1022 results about "Functional monomer" patented technology

The invention relates to the technical field of oil-displacing agents, and particularly discloses a targeted nano oil-displacing agent and a preparation method thereof. A preparation method of a targeted nano oil displacement agent comprises the following steps: S1, dispersing 10-30 parts by mass of silanized inorganic nanoparticles in an alcoholic solution, adding 5-12 parts by mass of a functional monomer, 8-20 parts by mass of a hydrophilic monomer and 5-15 parts by mass of a hydrophobic monomer in an inert atmosphere, uniformly mixing, heating to 75-85 DEG C, adding an initiator, carrying out a constant temperature reaction for 4-6 h, and cooling to obtain a pre-grafted nanoparticle dispersion liquid; s2, mixing the pre-grafted nanoparticle dispersion liquid with a composite surfactant, adjusting the pH value to 6.5-7.5, and mixing at 30-40 DEG C for 22-26 hours to obtain the targeted nano oil displacement agent, the targeting type nano oil displacement agent prepared by the invention can still keep excellent dispersion stability and ultralow interfacial tension under the condition of a high-salt oil reservoir, so that the oil displacement efficiency is remarkably improved.

The invention discloses a dynamic borate bond-based self-healing polyacrylic acid binder and a preparation method thereof. The dynamic borate bond-based self-healing polyacrylic acid binder comprises a polymer main chain and a dynamic cross-linking agent, the dynamic cross-linking agent is a polyol compound containing at least two pairs of ortho-hydroxyl groups; the polymer main chain is formed by copolymerizing the following monomers: an acrylic structural monomer, the molar fraction of which accounts for 85-94% of the total monomer; a functional monomer containing a boric acid group, wherein the molar fraction of the functional monomer accounts for 3-8% of the total monomer; the mole fraction of the flexible monomer containing the acrylate group accounts for 3-8% of the total monomer. Various stresses generated by different negative electrode materials in circulation can be effectively adapted and buffered through a network formed by dynamic boric acid ester bonds and reversible fracture and combination of the boric acid ester bonds, so that the service life of the battery is generally prolonged, the working temperature range of the battery can be remarkably widened, the low-temperature discharge capacity can be remarkably increased, and the high-temperature cycle life can be prolonged.

The invention discloses a preparation method of a grafted and substituted thiophene polymer material, which comprises the following steps: mixing poly (3-hexylthiophene), a grafting monomer, a catalyst and an auxiliary agent, and heating for reaction to obtain the grafted and substituted thiophene polymer material, the structural formula of the grafting monomer is as shown in formula (I); wherein B is fluorine, chlorine, bromine or iodine, A is a carbon atom or a nitrogen atom, and R is cyano, formyl, methoxycarbonyl or; according to the method, pre-synthesis of complex functional monomers is avoided, the main chain of the poly (3-hexylthiophene) can be directly modified without using an expensive catalyst or ligand, the polymerization reaction of the poly (3-hexylthiophene) is not interfered, and meanwhile, the method has the advantages of simplified steps and low cost.

The invention discloses a solvent-free vanillin-hydroxyethyl acrylate double-system closed waterborne polyurethane emulsion adhesive as well as a preparation method and a use method thereof, and belongs to the field of waterborne polyurethane emulsion adhesives. The invention is mainly prepared from the following components in parts by weight: 40 to 50 parts of soft segment monomer, 50 to 60 parts of hard segment monomer, 20 to 40 parts of sealing agent, 0.02 to 0.15 part of catalyst, 0.4 to 0.6 part of emulsifier, 0.2 to 0.6 part of initiator, 4 to 12 parts of neutralizer, 5 to 15 parts of functional monomer and 340 to 360 parts of deionized water. According to the double-system closed waterborne polyurethane emulsion adhesive disclosed by the invention, rapid crosslinking curing of the adhesive can be realized through thermocuring, the highest hardness of an adhesive layer can reach about 26 MPa, the adhesive strength is high, and the mechanical property is relatively good.

