838 results about "Acrylic monomers" patented technology

A fireproof magnesium oxide board is prepared by mixing the following raw materials, the raw material names and weight parts are as follows: 80-100 parts of magnesium oxide; 20-30 parts of anhydrous magnesium chloride; 10-20 parts of modified expanded vermiculite foaming agent; 20-30 parts of aluminum silicate fiber; 5-10 parts of sawdust; 10-15 parts of fly ash; 8-12 parts of glass magnesium board crushed powder; 1.5-5 parts of non-woven fabric; 10-20 parts of water; wherein the modified expanded vermiculite is prepared by the following steps: (1) Vermiculite is incompletely expanded and calcined; (2) acrylic acid monomer, sodium hydroxide, acrylamide monomer, initiator potassium persulfate, crosslinking aid pentaerythritol polyglycidyl ether, incompletely expanded vermiculite, and water are taken, stirred evenly and ultrasonically dispersed to obtain a first reaction solution, which is placed in a reactor for reaction to obtain a gel material; (3) the gel material is preliminarily crushed and dried, and then further crushed in a ball mill to obtain a fire-resistant expanded vermiculite with water absorption performance.

The invention belongs to the technical field of optical materials, and discloses a holographic polymer dispersed liquid crystal composition, a holographic grating and a preparation method. The composition comprises the following components in parts by mass: 0.5-1.5 parts of a photoinitiator, 2-5 parts of a co-initiator, 15-20 parts of a first monomer, 15-20 parts of a second monomer, 10-15 parts of a third monomer, 10-15 parts of a solvent and 10-20 parts of mixed liquid crystal. Wherein the first monomer is a monofunctional acrylic monomer, the second monomer is a bifunctional acrylic monomer, the third monomer is a polyfunctional acrylic monomer, the mixed liquid crystal comprises 10-25 wt% of a monomer liquid crystal and 75-90 wt% of a nematic liquid crystal, and the monomer liquid crystal contains fluorine as a benzene ring substituent and contains cyano or isothiocyano as an end group. Through cooperation of the monomer liquid crystal and the nematic liquid crystal in the mixed liquid crystal and cooperation of fluorine atoms and cyano / isothiocyano groups in the monomer liquid crystal, the holographic grating prepared from the composition has the characteristics of low haze and high diffraction efficiency, and the grating can be thinner, so that the requirements of light weight and clearness of AR glasses can be met.

The invention provides a thermal response self-ceramization fireproof coating and a preparation method thereof. The thermal response self-ceramization fireproof coating is prepared from the following raw materials in parts by mass: 3 to 10 parts of acrylic monomer, 3 to 10 parts of organic sulfonate, 1 to 4 parts of silane coupling agent, 0.5 to 3 parts of silicate ester, 4 to 6 parts of ceramic precursor, 3 to 6 parts of fluxing agent and 0.05 to 0.4 part of initiator. The fluxing agent comprises a component A and a component B, the component A is one of boric oxide, zinc borate or low-melting-point glass powder, and the component B is one of phosphorus pentoxide and ammonium polyphosphate. The silane coupling agent can be copolymerized with an acrylic monomer to construct a C-C main chain, the C-C main chain and silicate ester are subjected to hydrolytic condensation to form a Si-O-Si three-dimensional network, a chemical cross-linked skeleton is formed, and the chemical cross-linked skeleton can generate silicon dioxide at high temperature to participate in a ceramization reaction; the ceramic precursor and silicate ester can form a strong physical cross-linking effect, so that the fireproof coating with a chemical and physical double-cross-linked network can be formed, and the fireproof coating has excellent mechanical property and machinability at normal temperature.

