1056 results about "Acrylic monomers" patented technology

A fireproof magnesium oxide board is prepared by mixing the following raw materials, the raw material names and weight parts are as follows: 80-100 parts of magnesium oxide; 20-30 parts of anhydrous magnesium chloride; 10-20 parts of modified expanded vermiculite foaming agent; 20-30 parts of aluminum silicate fiber; 5-10 parts of sawdust; 10-15 parts of fly ash; 8-12 parts of glass magnesium board crushed powder; 1.5-5 parts of non-woven fabric; 10-20 parts of water; wherein the modified expanded vermiculite is prepared by the following steps: (1) Vermiculite is incompletely expanded and calcined; (2) acrylic acid monomer, sodium hydroxide, acrylamide monomer, initiator potassium persulfate, crosslinking aid pentaerythritol polyglycidyl ether, incompletely expanded vermiculite, and water are taken, stirred evenly and ultrasonically dispersed to obtain a first reaction solution, which is placed in a reactor for reaction to obtain a gel material; (3) the gel material is preliminarily crushed and dried, and then further crushed in a ball mill to obtain a fire-resistant expanded vermiculite with water absorption performance.

The specification relates to a wash-off label (100, 200) comprising a face (101, 301) and a pressure sensitive adhesive (102, 302) adjoined to the face, wherein the face (101, 301) comprises corona discharged filmic material and the pressure sensitive adhesive (102, 302) has a composition including at least one acrylic polymer comprising acrylic monomer(s) and / or non-acrylic comonomer(s) having a carbonyl group capable of undergoing a crosslinking reaction, amount of the acrylic monomer(s) and / or non-acrylic comonomer(s) having a carbonyl group capable of undergoing a crosslinking reaction being from 0.1 to 5 wt. % of monomer composition, and a crosslinking agent with dihydrazide functionality, amount of the crosslinking agent being from 20 to 150% with respect to the amount of the carbonyl groups capable of undergoing a crosslinking reaction. The wash-off label (100, 200) is detachable from a surface when exposed to an alkaline washing solution at a temperature of 85 degrees C. the detachability being such that the pressure sensitive adhesive (102, 302) remains attached to the face (101, 301). Further, the specification relates to a labelled item and use of the wash-off label for labelling an item. Still further, the specification relates to a label laminate web and a method of manufacturing the wash-off label as well as to a pressure sensitive adhesive composition for a wash-off label.

The present application relates to the technical field of lithium battery materials and binders, and discloses an aqueous polymeric binder, a preparation method therefor and a use thereof. The aqueous polymeric binder is obtained by copolymerizing a polymerization unit comprising an acrylic monomer, an acrylate monomer, an oil-soluble monomer, a water-soluble monomer, and an amphiphilic water-soluble monomer in an aqueous solvent; and the mass percentages of the monomers are as follows: acrylic monomer: 5%-15%; acrylate monomer: 45%-60%; oil-soluble monomer: 10%-40%; water-soluble monomer: 5%-20%; and amphiphilic water-soluble monomer: 5%-10%. The aqueous polymeric binder of the present application is mainly used for bonding of an edge coating of a negative electrode sheet of a lithium-ion battery; on the basis of the specific copolymerization monomer components and proportions, the obtained binder has excellent PP base film bonding performance and electrolyte swelling resistance; in addition, the binder avoids material mixing with a negative electrode, and has good prospects of application.

The invention provides a zinc negative electrode and gel electrolyte integrated structure and a preparation method thereof and a zinc ion battery, the integrated structure comprises a zinc negative electrode and a gel electrolyte layer combined on the surface of one side or two sides of the zinc negative electrode in situ, the gel electrolyte layer comprises a polymerization product of a zinc acrylate monomer, an acrylic monomer and a gel substance, the zinc ion battery has the advantages of no anion interference, high ionic conductivity, excellent contact with a zinc negative electrode and the like, can be applied to the field of batteries, and can effectively avoid an electrode concentration polarization effect, enhance the desolvation capability of zinc ions and prolong the cycle life of the batteries. The preparation method comprises the following steps: arranging a mixed raw material solution containing a zinc acrylate monomer, an acrylic monomer and a gel substance on the surface of the zinc negative electrode, and carrying out ultraviolet polymerization to generate a single-ion conductive dual-network polymer, namely the gel electrolyte layer, on the surface of the zinc negative electrode in situ. The method is suitable for industrial production.