The invention relates to the technical field of adsorption materials, and discloses a post-modified imine-COF adsorbent and a preparation method and application thereof, the adsorbent comprises the following structural units: a COF skeleton, which is a two-dimensional or three-dimensional porous skeleton formed by an aromatic aldehyde monomer and an amino monomer through a Schiff base reaction; the imine group is formed in a COF skeleton through a post-modification reaction, and the imine group is-C = NR, r is selected from one or more of a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkenyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted heterocyclic group and a hydrogen atom. The adsorbent retains excellent structural characteristics of the COF material, realizes high density and uniform distribution of functional groups, and avoids interference of functional monomers on crystal nucleation and growth, so that the adsorption performance of the adsorbent is improved, and the adsorbent can efficiently capture rare earth when being applied to a rare earth-containing solution.

A preparation method for a dual-enhanced interface solid polymer electrolyte by means of step-by-step polymerization, the preparation method comprising: mixing a matrix monomer and a first photoinitiator to obtain a mixed slurry, and illuminating same to obtain a pre-polymerized slurry; adding a lithium salt and a second photoinitiator to the pre-polymerized slurry, mixing same to obtain a polymer slurry, dividing the polymer slurry into a first polymer slurry and a second polymer slurry, adding a nitrogen-containing functional monomer to the first polymer slurry to obtain a polymer slurry A, and adding a fluorine-containing functional monomer to the second polymer slurry to obtain a polymer slurry B; and pouring the polymer slurry A on a first face of a base membrane, performing a treatment on same, pouring the polymer slurry B on a second face of the base membrane, and performing a treatment on same, so as to obtain a stepwise-polymerized dual-enhanced interface solid polymer electrolyte. The solid polymer electrolyte is prepared by means of using a step-by-step polymerization method, thereby optimizing a positive electrode side interface and a negative electrode side interface, and realizing continuous large-scale production of a solid polymer electrolyte.

The invention belongs to the technical field of oil field drilling, and particularly relates to a preparation method of modified sulfonated phenolic resin for drilling fluid, and the modified sulfonated phenolic resin is prepared by chemically bonding a functional monomer simultaneously containing sulfonic acid anions and quaternary ammonium cations in a phenolic resin structure in a free radical polymerization mode. The quaternary ammonium cation group adsorbs negatively-charged clay particles, the adamantyl group can be adsorbed in hydrophobic areas of the clay particles through association, and the sulfonated phenolic resin can be quickly adsorbed on the surface of the clay in a double adsorption mode of hydrogen bonds and electrostatic attraction. Besides, a large number of sulfonic acid anions can form a compact solvation layer after hydration, and a compact coating film can be formed when phenolic resin is quickly adsorbed on the surface of clay, so that the clay is prevented from being in contact with water, the stability of clay particles is realized, a compact mud cake can be formed, and the prepared phenolic resin has good filtrate loss reduction performance.

The invention belongs to the field of biomedical materials, and discloses a hydrogel patch with piezoelectricity, conductivity and high adhesion and a preparation method and application of the hydrogel patch. Polyvinyl alcohol (PVA) and acrylic acid (AA) serve as polymer frameworks of the hydrogel patch; the invention relates to a nano-zinc oxide / poly (3, 4-ethylenedioxythiophene) / poly (styrenesulfonic acid) (PEDOT: PSS) composite conductive adhesive, which comprises nano-zinc oxide (ZnO) as a piezoelectric material, poly (3, 4-ethylenedioxythiophene)-poly (styrenesulfonic acid) (PEDOT: PSS) as a conductive material, and N-hydroxysuccinimide acrylate (NHS-AA) as an adhesive functional monomer. According to the invention, active ester groups in the N-hydroxysuccinimide acrylate are utilized, so that the patch can quickly form covalent amido bonds with amino groups on the surface of a tissue in a dry state, firm adhesion is realized, local nerve repair can be effectively promoted through a piezoelectric effect, a novel ideal material is provided for disease treatment, and the patch has wide application prospects. Wide clinical application prospects are realized in the field of biological medicines.