The invention provides a marking coating capable of preventing normal-temperature layering and a preparation method of the marking coating, and belongs to the technical field of coatings. Comprising the following raw materials in parts by weight: 1-2 parts of a temperature-sensitive reversible cross-linking agent, 15-30 parts of epoxy resin, 10-20 parts of an acrylic monomer, 1-2 parts of an emulsifier, 2-4 parts of temperature-sensitive microcapsules, 0.5-1 part of nano titanium dioxide, 1-2 parts of inorganic asbestos fibers, 0.5-1.5 parts of polymer fibers, 0.01-0.02 part of an initiator, 3-4 parts of a water-soluble epoxy curing agent, 2-3 parts of hollow glass beads, 2-4 parts of an auxiliary agent and 40-80 parts of water. The marking paint has the temperature-sensitive characteristic, is a weak gel network at normal temperature, inhibits filler sedimentation, hydrogen bond fracture during construction heating, paint fluidity recovery and cooling recovery crosslinking, and has high strength and hardness, so that the tensile strength, bending strength, hardness and other mechanical properties of a paint film are remarkably improved, and the wear resistance and impact resistance are also enhanced.

The invention provides a bio-based composite liquid mulching film and a preparation method thereof. The bio-based composite liquid mulching film comprises a nanocellulose solution, modified starch, modified chitosan, glycerol and calcium carbonate, the modified starch is obtained by modifying starch with citric acid; the modified chitosan is obtained by grafting and copolymerizing chitosan with an acrylic monomer. According to the invention, a plurality of bio-based components such as modified starch, modified chitosan, a nanocellulose solution, glycerol and calcium carbonate are integrated, and natural characteristics of bio-based materials are utilized to form a uniform and degradable film layer; the soil moisture retention film can better isolate air and moisture loss, improves the soil moisture retention ability, ensures sufficient strength and flexibility in the application process, and avoids the problems of early cracking or deformation and the like.

The invention provides polyacrylic acid-carboxylated chitosan interpenetrating network hydrophobic modified hydrogel as well as a preparation method and application thereof, and belongs to the technical field of wastewater treatment. The preparation method comprises the following steps: mixing an acrylic monomer, a hydrophilic acrylate monomer, an etherification type acrylamide monomer, an allyl quaternary ammonium salt type hydrophobic monomer, a crosslinking monomer and water, then mixing with a chitosan compound, and adjusting the pH value to obtain a reaction solution; and mixing the reaction liquid and a photoinitiator, then carrying out polymerization reaction, and sequentially pre-freezing and freeze-drying the obtained polymer hydrogel. Through multiple synergistic effects of photo-initiated rapid polymerization, amphiphilic hydrophobic modification, etherification auxiliary crosslinking and a chitosan compound interpenetrating network, the structural stability, complexing efficiency, industrial applicability and heavy metal adsorption performance are comprehensively improved; the adsorption rate and capacity of the hydrogel disclosed by the invention are obviously superior to those of the existing similar polyacrylic acid-based or chitosan-based hydrogel.

The invention discloses an anti-freezing and self-healing hydrogel electrolyte of a water-based zinc ion battery and a preparation method of the anti-freezing and self-healing hydrogel electrolyte, and belongs to the technical field of water-based zinc ion batteries. The method comprises the following steps: (1) mixing a functional material, an acrylic monomer, an initiator, a cross-linking agent and soluble iron (III) salt to obtain a first product; (2) degassing the first product to remove bubbles, and then carrying out polymerization reaction to obtain a second product; and (3) soaking the second product in a 2-10 mol / L electrolyte aqueous solution for treatment to obtain the anti-freezing and self-healing hydrogel electrolyte. The hydrogel electrolyte prepared by the invention has high ionic conductivity and adhesion, and has good anti-freezing and self-healing capabilities. And when applied to the aqueous zinc ion battery, the composite material shows an ultra-long cycle life, can stably supply power even in an extremely severe environment, and has certain research significance for promoting flexible electronic equipment and large-scale energy storage application.

