2069results about "Carbon nanotubes" patented technology

To provide a new carbon nanotube molding having sufficient physical properties such as specific surface area and mechanical strength even when used as a carrier for an electrode for electrochemical water splitting, an electrode for electrochemical water splitting using the same, a method for producing the same, and an electrochemical water splitting device.SOLUTION: Provided are: a carbon nanotube molding containing carbon nanotubes, wherein a specific surface area of the carbon nanotube molding is 700 m2 / g or more, a pore distribution of the carbon nanotube molding is 3 to 15 nm, a tensile strength of the carbon nanotube molding is 45 MPa or more, and a Young's modulus of the carbon nanotube molding is 1600 MPa or more; and a method for producing the same. Also provided are: an electrode for electrochemical water splitting comprising the carbon nanotube molding and platinum supported on the carbon nanotube molding; a method for producing the same; and an electrochemical water splitting device comprising the electrode for electrochemical water splitting.SELECTED DRAWING: Figure 1

The invention provides a high-rate and high-first-effect biomass hard carbon composite negative electrode material and a preparation method and application thereof, the hard carbon composite negative electrode material has a core-shell structure, the core-shell structure comprises a core, an inner shell and an outer shell, the core comprises biomass hard carbon containing P and graphite microcrystals, the inner shell comprises graphene, and the outer shell comprises a carbon nanotube. According to the invention, the surface of the biomass hard carbon is coated with the graphene layer, the carbon nanotubes grow on the surface of the graphene in situ, and transition metal synergistically induces the hard carbon to be arranged and grow along the graphene layer in a high-temperature carbonization process, so that the graphene coating layer is tightly coated, and the cycle performance of the material is improved; transition metal ions catalyze graphitization to generate a more regular and ordered graphite-like layer microcrystalline structure coating layer, so that the defects of graphene and carbon nanotubes are reduced, and the first coulombic efficiency is improved; in addition, the ion transmission capability is improved by phosphorus doping, the electron transmission capability is improved by graphite microcrystals generated by catalysis in hard carbon, and the rate capability is ensured by synergistic improvement of ion transmission and electron transmission.

The invention discloses an AI-assisted carbon nanotube growth control method and system, and relates to the technical field of control systems. Comprising the steps that a three-dimensional AI virtual platform builds a carbon nano tube model by collecting carbon nano tube growth data and environment data in unit time, the growth data comprise the growth rate, the direction and the diameter size, the environment data relates to gas flow and electric field intensity, the carbon nano tube model is mapped into a three-dimensional coordinate system, and the three-dimensional coordinate system is constructed; wherein the X axis, the Y axis and the Z axis respectively represent the length, the width and the height of the carbon nanotube, and recording initial coordinates. By using the three-dimensional AI virtual platform and the real-time data acquisition technology, the environment change in the growth process of the carbon nanotubes can be accurately captured, and the environment change can be quickly coped with during actual control by combining the growth data and dynamically adjusting the environment parameters in the growth process; and unstable growth or deviation caused by incapability of timely adjustment in a traditional method is avoided.

The invention discloses a preparation method of porous carbon, the porous carbon, a negative electrode material and a secondary battery, the preparation method of the porous carbon comprises the following steps: granulation: drying and granulating a phenolic resin microsphere suspension to obtain powder; nano carbon nanotubes are dispersed in the phenolic resin microspheres; and carbonization: sequentially carrying out secondary curing, pre-oxidation and carbonization on the powder to obtain the porous carbon. According to the preparation method, the porous carbon is prepared by adopting the nanoscale carbon nanotubes, firstly, the conductivity of the porous carbon is favorably improved due to the good conductivity of the carbon nanotubes, and meanwhile, the nanoscale carbon nanotubes are utilized, so that the carbon nanotubes can be more sufficiently dispersed, and the effect of improving the conductivity of the porous carbon by the carbon nanotubes is more favorably exerted; secondly, the tin or germanium element doped into the negative electrode material assists lithium ion deintercalation by reducing lithium ion transition energy barriers, so that the first effect is improved.

