102results about How to "Improve intrinsic viscosity" patented technology

Multilayered plastic bottles are disclosed having oxygen scavenging capacity sufficient to maintain substantially zero or near zero (depending on product requirements) presence of oxygen in the bottle cavity for the planned shelf life of the bottled product under specified storage conditions. The bottles feature a layer comprised of oxygen scavenger copolyester and may be used for bottling beer and other products requiring nearly total absence of oxygen for the duration of the target product shelf life.

The invention discloses a polyamide and amine hybridized nanosilicon dioxide hyperbranched polymer and a preparation method thereof. The preparation method of the polymer comprises the following steps of firstly, modifying the surface of nanosilicon dioxide by using a coupling agent; then, carrying out Michael addition reaction and amidation reaction on the modified nanosilicon dioxide by using ethylenediamine and methyl acrylate; finally, carrying out functional modification by using allyl glycidyl ether to obtain a functional polyamide and amine hybridized nanosilicon dioxide monomer, and initiating polymerization reaction on the functional polyamide and amine hybridized nanosilicon dioxide monomer, acrylamide, acrylic acid and a heat-resistant and salt-tolerant monomer by using a redox initiator or azobis(isobutylamidine) initiator. The hyperbranched polymer has a network structure with a polyamide and amine hybridized nanosilicon dioxide unit as a center, has excellent shear resistance, strong thickening property, heat resistance and salt tolerance, and is wide in adaptability and capable of being used as an oil displacement agent for increasing the recovery rate of raw oil in an oil field environment with a high mineralization degree and a wide temperature range; the preparation method of the polyamide and amine hybridized nanosilicon dioxide hyperbranched polymer is reliable in principle, simple and convenient to operate and wide in application prospect.

The invention discloses a method for preparing a semi-aromatic polyamide. The method comprises the steps of adding aromatic dicarboxylic acid and aliphatic diamine containing 4 to 14 carbon atoms into a high-pressure autoclave, applying nitrogen pressure in the autoclave under a condition of water existence, rising the temperature so as to pre-polymerize, and then preparing high viscosity semi-aromatic polyamide resin by performing tackifying reaction on the pre-polymerized materials. The method of the invention prepares the semi-aromatic polyamide by applying nitrogen pressure, the diamine loss is avoided and the mole ratio of the dicarboxylic acid and the diamine can be accurately controlled so as to acquire the high viscosity semi-aromatic polyamide. The pre-polymerized material which has a viscosity eta ranged from 0.06 to 0.3 dl/g tested in 96% sulfuric acid at 25 DEG C by performing the pre-polymerization reaction is acquired. After the tackifying reaction is performed, the viscosity eta of the semi-aromatic aromatic polyamide is ranged from 0.8 to 2.5 dl/g, the melting point of the semi-aromatic aromatic polyamide is ranged from 270 to 330 DEG C, the content of the end carboxyl is ranged from 15 to 80 mol/t and the content of the end amino is ranged from 15 to 80 mol/t.

The invention discloses a method for preparing semi-aromatic polyamide. The method adopts low temperature of 170 DEG C to 190 DEG C for dehydration firstly, and then adopts a method for temperature-raising and prepolymerization to prepare the semi-aromatic polyamide, thus avoiding the loss of diamine and being capable of accurately controlling the molar ratio of the dicarboxylic acids and the diamine, obtaining the polyamide with high intrinsic viscosity and improving the quality of semi-aromatic polyamide. By the prepolymerization reaction, the prepolymer which is measured in 96 percent of sulphuric acid with the temperature of 25 DEG C and has the intrinsic viscosity Eta of 0.06 to 0.3dl/g can be obtained. After viscosifying reaction, the intrinsic viscosity Eta of the semi-aromatic polyamide is 0.8 to 2.5 dl/g and the melting point of the semi-aromatic polyamide is 270 to 330 DEG C; the content of terminal carboxyl group is 15 to 80 mol/t; and the content of amino-terminated group is 15 to 80 mol/t.

The invention discloses a semi-aromatic polyamide and a preparation method thereof. The method of the invention uses the aromatic dicarboxylic acid and aliphatic diamine containing 4 to 14 carbon atoms as the raw materials in order to prepare the semi-aromatic polyamide and acquire a new structure of the semi-aromatic polyamide. The semi-aromatic polyamide is prepared by combining high purity semi-aromatic polyamide salt so the polyamine loss is avoided and the mole ratio of the dicarboxylic acid and the diamine can be accurately controlled so as to acquire the high viscosity semi-aromatic polyamide. The monomer is purified in the salifying process, so the melting point, the crystallinity and the mechanical property of the semi-aromatic polyamide are promoted. The pre-polymerized material which has a viscosity eta ranged from 0.06 to 0.3 dl/g tested in 96% sulfuric acid at 25 DEG C by performing the pre-polymerization reaction is acquired. After the tackifying reaction is performed, the viscosity eta of the semi-aromatic aromatic polyamide is ranged from 0.8 to 2.5 dl/g, the melting point of the semi-aromatic aromatic polyamide is ranged from 270 to 330 DEG C, the content of the end carboxyl is ranged from 15 to 80 mol/t and the content of the end amino is ranged from 15 to 80 mol/t.

