that the PVC pipe composition is more stable in performance. The mechanical property of the PVC pipe can be improved; 4-carboxyphenylboronic acid in the composite modified attapulgite provided by the invention forms a B-O-B cross-linked network structure at a high temperature, the 4-carboxyphenylboronic acid can have a synergistic effect with composite metal oxides (zinc oxide and manganese oxide), the thermal stability and compactness of a carbon layer are improved, and the flame retardant property of the PVC pipe is further improved; a flexible alkyl long-chain structure is formed through copolymerization of 1, 4-diol, reversible deformation occurs under the action of external force, and the mechanical property of the PVC pipe is further improved.

The invention relates to the technical field of polypropylene, and discloses a high-strength polypropylene composite material as well as a preparation method and application thereof in an automobile bumper. The high-strength polypropylene composite material comprises the following components in parts by weight: 70-90 parts of polypropylene resin, 10-30 parts of polycarbonate resin, 25-40 parts of glass fibers, 3-10 parts of an allyl carbonate grafted polypropylene compatilizer and the like. The compatilizer contains carbonate groups similar to polycarbonate, so that the compatibility between polypropylene resin and polycarbonate resin is improved, and the compatilizer has higher mechanical properties. Moreover, the compatilizer contains carboxyl and can form interaction with the surface of the glass fiber, so that the compatibility between the glass fiber and the polypropylene resin is improved, the glass fiber has a better reinforcing effect, the tensile strength, the impact strength and the bending strength of the composite material are remarkably improved, and the compatilizer has good practical application in the aspects of automobile bumpers and the like.

The invention discloses a hydrophilic polyacrylate / epoxy silica sol composite coating and a preparation method thereof. The composite coating is prepared from a polyacrylate epoxy silica sol solution containing carboxyl and a polyethylene glycol side chain through blending, coating, drying and heating crosslinking. The polyacrylate is synthesized by taking methyl methacrylate, methacrylic acid, hydroxyethyl methylacrylate and allyl polyethylene glycol as comonomers through a solution free radical copolymerization method, and the epoxy silica sol solution is prepared by taking tetraethoxysilane and gamma-glycidoxypropyltrimethoxysilane as raw materials through a solution polymerization method. The composite material is prepared through a sol-gel and core-shell preparation process. The preparation method comprises the following steps: carrying out solution blending on polyacrylate and epoxy silica sol, and carrying out coating, drying and other processes to generate the cross-linked polyacrylate / epoxy silica sol composite coating through a cross-linking reaction between carboxyl and epoxy. The prepared composite coating has the characteristics of long durability, wear resistance, hydrophilicity, antifogging, protein adsorption resistance and the like.

The invention discloses a medium-temperature curing high-temperature-resistant high-adhesion epoxy structural adhesive film as well as a preparation method and application thereof. The preparation method comprises the following steps: reacting high-rigidity diisocyanate with polyether polyol to obtain a polyurethane prepolymer, then adding bisphenol epoxy resin to carry out grafting reaction, and then adding carboxyl-terminated nitrile rubber to react with an epoxy group to obtain the high-temperature-resistant high-adhesion epoxy resin. And finally, mixing with a curing system and coating to obtain the intermediate-temperature curing high-temperature-resistant high-adhesion epoxy structural adhesive film. The preparation process disclosed by the invention is reasonable, and the high-temperature resistance of the adhesive film is remarkably improved by introducing high-rigidity groups such as naphthalene ring, biphenyl or p-benzene while the excellent processing property of the adhesive film is ensured; and through the synergistic effect of the polyurethane flexible chain segment and the nitrile rubber, the toughness and the adhesive property of a resin system are improved, and the loss of the resin in the forming process is reduced.