The present invention relates to a porous silicon-carbon composite having a core-shell structure, a preparing method therefor, and an anode active material comprising same, wherein the core comprises silicon particles and the shell comprises two or more carbon layers including a first carbon layer and a second carbon layer, so that the application of the composite as an anode active material for a secondary battery can enhance the discharge capacity, initial efficiency, and capacity retention rate of the secondary battery. In addition, the preparing method for the porous silicon-carbon composite having the core-shell structure enables the mass production through a continuous process with minimized steps.

The invention discloses a device and a method for preparing a single-walled carbon nanotube by a two-step method. The device comprises a carbon nanotube growth chamber, a product collection module, a catalyst supply module, a carbon source supply module and an etching agent supply module, the carbon source supply module is used for introducing a first airflow containing a carbon source in a first direction, the etching agent supply module is used for introducing a second airflow containing an etching agent in a second direction, and the first direction is opposite to the second direction so that the airflow intersects to form a vortex; the catalyst supply module introduces catalyst particles in a third direction, and the third direction points to the position near the vortex; and the product collecting module is arranged above the vortex and is used for collecting the formed single-walled carbon tubes. Controllable preparation of catalyst nanoparticles and ordered separation of carbon nanotube growth steps are realized, the influence of hybrid variables on the reaction is reduced, the vortex is formed by opposite intersection of airflow, and the problem of local deposition and blockage of tangential laminar flow is avoided by the vortex, so that the influence on the quality and continuous growth of the carbon nanotubes is avoided.

The invention discloses a silicon-carbon material, a preparation method and application thereof and a lithium ion battery. The preparation method of the silicon carbon material comprises the following steps: S1, performing carbonization treatment and activation treatment on a mixture of a carbon source and transition metal salt to obtain porous carbon; s2, performing carbon deposition on the porous carbon by adopting a chemical vapor deposition method, and growing a carbon nanotube in situ to obtain a first precursor; s3, performing silicon deposition on the first precursor by adopting a chemical vapor deposition method to obtain a second precursor; s4, carrying out carbon coating on the second precursor; and carrying out acid pickling and drying to obtain the silicon-carbon material. The silicon-carbon material is relatively good in conductivity and pressure resistance and excellent in expansion inhibition performance, and the prepared lithium ion battery can give consideration to excellent first effect, gram volume, rate capability and cycle performance.

The invention discloses a method and equipment for rapidly and continuously preparing carbon nano tubes with adjustable tube diameters, which are used for continuously and rapidly preparing carbon nano tubes with different tube diameters and at least comprise a catalyst precursor atomizing chamber, a plasma device, a carbon nano tube preparation reactor, a collector and a tail gas treatment device. A catalyst precursor solution enters the atomizing chamber through the injection pump to be atomized, atomized mist enters the plasma treatment device and then enters a reaction from a sample inlet in the upper portion of the reactor, after the reaction in the reactor is completed for a short time, the carbon nanotubes are collected from a collecting device on the lower portion of the reactor, and tail gas can be returned to the reactor after being filtered by the filter. The tail gas can be repeatedly used; and the continuous preparation of the carbon nano tubes with different tube diameters can be realized.

The invention discloses a lithium iron phosphate carbon nanotube composite material and a preparation method thereof, and belongs to the technical field of battery materials. The polydopamine is used as a carbon source to coat the lithium iron phosphate, so that the direct contact between the lithium iron phosphate and the electrolyte is avoided; meanwhile, the compatibility of the carbon nanotube composite material and the lithium iron phosphate is enhanced due to the strong adhesion, so that the carbon nanotube composite material is favorably adsorbed on the lithium iron phosphate to be sintered; a carbon coating layer formed by polydopamine and the carbon nanotubes are beneficial to permeation of an electrolyte and exposure of surface active sites, and metal ions are introduced into the carbon nanotubes of the carbon nanotube composite material, so that the electrochemical performance of the material is improved, and meanwhile, the carbon nanotubes are supported; the condition that the cyclicity of the material is reduced due to collapse of the carbon nano tube in the reaction process is prevented; cobalt is introduced outside the carbon nano tube, so that the energy density of the battery can be improved, the structures of the carbon nano tube and the positive electrode material can be stabilized, and the degradation of the material is reduced.