The invention discloses a modified acrylate emulsion adhesive as well as a preparation method and application thereof, and belongs to the technical field of lithium ion batteries. The modified acrylate emulsion adhesive is prepared by adopting a semi-continuous emulsion polymerization method. The water-based adhesive is prepared from the following raw materials in parts by weight: 5-20 parts of water-based polyolefin, 50-200 parts of deionized water, 0.5-4 parts of an emulsifier, 20-50 parts of an acrylate monomer, 1-10 parts of an acrylic monomer, 0.2-1.5 parts of an initiator, 0-50 parts of styrene, 0.1-2 parts of a cross-linking agent and 0.5-15 parts of a neutralizer. The modified acrylate emulsion adhesive is obtained by taking the water-based polyolefin as a core structure of the emulsion and taking the acrylate polymer as a shell structure of the emulsion, and the adhesive has good compatibility with a polyolefin diaphragm and an electrolyte, so that the synergism of a lithium ion battery negative electrode, the electrolyte and the diaphragm is promoted; further, the electrochemical performance of the lithium ion battery is improved.

The invention belongs to the technical field of photoresists, and relates to a wide-color-gamut yellow dye for a color filter, a synthesis method of the wide-color-gamut yellow dye, a green photoresist and a preparation method of the green photoresist. The green photoresist is prepared from the following raw materials in parts by weight: 4 to 8 parts of green pigment, 3 to 8 parts of resin, 3 to 10 parts of acrylic monomer, 0.5 to 2 parts of photoinitiator, 0.2 to 0.4 part of auxiliary agent and 75 to 85 parts of organic solvent. The synthesized yellow dye has good photoresist system adaptability and high molar absorption coefficient, and meanwhile, due to the fact that acrylic acid is grafted, acrylic acid on the yellow dye has carbon-carbon double bonds, under the action of a photoinitiator, after bond breaking, the yellow dye can react with resin or an acrylic monomer and is cured in a film, and the yellow dye has good chemical resistance.

Disclosed are a negative electrode binder composition, a negative electrode binder and a preparation method therefor, a negative electrode sheet, a battery cell, and a battery. The negative electrode binder composition comprises the following components: an acrylic monomer, a hydroxydopamine monomer, a long-chain alkyl (meth) acrylate monomer, and a vinyl siloxane monomer.

The invention discloses a preparation method and application of a water-based mixed binder, and relates to the technical field of water-based binders. The water-based mixed binder is obtained by mixing and compounding a water-based polyurethane emulsion and polyvinylidene fluoride. Wherein in the preparation process of the waterborne polyurethane emulsion, amino-terminated polyacrylic acid-catechol is added to serve as a chain extender for use, the amino-terminated polyacrylic acid-catechol is prepared by initiating polymerization of 4-allyl catechol, alkenyl siloxane and an acrylic monomer, and after polyacrylic acid-catechol is prepared, the amino-terminated polyacrylic acid-catechol is added to serve as a chain extender for use; and carrying out an ultraviolet irradiation click reaction on the obtained product and mercaptoacetic acid ethanolamine ester. The waterborne polyurethane emulsion prepared by the invention can greatly improve the electrochemical performance of the lithium battery, and especially has a great improvement effect on the peel strength, the cycle discharge specific capacity and the coulombic efficiency of the lithium battery.

The invention relates to the technical field of lithium ion battery assistants, in particular to an anode slurry dispersing, compacting and anti-cracking assistant for a lithium battery and a preparation method of the anode slurry dispersing, compacting and anti-cracking assistant. The anti-cracking aid is prepared from the following raw materials in parts by mass: 20-80 parts of a special polymer, 10-30 parts of a wetting agent, 10-30 parts of a plasticizer and 10-100 parts of a solvent, wherein the preparation raw materials of the special polymer comprise a vinyl monomer, an acrylic monomer, a diene monomer and an initiator; the wetting agent comprises the following raw materials: an amine compound and a hydrazine compound; and the plasticizer is polyether phosphate. When the additive is used for preparing the lithium battery positive electrode slurry, the slurry is uniformly dispersed and low in viscosity, the use of solvents can be reduced, the production process is shortened, and the actual use effect is excellent.

An electrophotographic photosensitive member includes a surface layer containing a binder resin and an inorganic particle. A value of a ratio of a volume of the inorganic particle to a volume of the binder resin in the surface layer is 1.0 or more and 4.0 or less. The binder resin is a polymerization product of a composition containing a polymerizable monomer having a polymerizable functional group. The composition contains a (meth)acrylic monomer having 6 or more polymerizable functional groups. The (meth)acrylic monomer has a molecular weight of 540 or more and 1,300 or less. A content of the (meth)acrylic monomer in the composition is 40 mol % or more with respect to a total molar number of the polymerizable monomer in the composition. A surface of the surface layer has an arithmetic average roughness Rz of 150 nm or more and 400 nm or less.