A 5- amino-6-hydroxy-2-MAB and its production are disclosed. The production is carried out by: (1) R1-R2, green synthesizing 4-amino-6-ANR.HCL by resorcinol; (2) R3: preparing AB monomer precursor 5-nitro-6-hydroxy-2-NHAB, and refining purifying; (3) R4: catalyst hydrogenating reducing NHBA nitro group, and obtaining high-purity AB PBO monomer. It achieves simple process, short polymeric time and normal polymeric apparatus.

The invention discloses a preparation method of degradable glycolic acid copolyester. Glycolic acid copolyester with high molecular weight is obtained by condensation polymerization of glycollic acid, adipic acid and ethylene glycol. The direct condensation polymerization is adopted, so that the whole process is short in procedure, less in side reaction and low in energy consumption during production; glycollic acid, adipic acid and ethylene glycol are taken as raw materials, so that the cost of the raw materials is low. Thus, the finally obtained glycolic acid copolyester is low in production cost. The prepared glycolic acid copolyester is high in intrinsic viscosity, good in mechanical property and excellent in practicability. In addition, the glycolic acid copolyester is completely prepared by the condensation polymerization of biodegradable monomers, so that the glycolic acid copolyester has the complete biodegradability; catalysts containing stannum, plumbum and the like, which have large toxicity, are not adopted in the preparation process, so that the glycolic acid copolyester is nonhazardous to a human body. As a result, the glycolic acid copolyester disclosed by the invention is a safe and environment-friendly high molecular material.

The invention discloses a preparation method of polyfuran dioctyl phthalate glycol ester. The preparation method comprises the following steps: (1) esterification or ester exchange reaction: adding furan dioctyl phthalate or furan dioctyl phthalate diester, ethylene and nitrogen-containing catalyst to a reactor, and reacting for 2-5 hours at 160-210 DEG C to obtain an esterification or ester exchange product; (2) polycondensation: reacting the esterification or ester exchange product in the conditions of pressure of less than or equal to 150Pa and temperature of 220-250 DEG C to prepare polyfuran dioctyl phthalate glycol ester. According to the invention, the efficient and high-selectivity nitrogen-containing catalyst is adopted, thus being favorable for improving the esterification or ester exchange rate, promoting polycondensation and improving molecular weight; and the prepared product is colorless or shallow in color, less in byproducts and good in structure regularity. According to the preparation method, only one nitrogen-containing catalyst is needed and is only added before reaction, adding of catalyst is not needed in the medium process, the process is very simple, the process is environmentally friendly, and realization of industrialization is facilitated.

The present invention provides a copolyester preparation method comprising successive esterification and polycondensation of a dihydric alcohol, a fatty diacid and two or more aromatic diacid in the presence of a catalyst for preparation of an amorphous copolyester. The present invention also provides a method for using the copolyester material for preparation of a wire material and application of the wire material in 3D printing. The printing temperature of the wire material used in fused deposition method 3D printing is low, an obtained product is small in size deviation, and sample shrinkage rate is low.

The invention provides a preparation method of high-molecular-weight polyacrylamide. The method includes the steps of performing segmented polymerization to acrylamide and an initiator in a high-pressure kettle with a supercritical CO2 medium to obtain high-molecular-weight polyacrylamide; and then performing supercritical CO2 fluid extraction to extract small-molecular monomers which are incompletely reacted to obtain high-purity polyacrylamide. The product is pure and is free of follow-up treatment. The reaction medium is toxic-free and environment-friendly. The preparation method is economic and practical, and is green and environment-friendly.