The invention discloses a temperature-resistant high-strength powder coating and a preparation method thereof, and belongs to the field of coatings. The invention relates to a temperature-resistant high-strength powder coating which is prepared from the following raw materials in percentage by weight: 40-50% of epoxy resin; 20-30% of polyester resin; 6-10% of a curing agent; 1-3% of a leveling agent; 1-2% of a filler; and the balance of pigment. According to the polyester resin, aliphatic diisocyanate reacts with polyether polyol and hydroxyl silicone oil to obtain a polyurethane prepolymer, and then the polyurethane prepolymer reacts with vinyl benzylamine, an acrylate monomer and an acrylic monomer to obtain the polyester resin. The powder coating has the advantage that the temperature resistance and the strength of the powder coating are improved.

The invention belongs to the technical field of optical materials, and discloses a holographic polymer dispersed liquid crystal composition, a holographic grating and a preparation method. The composition comprises the following components in parts by mass: 0.5-1.5 parts of a photoinitiator, 2-5 parts of a co-initiator, 15-20 parts of a first monomer, 15-20 parts of a second monomer, 10-15 parts of a third monomer, 10-15 parts of a solvent and 10-20 parts of mixed liquid crystal. Wherein the first monomer is a monofunctional acrylic monomer, the second monomer is a bifunctional acrylic monomer, the third monomer is a polyfunctional acrylic monomer, the mixed liquid crystal comprises 10-25 wt% of a monomer liquid crystal and 75-90 wt% of a nematic liquid crystal, and the monomer liquid crystal contains fluorine as a benzene ring substituent and contains cyano or isothiocyano as an end group. Through cooperation of the monomer liquid crystal and the nematic liquid crystal in the mixed liquid crystal and cooperation of fluorine atoms and cyano / isothiocyano groups in the monomer liquid crystal, the holographic grating prepared from the composition has the characteristics of low haze and high diffraction efficiency, and the grating can be thinner, so that the requirements of light weight and clearness of AR glasses can be met.

The invention discloses a novel modified starch-based polycarboxylate superplasticizer and a preparation method thereof, and belongs to the technical field of concrete admixtures. The preparation process comprises the following steps: (1) performing acidolysis treatment on starch to obtain acidolysis starch; (2) modifying the acidolysis starch and a double-bond modifier under the action of auxiliaries such as a polymerization inhibitor to prepare novel double-bond-containing modified starch (AS); (3) mixing AS and a polyether macromonomer in water to form a base solution; (4) dropwise adding an acrylic monomer and a chain transfer agent into the base solution, and carrying out a copolymerization reaction through an initiation system; and (5) insulating and neutralizing to obtain a finished product. In order to solve the problems of non-renewable petroleum-based raw materials, high production cost and the like of the traditional polycarboxylate superplasticizer (PCA), active double bonds are introduced into modified starch by a solvent-free semi-dry process to replace part of polyether macromonomers, so that the polymerization activity and grafting ratio of the modified starch are effectively improved, the water-reducing dispersion effect of the modified starch is enhanced, and the water-reducing property of the modified starch is improved. The water reducer has the advantages of low mixing amount, high water reduction and the like, and has economic and environmental benefits.

The invention relates to a preparation method of composite porous carbon beneficial to silicon deposition and a silicon-carbon composite negative electrode. The method comprises the following steps: (P1) carrying out surface oxidation treatment on porous carbon fine powder to obtain oxidized porous carbon fine powder; (P2) adding the oxidized porous carbon fine powder and ether polycarboxylic acid silanol into a solvent to obtain ether polycarboxylic acid silanol modified porous carbon fine powder; the ether polycarboxylic acid silanol is prepared by copolymerizing a polyether macromonomer, an acrylic monomer and an alkenyl silane coupling agent in water; (P3) soaking the ether polycarboxylic acid silanol modified porous carbon fine powder in a salt aqueous solution to obtain catalyst-loaded porous carbon; (P4) mixing the porous carbon loaded with the catalyst with a carbon source precursor solution, and performing spray drying to obtain a composite carbon precursor; and (P5) carbonizing and activating the composite carbon precursor to obtain the composite porous carbon beneficial to silicon deposition. The composite porous carbon prepared by the invention is beneficial to more uniform deposition of silicon in pores of the core porous carbon fine powder.