The invention relates to the technical field of WPC mould pressing floors, in particular to UV paint for WPC mould pressing floor surface coating and a preparation technology of the UV paint. The UV paint for coating the surface of the WPC mould pressing floor is prepared from the following raw materials in parts by mass: 40 to 60 parts of trifunctional polyurethane acrylate, 5 to 15 parts of hexa-functional polyurethane acrylate, 10 to 20 parts of trifunctional polyester acrylate, 1 to 5 parts of acrylic monomer, 5 to 15 parts of wet aluminum oxide and 1 to 2 parts of gamma-glycidyl ether oxypropyl trimethoxy silane. The coating is prepared from the following components in parts by weight: 1-3 parts of diphenylmethane diisocyanate, 0.1-1 part of 5-aminotetrazole, 1-3 parts of carboxyl functionalized PMMA microspheres, 1-3 parts of a flatting agent, 1-3 parts of a photoinitiator, 1-2 parts of a dispersing agent, 1-2 parts of a wetting agent and 20-40 parts of a mixed solvent. The coating is high in curing speed, high in adhesive force, good in flexibility and excellent in wear resistance.

The invention discloses a high-weather-resistance resin production process, and belongs to the technical field of high polymer material synthesis. The production process comprises the following steps: preparing an acrylic monomer, an emulsifier and an initiator according to a specific ratio, forming a pre-emulsion, performing staged normal-pressure polymerization, controlling the dropwise adding time and temperature, reacting, and performing condensation reflux and acid-base adsorption to obtain the product. Wastewater recycling needs to collect washing wastewater of the reaction kettle, the wastewater is subjected to multi-stage filtration, flocculent precipitation and precise filtration, the water quality is detected, and qualified water is reused for next-batch production. By optimizing the monomer ratio and the polymerization process, the weather resistance of the acrylic resin is remarkably improved, and the requirements of high-end coatings are met; meanwhile, through systematic wastewater recycling, fresh water consumption and wastewater discharge are greatly reduced, the resource utilization rate is increased, and environmental pollution is reduced. The technical treatment process is closely linked with production, the cost is low, and the method is suitable for large-scale continuous production and has both economic and environmental benefits.

The invention provides a heat-insulating fire-extinguishing film and a preparation method and application thereof, and relates to the technical field of heat-insulating fire-extinguishing material preparation. The preparation method of the heat-insulating fire-extinguishing film comprises the following steps: uniformly mixing 100 parts by weight of acrylic monomers and 50-300 parts by weight of urethane acrylate, adding a cross-linking agent and a functional additive, uniformly mixing, then adding a photoinitiator to obtain a mixed base material, adding 50-300 parts by weight of fire-extinguishing capsules and 50-300 parts by weight of heat-insulating filler into the mixed base material, uniformly mixing, and finally, carrying out heat-insulating fire-extinguishing treatment on the mixed base material to obtain the heat-insulating fire-extinguishing film. Uniformly stirring to obtain slurry; and calendering and curing the slurry to obtain the heat-insulating fire-extinguishing film. The prepared heat-insulating and fire-extinguishing film has good heat-insulating and fire-extinguishing performance.

The invention relates to a transparent phosphorescence-containing cured flame-retardant coating as well as a preparation method and application thereof. The transparent phosphorescence-containing cured flame-retardant coating comprises the following components: phosphorus-containing polyurethane acrylate, polyurethane acrylate, a double-bond-containing polyurethane organosilicon prepolymer, a nitrogen-containing acrylic monomer, a phosphorus-based flame retardant A, a phosphorus-based flame retardant B, silica sol, a reactive diluent B, a silane coupling agent and other auxiliaries. The coating disclosed by the invention has adhesive force, flame retardance and weather resistance, and can be directly cured on a light flexible photovoltaic module panel and a back plate through UV to achieve transparent, fireproof, flame-retardant and weather-resistant effects.