The invention relates to the technical field of fabrics, and discloses a preparation method of an anti-wrinkle comfortable fabric, which comprises the following steps: by taking alkyl diamine, acrylonitrile, gamma-chloropropyl methyl dimethoxy silane and the like as raw materials, carrying out addition reaction, hydrolysis reaction and quaternization reaction to obtain polycarboxyl disilane gemini quaternary ammonium salt; octamethylcyclotetrasiloxane, polycarboxyl disilane gemini quaternary ammonium salt and the like are used as raw materials, quaternary ammonium salt modified polysiloxane is obtained through base catalysis copolymerization, then the quaternary ammonium salt modified polysiloxane is emulsified and prepared into finishing liquid, pure cotton fabric is soaked in the finishing liquid, and the anti-wrinkle comfortable fabric is obtained through two-dipping and two-rolling finishing. The crease resistance of the fabric is improved by utilizing a large number of amino groups and carboxyl groups contained in the finishing liquid, and the antibacterial property of the fabric is improved by utilizing a quaternary ammonium salt structure contained in the finishing liquid. Experiments prove that the prepared fabric has good crease-resistant comfort performance and antibacterial performance.

The invention relates to the technical field of environmental materials and water treatment, in particular to a graphene amino silica gel composite adsorbent for heavy metal wastewater treatment and a preparation method thereof.The graphene amino silica gel composite adsorbent is prepared from # imgabs0 nanoparticles, an amino-functionalized silicon dioxide coating layer, carboxylated reduced graphene oxide, a polydopamine modification layer and tetraethyl orthosilicate; the coating is prepared from the following raw materials: 3-aminopropyltriethoxysilane, 3-mercaptopropyltrimethoxysilane, N-((4-vinyl benzyl) amino) diacetic acid, chitosan, beta-cyclodextrin, hexadecyl trimethyl ammonium bromide, polyethylene glycol, L-ascorbic acid, 1-ethyl-3-(3-dimethyl aminopropyl) carbodiimide hydrochloride and N-hydroxysuccinimide. The composite adsorbent shows excellent adsorption performance on various heavy metal ions, and the adsorption performance is far higher than that of traditional adsorption materials and existing composite adsorbents.

The invention discloses a waterproof anticorrosive coating and a preparation method and application thereof, and relates to the technical field of coatings, and the waterproof anticorrosive coating is prepared from the following raw materials in parts by weight: 30-40 parts of carboxyl-terminated hyperbranched polyester resin, 20-30 parts of carboxyl-terminated functional polyamide, 10-15 parts of hyperbranched polyurethane containing epoxy groups, 15-20 parts of filler, 1-3 parts of (3, 6-diamino acridine-9-yl) boric acid, 1-3 parts of 1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5- the component A is prepared from the following components in parts by weight: 3-5 parts of 2, 3, 5-triglycidyl-S-triazinetrione, 1-2 parts of a coupling agent, 0.8-1.2 parts of a flatting agent and 0.6-1.3 parts of a defoaming agent; the carboxyl-terminated functional polyamide comprises a structural unit introduced by the following monomers: N-(4H-1, 2, 4-triazole-4-yl) diphenylamine-4, 4 '-dicarboxylic acid, and 3, 3'-diamino-4, 4 '-difluorodiphenyl sulfone. The coating is good in waterproof and anti-corrosion performance, high in adhesive force with a base material, sufficient in solvent resistance and aging resistance and long in service life.

The invention discloses a bamboo powder-containing biodegradable plastic for food contact and a preparation method thereof, and relates to the technical field of bio-based materials. The bamboo powder-containing biodegradable plastic for food contact comprises chitosan starch and modified bamboo powder, the chitosan starch is prepared by adding composite chitosan and amino-terminated polyethylene glycol into oxidized corn starch, and the composite chitosan is prepared by grafting chlorogenic acid on the surface of chitosan and then coating succinic anhydride derivatives. The succinic anhydride derivative is prepared from dodecenyl succinic anhydride and 1, 4-butanediamine through a reaction, so that the plastic has the antibacterial property, and meanwhile, the mechanical property is enhanced; the modified bamboo powder is prepared by reacting bamboo powder with a carboxyl-terminated composition, and the carboxyl-terminated composition comprises carboxyl-terminated polylactic acid and carboxyl-terminated polyamide. The toughness of the plastic is enhanced, and the mechanical property of the plastic is further enhanced.