The invention discloses eutectic gel as well as a preparation method and application thereof. The eutectic gel at least comprises a polymer obtained by polymerizing an acrylamide monomer, an acrylic monomer and a cross-linking agent in a eutectic solvent, and cellulose nanocrystals are also added into the polymer. The preparation method comprises the following steps: preparing the eutectic solvent; the preparation method comprises the following steps: at least adding an acrylamide monomer, an acrylic monomer, a cross-linking agent and cellulose nanocrystals into a deep-eutectic solvent, and uniformly mixing; and carrying out polymerization reaction to obtain the eutectic gel. According to the invention, two polymer monomers with different compatibility with the eutectic solvent are copolymerized to prepare the eutectic gel with phase separation, and meanwhile, the cellulose nanocrystal with different interaction with two phases in the eutectic gel is used as the flexibilizer, so that the mechanical property of the eutectic gel is effectively enhanced, and the mechanical property of the eutectic gel is improved. And the eutectic gel has temperature and strain dual response characteristics and good environmental stability.

The invention relates to the technical field of waterproof agents for fabrics, and particularly discloses a fluoride-free waterproof agent for fabrics and a preparation method of the fluoride-free waterproof agent. The preparation method specifically comprises the following steps: dehydrating polyol / ester, adding isocyanate, heating to 80-90 DEG C, reacting for 2-3 hours, cooling, dropwise adding a chain extender, reacting for 0.5-1 hour at 45-48 DEG C, adding POSS, stirring for 1-2 hours at 45-48 DEG C, adding an acrylic monomer A for blocking, cooling, dropwise adding acid, stirring and neutralizing to obtain a prepolymer; pouring the prepolymer into water, stirring and emulsifying to obtain a POSS-PU emulsion; quickly stirring the POSS-PU emulsion, an acrylic monomer B, an emulsifier, water, a co-emulsifier, a pH regulator and the like to obtain a composite emulsion; homogenizing the composite emulsion until the composite emulsion has obvious blue light; and adding dodecanethiol and an azo amidine initiator, reacting at 68-70 DEG C for 3-7 hours, cooling, filtering and taking out to obtain the fluoride-free waterproof agent.

The invention discloses a lithium battery negative electrode binder of modified carboxymethyl cellulose lithium, and belongs to the technical field of lithium ion batteries, and the modified carboxymethyl cellulose lithium is prepared by grafting carboxymethyl cellulose with an acrylic monomer and a sulfonic monomer, acidifying, lithiating, cross-linking with cystine, and carrying out surface modification with 2-(3, 4-dihydroxyphenyl) ethylamine. The preparation method comprises the following steps: grafting an acrylic monomer and a sulfonic monomer copolymerization long chain on a main chain of carboxymethyl cellulose, introducing additional carboxyl and sulfonic groups, and introducing cystine with a disulfide bond as a cross-linking agent and 2-(3, 4-dihydroxyphenyl) ethylamine with a catechol group as a tackifier to prepare modified carboxymethyl cellulose lithium; the lithium content of the obtained modified lithium carboxymethyl cellulose is higher than that of common lithium carboxymethyl cellulose, the adhesive property is enhanced, the toughness is improved, and the cycle performance is enhanced.

The invention discloses a far-infrared high-transmittance composite material, a preparation method thereof and an optical device, and the far-infrared high-transmittance composite material comprises the following components in parts by weight: 70-99 parts of a polymer matrix; 1-30 parts of an anti-reflection auxiliary agent; the polymer matrix is a sulfur-containing polymer prepared by polymerization reaction of a polymeric monomer and sulfur, and the proportion of carbon-carbon unsaturated bonds is less than 3%; the polymeric monomer is selected from at least one of a vinyl monomer, a propenyl monomer, an acrylic acid monomer, a methacrylic acid monomer, an epoxide monomer, a thiopropyl ring monomer, an alkynyl monomer, a butadiene monomer, an isoprene monomer and a norbornene monomer; the anti-reflection auxiliary agent comprises at least one of nano zinc sulfide, nano zinc selenide, nano calcium fluoride, nano magnesium fluoride and nano magnesium oxide. The composite material and the optical device thereof have high far infrared transmittance and good mechanical properties and processability, and can meet the requirements of various far infrared optical fields.

