The invention discloses a preparation method for treating
bagasse to obtain hard carbon, application of the hard carbon and a
sodium-
ion battery negative
electrode, and relates to the field of
sodium-
ion batteries. The preparation method of the
bagasse-based hard carbon comprises the following steps: crosslinking
lignin and
cellulose in the
bagasse-based hard carbon by using an acid solution, and partially stripping ash of
biomass. And stripping
hemicellulose of the bagasse by using a
weak base solution to
expose cellulose. By regulating and controlling the concentration, the
treatment time and the treatment temperature of the alkali solution, reasonable
lignin is reserved in the
cellulose, so that regulation and control of a plain pore structure in the
carbonization process are promoted. After the alkali
solution treatment, a
hydrochloric acid solution is used for cleaning the
solid, and
freeze drying is carried out, so that a proper pore structure is reserved. And then carrying out high-temperature heat treatment in a protective
atmosphere, wherein the heat treatment is carried out in three stages. The reaction process is a cellulose deoxidation process, the treatment temperature is 300-400 DEG C, and primary
carbonization of cellulose is realized; secondly, carbonizing, namely further deoxidizing after primary
carbonization, wherein a large number of C = C / C-C bonds are formed at the treatment temperature of 800-1000 DEG C; and finally, forming a hard
carbon graphite layer, wherein the treatment temperature is 1300-1500 DEG C. The bagasse-based hard carbon prepared by the preparation method can be efficiently and stably circulated in a
sodium ion battery, and shows excellent rate capability.