The invention discloses a super-tough temperature-resistant self-repairing copolymer based on SBS acrylate dynamic synergistic reinforcement and a preparation method thereof, and belongs to the technical field of self-repairing materials in compositions of high-molecular compounds. The copolymer comprises SBS, an acrylate monomer, a dynamic bond functional monomer, an initiator, a cross-linking agent, a nano reinforcing agent and a temperature-resistant modifier, wherein the dynamic bond functional monomer comprises at least one of acryloyloxyethyl disulfide, acrylamide acryloyloxyethyl disulfide or anthracene methyl acrylate. The molecular structure of the dynamic bond functional monomer contains a carbon-carbon double bond and a disulfide bond, in the free radical polymerization reaction initiated by the initiator, the carbon-carbon double bond is opened and is subjected to a copolymerization reaction with an SBS chain segment or an acrylate chain segment, so that the disulfide bond enters the polymer chain segment, the dynamic disulfide bond can be reversibly broken and recombined at high temperature, and the dynamic bond functional monomer is obtained. The high-temperature viscoelasticity is maintained, the material is endowed with self-repairing capability, and the problem that the viscoelasticity of the material in the prior art is sharply reduced at high temperature (gt; 120 DEG C) is solved.

The application discloses a kind of nanocellulose modified acrylic water-based emulsion and its preparation method and application, it is related to the technical field of polymer composite.A kind of modified acrylic water-based emulsion includes 180-220 parts of acrylate monomer, 45-60 parts of functional monomer, 3-5 parts of nanocellulose liquid, 4-6 parts of emulsifier, 1.5-2 parts of initiator, 2-3 parts of sodium bicarbonate and 275-300 parts of deionized water, wherein functional monomer includes hydroxy acrylate, acrylonitrile and fluorine-containing acrylate.By using fluorine-containing acrylate with nanocellulose to modify acrylic emulsion, water-based emulsion with good film-forming performance can be prepared, and the formed coating has good adhesion, stain resistance, heat oil resistance and mechanical strength, if the water-based emulsion is applied to the surface modification of filter material, not only can improve the hand feeling of filter material, but also can improve the stain resistance and service life of filter material surface.

The invention relates to the technical field of printed circuit board manufacturing, in particular to a high-chemical-resistance light-sensitive dry film and a preparation method thereof.The high-chemical-resistance light-sensitive dry film at least comprises, by weight, 5-15 parts of benzene ring-containing monomers, 100-200 parts of acrylic monomers, 20-70 parts of functional monomers, 200-300 parts of solvents and 0.5-2 parts of photoinitiators. The thickness of the dry film is reduced while the etching precision and the circuit quality are ensured, the problem that the etching precision is insufficient due to reduction of the thickness of the dry film in the prior art is effectively solved, and the actual application requirement is better met.

The invention discloses a self-adaptive hydrogel coupling agent as well as a preparation method and application thereof, belongs to the field of medical instruments, and particularly relates to a preparation method of the self-adaptive hydrogel coupling agent. The preparation method comprises the following steps: dissolving a main monomer, a functional monomer, a molecular weight regulator and a reinforcing filler in sterilized deionized water under dark and sterile conditions, carrying out a free radical polymerization reaction under the action of a persulfate solution and tetramethylethylenediamine, and carrying out dialysis and sterilization treatment to obtain the self-adaptive hydrogel coupling agent. The self-adaptive hydrogel coupling agent prepared by the invention eliminates tissue deformation caused by probe pressurization, significantly improves the accuracy of measurement of the actual distance of a target by ultrasound in an operation, and meanwhile, the self-adaptive hydrogel coupling agent is good in biocompatibility, can be sterile, is convenient to operate, and is suitable for open or endoscopic surgical wounds.

The invention discloses an organic silicon modified polyurethane-acrylate composite emulsion and a preparation method of the organic silicon modified polyurethane-acrylate composite emulsion, and relates to the technical field of polymer composite emulsions. Comprising the following raw materials: 70 to 120 parts of oligomer polyol with an average molecular weight of 500 to 2000, 5 to 15 parts of a composite organosilicon component, 40 to 80 parts of diisocyanate, 0.05 to 0.2 part of a catalyst, 2 to 5 parts of a hydrophilic chain extender, 3 to 6 parts of a self-crosslinking hydrophilic chain extender, 4 to 12 parts of a neutralizer, 2 to 8 parts of a water-based chain extender and 50 to 150 parts of an acrylate monomer. 1-5 parts of an acrylate functional monomer, 1-3 parts of a cross-linking agent, 2-8 parts of an emulsifier and 0.5-3 parts of an initiator; the organic silicon modified polyurethane-acrylate composite emulsion prepared by the invention has a composite core-shell structure taking organic silicon modified polyurethane as a core and an acrylate polymer as a shell, so that the emulsion can form a more compact and more stable three-dimensional cross-linked network during film formation, and the weather resistance, water resistance, mechanical strength and surface glossiness of a coating film are remarkably improved.