The invention provides a thermal response self-ceramization fireproof coating and a preparation method thereof. The thermal response self-ceramization fireproof coating is prepared from the following raw materials in parts by mass: 3 to 10 parts of acrylic monomer, 3 to 10 parts of organic sulfonate, 1 to 4 parts of silane coupling agent, 0.5 to 3 parts of silicate ester, 4 to 6 parts of ceramic precursor, 3 to 6 parts of fluxing agent and 0.05 to 0.4 part of initiator. The fluxing agent comprises a component A and a component B, the component A is one of boric oxide, zinc borate or low-melting-point glass powder, and the component B is one of phosphorus pentoxide and ammonium polyphosphate. The silane coupling agent can be copolymerized with an acrylic monomer to construct a C-C main chain, the C-C main chain and silicate ester are subjected to hydrolytic condensation to form a Si-O-Si three-dimensional network, a chemical cross-linked skeleton is formed, and the chemical cross-linked skeleton can generate silicon dioxide at high temperature to participate in a ceramization reaction; the ceramic precursor and silicate ester can form a strong physical cross-linking effect, so that the fireproof coating with a chemical and physical double-cross-linked network can be formed, and the fireproof coating has excellent mechanical property and machinability at normal temperature.

The invention relates to a micro-nano aggregate based on silanized calcium sulfate whisker in-situ polymerization, the main component of the micro-nano aggregate is acrylate copolymerized CSW / NS-GO, and the preparation method comprises the following steps: loading nano silicon dioxide on the surface of calcium sulfate whisker to obtain CSW / NS; carrying out silanization modification on CSW / NS; preparing graphene oxide by a Hummers method; and carrying out in-situ polymerization to prepare the acrylate copolymerized CSW / NS-GO. Calcium sulfate whiskers are loaded and bonded with epoxy modified nano silicon dioxide and then subjected to in-situ polymerization with graphene oxide in an acrylic monomer, a polymer chain is tightly combined with a functional group of CSW / NS-GO, good interface bonding is formed, and the strength and toughness of the composite material are improved. The acrylate copolymerized CSW / NS-GO has a microscopic three-dimensional network structure and excellent stability, so that the internal structure of the concrete is more compact, the porosity is reduced, the permeation of water is prevented, and the invasion of harmful substances such as chloride ions and sulfate ions into channels is reduced, thereby reducing the structural damage caused by environmental factors such as dry-wet cycle and freeze-thaw cycle; the durability of the concrete is improved.

The invention discloses a bag-pasting-preventing self-cleaning dust-removing filtering material and a preparation technology thereof, and relates to the technical field of dust-removing filtering materials.The preparation technology comprises the following steps that fluorine-containing alkenyl monomers, allyl monomers, fibers and an initiator are mixed in dimethyl sulfoxide, and dispersion liquid is obtained; and coating the surface of a needled felt with the dispersion liquid, and baking to obtain the dust removal filtering material. The preparation method comprises the following steps: mixing an alkenyl fluorine-containing monomer, a propenyl monomer and fibers to prepare a dispersion liquid, coating the dispersion liquid on the surface of a needled felt, and carrying out a baking reaction to form the dust removal filtering material deposited with a fluorine-containing coating, so that the surface energy of the filtering material is remarkably reduced, and the filtering material is endowed with good surface moisture condensation resistance and dust stripping resistance; bag pasting caused by the effects of smoke humidity, dust humidity and the like is effectively avoided, the self-cleaning capacity is achieved, and the service life is prolonged. And the loading of the high-strength fibers on the surface of the needled felt is beneficial to improving the mechanical strength and stability of the prepared filtering material.

The invention relates to chitin-based acrylic resin and a preparation method thereof, and belongs to the technical field of intersection of high value-added utilization of biomass resources and acrylic resin. The chitin-based acrylic resin is prepared from the following components in parts by weight: 30 to 50 parts of acrylic modified chitin, 20 to 30 parts of acrylic monomer, 10 to 20 parts of polyaldehyde monomer, 5 to 10 parts of polybasic organic amine, 1 to 5 parts of emulsifier, 0.1 to 0.5 part of initiator, 0.2 to 0.4 part of defoaming agent and 80 to 120 parts of deionized water. According to the method, forestry and agricultural residues are used as raw materials, chitin with small molecular chains is obtained through deacetylation treatment, meanwhile, a large number of primary amino groups with high chemical reactivity are exposed on the surfaces of the molecular chains of the chitin, and 3-formyl-2-butenoic acid is further utilized to react with the chitin, so that the yield of the chitin is increased. Acrylic acid groups are successfully grafted to chitin molecular chains to be subjected to polymerization reaction with acrylic acid monomers to form macromolecule resin, meanwhile, the macromolecule resin is subjected to cross reaction with polyaldehyde and polybasic organic amine to generate net-shaped crosslinking, and the strength of the acrylic resin after film forming is improved.