The invention belongs to the technical field of conductive carbon paste, and discloses a method for efficiently preparing single-walled carbon nanotube paste, which comprises the following steps of: 1, mixing single-walled carbon nanotube powder with a dispersing agent and a solvent, and dispersing the mixture into uniform carbon nanotube bundle paste in manners of mechanical stirring, emulsifying and the like; and step 2, enabling the uniform carbon nanotube bundle slurry to pass through different micropore channels for multiple times in a high-pressure environment, so that the carbon nanotube bundle slurry is dispersed into uniform single carbon nanotube slurry. Through a special high-pressure homogenizing channel, the adhered and wound single-walled carbon nanotube bundles can be dispersed into the slurry of the single single-walled carbon nanotubes on the premise of ensuring the lengths of the single-walled carbon nanotubes as much as possible. The uniform dispersion is realized, the tube diameter of the single-walled carbon nanotubes is relatively long, and the excellent conductivity of the slurry is ensured by the single single-walled carbon nanotubes and the microcosmic number of the single single-walled carbon nanotubes.

The invention provides a quick-charge and quick-discharge type lithium battery and a preparation method thereof, and belongs to the technical field of lithium battery preparation. The preparation process comprises the following steps: preparing a fluorinated carbon nanotube based on biomass carbon; preparing a positive electrode plate; preparing the dendritic mesoporous silicon dioxide nano particles; preparing a cerium oxide-loaded two-dimensional hierarchical porous composite material; preparing a negative electrode plate; and assembling the lithium battery. According to the preparation method, the eutectic and the carbon fluoride nanotubes are added in the preparation of the positive electrode plate, and the cerium oxide-loaded two-dimensional hierarchical porous composite material and the carbon fluoride nanotubes are added in the preparation of the negative electrode plate, so that the prepared positive electrode plate and the prepared negative electrode plate have relatively high conductivity; and moreover, the ion transmission efficiency is improved, the rapid ion transmission is beneficial to reducing the polarization phenomenon of the battery, improving the charging and discharging rate and the power performance of the battery, enhancing the structural stability of the electrode, improving the performance and the safety of the battery, and being more beneficial to rapid charging and rapid discharging.

The invention discloses a high-conductivity bridged silicon-carbon composite material as well as a preparation method and application thereof, and belongs to the technical field of lithium ion batteries. The high-conductivity bridged silicon-carbon composite material comprises a core-shell structure with an inner core and an outer shell, the inner core is porous carbon and a carbon nano tube growing on the surface of the porous carbon in situ, and a nano silicon layer is attached to pores and surfaces of the porous carbon and the carbon nano tube; and the shell is a carbon coating layer. According to the high-conductivity bridged silicon-carbon composite material provided by the invention, the carbon nanotubes are grown on the surface of the porous carbon in situ, and contact among particles is similar to bridging, so that a point-line conductive network is formed, the intrinsic conductivity of the composite material is improved, and the electron transfer rate is accelerated. Meanwhile, the carbon nanotubes have extremely high strength and hardness, the mechanical strength of the porous carbon substrate can be remarkably improved by introducing the carbon nanotubes into the porous carbon material, expansion of nano silicon in the charging and discharging process can be better restrained, and the performance of high capacity, high first efficiency, long circulation and high magnification is shown.