The invention relates to a macromolecular drag reducer, a preparation method and application thereof. The macromolecular drag reducer is prepared by slurry polymerization reaction of a macromolecular compound shown as formula (I), an alpha-olefin monomer and a catalytic system in an inert solvent, wherein the macromolecular compound shown as formula (I), the alpha-olefin monomer and the inert solvent are in a weight ratio of 0.1-0.3:1:0.5-0.8, the catalytic system is composed of a main catalyst and a cocatalyst, wherein the total weight of the main catalyst and the cocatalyst is 5-10% of the weight of the alpha-olefin monomer, and the weight ratio of the main catalyst to the cocatalyst is 1:0.3-0.5; and specifically, a, b and c are the number of links of repetitive unit, and the macromolecular compound shown as formula (I) has a molecular weight of 5000-10000. The macromolecular drag reducer provided by the invention has superior shear resistance and stability, even if after a fluid flows through a high shear part, the drag reduction effect is slightly reduced, the macromolecular drag reducer still has good drag reduction effect.

The invention relates to the field of polymer materials, and in particular relates to a method for preparing polytrimethylene terephthalate. The method comprises the following steps: (1) preparing a nano-tetrabutyl titanate/nano-silicon dioxide supported catalyst; and (2) synthesizing polytrimethylene terephthalate. The nano-tetrabutyl titanate/nano-silicon dioxide supported catalyst prepared by the method is high in activity, can be used either in a catalytic esterification reaction or a catalytic polycondensation, PPT (polytrimethylene terephthalate) prepared by utilizing the catalyst has high intrinsic viscosity, and is low in content of a terminal carboxyl group, so that titanate can be directly used as a catalyst and has high stability and good color.

The invention relates to the technical field of biodegradable materials, and discloses a polyglycolic acid-based biodegradable random copolymer and a preparation method thereof, wherein the copolymer comprises 71-95 mol% of a first repetitive unit and 5-29 mol% of a second repetitive unit; the structure of the first repetitive unit is represented by a formula I, and the structure of the second repetitive unit is represented by any one of formulas II-1-II-3; and a first monomer and a second monomer are subjected to esterification, prepolymerization and polycondensation to obtain the polyglycolic acid copolymer, and the copolymer not only has high thermal stability and good toughness, but also has the advantages of biodegradability, high barrier property, high strength and the like, and is excellent in comprehensive performance and wide in application prospect.

The invention relates to a method for preparing poly-oxalate-1,4-butylene, and belongs to the technical field of high polymer materials. The method comprises the following steps of: putting diethyl oxalate, 1,4-butanediol and a catalyst into a reactor, and reacting at the constant temperature of between 80 and 170 DEG C with stirring under the protection of N2 with the flow of between 0.06 and 0.16 m<3>/hour for 0.5 to 5 hours to obtain the poly-oxalate-1,4-butylene, wherein a ratio of the diethyl oxalate to the 1,4-butanediol is 1:1-1:3; and the catalyst is oxalic acid preferably, and the catalyst is 0.1 to 5.0 molar percent based on the diethyl oxalate. In the method, the diethyl oxalate and the 1,4-butanediol also can react at the constant temperature of between 110 and 180 DEG C under the vacuum degree of between 200 and 500 Pa under constant pressure for 3 to 8 hours in the presence of the catalyst to obtain the poly-oxalate-1,4-butylene with higher intrinsic viscosity. By the method, the reaction time is shortened, the vacuum degree of the reaction is reduced, the cost is low, and operation and aftertreatment are simple, so the method is suitable for industrial production.

The invention discloses an aliphatic polyester ionic polymer, which is prepared from aliphatic dibasic acid, aliphatic dihydric alcohol and a quaternary ammonium salt ionic monomer according to a mol ratio of 100:99.7:0.3-100:85:15 under the protection of nitrogen through esterification and polycondensation in sequence. The general structural formula of the aliphatic polyester ionic polymer is defined in the description. The aliphatic polyester ionic polymer has the intrinsic viscosity of 1.5-2.0 dL/g and the complex viscosity which is 1.6-3.1 times of that of pure aliphatic polyester at any appointed temperature in a range of 120-200 DEG C. The intrinsic viscosity and complex viscosity of the aliphatic polyester ionic polymer obtained in the invention are greatly improved, so that relatively high melt-strength, a low shear thinning effect, and excellent blow molding ability are ensured during a machine-shaping process, especially a blow molding process, and excellent foundation is laid in the application of extending the aliphatic polyester ionic polymer to the field of a film.

The invention discloses a novel preparation method of a starch-acrylamide grafted copolymer. The novel preparation method of the starch-acrylamide grafted copolymer comprises the following steps of: weighing starch and distilled water, and putting into a reaction vessel; stirring to gelatinize the starch; and adding an acrylamide monomer for reacting to obtain a product, and the like. In the invention, the starch and the acrylamide are reacted, so that the starch-acrylamide grafted copolymer can be synthesized successfully; moreover, synthesis efficiency is high, synthesis steps are simple, and synthesis cost is reduced; and initiator concentration in a preparation process is controlled, so that the transformation rate of a polymerization reaction and the limiting viscosity number of a polymer are increased.