The invention provides a marking coating capable of preventing normal-temperature layering and a preparation method of the marking coating, and belongs to the technical field of coatings. Comprising the following raw materials in parts by weight: 1-2 parts of a temperature-sensitive reversible cross-linking agent, 15-30 parts of epoxy resin, 10-20 parts of an acrylic monomer, 1-2 parts of an emulsifier, 2-4 parts of temperature-sensitive microcapsules, 0.5-1 part of nano titanium dioxide, 1-2 parts of inorganic asbestos fibers, 0.5-1.5 parts of polymer fibers, 0.01-0.02 part of an initiator, 3-4 parts of a water-soluble epoxy curing agent, 2-3 parts of hollow glass beads, 2-4 parts of an auxiliary agent and 40-80 parts of water. The marking paint has the temperature-sensitive characteristic, is a weak gel network at normal temperature, inhibits filler sedimentation, hydrogen bond fracture during construction heating, paint fluidity recovery and cooling recovery crosslinking, and has high strength and hardness, so that the tensile strength, bending strength, hardness and other mechanical properties of a paint film are remarkably improved, and the wear resistance and impact resistance are also enhanced.

The invention discloses rosin modified zinc acrylate self-polishing resin, an antifouling paint containing the resin and a synthesis method. Firstly, under the action of an initiator, an acrylic prepolymer is synthesized from an acrylic monomer through a polymerization reaction; then, under the action of zinc oxide and benzoic acid, rosin resin is grafted to the side chain of the acrylic prepolymer, and zinc acrylate resin with the side chain containing rosin is obtained; and mixing, dispersing and grinding the rosin modified zinc acrylate resin, an anti-fouling agent, pigment filler, an auxiliary agent and a solvent to obtain the self-polishing anti-fouling paint based on the rosin modified zinc acrylate resin. The prepared rosin modified zinc acrylate self-polishing resin is high in polymerization degree, concentrated in molecular weight distribution and good in plasticity and flexibility, and the self-polishing antifouling paint based on the rosin modified zinc acrylate self-polishing resin comprises a cuprous oxide main antifouling agent and a composite organic antifouling agent and has the stable copper ion seepage rate and the good antifouling effect.

The invention relates to the technical field of organic adhesives, in particular to a dual-curing composition and a preparation method and application thereof. The dual-curing composition comprises an acrylic monomer, an acrylate oligomer, a photoinitiator, dual-curing resin, first epoxy resin and a modified curing agent, wherein the molecules of the dual-curing resin contain acrylate groups and epoxy groups at the same time; the modified curing agent comprises an amine curing agent and a prepolymer of second epoxy resin. According to the dual-curing composition disclosed by the invention, through compounding and synergistic interaction of the components, reactions such as carbon-carbon double bond polymerization, epoxy ring opening and amido addition are carried out under ultraviolet irradiation and normal temperature, so that dual curing is realized through cross-linking polymerization, and devices such as a perovskite battery and the like can be efficiently packaged. Wherein the dual-curing resin further increases the chain length of the polymer, so that a compact three-dimensional network structure is formed after the composition is cured, the moisture and gas blocking performance of the cured composition is improved, and the stability of a packaged device is improved.

The invention provides a bio-based composite liquid mulching film and a preparation method thereof. The bio-based composite liquid mulching film comprises a nanocellulose solution, modified starch, modified chitosan, glycerol and calcium carbonate, the modified starch is obtained by modifying starch with citric acid; the modified chitosan is obtained by grafting and copolymerizing chitosan with an acrylic monomer. According to the invention, a plurality of bio-based components such as modified starch, modified chitosan, a nanocellulose solution, glycerol and calcium carbonate are integrated, and natural characteristics of bio-based materials are utilized to form a uniform and degradable film layer; the soil moisture retention film can better isolate air and moisture loss, improves the soil moisture retention ability, ensures sufficient strength and flexibility in the application process, and avoids the problems of early cracking or deformation and the like.