To provide a multilayer carbon nanotube assembly having high conductivity and excellent dispersibility to a dispersant, a multilayer carbon nanotube dispersion, a conductive material, an electrode, a secondary battery, a planar assembly, a filter, an electromagnetic wave-shielding and a pellicle for extreme-ultraviolet light.SOLUTION: A multilayer carbon nanotube assembly includes a multilayer carbon nanotube with a maximum length of 1000 to 30000 μm and an Fe atom, in which a content ratio of the Fe atom to a total mass of the assembly is 0.5 mass% or more and less than 10 mass%. There are also provided a multilayer carbon nanotube dispersion, a conductive material, an electrode, a secondary battery, a planar assembly, a filter, an electromagnetic wave-shielding and a pellicle for extreme-ultraviolet light.SELECTED DRAWING: None

The invention belongs to the field of flow energy storage battery materials, and particularly relates to a multi-dimensional conductive material, a preparation method thereof and application of the multi-dimensional conductive material in an all-vanadium flow battery. Graphite and multi-walled carbon nanotubes are bonded together by adopting a biomass precursor, a carbon base of biomass is converted into graphitized carbon nanotubes through step-by-step pyrolysis, amorphous carbon in the graphite and the original carbon nanotubes is further graphitized, and finally the multi-dimensional conductive material with the carbon nanotubes inserted on a graphite matrix is formed. The multidimensional characteristic of the surface of the multidimensional conductive material is beneficial to formation of a longitudinal conductive path of the bipolar plate and reduction of vertical body resistance of the bipolar plate, and is also beneficial to wetting of epoxy resin among conductive particles and mechanical interlocking of molecular chains of the epoxy resin, so that the mechanical strength of the bipolar plate is improved, the use performance of the bipolar plate is effectively enhanced, and the service life of the bipolar plate is prolonged. The requirement of long-time operation of the flow battery is met, the material cost of the flow battery is relatively reduced, the industrialization of the bipolar plate is powerfully promoted, and the application value is very good.

The invention relates to the technical field of lithium ion battery negative electrode materials, in particular to a graphite composite material and a preparation method and application thereof. The preparation method comprises the following steps: heating metal lithium to obtain lithium steam, and depositing the lithium steam into a metal organic framework material to obtain a lithium-doped metal organic framework material; a chemical vapor deposition method is adopted, carbon source gas and oxygen are introduced, amorphous carbon is deposited in the lithium-doped metal organic framework material, and an amorphous carbon and lithium co-doped metal organic framework material is obtained; and mixing the amorphous carbon and lithium co-doped metal organic framework material, a metal salt solution and a graphite material to obtain a mixture, heating, carrying out solid-liquid separation, taking solid components, introducing carbon source gas, and reacting to generate carbon nanotubes, thereby obtaining the graphite composite material. When the prepared graphite composite material is applied to a lithium ion battery as a negative electrode material, the battery has the advantages of high first efficiency, good liquid retention performance, low expansion, fast charge, good cycle performance and the like.

The invention provides a carbon nanotube modified polypropylene composite material and a preparation method thereof, and belongs to the technical field of antibacterial materials. According to the method, plant fibers are used as precursors, carbon nanotubes are prepared through high-temperature calcination, and the carbon nanotubes are subjected to surface activation treatment by using aids such as L-cysteine hydrochloride, sodium ascorbate and ethylenediamine, so that the dispersity and interface bonding force of the carbon nanotubes in a polypropylene matrix are remarkably improved. And then, mixing the modified carbon nano tube with polypropylene, polyhydric alcohol and a catalyst, reacting, and granulating through a double-screw extruder to prepare the composite material with excellent performance. The composite material disclosed by the invention has excellent mechanical properties, thermal stability, antibacterial property and conductivity, and is suitable for the fields of automobile parts, electronic device shells, building materials, medical apparatuses and instruments and the like. The method is simple in process, environment-friendly and efficient, renewable resources are fully utilized, and the method has a wide industrial application prospect.

There is provided a method for producing graphene or a hollow carbon nanostructure such as hollow spherical, ellipsoidal and tubular nanostructures. The method comprises a) mixing together water, an organic solvent that is immiscible with water, and a surfactant to prepare a suspension of self-assembled surfactant templates, b) adding a monomer to the suspension, c) polymerizing the monomer to form a polymer on the self-assembled surfactant template, and d) decomposing the polymer into carbon, thereby forming graphene or the hollow carbon nanostructure. There is also provided crystalline twisted bilayer or few-layer graphene which can be produced by this method.

