7572 results about "Mechanical properties of carbon nanotubes" patented technology

A symmetric touch screen switch system in which both the touch side and panelside transparent electrodes are comprised of carbon nanotube thin films is provided. The fabrication of various carbon nanotube enabled components and the assembly of a working prototype touch switch using those components is described. Various embodiments provide for a larger range of resistance and optical transparency for the both the electrodes, higher flexibility due to the excellent mechanical properties of carbon nanotubes. Certain embodiments of the symmetric, CNT-CNT touch switch achieve excellent optical transparency (<3% absorption loss due to CNT films) and a robust touch switching characteristics in an electrical test.

The invention prepares a nanometer rare earth inorganic substance/ rubber composite with high wear resistant and excellent dynamic property. The invention adopts a mechanical blending method to prepare the nanometer rare earth inorganic substance and rubber composite. After the nanometer rare earth inorganic substance and the rubber are composited, higher modulus can be provided, the mechanical property of the rubber composite is improved, the abrasion stripes are blocked up to achieve the aim of dispersing stress through the high strength of the nanometer rare earth inorganic substance so as to improve wear-resisting property, and the internal friction of the composite is improved by utilizing the specific characteristic of smooth surface of the rare earth material so as to achieve the aim of reducing internal friction and resistance to rolling. According to the material prepared by the invention, the modulus can be improved, the mechanical property is improved, the abrasion is greatly reduced simultaneously, the internal friction and the resistance to rolling are reduced, and the composite can be widely applied to materials such as tyres, conveyer belts, sealing elements, piston rings, soles and the like.

The invention discloses a graphene-based barrier composite material, which has high barrier and mechanical performance and is prepared by using grapheme sheets which are two-dimension nano materials as an intensifier and uniformly dispersing the grapheme sheets in a polyolefin polymer by chemical crosslinking. The preparation method of the barrier composite material comprises: 1, functionally modifying the surface of the graphene oxide by using coupling agent to graft active functional groups on the surface of the graphene oxide, and reducing the modified graphene oxide into grapheme; and 2, uniformly dispersing the modified graphene into solution of the polyolefin to perform crosslinking under the action of an initiator to obtain the nano composite material. In the invention, the raw material is low in cost and readily available; the operation is easy, the process is simple, the repeatability is high, the graphene can well disperse in the polyolefin, and the prepared graphene-based barrier composite material has high polar and nonpolar solvent barrier performance and is obviously improved in tensile strength and fracture toughness.

The invention discloses a nanometer multiple-layer composite thermal insulation material and a preparation method thereof. The nanometer multiple-layer thermal insulation composite material is formed by alternatively overlapping an infrared reflecting screen and a spacer; the ratio of total layer amounts n of the infrared reflecting screens and the spacers to the total thickness of the nanometer multiple-layer composite thermal insulation material is 0.5-4; the infrared reflecting screen is a metal foil or a metal plated foil; the spacer is a thermostability nanometer porous aerogel composite thermal insulation material; the infrared reflecting screen and the spacer are combined by being adhered with thermostability adhesives or in puncturing connection by thermostability sewing threads. The invention also comprises the preparation method of the nanometer multiple-layer composite thermal insulation material. The nanometer multiple-layer composite thermal insulation material of the invention has low density, favorable mechanical property and favorable high-temperature thermal insulation property, lowers requirements on the vacuum degree by a VIP plate when being used as vacuum thermal insulation plate core materials, does not need getter and can satisfy harsh high-efficiency thermal insulation using requirements on materials by aviation, aerospace and civil fields. The method of the invention can prepare thermal insulation material members with large size and complex shape.

The invention relates to a carbon fiber reinforced boron carbide composite material and a preparation method thereof. The preparation method comprises the following steps of: preparing a carbon fiber preform by adopting a needling, puncturing or three-dimensional weaving process; and depositing boron carbide matrix in the porous carbon fiber preform by osmosis to form the compact carbon fiber reinforced boron carbide composite material. Aiming at a certain specific application environment, a boron carbide coat can be deposited on the surface of a sample by adopting the same chemical vapor osmosis process. The carbon fiber reinforced boron carbide-based composite material manufactured by the method has the characteristics of good mechanical property, toughness superior to that of the traditional sintered boron carbide, compact structure, light weight, abrasion resistance and high hardness, and is suitable to be applied to a high-temperature light structural component.