A photocurable composition, contains a (meth)acrylic monomer component, and photopolymerization initiator, in a case in which a rectangular sheet-like test piece A1 with a length of 40 mm, a width of 10 mm, and a thickness of 1.0 mm is produced by photomodeling under conditions in which the photocurable composition is irradiated with visible light having a wavelength of 405 nm at an irradiation dose of 11 mJ / cm2 to form a cured layer A1 with a thickness of 50 μm, the cured layer A1 is stacked in a thickness direction thereof to form a rectangular sheet-like modeling product A1 with a length of 40 mm, a width of 10 mm, and a thickness of 1.0 mm, and the modeling product A1 is irradiated with ultraviolet rays having a wavelength of 365 nm at an irradiation dose of 3 J / cm2 to produce the test piece A1.

The invention relates to a composite water reducing agent for lithium slag concrete as well as a preparation method and application thereof, and the composite water reducing agent comprises the following raw materials in parts by weight: 40-60 parts of a siloxane modified polycarboxylic acid polymer solution, 25-40 parts of a POSS-based silane coupling agent, 3-5 parts of polyethylene glycol and 20-25 parts of an alkali activator. The POSS-based silane coupling agent is prepared by carrying out a Michael addition reaction on acryloyloxy silane and amino propyl heptyl-polyhedral oligomeric silsesquioxane according to a molar ratio of 1: (1 to 1.03); the siloxane modified polycarboxylic acid polymer solution is prepared by polymerizing polymeric monomers, namely a monoalkenyl polyether monomer, an acrylic monomer, monoalkenyl dibasic acid and unsaturated siloxane in the solution according to a molar ratio of 1: (2-3): (2-3): (0.1-0.3), and the solid content of the polycarboxylic acid polymer solution is 40-50wt%. Under the synergistic and balanced effects of all the components of the composite water reducer, the workability of the lithium slag concrete can be remarkably improved, and the water reducing effect of the water reducer is fully exerted.

The invention provides polyacrylic acid-carboxylated chitosan interpenetrating network hydrophobic modified hydrogel as well as a preparation method and application thereof, and belongs to the technical field of wastewater treatment. The preparation method comprises the following steps: mixing an acrylic monomer, a hydrophilic acrylate monomer, an etherification type acrylamide monomer, an allyl quaternary ammonium salt type hydrophobic monomer, a crosslinking monomer and water, then mixing with a chitosan compound, and adjusting the pH value to obtain a reaction solution; and mixing the reaction liquid and a photoinitiator, then carrying out polymerization reaction, and sequentially pre-freezing and freeze-drying the obtained polymer hydrogel. Through multiple synergistic effects of photo-initiated rapid polymerization, amphiphilic hydrophobic modification, etherification auxiliary crosslinking and a chitosan compound interpenetrating network, the structural stability, complexing efficiency, industrial applicability and heavy metal adsorption performance are comprehensively improved; the adsorption rate and capacity of the hydrogel disclosed by the invention are obviously superior to those of the existing similar polyacrylic acid-based or chitosan-based hydrogel.

The invention discloses an anti-freezing and self-healing hydrogel electrolyte of a water-based zinc ion battery and a preparation method of the anti-freezing and self-healing hydrogel electrolyte, and belongs to the technical field of water-based zinc ion batteries. The method comprises the following steps: (1) mixing a functional material, an acrylic monomer, an initiator, a cross-linking agent and soluble iron (III) salt to obtain a first product; (2) degassing the first product to remove bubbles, and then carrying out polymerization reaction to obtain a second product; and (3) soaking the second product in a 2-10 mol / L electrolyte aqueous solution for treatment to obtain the anti-freezing and self-healing hydrogel electrolyte. The hydrogel electrolyte prepared by the invention has high ionic conductivity and adhesion, and has good anti-freezing and self-healing capabilities. And when applied to the aqueous zinc ion battery, the composite material shows an ultra-long cycle life, can stably supply power even in an extremely severe environment, and has certain research significance for promoting flexible electronic equipment and large-scale energy storage application.

