The present application belongs to the technical field of thermosetting
polyphenyl ether, and particularly relates to a thermosetting
polyphenyl ether, a preparation method and application thereof. The preparation method of the thermosetting
polyphenyl ether comprises the following steps: mixing a
copper catalyst, an amine compound, an
organic acid compound, an
organic acid ester compound, a monohydric
phenol, a dihydric
phenol and a
solvent, reacting, removing the
copper catalyst, and obtaining a double-end hydroxyl polyphenyl
ether solution; mixing a capping catalyst, an alkenylating agent and the double-end hydroxyl polyphenyl
ether solution, reacting, and separating and purifying to obtain the thermosetting polyphenyl
ether. In the process of oxidative copolymerization, the
organic acid compound and the organic acid ester compound are simultaneously added, the two compounds synergize, and in combination with other components, the colority of the thermosetting polyphenyl ether can be obviously reduced, and the
platinum-
cobalt colority value of a 50wt%
butanone solution can be as low as 14-16; at the same time, the
inherent viscosity and the molecular structure of the thermosetting polyphenyl ether are not obviously changed.