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83 results about "Carboxycellulose" patented technology

Method for preparing composite fibers in ionic liquid medium

The invention discloses a method for preparing composite fibers in an ionic liquid medium. The method comprises the following steps: (1) oxidating cellulose into carboxyl cellulose in an oxidation system prepared from ionic liquid, nitric acid and NaNO2, and preparing a carboxyl cellulose solution; (2) subjecting silkworm cocoons to soda boiling, degumming, LiBr dissolving, dialysis and vacuum freeze drying so as to obtain silk fibroin, and then, preparing a silk fibroin solution in ionic liquid; (3) grafting the carboxyl cellulose to the silk fibroin in ionic liquid, thereby obtaining the composite fibers. According to the method, the ionic liquid serves as a solvent, cellulosic materials and the silkworm cocoons serve as raw materials, the chemical principle of amidation reaction is adopted, the preparation process is simple, the reaction is green, environment-friendly and pollution-free, the ionic liquid solvent can be recovered and reused through rotary-evaporation drying, and the recovery rate reaches 98%. The reaction system only needs an isothermal reaction of 1 to 2 hours, the percentage of grafting of the cellulosic materials reaches 21% to the maximum, and the composite fibers are excellent in mechanical properties, crinkle resistance, wear resistance and hygroscopic property and are degradable and reproducible.
Owner:JIANGSU UNIV OF SCI & TECH

High-carboxyl-substituted hairy cellulose nanocrystal and preparation method thereof

PendingCN113754786AIncrease contentPromotes selective oxidationMaterial nanotechnologyBiopolymerChain scission
The invention relates to the field of biopolymer materials, and particularly discloses a highly substituted carboxyl cellulose nanocrystal and a preparation method thereof. The preparation method comprises the steps: dispersing plant cellulose in deionized water, firstly oxidizing by using a TEMPO/NaClO/NaClO2 oxidation system, then carrying out ultrasonic treatment, adding periodate for oxidation, adding a sodium chloride-sodium chlorite-hydrogen peroxide multi-element oxidant, carrying out stirring reaction at room temperature, and finally carrying out heating treatment to obtain a final product. According to the method, carboxyl substitution is controlled in an amorphous region of cellulose by adopting a step-by-step oxidation method, so that the carboxylation substitution degree is improved, and then chain scission is performed on the carboxylated cellulose in the amorphous region through thermal degradation, so that the hairy cellulose nanocrystal with amorphous carboxylated cellulose at two ends is formed. The surface carboxyl content, the carboxyl substitution degree and the like of the nanocellulose crystal are remarkably improved, the operation process is simple and convenient, pollution is avoided, and large-scale popularization and production can be achieved.
Owner:SOUTH CHINA UNIV OF TECH

Preparation method for three-dimensional network structure flocculation material structured by bacterial cellulose

The invention discloses a preparation method for a three-dimensional network structure flocculation material structured by bacterial cellulose. The preparation method comprises the steps that a bacterial cellulose material is dissolved and is modified after sodium periodate and ethylene glycol are added, and carboxyl cellulose is generated; then the three-dimensional network structure flocculation material is obtained after processing and drying; and then the three-dimensional network structure flocculation material is added into waste water to conduct a flocculation application experiment. The preparation method has the advantages that operation is easy, material sources are extensive and cost is low, and the application range is wide. According to the preparation method, the bacterial cellulose is used as a raw material of the flocculation material, so that the bio-degradable material is fully utilized and secondary pollution to the environment is reduced; and meanwhile, material-dependence on oil resources is reduced greatly. The prepared three-dimensional network structure flocculation material can be applied to waste water treatment such as industrial waste water and domestic waste water treatment, and has important economy and social environment benefits.
Owner:JIAXING SAIWEI ENVIRONMENTAL PROTECTION TECH CO LTD
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