Novel preparation method of starch-acrylamide grafted copolymer

A technology of graft copolymer and acrylamide, which is applied in the field of new preparation of starch-acrylamide graft copolymer, can solve the problems of molecular weight reduction, slow reaction speed, fast product reaction speed, etc., so as to improve the conversion rate of polymerization reaction and The effects of polymer intrinsic viscosity, reduced synthesis cost, and simple synthesis steps

Inactive Publication Date: 2012-05-23
李波
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Problems solved by technology

[0014] In the preparation process of starch-acrylamide graft copolymer, the concentration of the added initiator has a great influence on the conversion rate of the polymerization reaction and the intrinsic viscosity of the polymer. When the concentration of the initiator is low, the concentration of free radicals is low and the reaction speed is slow. , the conversion rate is low; if the concentration of the initiator is too high, the reaction speed of the product will be too fast, the molecular weight will decrease, and the side reactions will increase at the same time

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  • Novel preparation method of starch-acrylamide grafted copolymer
  • Novel preparation method of starch-acrylamide grafted copolymer
  • Novel preparation method of starch-acrylamide grafted copolymer

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Embodiment

[0036] The novel preparation method of a kind of starch-acrylamide graft copolymer that the present invention relates to, its concrete steps are as follows:

[0037] (a) take starch and distilled water, place in reaction vessel, place reaction vessel in water bath;

[0038] (b) Install the stirring device and start stirring;

[0039] (c) feed nitrogen to remove the oxygen of the starch liquid in the reaction vessel;

[0040] (d) heating up and keeping it for a period of time to make the soluble starch gelatinize completely;

[0041] (e) system is cooled to reaction temperature;

[0042] (f) Continue to feed nitrogen into the gelatinized and cooled starch liquid, add an initiator, and the concentration of the initiator is 1.4mmol / L-1.6mmol / L, stir, and then add a certain amount of acrylamide monomer;

[0043] (g) Stirring is continued, and the starch and acrylamide are polymerized within a specified time to obtain a starch-acrylamide graft copolymer product.

[0044] In the s...

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Abstract

The invention discloses a novel preparation method of a starch-acrylamide grafted copolymer. The novel preparation method of the starch-acrylamide grafted copolymer comprises the following steps of: weighing starch and distilled water, and putting into a reaction vessel; stirring to gelatinize the starch; and adding an acrylamide monomer for reacting to obtain a product, and the like. In the invention, the starch and the acrylamide are reacted, so that the starch-acrylamide grafted copolymer can be synthesized successfully; moreover, synthesis efficiency is high, synthesis steps are simple, and synthesis cost is reduced; and initiator concentration in a preparation process is controlled, so that the transformation rate of a polymerization reaction and the limiting viscosity number of a polymer are increased.

Description

technical field [0001] The invention relates to a novel preparation method of a starch-acrylamide graft copolymer. Background technique [0002] my country is one of the countries with severe water shortage in the world, and the total amount of water resources in my country ranks fourth in the world, but according to the population statistics in 2002, the per capita water resources are 2220m 3 , only 1 / 4 of the world's per capita water resources, equivalent to 1 / 4 of the United States, 1 / 2 of Japan, and 1 / 44 of Canada, ranking 110th in the world. Moreover, the temporal and spatial distribution of water resources is extremely uneven, that is, there is more water in the south, less water in the north, more water in summer, and less water in winter, resulting in a situation of flooding in the south and drought in the north. The water resources in the south of the Yangtze River Basin account for more than 80% of the country's water resources, and only 1 / 3 of the country's culti...

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F251/00
Inventor 李波
Owner 李波
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