The invention relates to a rubber blend, to a sulfur-crosslinkable rubber mixture comprising the rubber blend and to a vehicle tire comprising such a rubber mixture.The rubber blend comprisesat least one solution-polymerized diene polymer A of high molecular weight andat least one solution-polymerized polymer B of low molecular weight,wherein at least one of polymers A and B has been functionalized at the chain end and / or along the polymer chain and / or at a coupling site with at least one group selected from epoxy groups, hydroxyl groups, carboxyl groups, silane sulfide groups, amino groups, siloxane groups, organosilicon groups, phthalocyanine groups and amino group-containing alkoxysilyl groups.

The invention provides a leaching agent for removing thallium and beryllium in lithium slag and application. The leaching agent comprises a first leaching agent and a second leaching agent. The first leaching agent is an organic acid solution, and organic acid comprises carboxyl and at least one group of hydroxyl, sulfydryl, carbonyl and sulfonic acid group; the organic acid is single organic acid or mixed organic acid; the second leaching agent comprises a cationic agent and a reducing agent, the cationic agent can form at least one of K < + >, NH4 < + >, Mg < 2 + >, Na < + > and Fe < 3 + > in an aqueous solution, and the reducing agent comprises an inorganic reducing agent and / or an organic reducing agent. Organic acid in the first leaching agent can destroy the crystal structure of the lithium slag, and meanwhile groups such as carboxyl and hydroxyl can be complexed with thallium and beryllium ions so that the thallium and beryllium ions can be dissolved out more easily. On the basis, cations in the second leaching agent and the reducing solution accelerate the release of thallium and beryllium through ion exchange and reduction effects. The leaching agent can remove thallium and beryllium in the lithium slag at the same time, and the removal rate of thallium and beryllium is high.

The present invention uses commercially available 3-aminopropylsilane coupling agent, diallylamino polyether acrylate, and an alkylating agent, or γ-propanesultone, or γ-butyrolactone as raw materials, and through an aza-Michael addition reaction and a quaternization reaction, a multifunctional silane coupling agent containing one or more quaternary ammonium cations, or sulfobetaine, or carboxybetaine in its molecular structure is prepared, which is used for the surface modification of bioactive glass, and the bioactivity, antibacterial and antifungal properties, and hydrophilicity enhancement effects after the surface modification of bioactive glass are obtained.

The invention relates to the technical field of nylon 6, and discloses a carbon nanotube grafted ABS modified nylon 6 composite material, acylating chlorinated carbon nanotubes and lysine are subjected to an amidation reaction, double bonds on ABS and double bonds on maleic anhydride are combined, anhydride modified ABS and amino modified carbon nanotubes are subjected to a ring-opening reaction, and the carbon nanotube grafted ABS modified nylon 6 composite material is obtained. The carbon nanotubes are grafted to the ABS, agglomeration of the carbon nanotubes is avoided, the carbon nanotubes can form a uniform network structure under the action of external force, a large amount of external force is absorbed, the toughness of a matrix is improved, a large amount of carboxyl introduced to the surface of the ABS plastic and amide groups in the nylon 6 matrix are subjected to hydrogen-bond interaction, a three-dimensional hydrogen-bond network is formed, and the toughness of the matrix is improved. According to the present invention, the compatibility and the interfacial force between the nylon 6 and the carbon nano-tube grafted ABS are improved, such that the nylon 6 and the carbon nano-tube grafted ABS can be uniformly distributed so as to form the sea island structure, and can buffer more stress effects under the action of the external force, such that the obtained composite material has excellent toughness.