The invention relates to an EPEG slump retaining agent and a preparation method thereof, and the EPEG slump retaining agent is prepared from the following raw materials in parts by weight: 160-180 parts of ethylene glycol monovinyl polyethylene glycol ether monomer; 25-35 parts of an unsaturated acid monomer; 20 to 25 parts of an unsaturated slow-release ester functional monomer; 12-18 parts of an unsaturated double-bond siloxane functional monomer; 10-15 parts of a modified core-shell functional monomer; 6-8 parts of a rigid functional monomer; 10 to 15 parts of an initiator; 5-8 parts of a transfer agent; and 200 to 220 parts of water. The EPEG slump retaining agent and the preparation method of the EPEG slump retaining agent are prepared by performing molecular design and key synthesis technology research on a polycarboxylic acid high-performance polycarboxylic acid slump retaining agent, and the long-acting slump retaining capacity and the slow-release dispersing capacity of the polycarboxylic acid slump retaining agent in cement concrete are further improved.

The invention relates to the technical field of admixtures for cement concrete, in particular to a polycarboxylic acid admixture for enhancing low-activity admixtures and a preparation method thereof, the polycarboxylic acid admixture is formed by polymerizing the following components: polyether macromonomer, unsaturated carboxylic acid I, exciting functional monomer A, slump retaining functional monomer B, rheological functional monomer C, oxidizing agent, reducing agent, chain transfer agent and water; the exciting functional monomer A, the slump retaining functional monomer B and the rheological functional monomer C are sequentially added, and the exciting functional monomer A is formed by polymerizing polyhydric alcohol, unsaturated carboxylic acid II, an initiator, phosphonic acid and an alcohol amine small monomer. Through molecular design, key functional groups such as phosphonic acid groups, amino groups and sulfonic acid groups are innovatively introduced into a polycarboxylic acid main chain, so that the polycarboxylic acid admixture has multiple synergistic functions of reducing the cement consumption, effectively activating a low-activity cementing material, stably improving the working performance of concrete and the like.

The invention relates to the technical field of concrete admixtures, in particular to a viscosity reduction type polycarboxylate superplasticizer and a preparation method thereof. The viscosity reduction type polycarboxylate superplasticizer is formed by polymerizing a comonomer under the action of an oxidizing agent, a reducing agent and a chain transfer agent, the comonomer comprises methoxyallyl polyoxyethylene ether, an air-entraining functional monomer, a viscosity-reducing functional monomer, a silicon-containing functional monomer, unsaturated acid and ferrous sulfate. The polycarboxylate superplasticizer provided by the invention can effectively reduce the viscosity of concrete, so that a concrete mixture has good flowability, workability and wrapping property, meanwhile, the strength of the concrete is not influenced as far as possible, the strength of the concrete is kept at a good level, and the concrete keeps good constructability. Moreover, when the viscosity-reducing polycarboxylate superplasticizer is prepared, the reaction can be completed at the normal pressure of 20-25 DEG C, the preparation steps are simple, the reaction condition is mild, no toxic gas is released, energy can be effectively saved, and the viscosity-reducing polycarboxylate superplasticizer meets the green building material standard.

The invention discloses a composite membrane with adsorption separation and catalytic degradation functions as well as a preparation method and application of the composite membrane. The composite membrane is supported by a porous base membrane, a polyamide separation layer formed by reaction of a 3, 4-dihydroxyphenylethylamine and 2, 3-diaminophenol comonomer and acyl chloride is constructed on the surface of the porous base membrane through interfacial polymerization, and FeCo-g-C3N4 nanosheets are anchored in situ; the membrane can efficiently activate peroxymonosulfate (PMS) to generate free radicals under the nearly neutral condition, efficient interception and catalytic degradation of organic pollutants (such as antibiotics) are synchronously achieved, and heavy metal ions (such as Pb < 2 + > and Cd < 2 + >) are adsorbed through a functional monomer structure; the invention provides an interfacial polymerization preparation method of the membrane. The composite membrane breaks through the limitation of'only interception but not degradation 'of a traditional membrane, realizes integration of'separation-adsorption-degradation', can remarkably reduce the volume of concentrated water and reduce the toxicity of the concentrated water, and is suitable for advanced treatment of wastewater containing composite pollutants in the industries of pharmacy, printing and dyeing and the like.