The invention belongs to the technical field of oil field gas channeling plugging agents, and discloses a high-molecular pre-crosslinked gel particle plugging agent suitable for a carbon dioxide drive oil reservoir and a preparation method of the high-molecular pre-crosslinked gel particle plugging agent. The raw materials comprise an acrylamide monomer, sodium bentonite, an acrylic monomer, an acid-resistant functional monomer, a temperature-resistant and salt-resistant functional monomer, a first cross-linking agent, a second cross-linking agent, an initiator, an inorganic reinforcing agent, an antioxidant and water. The prepared acid-resistant gel particle is good in temperature resistance, salt resistance and acid resistance and long in effective period of action, the viscosity of a system is increased after the particle swells for a certain time, the plugging capacity is enhanced, and the acid-resistant gel particle can be used as an excellent CO2 drive reservoir gas channeling plugging agent and is used for plugging a heterogeneous formation with developed micro-cracks.

The invention discloses a water-based paint of polydopamine modified acrylic resin and a preparation process of the water-based paint, and belongs to the technical field of water-based paint preparation. The water-based paint of the polydopamine modified acrylic resin is prepared from the following components in parts by weight: 30 to 40 parts of a mixed solvent, 1 to 5 parts of modified polydopamine, 12 to 28 parts of a modified viscosity agent, 15 to 25 parts of an acrylic monomer, 0.2 to 1 part of an initiator, 0.8 to 1 part of an emulsifier, 1 to 5 parts of a pH regulator and 60 to 70 parts of deionized water. The water-based paint prepared by the method has excellent adhesion, stability and mechanical properties.

The invention discloses a gallium-based liquid metal conductive hydrogel and a preparation method and application thereof.The method includes the steps that firstly, liquid metal gallium is modified through an amphiphilic block copolymer, so that the liquid metal gallium can be stably dispersed in a hydrogel precursor solution, hydroxyl radicals are generated through the liquid metal gallium, and the hydrogel precursor solution is formed; in-situ polymerization of an ionic liquid monomer and an acrylic acid monomer is further initiated to form a second network in the dual-network hydrogel, and the second network cooperates with a borate bond cross-linked polyvinyl alcohol first network to prepare the liquid metal-based conductive hydrogel with excellent conductivity, good mechanical properties and relatively strong interface adhesion. The problems that existing conductive hydrogel is poor in conductive filler compatibility, poor in liquid metal interface stability and the like are solved.

The invention provides nano-modified clay compounded hollow micro-powder and a preparation method thereof. The nano-modified clay compounded hollow micro-powder comprises the following components in percentage by mass: 55%-68% of nano-modified clay, 32%-45% of hollow micro-powder, 0.8%-4% of a functional aid and 0.1%-2% of a coupling enhancer, wherein the nano modified clay is obtained by performing dual modification treatment on natural clay, and the dual modification comprises the following steps: performing intercalation modification, adopting a composite modifier of a silane coupling agent and a titanate coupling agent, and stirring and reacting for 3-6 hours at 60-85 DEG C, the total dosage of the modifier is 3-8% of the mass of the clay; on the basis of intercalation modification, an acrylic monomer is introduced for free radical graft polymerization, and the grafting rate is 5-15%. According to the invention, through gradient compounding of the nano modified clay and the core-shell hollow micro-powder and the synergistic effect of intercalation modification and surface grafting modification, the interlayer spacing of the clay is enlarged to 1.85 nm or more, the specific surface area is increased to 120 m < 2 > / kg, and the interface bonding force with a polymer matrix is significantly enhanced.

The application discloses a kind of corrosion and scale integrated fracturing fluid, and relates to fracturing fluid technical field.The fracturing fluid includes thickening agent, crosslinking agent, composite corrosion and scale inhibitor and water;The composite corrosion and scale inhibitor includes the first component and the second component with mass ratio of 3:0.5~1, wherein the first component is prepared by the reaction of polyethyleneimine, long-chain acrylate monomer, acrylic acid monomer and hydroxyethyl acrylate monomer, and the second component is prepared by imidazole compound containing a primary amine and glyoxylic acid.The corrosion and scale integrated fracturing fluid of the application has good compatibility between components, and at the same time, it has good corrosion and scale inhibition and anti-sloughing performance.