The invention belongs to the field of electrode paste preparation, and provides low-temperature curing silver-coated copper paste for a heterojunction solar cell and a preparation method of the low-temperature curing silver-coated copper paste. Ethyl cellulose is adopted as a matrix material, a stable matrix network is provided for slurry through good cohesiveness and dispersity of ethyl cellulose, and a network structure with a high crosslinking degree is formed by adding modified phenolic resin, organic silicon modified epoxy acrylate and other chemical modification materials into the slurry. The mechanical strength and adhesive force of the slurry are further enhanced, surface modification is carried out on inorganic filler such as silver-coated copper powder and bismuth oxide through a silane coupling agent and a titanate coupling agent, and the interface bonding force between the filler and an organic matrix is enhanced through silicon-oxygen bonds formed on the surface of the filler; by adding the carboxylated polyamide wax and the organic bentonite, the agglomeration tendency of the filler is reduced by utilizing the adsorption and electrostatic repulsion effects of the carboxylated polyamide wax and the organic bentonite on filler particles, and the obtained conductive slurry has the characteristics of excellent conductivity and low-temperature rapid curing.

The invention discloses a polytetrafluoroethylene film with high tensile strength and a preparation process thereof, and relates to the technical field of polytetrafluoroethylene films. The preparation method comprises the following steps: step 1, preparing a composite raw material: S1-1, sequentially putting a tetrafluoroethylene copolymer into acetone and methanol to be soaked, washed and dried; dispersing in a glycidyl methacrylate-methanol solution, and carrying out irradiation grafting in a nitrogen atmosphere; filtering, washing and drying to obtain an epoxy tetrafluoroethylene copolymer; s1-2, sequentially putting an epoxy tetrafluoroethylene copolymer and a composite filler into tetrahydrofuran, stirring for 24-48 hours at the temperature of 70-75 DEG C in a nitrogen atmosphere, filtering, washing and drying to obtain a composite raw material; 2, mixing polytetrafluoroethylene, the composite raw material and carboxylated polyphenylene sulfide to obtain a mixture; performing cold press molding and temperature-controlled sintering to obtain a basic film; 3, the basic film is subjected to turning forming and continuous rolling, and the polytetrafluoroethylene film is obtained.

The invention relates to the technical field of adsorbents, in particular to modified sodium alginate as well as a preparation method and application thereof. The modified sodium alginate is prepared from the following raw materials: sodium alginate, an activating agent, a sulfhydrylation reagent, a carboxylic acid compound containing unsaturated double bonds and an initiator. Natural polysaccharide sodium alginate is adopted as a raw material, the natural polysaccharide sodium alginate is wide in source, non-toxic and biodegradable, a functional group carboxyl is introduced into sodium alginate through a thiol-ene click reaction, adsorption active sites on the surface of the modified sodium alginate are increased, methylene blue and ciprofloxacin in water can be effectively adsorbed and removed, and the service life of the modified sodium alginate is prolonged. And after multiple times of cyclic adsorption-desorption, relatively good adsorption performance can be maintained.

The invention relates to the technical field of friction materials, and particularly discloses an electromagnetic brake friction material prepared from granules and a preparation process of the electromagnetic brake friction material in order to solve the problem that an existing electromagnetic brake friction plate is difficult to prepare or insufficient in performance. The reinforcing material comprises plasma modified aramid pulp, coupling modified composite mineral fibers, SiO2 coated tetrapod-like zinc oxide whiskers and carbon fiber-aluminum silicon whiskers; the filler comprises modified needle-like wollastonite and organic modified precipitated barium sulfate; the adhesive comprises boron-silicon synergistic modified phenolic resin and modified carboxy nitrile rubber. The raw materials are improved, and granules are prepared by adopting a mixing and crushing process, so that the content of an adhesive can be greatly reduced, meanwhile, the die filling efficiency can be improved, the die thickness and the high-temperature heat fading of the friction material can be reduced, a cold press molding process can be omitted, and the qualification rate of finished friction materials can be improved.