The invention belongs to the technical field of preparation of thickening agents, and particularly relates to a preparation method of a polymer thickening agent for fracturing. The preparation method comprises the following steps: preparing a pretreated methacrylic acid (triethoxysilyl) methyl ester solution; preparing a pretreated 2-[[2-(methacryloyloxy) ethyl] dimethylammonium] acetate solution; preparing a water phase; and preparing the polymer thickening agent for fracturing. According to the preparation method of the polymer thickening agent for fracturing, acrylamide is used as a main monomer, maleic acid mono [2 (1-oxy-2-propenyl) oxyethyl] ester, methacrylic acid (triethoxysilyl) methyl ester and 2-[[2-(methacryloyloxy) ethyl] dimethylammonium] acetate are used as functional monomers, and the acrylamide, the maleic acid mono [2 (1-oxy-2-propenyl) oxyethyl] ester, the methacrylic acid (triethoxysilyl) methyl ester, the methacrylic acid (triethoxysilyl) methyl ester and the 2-[[2-(methacryloyloxy) ethyl] dimethylammonium] acetate are used as functional monomers. A redox initiator and an azo initiator are combined to serve as an initiator system, multi-monomer copolymerization is achieved through gradient temperature polymerization, and the temperature-resistant and salt-resistant polymer thickening agent for fracturing is prepared.

The invention discloses a hollow covalent organic framework fiber separation membrane with a molecular recognition function and a preparation method and application thereof.The method comprises the steps that polylactic acid and aldehyde monomers are added into a solvent A, and an aldehyde-loaded spinning solution is prepared; spinning the aldehyde-loaded spinning solution to obtain an aldehyde fiber precursor membrane; taking the formylated fiber precursor membrane as a template, immersing the formylated fiber precursor membrane into a reaction system consisting of an amino monomer, a catalyst and a solvent B, and initiating dynamic covalent assembly to prepare a COF shell-coated fiber membrane; immersing the fiber membrane coated with the COF shell layer into a solvent C to remove the polylactic acid template so as to prepare hollow COF fibers; and immersing the hollow COF fiber into a solvent system containing a gas recognition functional monomer, and constructing a gas molecule recognition layer on the surface of the hollow COF fiber to prepare the hollow COF fiber separation membrane. According to the application, the hollow covalent organic framework fiber separation membrane is applied to precise recognition operation of sulfur-containing gas. According to the invention, an efficient and energy-saving innovative membrane material with resource enrichment potential can be prepared.

The invention belongs to the technical field of supporting films, and particularly relates to an acrylate pressure-sensitive adhesive, a supporting film adhesive tape, a preparation method and application. The acrylate pressure-sensitive adhesive is prepared from the following raw materials in parts by weight: 60 to 90 parts of acrylate soft monomer, 5 to 20 parts of polar functional monomer, 5 to 20 parts of high-Tg hard monomer, 0.1 to 0.5 part of initiator, 0.5 to 3 parts of polyfunctional thermocuring cross-linking agent and a proper amount of solvent. According to the acrylate pressure-sensitive adhesive disclosed by the invention, the acrylate pressure-sensitive adhesive which has the characteristics of low modulus and high cohesion microcosmically is prepared under a solution polymerization and thermocuring process through a specific'soft monomer-hard monomer-crosslinking agent 'formula system design. The pressure-sensitive adhesive macroscopically realizes the performance balance, which is difficult to realize at the same time, among adhesion, buffering and impact resistance.

The invention relates to a chromium-targeted adsorbing material as well as a preparation method and application thereof. The preparation method of the targeted chromium adsorption material comprises the following steps: S1, crushing, sieving and pyrolyzing stems of potassium-rich plants to obtain biomass carbon; s2, dispersing biomass carbon in a solvent, adding Cr < 6 + > template ions, Cr < 3 + > template ions, a functional monomer, a cross-linking agent and an initiator for reaction, and washing and drying after reaction to obtain an ion imprinted polymer; and S3, dissolving a reduction barrier agent in a solvent, adding the ion imprinted polymer, and reacting at room temperature to obtain the chromium-targeted adsorption material, the potassium-rich plants are plants with the total potassium mass content of 5%-8%. The long-acting reduction adsorption material for targeted remediation of heavy metal Cr < 6 + > / Cr < 3 + > polluted soil and underground water is prepared, has extremely high specific selectivity and efficient adsorbability, and has obvious advantages in the aspects of heavy metal treatment efficiency, continuity and acid interference resistance.

