Composite low-phosphorus corrosion and scale inhibitor and application thereof

A corrosion and scale inhibitor, compound application technology, applied in the direction of scale removal and water softening, water/sludge/sewage treatment, chemical instruments and methods, etc., can solve the problem of long-term operation without production equipment, damage to ecological balance, environmental Pollution and other problems, to achieve the effect of low phosphorus content, pollution reduction, wide pH range

Inactive Publication Date: 2012-09-19
CHINA PETROLEUM & CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

On the one hand, it has made a great positive contribution to solving the corrosion and scaling problems of industrial circulating water systems. It is conceivable that without the presence of polymeric phosphorus and organic phosphine, there will be no safe long-term operation of industrial circulating water systems and production equipment. Phosphorus systems Water treatment agents have brought huge wealth to society
On the other hand, because the phosphorus content in circulating water is generally 8-15mg / L, it brings a large amount of phosphorus-containing compounds to industrial wastewater, causing environmental pollution. Although phosphorus is non-toxic, as a nutrient source, it makes the water eutrophic It promotes the overgrowth of microorganisms, especially algae, causes lake water blooms, seawater red tides and other hazards, and destroys the ecological balance

Method used

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  • Composite low-phosphorus corrosion and scale inhibitor and application thereof
  • Composite low-phosphorus corrosion and scale inhibitor and application thereof
  • Composite low-phosphorus corrosion and scale inhibitor and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A compound low-phosphorus corrosion and scale inhibitor formula, which is composed of corrosion and scale inhibitor A and corrosion and scale inhibitor B, wherein:

[0024] Corrosion and scale inhibitor A is made by mixing polyepoxysuccinic acid (PESA), sodium gluconate, and water, and the weight ratio of each component is:

[0025] Polyepoxysuccinic acid (PESA) 20 parts

[0026] Sodium Gluconate 40 parts

[0027] 40 parts of water

[0028] Corrosion and scale inhibitor B consists of hydrolyzed polymaleic anhydride (HPMA), acrylic acid / 2-acrylamide-2-methylpropenesulfonic acid copolymer (AA / AMPS), 2-phosphonic acid butane-1,2,4 -Tricarboxylic acid (PBTCA), zinc salt, fluorescent tracer, and water are mixed, and the weight ratio of each component is:

[0029]

[0030] The zinc salt is zinc sulfate.

[0031] The above composite low-phosphorus corrosion and scale inhibitor formula is applied to circulating cooling water, and 30 mg of corrosion and scale inhibitor A ...

Embodiment 2

[0033] A compound low-phosphorus corrosion and scale inhibitor formula, which is composed of corrosion and scale inhibitor A and corrosion and scale inhibitor B, wherein:

[0034] Corrosion and scale inhibitor A is made by mixing polyepoxysuccinic acid (PESA), sodium gluconate, and water, and the weight ratio of each component is:

[0035] Polyepoxysuccinic acid (PESA) 25 parts

[0036] Sodium Gluconate 20 parts

[0037] 55 parts of water

[0038] Corrosion and scale inhibitor B is made by mixing hydrolyzed polymaleic anhydride (HPMA), acrylic acid / 2-acrylamide-2-methylpropenesulfonic acid copolymer (AA / AMPS), zinc salt, fluorescent tracer, and water , the weight ratio of each component is:

[0039]

[0040]

[0041] The zinc salt is zinc sulfate.

[0042] The above composite low-phosphorus corrosion and scale inhibitor formula is applied to circulating cooling water, and 35 mg of corrosion and scale inhibitor A and 70 mg of corrosion and scale inhibitor B are added ...

Embodiment 3

[0044] A compound low-phosphorus corrosion and scale inhibitor formula, which is composed of corrosion and scale inhibitor A and corrosion and scale inhibitor B, wherein:

[0045] Corrosion and scale inhibitor A is made by mixing polyepoxysuccinic acid (PESA), sodium gluconate, and water, and the weight ratio of each component is:

[0046] Polyepoxysuccinic acid (PESA) 30 parts

[0047] Sodium Gluconate 20 parts

[0048] 50 parts of water

[0049] Corrosion and scale inhibitor B is made by mixing hydrolyzed polymaleic anhydride (HPMA), acrylic acid / 2-acrylamide-2-methylpropenesulfonic acid copolymer (AA / AMPS), zinc salt, fluorescent tracer, and water , the weight ratio of each component is:

[0050]

[0051] The zinc salt is zinc sulfate.

[0052] The above composite low-phosphorus corrosion and scale inhibitor formula is applied to circulating cooling water, and 40 mg of corrosion and scale inhibitor A and 80 mg of corrosion and scale inhibitor B are added to each 1 li...

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Abstract

The invention provides a composite low-phosphorus corrosion and scale inhibitor and application thereof. The composite low-phosphorus corrosion and scale inhibitor is prepared from a corrosion and scale inhibitor A and a corrosion and scale inhibitor B, wherein the corrosion and scale inhibitor A is prepared from 20-40 parts of polyepoxysuccinic acid (PESA), 20-40 parts of sodium gluconate and 20-60 parts of water; and the corrosion and scale inhibitor B is prepared from 10-25 parts of hydroxypropyl methacrylate (HPMA), 10-25 parts of acrylic acid / 2-acrylamido-2-methylacrylsulfonic acid copolymer (AA / AMPS), 5-10 parts of 2-phosphonobutyl-1,2,4-tricarboxylic acid (PBTCA), 10-25 parts of zinc salt, 1-2 parts of fluorescent tracer and 13-64 parts of water. The technical scheme is as follows: the corrosion and scale inhibitor A and the corrosion and scale inhibitor B in a weight ratio of 1:2 are compounded with water. The composite low-phosphorus corrosion and scale inhibitor has excellent corrosion and scale inhibition effects, and thus, the phosphorus content in the product is low, thereby reducing the phosphorus discharge and having favorable environmental protection performance.

Description

technical field [0001] The invention relates to a composite low phosphorus corrosion and scale inhibitor and its application. Background technique [0002] Phosphorus formulations have been applied for more than 30 years since the mid-1970s. Phosphorus-based water treatment agents still occupy an absolutely dominant position in water treatment because of their low price and good corrosion and scale inhibition properties. On the one hand, it has made a great positive contribution to solving the corrosion and scaling problems of industrial circulating water systems. It is conceivable that without the presence of polymeric phosphorus and organic phosphine, there will be no safe long-term operation of industrial circulating water systems and production equipment. Phosphorus systems Water treatment agents have brought huge wealth to society. On the other hand, because the phosphorus content in circulating water is generally 8-15mg / L, it brings a large amount of phosphorus-conta...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/14
CPCC23F11/08C23F14/02
Inventor 胡迳嵩何思列彭亚南
Owner CHINA PETROLEUM & CHEM CORP
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