The invention belongs to the technical field of lithium ion batteries, and particularly relates to a self-repairing type lithium ion battery positive electrode adhesive, a preparation method, positive electrode slurry and a positive electrode plate. The adhesive comprises a mixed solvent, and a first copolymer serving as a main component and a second copolymer serving as a cross-linking agent are dissolved in the mixed solvent; the first copolymer is an acrylate-based multipolymer containing carboxyl or hydroxyl; the second copolymer is isocyanate terminated UPy functional polyurethane; the adhesive is in a liquid state at room temperature, when the adhesive is subjected to vacuum heat treatment at 60-180 DEG C, carboxyl or hydroxyl in main components of the adhesive reacts with isocyanate groups of a cross-linking agent to form amido bonds along with volatilization of a mixed solvent, and UPy groups are associated through quadruple hydrogen bonds to form dual dynamic cross-linking points. The method can effectively adapt to the volume change of the positive electrode material in the lithium removal / insertion process, and maintains the integrity of the electrode structure, thereby improving the cycling stability and rate capability of the lithium ion battery.

The invention discloses a waterborne acrylic acid-polyurethane composite emulsion, a waterborne acrylic acid-polyurethane composite paint, and a preparation method and application of the waterborne acrylic acid-polyurethane composite emulsion. According to the preparation method of the water-based acrylic acid-polyurethane composite emulsion, a core-shell structure polyacrylic acid-polyurethane emulsion is synthesized in situ by utilizing a core-layer monomer pre-emulsion and a shell-layer monomer pre-emulsion through a semi-continuous seed emulsion polymerization method. The shell layer of the core-shell structure has hydrophilic functional groups including carboxyl, sulfo group and hydroxyl, so that the emulsion has a self-thickening effect, and rheological properties and good constructability required by the coating can be provided. A nonionic hydrophilic group composite sodium sulfonate type post chain extender is selected as waterborne polyurethane, the emulsifying capacity is high, the emulsion stability is good, strong-acid monomers such as acrylic acid and methacrylic acid can be selected, high-thixotropy resin can be obtained through adjustment, meanwhile, the PA content can be effectively increased, the water resistance and weather resistance of a paint film can be improved, and the water resistance and weather resistance of the paint film can be improved. Therefore, the requirements of the automobile paint on moisture resistance, especially high-pressure flushing resistance, are met.

The invention relates to the technical field of pressure-sensitive adhesives, in particular to a high-temperature-resistant high-impedance pressure-sensitive adhesive, a supporting film and a preparation method of the supporting film. A styrene-butadiene-styrene block copolymer (SBS) is used as a main body material, an acrylic copolymer with high carboxyl content is grafted in a solvent in a thermal initiation mode, the high-temperature-resistant and high-impedance pressure-sensitive adhesive is obtained after the high-temperature-resistant and high-impedance pressure-sensitive adhesive is compounded with tackifying resin, a curing agent and an antioxidant, and after optical-grade PET is coated with the high-temperature-resistant and high-impedance pressure-sensitive adhesive, the high-temperature-resistant and high-impedance pressure-sensitive adhesive is obtained. According to the novel supporting film, the polarity of the SBS main body material is low, the excellent electrical insulation performance is provided, the supporting film body has the characteristic of high impedance, and therefore the requirement for high impedance of the supporting film in a copper bar friction experiment is met; in addition, after the acrylic copolymer with high carboxyl content is grafted, a large number of crosslinking points can be provided, and the overall crosslinking degree is greatly increased after thermocuring, so that the high-temperature modulus of the adhesive layer is improved, and the adhesive layer is endowed with the characteristic of high-temperature deformation resistance.