The invention belongs to the technical field of polyester production, and particularly discloses a method. The method comprises the following steps: Step 1: preparation of a catalyst: firstly continuously stirring a hydroxycarboxylic acid, dropwise adding titanium alkoxide into the hydroxycarboxylic acid at the same time to carry out stirring reaction, adding an alkali solution, and controlling the pH to be less than or equal to 7, then allowing standing still to layer the solution to obtain lower supernate which is a hydrolysis-resistant titanium-based liquid catalyst, and taking out the lower supernate; Step 2: polyester synthesis: placing terephthalic acid and 1,4-butanediol in a reactor, catalyzing the terephthalic acid and the 1,4-butanediol by using the hydrolysis-resistant titanium-based liquid catalyst prepared in Step 1 for esterification for 60 to 240 min to synthesize a PBT oligomer, lowering the pressure of the PBT oligomer within 30 to 120 min to 1 to 100 Pa, adjusting thetemperature to 240 to 260 DEG C, and performing condensation for 60 to 300 min to synthesize the PBT polyester. The catalyst preparation process used in the method is simple, and no hydrolytic precipitations are produced in the synthesis process; furthermore, the titanium-based liquid catalyst is uniform and high in flowability.

The present invention relates to a semi-aromatic PA6T/6 composite material, particularly to an organic montmorillonite (OMMT)/halogen-free diphosphonate fire retardation PA6T/6 composite material and a preparation method thereof. The organic montmorillonite (OMMT)/halogen-free diphosphonate fire retardation PA6T/6 composite material comprises, by mass, 20-200 parts of a PA6T/6 resin, 5-50 parts of a halogen-free diphosphonate fire retardation agent, and 1-10 parts of organic montmorillonite. The fire retardation composite material of the present invention has characteristics of high fire retardation efficiency, halogen-free fire retardation, green environmental protection, low harm on human health, low environment pollution, high fire retardation grade, and significant effect.

The invention relates to a polyester high polymer material, and discloses a high-transparency and high-heat-resistance copolyester resin and a preparation method thereof. The copolyester resin comprises the following components: (1) a binary acid component comprising: (a) 80-100 mol% of terephthalic acid residue, (b) 0-20 mol% of aromatic diacid residues; and (2) a dihydric alcohol component comprising: (a) 20-85 mol% of 2, 2, 4, 4-tetramethyl-1, 3-cyclobutanediol residues, (b) 15-80 mol% of a first diol residue, and (c) 0-30 mol% of a second diol residue. According to the copolyester resin disclosed by the invention, pentanediol residues or propylene glycol residues are introduced, so that blockage is avoided in the preparation process, the intrinsic viscosity is increased, the loss of CBDO monomers is inhibited, and the obtained copolyester has high glass transition temperature and excellent strength, toughness and thermal stability; and the foaming, foaming and expansion phenomena caused by thermal decomposition can be effectively inhibited in the melt processing process.

The invention discloses a synthetic method of polyglycollide in the technical field of polymers. The synthetic method comprises the following steps: respectively preparing chemically pure diglycolide, stannous octoate of which the mole fraction is 0.01% and lauryl alcohol of which the mole fraction is 0.01%; adding the diglycolide, the stannous octoate and the lauryl alcohol into a reaction kettle for reaction, sealing and vacuumizing the reaction kettle, and introducing nitrogen into the reaction kettle; rapidly heating the reaction kettle to 160 DEG C after reacting for 30 minutes, starting stirring the reactants in the reaction kettle at the same time, heating the inside of the reaction kettle to 230 DEG C at a rate of 1.67 DEG C/min after 45 minutes, and taking out a polymer after reacting for 105 minutes; and performing vacuum drying on the polymer for 24 hours at 30-35 DEG C, performing extraction on a dried sample for 48 hours on soxhlet extractor by using ethyl acetate, and performing vacuum drying on the polymer for 24 hours at 30-35 DEG C. the polyglycollide prepared by the synthetic method disclosed by the invention is uniform in performance, can realize batch production, and is relatively high in conversion rate.

A method for treating polyesters comprises combining discrete particles of a polyester with an alkaline composition such that the alkaline composition coats the polyester particles. The particles are then heated in an environment that is at least substantially free of water. The method can be effectively used in cleaning, decontaminating and even increasing the intrinsic viscosity of polyester materials. Moreover, when used in the recovery of polyester materials containing contaminants and/or impurities, the method can provide a superior polyester product both in terms of intrinsic viscosity and color.