The invention relates to an oxidized graphene and graphene reinforced cement based composite material and a preparation method thereof. The oxidized graphene and graphene reinforced cement based composite material comprises the oxidized graphene, the graphene, a dispersing agent, a thickening stabilizer, a water reducer, a defoaming agent and a cement matrix, the mass ratio of the total mass of the oxidized graphene and the graphene to the cement matrix is (0.0005-0.5):1, and the mass ratio of the total mass of oxidized graphene and the graphene to the dispersing agent to the water reducer to the thickening stabilizer to the defoaming agent is 1:(0.05-10):(0.1-20):(0.1-20):(0.05-5). In the composite material, the oxidized graphene and the graphene are dispersed in the cement matrix uniformly; compared with the traditional cement material, the tensile strength, rupture strength and conductivity of the composite material are all improved remarkably; and the composite material has more excellent mechanical property and electrical property, and is applicable to the field of multifunctional construction materials.

The invention discloses a preparation method of a copper-plated graphene reinforced metal-based composite. The preparation method comprises the following steps: firstly, chemically plating the surfaces of oxidized graphene powder with copper to obtain copper-plated graphene powder; ball-grinding and mixing the copper-plated graphene powder and metal powder to obtain copper-plated graphene/metal mixed powder; and performing warm-pressing forming to the copper-plated graphene/metal mixed powder by adopting powder metallurgy warm-pressing technology, sintering, and performing composite processing and forming by adopting extrusion, forging, rolling and other technologies. The copper-plated graphene powder is adopted as a reinforcing body, the preparation method is simple, the cost is low, the designability is strong, and the copper-plated graphene reinforced metal-based composite which is good in interface binding, high in compactness and good in mechanical performance and thermophysical performance can be obtained.

The invention relates to a method for preparing polyacrylonitrile-based carbon fiber with reinforced carbon nanometer tubes, which comprises the following steps: respectively dispersing and dissolving carbon nanometer tubes (CNT) and polyacrylonitrile (PAN) in dissolvent, obtaining PAN/CNT spinning solution through mixing the solution, obtaining PAN/CNT fiber through carrying out the wet-spinning method to the solution, then carrying out pre-oxidation and carbonization to the wet-spinning fiber to prepare the carbon fiber with reinforced carbon nanometer tubes. The mechanical property of the carbon fiber which is prepared by the method of the invention is obviously improved, and the prepared carbon fiber can be applied to the fields of reinforcing materials, conducting, electrostatic resistance, heat conducting and the like.

The invention discloses a graphene and carbon nanotube mixed enhanced metal-matrix composite material and a preparation method thereof. The graphene and carbon nanotube mixed enhanced metal-matrix composite material is characterized in that graphene and a carbon nanotube are mutually connected to constitute an enhanced network in a metal matrix, wherein the graphene is few-layer graphene with 10 layers or less, the radius-thickness ratio of the graphene is larger than 200, and the volume fraction of the graphene is 0.1-1%; and the carbon nanotube is a single-wall, double-wall or multi-wall carbon nanotube, the length-diameter ratio of the carbon nanotube is larger than 20, and the volume fraction of the carbon nanotube is 0.5-5%. Compared with the composite material enhanced only by the carbon nanotube, the graphene and carbon nanotube mixed enhanced metal-matrix composite material disclosed by the invention not only has greatly improved mechanical properties, but also has more excellent electric conduction and heat conduction properties, and is a multi-purpose structure and function integrated material. In addition, the preparation method provided by the invention based on slurry blending and graphene oxide reduction is simple and efficient and is easy for large-scale production.

The invention relates to a method for preparing graphene-reinforced polyacrylonitrile carbon fibers. The method comprises the following steps of: (1) preparing graphene or graphene oxide; (2) preparing a graphene/polyacrylonitrile spinning solution; (3) preparing graphene/polyacrylonitrile-based composite fibers; and (4) preparing graphene/polyacrylonitrile-based carbon. By the method, the dispersibility and interface bonding strength of the graphene oxide in a polymer matrix are effectively improved, and the comprehensive performance of the carbon fibers is further improved; the mechanical properties of the prepared carbon fibers are obviously improved, and the prepared carbon fibers can be used in the fields such as material reinforcement, electric conduction, anti-static electricity and heat conduction; and moreover, the preparation process is simple, easy to control and low in cost.

The invention relates to a method for preparing a B4C-Al composite material, which is characterized by comprising the following steps of: 1, uniformly mixing a certain proportion of raw material boron carbide powder with aluminum alloy powder in a high-energy ball milling way; 2, compressing the uniformly-mixed power for molding; 3, sintering compression-molded compact in the step 2 at certain temperatures; 4, extruding sintered compact sintered in the step 3 at certain temperatures; and 5, conducting multiple-time hot rolling for the extruding-molded material in the step 4 at certain temperatures to obtain B4C-Al composite boards. By adopting the preparation method in the invention, the ball milling efficiency is high, the preparation process almost has no material loss, and the prepared B4C-Al composite boards have the characteristics of uniform distribution of boron carbide and good mechanical property and can be applied to neutron absorption/shielding.