The present invention relates to the technical field of building materials, and discloses a seawater-resistant calcium ferrite cement concrete and a preparation method thereof, which are obtained by using bis[3-(trimethoxysilyl)propyl]amine, perfluorohexylethylene, and 3-bromopropene as raw materials, through addition and quaternization reactions, polymerizing with acrylic monomers, and then compounding with calcium ferrite cement, composite steel slag powder, and modified basalt fibers, etc.; the fluorinated quaternary ammonium salt siloxane modifier has relatively rich siloxane bond functional groups on the surface of the siloxane, which can undergo a condensation reaction with the silanol groups on the surface of the concrete substrate after hydrolysis, effectively filling the pores and cracks in the concrete material; the composite steel slag powder admixture has fine particles, which can make the system structure filled more tightly and improve the ability to hinder the penetration and diffusion of Cl ‑ ions; the modified basalt fibers improve the dispersion stability in the matrix and further improve the seawater erosion resistance of the concrete.

The invention discloses a method for in-situ rapid growth of a dual-network hydrogel coating on the surface of a base material by a one-step method, which comprises the following steps: putting the base material with an adhesion initiation layer on the surface into a hydrogel precursor solution, and carrying out in-situ polymerization for 0.1-10 minutes under light irradiation, wherein the adhesion initiation layer comprises an adhesive compound based on a catechol group and a first photoinitiator, and the hydrogel precursor solution comprises a natural polymer containing tyrosine, an acrylic monomer, a cross-linking agent and a second photoinitiator, and wherein the first photoinitiator and the second photoinitiator are different from each other and are independently selected from a divalent ruthenium compound and a persulfate. Compared with the prior art, the natural / synthetic polymer double-network gel coating with biological activity and mechanical property can grow on the surfaces of different substrates more quickly and efficiently through a one-step method; and the base material, the surface of which is modified by the in-situ grown double-network hydrogel coating, obtained by the method can be applied to in-vivo medical apparatuses and instruments.

The invention belongs to the technical field of high polymer materials, and relates to a modified epoxy emulsion which comprises 70-80 parts of epoxy resin, 5-7 parts of an emulsifier, 0.4-0.8 part of an initiator, 60-80 parts of a mixed monomer and 180-220 parts of water. The mixed monomer is prepared from a soft and hard acrylic monomer, acrylic acid, glycidyl methacrylate, alkenyl silane modified nano silicon dioxide and caprolactone acrylate according to a specific proportion. The invention also discloses a preparation method of the modified epoxy emulsion, and in-situ grafting of nano silicon dioxide is realized by adopting a pre-emulsion step-by-step dropwise adding process. When the emulsion is applied to the three-dimensional anti-counterfeiting temperature-sensitive ink, the emulsion has a synergistic effect with expanded microspheres grafted with amino-containing benzene rings on the surfaces: epoxy groups of glycidyl methacrylate and amino groups on the surfaces of the expanded microspheres are crosslinked to form an interpenetrating network, nano silicon dioxide is dispersed in the interpenetrating network as a rigid node, and caprolactone chain segments provide network elasticity, so that the three-dimensional anti-counterfeiting temperature-sensitive ink is prepared. Therefore, the ink has high adhesive force, excellent wear resistance and weather resistance, and is particularly suitable for printing temperature change-three-dimensional double anti-counterfeiting marks.

