High-barrier polyolefin composite film
A polyolefin, high-barrier technology, used in polyurea/polyurethane adhesives, non-polymer adhesive additives, adhesive types, etc., can solve the problem of long drying tunnel, poor heat resistance, and no barrier properties. and other problems, to achieve the effect of overcoming technical defects, reducing packaging costs, and excellent barrier performance.
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[0035] The present invention also provides a kind of preparation method of polyurethane adhesive, comprises the following steps:
[0036] 1) Add diphenylmethane diisocyanate, polytetrahydrofuran diol, epoxy resin, castor oil, styrene, dibenzoyl peroxide and additives into a stirring tank and heat and stir evenly;
[0037] 2) Continue to add filler and curing agent, heat and stir evenly to obtain polyurethane adhesive.
[0038] Then the polyurethane adhesive is rolled between the layers (between the printing decoration layer 2 and the flake inorganic silicon dioxide PVA coating 4), and the polyurethane adhesive layer 3 is obtained after drying.
Embodiment 1
[0041] The polyurethane adhesive comprises the following materials by weight:
[0042]
[0043] Wherein, the polyurethane adhesive also includes 15 parts by weight of closed-1,2-docaborane. The filler is a mixture of nano-zinc oxide powder, nano-calcium carbonate powder and nano-alumina powder. Auxiliaries also include stabilizers and coupling agents.
Embodiment 2
[0045] The polyurethane adhesive comprises the following materials by weight:
[0046]
[0047] Wherein, the polyurethane adhesive also includes 18 parts by weight of closed-1,2-docaborane. The filler is a mixture of nano-zinc oxide powder, nano-calcium carbonate powder and nano-alumina powder. Auxiliaries also include stabilizers and coupling agents.
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