The utility model belongs to the technical field of preparation of carbon nanotubes, and particularly relates to a carbon nanotube discharging device. The discharging device is arranged at the discharging end of the tubular heating furnace and comprises a collecting bin, and a collecting cavity communicating with a discharging opening of the tubular heating furnace is formed in the collecting bin. An operation opening is formed in the collecting bin, a flexible pipeline is connected to the operation opening, and the operation opening is connected with the near end of the flexible pipeline in a sealed mode; at least one operating rod penetrates through the flexible pipeline and extends into the collecting cavity, and the far end of the flexible pipeline is in sealed connection with the operating rod; a discharging connector is arranged at the bottom of the collecting bin. The collecting bin arranged at the discharging end is beneficial to timely removal of flocculent single-walled carbon nanotubes formed in the growth process, furnace tube blockage is prevented, production continuity is guaranteed, and safety is improved. And a flexible pipeline and an operating rod are arranged on the collecting bin, so that an operator can collect the carbon nanotubes under the condition that the normal operation of the heating furnace is not influenced. The winding roller is beneficial to orderly collection of carbon nanotube floccules.

The invention is applicable to the technical field of carbon nanotube materials, and provides a cobalt-selenium co-doped carbon nanotube and a preparation method and application thereof, and the preparation method comprises the following steps: adding cobalt nitrate hexahydrate and a carbon nanotube into a methanol solution to obtain a solution A; dissolving 2-methylimidazole in a methanol solution to obtain a solution B; mixing the solution A and the solution B to form a purple precipitate, separating and washing the purple precipitate, and performing vacuum drying to obtain a ZIF-67 (at) CNT precursor; and putting the ZIF-67 (at) CNT precursor and selenium powder into a tubular furnace, raising the furnace temperature and preserving heat under argon flow, and then cooling to room temperature to obtain the Co-CoSe (at) CNT. According to the invention, a diatomic cobalt (Co) and selenium (Se) co-doped carbon nanotube (CNT) material is adopted as a main body material of sulfur, through a synergistic effect, the chemical adsorption capacity of the electrode material is remarkably enhanced, polysulfide is effectively captured, and excellent physical barrier performance is provided, so that the shuttle effect is further inhibited, and the long cycle life of the lithium-sulfur battery is prolonged.

The invention discloses a high-initial-efficiency fast-charge graphite composite material and a preparation method thereof, the composite material is of a core-shell structure, the core is graphite, and the shell is lithium sulfonate / lithium molybdate and an amorphous carbon coating layer thereof; the mass ratio of the shell is 5-15 wt% according to the mass ratio of the composite material being 100%. The preparation method comprises the following steps: adding a molybdenum compound into a solvent to prepare a solution, adding graphite oxide, an inorganic lithium salt and a carbon nanotube conductive solution, reacting for 2-12 hours at the temperature of 50-120 DEG C, filtering, carbonizing filter residues to obtain a lithium molybdate conductive agent coated graphite material, and depositing a lithium sulfonate derivative on the surface of the lithium molybdate conductive agent coated graphite material by an atomization method to obtain the lithium molybdate conductive agent coated graphite material. The electron and ion conductivity of the material can be improved, and the rate and the first efficiency of the material can be improved.

The invention relates to the technical field of lithium ion battery negative electrode materials, in particular to a coating modification method of a negative electrode material, the negative electrode material and application of the negative electrode material, and the negative electrode material sequentially comprises a silicon core, a gradient interface layer, a self-repairing elastic layer and a hierarchical porous carbon skeleton from inside to outside; the gradient interface layer coats the surface of the silicon core and sequentially comprises an amino silane coupling agent modification layer and a conductive polymer layer from inside to outside; the self-repairing elastic layer covers the outer side of the gradient interface layer and comprises a dynamic covalent bond cross-linked network; the hierarchical porous carbon skeleton coats the outer side of the self-repairing elastic layer, a strongly-combined gradient interface layer is firstly constructed on a silicon core through hydroxylation, amino silane coupling and conducting polymer in-situ polymerization, then a reversible cross-linked network is formed outside the gradient interface layer based on Diels-Alder dynamic covalent bonds, and in-situ crack repairing is achieved. And finally, biomass carbon and CVD carbon nanotubes are compounded, and a micropore / mesopore synergistic conductive buffer structure is formed outside the reversible cross-linked network, so that the cycling stability of the battery is improved.