The invention belongs to the technical field of rainwater treatment, and relates to a multifunctional bioretention pond for enhancing nitrogen and phosphorus removal, a water accumulation layer, a covering layer, a planting layer, a medium layer, a submerging layer and a drainage layer are sequentially distributed in the pond from top to bottom, the drainage layer is provided with a drainage pipe, and a water outlet of the drainage pipe is flush with the top of the submerging layer; the submerged layer contains modified wood chips and scrap iron which are filled in a layered manner, the modified wood chips are obtained by grafting reaction of wood chips through a functional copolymer, and the use amount of the functional copolymer is 6-10 wt% of the wood chips; the functional copolymer is obtained by carrying out a copolymerization reaction on a pyridyl-containing acrylic acid monomer and a double-bond-containing acyl halide monomer according to a molar ratio of 1: (0.1-0.3). Through wood chip modification and filling structure improvement, a submerged layer of the bioretention pond is filled with modified wood chips and scrap iron in a layered manner, so that the bioretention pond has the effect of enhancing nitrogen and phosphorus removal, and meanwhile, the removal effect on heavy metal pollutants is also greatly improved.

The application discloses a kind of marine reinforced concrete crack fast self-repairing agent and preparation method thereof, the self-repairing agent includes the following components by mass fraction: polyacrylic acid hydrogel 20-30%, microorganism 5-10%, betaine 20-30%, calcium salt 15-25%, aluminum salt 20-30%.Its preparation method is: acrylic acid monomer is mixed with crosslinking agent, initiator, auxiliary crosslinking agent;Aluminum salt, acrylic acid are mixed to obtain aluminum acrylate;The two are mixed with microorganism and betaine, stirring and heating, and microorganism-polyacrylic acid hydrogel is prepared;After drying, it is broken, and calcium salt powder is wrapped, then immersed in polymer emulsion, dried, and prepared.The application can quickly block cracks by forming organic-inorganic composite repair products, solidify harmful media, release beneficial ions, achieve the dual goal of crack self-repairing and reinforcement corrosion inhibition.

A photocurable composition includes a (meth)acrylic monomer component and a photopolymerization initiator, wherein an adhesive force of a cured product is less than or equal to 1.5 N, and a rupture elongation of the cured product is greater than or equal to 20%.

The invention relates to the technical field of photovoltaic packaging adhesive films, and discloses an EVA photovoltaic packaging adhesive film and a preparation method and application thereof. The EVA photovoltaic packaging adhesive film is prepared from 95 to 100 parts of EVA, 1 to 5 parts of high-bulk-resistance master batch, 0.5 to 1 part of main cross-linking agent, 0.1 to 0.8 part of auxiliary cross-linking agent, 0.1 to 5 parts of polyfunctional acrylic monomer and 0.25 to 3 parts of auxiliary agent, the high-bulk-resistance master batch is prepared from 70 to 100 parts of EVA (Ethylene Vinyl Acetate), 1 to 15 parts of modified boron nitride nanosheet and 1 to 15 parts of N-hydroxymethyl acrylamide. The EVA photovoltaic packaging adhesive film has the advantages of good light transmittance, high temperature, high bulk resistivity, low PCT aging and yellowing, low PID power attenuation and the like, can effectively improve the problems of polarization resistance, PID power attenuation and the like of the adhesive film after damp-heat aging, can ensure the power stability of a photovoltaic module in a damp-heat aging environment, is favorable for prolonging the service life of the photovoltaic module, and is suitable for popularization and application. And the photoelectric conversion efficiency is improved.

The invention relates to the technical field of batteries, and particularly discloses a low-porosity solid-state battery negative electrode and a preparation method thereof.The negative electrode slurry of the negative electrode comprises a polymer electrolyte A and a small molecule mixture B. The polymer electrolyte A is obtained by polymerizing an acrylic acid monomer, an acrylonitrile monomer and a sulfydryl-containing monomer; the small molecule mixture B at least comprises a flexible chain segment, fluorinated acrylate, a lithium salt, a plasticizer and a free radical initiator. In-situ polymerization is carried out in the coating process of the small molecule mixture B to generate a self-adaptive pore polymer electrolyte so as to reduce pores, and the polymer electrolyte A not only can improve the conversion rate of in-situ polymerization of the small molecule mixture B, but also can interact with the small molecule mixture B to form a dynamic cross-linked network for improving the stripping force of the pole piece; under the synergistic effect, the negative electrode / solid electrolyte interface contact is optimized, and the problems of poor interface contact and large interface impedance between the negative electrode active material and the solid electrolyte of the existing solid-state battery are solved.