The invention discloses a high-barrier polyolefin composite film, which comprises a printing protection layer, a printing decoration layer, an adhesive layer, a sheet-shaped inorganic silica PVA coating layer and a heat sealing layer which are sequentially arranged. The high-barrier polyolefin composite film well overcomes the technical defects of the existing polyolefin composite film by adoptinga PVA coating technology of a sheet-shaped inorganic silica. The high-barrier polyolefin composite film still has excellent barrier performance under high humidity, can reach 0.5-1.0 CC/M2.24 H onlyby coating 0.6-0.8 micron, has excellent fragrance retention, is obviously superior to VMPET and PVDC coating layers, is environment-friendly, has no organic matter emission in the processing process,so that the film is beneficial to recycling; the high-barrier polyolefin composite film can be widely used for packaging liquid foods, such as refrigerated fresh milk, refrigerated yogurt, edible soybean oil, edible vinegar and the like, the packaging cost is reduced, and meanwhile, the quality guarantee performance is improved.