The invention belongs to the technical field of oil field gas channeling plugging agents, and discloses a high-molecular pre-crosslinked gel particle plugging agent suitable for a carbon dioxide drive oil reservoir and a preparation method of the high-molecular pre-crosslinked gel particle plugging agent. The raw materials comprise an acrylamide monomer, sodium bentonite, an acrylic monomer, an acid-resistant functional monomer, a temperature-resistant and salt-resistant functional monomer, a first cross-linking agent, a second cross-linking agent, an initiator, an inorganic reinforcing agent, an antioxidant and water. The prepared acid-resistant gel particle is good in temperature resistance, salt resistance and acid resistance and long in effective period of action, the viscosity of a system is increased after the particle swells for a certain time, the plugging capacity is enhanced, and the acid-resistant gel particle can be used as an excellent CO2 drive reservoir gas channeling plugging agent and is used for plugging a heterogeneous formation with developed micro-cracks.

The invention discloses a novel phosphorus-containing macromolecular flame retardant and a preparation method and application thereof, the flame retardant is a polymer with a general formula (I), the main chain of the flame retardant is composed of an olefin-containing phosphonate structural unit, and the side chain R2 is a phosphonate group or a phosphonate metal salt group. The preparation method comprises the following steps: firstly, carrying out reaction on trialkyl phosphite and halogenated olefin containing active groups to efficiently prepare a functional monomer containing polymerizable double bonds and phosphonate side chains; then carrying out free radical polymerization to obtain a macromolecular polymer; the phosphonate can be further partially or completely hydrolyzed and complexed with multivalent metal ions to form the flame retardant with an ionic cross-linked structure. The macromolecular flame retardant is high in phosphorus content, good in thermal stability and excellent in compatibility with a polymer matrix, can play a flame-retardant role in a condensed phase and a gas phase at the same time, and effectively overcomes the problems that a micromolecular flame retardant is easy to migrate and poor in durability, and the mechanical property of a matrix material is reduced. The preparation method is efficient, controllable and suitable for continuous production.

The invention provides a water-based binder, a preparation method and application thereof, negative electrode slurry, a negative electrode plate and a lithium ion battery, and relates to the technical field of lithium ion batteries. The water-based binder is obtained by free radical polymerization of a hard monomer, a soft monomer, a functional monomer and an interface modification monomer according to the mass ratio of (40-60): (30-50): (8-20): (0.5-5). The interface modification monomer comprises a small molecule compound with more than two functional groups; and the small molecule compound with more than two functional groups per se or after hydrolysis comprises at least two functional groups of hydroxyl, carboxyl, amido, ester group, acylamino, alkoxy or epoxy group. The aqueous binder provided by the invention can provide enough bonding strength in a silicon-based negative electrode of a lithium ion battery so as to inhibit the phenomenon of interface crushing and demolding in a circulation process, and can meet the requirement of high-solid-content homogenate and good liquid absorbency so as to improve the overall performance of the battery.

The invention provides an acrylate functional copolymer binder as well as a preparation method and application thereof, and relates to the technical field of binders for sulfide solid-state batteries. The acrylate functional copolymer binder is prepared from the following raw materials in parts by weight: 40 to 60 parts of acrylate flexible monomers, 20 to 40 parts of acrylate wetting functional monomers containing ether bonds and 10 to 30 parts of acrylate rigid monomers. The acrylate binder provided by the invention is adjustable in molecular structure and soft and hard in synergy, can adapt to a sulfide solid-state battery system, gives consideration to both flexibility and mechanical strength, and improves the overall stability of a positive plate.