The present invention provides a biomass negative carbon emission power generation system and a working method thereof, comprising: a biomass power generation unit; a flue gas outlet of the biomass power generation unit is connected to an inlet of a flue gas pretreatment unit, and the outlet of the flue gas pretreatment unit is connected to a CO2 inlet of a carbon dioxide to carbon nanotube unit; a wastewater outlet of the biomass power generation unit is connected to an inlet of a water pretreatment unit, and the outlet of the water pretreatment unit is connected to a water inlet of an electrolytic hydrogen production unit; a hydrogen outlet of the electrolytic hydrogen production unit is connected to an inlet of a hydrogen collection unit, and the outlet of the hydrogen collection unit is connected to a hydrogen inlet of the carbon dioxide to carbon nanotube unit; the above system can effectively reduce carbon dioxide emissions, which not only improves biomass utilization, and the generated products have higher economic value, but also achieves negative CO2 emissions.

In order to solve the problems that an existing positive electrode material is unstable in structure and low in energy density, the invention provides a positive electrode material and a preparation method thereof, a positive electrode plate and a battery, the positive electrode material comprises lithium cobalt oxide of a layered structure, the chemical formula of the lithium cobalt oxide is Li < 1-alpha-beta > Na < alpha > (Mg < gamma > Ti < delta > Co < 1-gamma-delta >) O2, alpha is smaller than or equal to 0.005, and beta is 0.02-0.05; gamma is equal to 0.002 to 0.004, delta is equal to 0.001 to 0.003, and gamma + delta is equal to 0.003 to 0.006.

The invention provides a preparation method of a small-diameter single-walled carbon nanotube, and relates to the technical field of carbon nanomaterials. The preparation method comprises the following steps: mixing a nanoscale catalyst, high-purity graphite powder and a liquid carbon source binder, and sequentially molding and sintering to obtain a mixed graphite rod; the nanoscale catalyst contains metal elements, and the metal elements are transition metal elements and / or aluminum elements; and carrying out plasma catalytic pyrolysis by taking the mixed graphite rod as an anode and a pure graphite rod as a cathode to obtain the small-diameter single-wall carbon nanotube. The preparation method provided by the invention is high in yield (the mass ratio of the single-walled carbon nanotubes in a crude product is high), and the single-walled carbon nanotubes with smaller tube diameters can be prepared. Results of the embodiment show that when the preparation method provided by the invention is adopted to prepare the single-walled carbon nanotube, the mass ratio of the single-walled carbon nanotube in a crude product can reach 79%, and the diameter of the single-walled carbon nanotube can be as low as 1.2 nm.

The present disclosure provides a nanotube dispersion that includes a dispersion medium, a polyetheralkanol amine dispersant and carbon nanotube material. The nanotube dispersion may be used in various applications, such as in the production of electrodes for secondary batteries.

The invention provides a preparation method and application of a carbon nanotube sponge / liquid metal composite material. The preparation method of the carbon nanotube sponge / liquid metal composite material comprises the following steps: 1) preparing a porous carbon nanotube sponge by adopting a chemical vapor deposition method, and removing surface impurities through plasma cleaning to form a hydrophilic oxygen-containing group; 2) placing the liquid metal gallium-indium eutectic in an ethanol solution, and carrying out ultrasonic dispersion to prepare a uniform liquid metal dispersion liquid; 3) immersing the pretreated carbon nanotube sponge into the liquid metal dispersion liquid, and placing in vacuum to realize vacuum-assisted impregnation; and 4) drying the soaked carbon nanotube sponge in a drying oven at 40 DEG C, and compacting the composite material through rolling operation. According to the application of the carbon nanotube sponge / liquid metal composite material in the field of electromagnetic shielding, the conductivity and the electromagnetic shielding effectiveness of the material are remarkably improved, and the carbon nanotube sponge / liquid metal composite material has a wide application prospect.

