The application relates to the technical field of catalysts, and discloses a modified bimetallic catalyst and a preparation method and application thereof, the preparation method of the modified bimetallic catalyst comprises the following steps: adding a
niobium compound, a template agent, a
titanium compound and carbon balls into a
solvent to obtain a
mixed solution; then adding an amino precipitate into the
mixed solution to carry out reaction, and obtaining a crude product after
calcination; then reacting the crude product with an amino modification solution, and obtaining the product after
drying; on the one hand, the
titanium compound is added to modify the
niobium-based catalyst, chemical action occurs between the two kinds of metals, and the catalytic activity is enhanced; on the other hand, the hollow
porous catalyst is prepared by using the double-template combination and the hydrothermal method, transmission channels are provided for macromolecular sulfides, and the adsorption and
diffusion processes in the pore channel are accelerated; meanwhile, after the amino modification, the catalyst surface is rich in amino groups and the hydroxyl group polarity is enhanced, the catalyst can directly adsorb the
sulfone substances generated in the desulfurization process, and low-temperature and high-efficiency desulfurization is realized.