The invention belongs to the technical field of building materials, and discloses a special emulsion for large-particle-size high-air-permeability soft porcelain and a preparation method and application thereof, and the emulsion comprises a seed phase, a core emulsion phase, a hard-shell pre-emulsion phase, an initiation system and a post-treatment auxiliary agent; the core emulsion phase comprises deionized water, 2-ethylhexyl acrylate, glycidyl methacrylate, a toughening aid, ethyl phosphate methacrylate and an OP-10 emulsifier; the toughening aid is a polyether-polyester block copolymer; the post-treatment auxiliary agent comprises an antibacterial flame retardant, an organic silicon defoaming agent and ammonia water, the antibacterial flame retardant is a benzisothiazolinone derivative containing phosphorus and nitrogen, performance complementation is achieved through the layered design of a core-shell structure, and meanwhile the stability and adhesive force are improved by means of the reactive emulsifier and the functional monomer; in addition, the polyether polyester block type reactive toughening aid and the phosphorus and nitrogen-containing benzisothiazolinone derivative antibacterial flame retardant are added, so that synergistic optimization of toughening, antibacterial and flame retardant is realized.

The invention discloses a photoresponse biomass-based material for removing organic-inorganic combined pollution in water as well as a preparation method and application of the photoresponse biomass-based material. The preparation method specifically comprises the following steps: (1) designing a photosensitive functional monomer; (2) preparing a biomass macromolecular initiator; (3) preparing the photoresponse biomass adsorbent; and (4) preparing the photoresponse biomass-based intelligent material. The photoresponse biomass-based material prepared by the method is rich in raw material source, green and environment-friendly, can be used for adsorption of composite pollutants (such as heavy metal / organic matter composite pollution and the like) in the environment, and can simultaneously realize desorption of the pollutants, photocatalytic degradation of the pollutants and regeneration of an adsorbent under the illumination condition; the defects that the traditional adsorbent regeneration process is complicated, secondary pollution is easy to generate, the repeated utilization rate of the adsorbent is low and the like are effectively overcome, and wide application prospects are achieved.

The invention discloses a water-based laminating adhesive and a preparation method thereof, and the laminating adhesive is a uniform emulsion prepared by taking a monomer, a nano filler, a cross-linking agent, an initiator, a compound additive and deionized water as raw materials through the steps of pretreatment, polymerization reaction, cross-linking modification and post-treatment. The monomers comprise a hard monomer, a soft monomer and a functional monomer; the nanofiller is a modified cellulose nanocrystal, and the cross-linking agent is a polyisocyanate cross-linking agent; the adsorption of the nanofiller on the surfaces of polymer particles is further improved through the modified cellulose nanocrystals, the peel strength is further improved by introducing the cross-linking agent, the mechanical property is improved, and the problem of'strength-toughness' contradiction in the prior art is solved.

The invention discloses a preparation method and application of high-sensitivity and high-stability time-resolved fluorescent microspheres, and relates to the technical field of immunochromatography. The preparation method comprises the following steps: (1) preparing high-stability high-carboxyl-density polystyrene microspheres; (2) preparing a high-stability europium ion chelate; and (3) preparing the high-stability fluorescent microspheres. Through a strategy of combining functional monomer copolymerization and surface covalent labeling, the fluorescent microspheres which are connected through strong covalent bonds from inside to outside and are high in stability and carboxyl density are constructed; obvious differential advantages and innovativeness are shown in the aspects of chemical stability, anti-leakage capability of fluorescent markers and surface functional group density. A time-resolved fluorescent microsphere test strip developed based on the microspheres has the advantages of good stability, high detection sensitivity and the like, and can realize rapid detection and analysis of a substance to be detected.

The invention discloses a high-temperature-resistant and high-modulus adhesive and a preparation method thereof, and relates to the technical field of adhesives. The water-based adhesive comprises the following raw materials: 40-60 parts of a soft monomer, 20-30 parts of a hard monomer, 5-10 parts of a functional monomer, 1-3 parts of a cross-linking agent, 0.5-1.5 parts of an initiator, 2-5 parts of a modified nano filler and 30-50 parts of a solvent, the functional monomer is prepared by compounding N-methoxy methyl acrylamide, acrylic acid and 2-acrylic acid-hexahydro-4, 7-methylene-1H-indenyl ester according to a mass ratio of 2 to 1 to (1 to 1.5); the cross-linking agent is prepared by compounding N, N '-methylene bisacrylamide and 1, 1, 3, 3-tetramethyl-1, 3-divinyl disilazane according to a mass ratio of 1: (0.5 to 1). The adhesive has the advantages of favorable adhesive property, favorable high-temperature resistance and high modulus.