The invention belongs to the technical field of thin film capacitors, and particularly relates to a chemical grafting modified polypropylene capacitor film material and a preparation method and application thereof. According to the preparation method of the chemical grafting modified polypropylene capacitor film material, provided by the invention, diethylenetriamine ethyl acrylate with a plurality of specific groups such as amino groups and carboxyl groups and unsaturated double bonds is synthesized through esterification reaction, and the diethylenetriamine ethyl acrylate is introduced into a polypropylene material through chemical grafting to obtain chemical grafting modified polypropylene; the prepared polypropylene capacitor film material has the excellent properties of good compatibility, difficulty in film breakage, capability of adsorbing and removing residual moisture, difficulty in oxidation corrosion, excellent breakdown resistance and the like, and the preparation method is a preparation method of the high-performance polypropylene capacitor film material; therefore, the technical problem that a polypropylene capacitor film material prepared in the prior art is low in performance is solved.

The invention belongs to the technical field of materials, and particularly relates to a modified TB polymer, a preparation method and application of the modified TB polymer in an aluminum alloy surface coating. The prepared modified TB polymer has a structure as shown in a formula I, is used as a flexibilizer component in an aluminum alloy surface coating, can provide a large number of hydrophilic hydroxyl or carboxyl groups which are easily subjected to an activation reaction with a metal surface, and improves the adhesive force of the coating; meanwhile, the group can also improve the dispersity of the filler, so that the coating is more uniform, the stress effect of the coating can be improved, and the coating has better flexibility. In addition, a modified TB polymer is introduced into the coating, so that the prepared coating is green and environment-friendly, excellent in salt fog resistance and chemical corrosion resistance, capable of adapting to a complex marine environment, capable of well protecting metal materials and capable of prolonging the service life of the metal materials. And # imgabs0 # I is adopted.

The invention relates to the technical field of composite pipes, and discloses a wear-resistant acid-corrosion-resistant environment-friendly anti-explosion PE pipe. The pipe adopts a multi-layer co-extrusion structural design, and comprises a wear-resistant inner layer, a reinforced middle layer and a protective outer layer. High-density polyethylene is used as a base material, silicon carbide particles and aluminum oxide particles with the surfaces subjected to multifunctional modification are combined to serve as reinforcing filler, and functional polyethylene is used as a base interface modification material, so that the problems that in a traditional pipe, particles and a base interface are low in bonding force, uneven in dispersion, prone to falling off and the like are solved. Carboxyl and unsaturated double bonds are introduced into the functionalized polyethylene through a maleic anhydride grafting technology, so that efficient chemical combination of particles and a matrix is realized, and the mechanical property and the chemical stability of the composite material are improved. The inner layer enhances wear resistance through high particle content, the middle layer provides support and corrosion resistance, and the outer layer improves weather resistance and protection performance of the pipe.

The invention provides a perfluoroether rubber sealing element and a preparation method thereof, and the preparation method comprises the following steps: taking tetrafluoroethylene and perfluoroalkyl vinyl ether as comonomers, and carrying out emulsion polymerization under the condition of a vulcanization point monomer and a chain transfer agent to obtain raw perfluoroether rubber; the preparation method comprises the following steps: mixing the raw perfluoroether rubber, the carboxyl fluorinated modified carbon nanotubes, a filler, a vulcanizing agent and an accelerant, and performing first-stage vulcanization and second-stage vulcanization to obtain the perfluoroether rubber sealing element. According to the perfluoroether rubber sealing element and the preparation method thereof provided by the invention, the compressive deformation resistance of the perfluoroether rubber sealing element is improved by adding the carboxyl fluorinated modified carbon nanotubes, so that the sealing element is ensured to meet the sealing requirement of semiconductor equipment.

The invention provides a gas for plasma etching, a gas combination, an etching method and semiconductor equipment, which belong to the field of plasma etching, and are mainly characterized in that one or more of carbonyl halide, aldehyde halide and carboxyl halide are provided as process gases in the etching process to excite and form plasma, and the plasma is used as a plasma source. According to the method, the to-be-etched layer is etched, so that the problem of upper and lower inconsistency caused by large difference between the bottom etching rate and the middle etching rate when a high-aspect-ratio hole or groove is formed by etching to a certain degree is solved, the morphology of high-aspect-ratio etching is remarkably improved, the collimation is ensured, and the effectiveness of the semiconductor structure is improved.