The invention discloses single-walled carbon nanotube production equipment and a control method thereof, and belongs to the technical field of single-walled carbon nanotube production. The production equipment comprises a main reactor as well as an arc plasma torch assembly and a catalyst assembly which are mounted on the main reactor, and the arc plasma torch assembly and the catalyst assembly respectively extend into the main reactor and are arranged at intervals; a catalyst supplementing opening is formed in the upper side of the main reactor and is communicated with a catalyst feeding assembly through a catalyst supplementing pipeline; and the control unit is used for controlling the state of the catalyst supply assembly according to the voltage value of the arc plasma torch assembly. The invention solves the problem of production interruption caused by unstable electric arc between the cathode and the anode of the existing single-walled carbon nanotube production equipment.

The invention provides a preparation method of a heteroatom-doped mesoporous carbon nanotube material and application of the heteroatom-doped mesoporous carbon nanotube material in a lithium-sulfur battery. The preparation method comprises the following steps: S1, preparing a polyphosphazene nanotube by utilizing a self-template method; s2, preparing PZS coated SiO2 by adopting a sol-gel method; s3, NPS-C coated SiO2 is prepared through carbonization; and S4, adding the NPS-C-coated SiO2 powder into an etching solution, stirring, centrifuging, washing, and finally performing vacuum drying at room temperature to obtain the NPS-C material. The NPS-C obtained by carbonizing the precursor prepared on the basis of a self-template method and a sol-gel method has excellent conductivity, the mesoporous hollow structure can be used as a sulfur species packaging framework to inhibit large volume fluctuation in the circulation process, heteroatoms can adsorb and fix polysulfide to effectively inhibit the shuttle effect, and the performance of the NPS-C is improved. And a new thought is opened up for exploration and design of the high-performance electrode material of the lithium-sulfur battery.

The invention discloses an ethanol-regulated layered metal oxide, a preparation method thereof and an application of the ethanol-regulated layered metal oxide in preparation of a single-walled carbon nanotube by catalytic cracking of methane, alkali liquor and soluble metal salt containing Fe, Mo, Mg and Al are dropwise added into an alkaline ethanol aqueous solution to form a precipitate, and the ethanol-regulated Fe-Mo / MgAl-LDOs catalyst is obtained after aging, drying and calcining. The catalyst is applied to methane catalytic cracking to prepare the single-walled carbon nanotube. According to the technical scheme, the dispersity of active components in the layered metal oxide is effectively improved, the layered metal oxide has larger specific surface area and pore diameter, but the pore volume is reduced, and the situation that growth of SWCNTs stops due to wall collision in the growth process is effectively avoided.

The invention relates to the technical field of energy storage, in particular to an iron monatomic modified carbon nanotube array, a preparation method and application of the iron monatomic modified carbon nanotube array in an aqueous zinc-iodine battery, simple and convenient solid-phase reaction and high-temperature carbonization strategies are adopted, carbon cloth serves as a substrate, ferric acetylacetonate, boric acid, polyethylene glycol and urea serve as an iron source, a boron source, a carbon source and a nitrogen source respectively, and the iron monatomic modified carbon nanotube array is prepared. And after high-temperature calcination, growing an iron monatomic modified carbon nanotube array on the carbon cloth in situ. The iron single atom not only enhances the chemical capture capability of the carbon nanotube on the polyiodide, but also promotes the oxidation-reduction conversion of iodine; the carbon nanotube array provides a physical space for limited adsorption of iodine species and effectively promotes ion diffusion. Therefore, the obtained water-based zinc-iodine battery shows high specific capacity and good cycling stability. The whole technological process is simple and convenient to operate, has industrial application prospects, and provides a novel preparation method for the carbon-based iodine positive electrode host material of the aqueous zinc-iodine battery.