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883 results about "Tricarboxylic acid" patented technology

A tricarboxylic acid is an organic carboxylic acid whose chemical structure contains three carboxyl functional groups (-COOH). The best-known example of a tricarboxylic acid is citric acid.

Cu-based organic skeleton-graphene oxide composite porous material and preparation method thereof

ActiveCN103432997AEasy to cleanReduce the activation energy of the interactionOther chemical processesMolecular sieveBenzene
The invention belongs to the technical field of metal organic skeletal materials, and discloses a Cu-based organic skeleton-graphene oxide composite porous material and a preparation method and application thereof. The preparation method particularly comprises the following steps of uniformly mixing copper acetate, 1,3,5-benzene tricarboxylic acid and graphene oxide; carrying out ball milling; washing; centrifugalizing; and drying to obtain the Cu-based organic skeleton-graphene oxide composite porous material. The preparation method disclosed by the invention has the advantages of short reaction time (only 30 minutes), no solvent, large preparation quantity, low energy consumption, simple operation method, and the like, is a high-efficiency, clean and environment-friendly novel green synthetic method. The obtained Cu-based organic skeleton-graphene oxide composite porous material greatly increases the adsorption capacity on hydrocarbon VOCs (Volatile Organic Compounds) and achieves the purposes that the adsorption capacity on methanol is 2.06 times of the adsorption capacity on the methanol caused by a Na-ZSM molecular sieve, 2.54 times of the adsorption capacity on the methanol caused by flexible-MOF(E), and 1.79 times of the adsorption capacity on the methanol caused by HKUST-1 under the same condition.
Owner:SOUTH CHINA UNIV OF TECH

Copper-based metal-organic framework porous material and preparation method and application thereof

The invention belongs to the technical field of metal-organic framework materials and discloses a copper-based metal-organic framework porous material and a preparation method and application of the copper-based metal-organic framework porous material. The preparation method comprises the following steps that copper acetate and 1,3,5-benzene tricarboxylic acid are mixed evenly and then subjected to ball milling; the mixture is washed 2-3 times with ethanol water and then is soaked, centrifuged and dried, and finally the copper-based metal-organic framework porous material is obtained. By means of the preparation method, solvents do not need to be added in the reaction process, the reaction is quick, operation is simple, and the organic solvents which are cheap and easy to get are adopted as exchange solvents in the activation process, so the preparation method is a novel efficient and economical green synthesis method. The copper-based metal-organic framework porous material obtained through the preparation method has a large specific surface area and high porosity, can well adsorb volatile organic compounds and has higher adsorbing capacity to methanol than activated carbon, zeolite and other traditional adsorbing agents on the same conditions, the adsorbing capacity of the copper-based metal-organic framework porous material is about twice that of a metal-organic framework material HKUST-1 prepared through a hydrothermal synthesis method.
Owner:SOUTH CHINA UNIV OF TECH

Preparation of corrosion and scale inhibitor used for high alkaline high chlorine circulating cooling water

The invention provides a preparation of a corrosion and scale inhibitor used for high alkaline high chlorine circulating cooling water which is prepared according to the following parts by weight: 23-25 parts of PESA, 23-25 parts of 2-phosphonic acid butane-1, 2, 4-tricarboxylic acid, 12-15 parts of corrosion and scale inhibitor, 10-15 parts of sodium gluconate, 5-8 parts of alkyl epoxy carboxylate, 2-3 parts of BTA, and 10-20 parts of pure water. The preparation comprises the following steps: adding industrial phosphoric acid of 400-420kg into a reaction kettle for stirring, adding triethanolamine of 140-160kg slowly within 30-35min, stirring for 50-60min, keeping the temperature at 40-80 DEG C, adding pure water of 385-400kg and stirring for 20-30min; adding zinc oxide of 45-55kg under stirring, stirring for 90-120min, and keeping the temperature at 40-80 DEG C to obtain the corrosion inhibition potentiating agent, adding PESA into the 2-phosphonic acid butane-1, 2, 4-tricarboxylic acid to mix with the solution of the corrosion inhibition potentiating agent, sequentially adding alkyl epoxy carboxylate, pure water and sodium gluconate to stir for 30-40min, keeping the temperature at 20-35 DEG C, then adding BTA, stirring for 30-60 min, and keeping the temperature at 20-35 DEG C to obtain the composite corrosion and scale inhibitor.
Owner:XINJIANG DELAND

Environment-friendly type composite pre-film reagent used for recirculated cooling water system pre-film processing and method of use thereof

The invention belongs to the circulating cooling water treatment technical field, and refers in detail to an environment-protecting composite pretreatment filming agent used for the pre-treatment filming in a circulating cooling water system and a use method thereof. The environment-protecting composite pretreatment filming agent comprises the main components of 2-phosphonobutane- 1, 2, 4-tricarboxylic acid and sodium of polyepoxysuecinic acid as well as a proper amount of carboxylic acid copolymer, benzotriazole, sodium molybdate, zinc sulphate and so on. When used, the composite pre-treatment filming agent is added into the circulating cooling water directly, and a corrosion-resistant protecting film is formed after 48 years of operation, the corrosion resistance of which to the standard copper sulphate drip solution is far better than the traditional phosphor-zinc pretreatment filming agent. The total phosphor content of the environment-protecting composite pretreatment filming agent is less than 7.5mg / l, and the water pH value does not have to be adjusted. After the pretreatment filming, the water is clear and transparent, and the normal operation can be started without replacing the water. Thus, not only the water to be replaced is saved, but also the chemical base investment expense during the normal operation after the water replacement is reduced. Meanwhile, no waste liquor of pretreatment filming is discharged, so the invention belongs to the environment-friendly pretreatment filming method.
Owner:TONGJI UNIV
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