The invention provides a fluorescent antibacterial acrylic emulsion as well as a preparation method and application thereof. The fluorescent antibacterial acrylic emulsion comprises an acrylic monomer, AIE fluorescent micromolecules, an antibacterial quaternary ammonium salt monomer, a nonionic emulsifier, a cationic emulsifier, an initiator, a stabilizer and deionized water. The cosolvent of the water-based acrylic coating is water, no VOC (volatile organic compound) is discharged when the water-based acrylic coating is used, and harm to the environment and human bodies is reduced to the minimum; meanwhile, the antibacterial coating is prepared in a positive ion and ROS joint antibacterial mode, and the antibacterial effect is more excellent; and a convenient detection method for reflecting the change of the antibacterial property of the coating through the fluorescence change of the coating avoids the trouble of professional biological detection.

A binder for rechargeable lithium batteries and a rechargeable lithium battery including the binder are disclosed. The binder for rechargeable lithium batteries includes a unit derived from a (meth)acrylic monomer containing a carboxylic acid group or a carboxylic acid metal salt as a first monomer; a unit derived from a (meth)acrylic monomer containing an amide group or a nitrile group as a second monomer; and a unit derived from a Zwitterionic vinyl or (meth)acrylic monomer as a third monomer.

The invention discloses a modified acrylate emulsion adhesive as well as a preparation method and application thereof, and belongs to the technical field of lithium ion batteries. The modified acrylate emulsion adhesive is prepared by adopting a semi-continuous emulsion polymerization method. The water-based adhesive is prepared from the following raw materials in parts by weight: 5-20 parts of water-based polyolefin, 50-200 parts of deionized water, 0.5-4 parts of an emulsifier, 20-50 parts of an acrylate monomer, 1-10 parts of an acrylic monomer, 0.2-1.5 parts of an initiator, 0-50 parts of styrene, 0.1-2 parts of a cross-linking agent and 0.5-15 parts of a neutralizer. The modified acrylate emulsion adhesive is obtained by taking the water-based polyolefin as a core structure of the emulsion and taking the acrylate polymer as a shell structure of the emulsion, and the adhesive has good compatibility with a polyolefin diaphragm and an electrolyte, so that the synergism of a lithium ion battery negative electrode, the electrolyte and the diaphragm is promoted; further, the electrochemical performance of the lithium ion battery is improved.

The invention belongs to the technical field of photoresists, and relates to a wide-color-gamut yellow dye for a color filter, a synthesis method of the wide-color-gamut yellow dye, a green photoresist and a preparation method of the green photoresist. The green photoresist is prepared from the following raw materials in parts by weight: 4 to 8 parts of green pigment, 3 to 8 parts of resin, 3 to 10 parts of acrylic monomer, 0.5 to 2 parts of photoinitiator, 0.2 to 0.4 part of auxiliary agent and 75 to 85 parts of organic solvent. The synthesized yellow dye has good photoresist system adaptability and high molar absorption coefficient, and meanwhile, due to the fact that acrylic acid is grafted, acrylic acid on the yellow dye has carbon-carbon double bonds, under the action of a photoinitiator, after bond breaking, the yellow dye can react with resin or an acrylic monomer and is cured in a film, and the yellow dye has good chemical resistance.

The invention relates to the technical field of UV adhesives, in particular to a photovoltaic UV adhesive and a preparation method thereof. The photocuring adhesive is prepared from the following components in percentage by weight: 30 to 40 weight percent of acrylic monomer, 30 to 40 weight percent of polyurethane acrylate resin, 15 to 30 weight percent of filler, 5 to 10 weight percent of thixotropic agent, 2 to 6 weight percent of photoinitiator and the balance of auxiliaries. The acrylic monomers comprise isobornyl acrylate and acryloyl morpholine, and the weight ratio of the isobornyl acrylate to the acryloyl morpholine is limited to be 1: (0.7-1.5), so that the curing speed and the welding fastness can be improved at the same time; the weight ratio of the isobornyl acrylate to the acryloyl morpholine is 1: (0.8-1.2), and the welding fastness can reach 2.5 N; the thixotropic agent comprises bentonite and fumed silica, the weight ratio of the bentonite to the fumed silica is (3-6): 1, and the leveling performance can be improved while the curing time can be shortened.

Disclosed are a negative electrode binder composition, a negative electrode binder and a preparation method therefor, a negative electrode sheet, a battery cell, and a battery. The negative electrode binder composition comprises the following components: an acrylic monomer, a hydroxydopamine monomer, a long-chain alkyl (meth) acrylate monomer, and a vinyl siloxane monomer.