The invention provides a preparation method of a self-suspension proppant for natural hydrofracturing construction, which comprises the following steps: by using 6-200-mesh granules as aggregate, adding an adhesive solution accounting for 10-30 wt% of the aggregate into the aggregate, and adding a water-soluble high polymer material accounting for 0.1-5 wt% of the aggregate; and stirring uniformly, drying and screening. The optimal selection of the raw materials and technological conditions greatly enhances the mechanical properties of the proppant. The obtained proppant has the advantages of small friction resistance and high strength, can be suitable for high-temperature conditions, and can be easily recovered; and the used coating material can not cause environmental pollution.

The invention discloses an organic-inorganic composite membrane as well as preparation and application thereof, and belongs to the technical field of preparation of a lithium ion battery material. The organic-inorganic composite membrane is prepared from inorganic particles and a high-molecular polymer, wherein the inorganic particles are evenly embedded and distributed inside the high-molecular polymer, and are selected from layered inorganic materials and/or porous inorganic materials; the mass ratio of the inorganic particles to the high-molecular polymer is (5-20):1; the particle sizes of the inorganic particles are 2-100nm. The organic-inorganic composite membrane disclosed by the invention has good mechanical property and lithium ionic conduction ability after absorbing electrolyte; the composite membrane has excellent safety performance after being prepared into an electric element, and is suitable for being applied to the field of a large battery, especially a large fixation energy storage battery. The organic-inorganic composite membrane is simple and feasible in preparation technology, and conveniently achieves industrial production.

The invention discloses a method for preparing high-strength conductive graphene fiber by a large-size graphene oxide sheet. The method comprises the steps of: oxidizing expanded graphite and obtaining graphene oxide; dispersing the graphene oxide into water, carrying out centrifugal classification treatment on the dispersed graphene oxide, and obtaining the large-size even graphene oxide sheet; and finally, dispersing the graphene oxide into water or polar organic solvent, preparing spinning solution liquid crystal sol with the mass concentration of 1-20%, transferring the spinning solution liquid crystal sol into a spinning device, continuously squeezing spinning solution out from a spinning head capillary tube at the uniform velocity, leading the squeezed spinning solution into solidification liquid, drying the solidified primary fiber, obtaining graphene oxide fiber, and then obtaining the graphene fiber by chemical reduction. A spinning technology is simple; and the obtained graphene fiber is good in electrical conductivity, excellent in mechanical property and better in toughness, can be woven into pure-graphene fiber cloth, and also can be woven with other fibers in a blending way so as to make various functional fabrics, so that the high-strength conductive graphene fiber can be used for replacing carbon fiber in a plurality of fields.

The invention provides a ceramic bovine flame retardant polymer composite material based on polyolefin or a thermoplastic polyurethane elastomer. The ceramic bovine flame retardant polymer composite material is prepared from the following components in parts by weight: 30-40 parts of polyolefin resin or the thermoplastic polyurethane elastomer, 25-45 parts of a ceramic forming filler, 20-30 parts of a halogen-free flame retardant, 1-5 parts of a flame-retardant synergist, 1-3 parts of a plasticizer, 0.5-2 parts of an antioxidant and 0.02-0.15 part of a crosslinking agent, wherein the ceramic forming filler is prepared from the following components including low softening point glass powder and a silicate mineral filler. The invention also provides application of the ceramic bovine flame retardant polymer composite material in the field of cables. According to the ceramic bovine flame retardant polymer composite material disclosed by the invention, a dense ceramic bovine product can be formed within a range from 600 DEG C to 1000 DEG C, and the formed ceramic bovine product is good in high-temperature strength and flame retardancy and is also good in mechanical properties under room temperature.

The invention discloses a polyurethane composite material for 3D printing, and a preparation method and application thereof. The invention is characterized in that the polyurethane composite material is prepared from the following initial raw materials in parts by weight: 100 parts of polyurethane, 0.1-10 parts of inorganic filler, 0.1-0.5 part of light stabilizer and 0.1-0.5 part of antioxidant. The preparation method comprises the following steps: evenly mixing 100 parts of polyurethane, 0.1-10 parts of inorganic filler, 0.1-0.5 part of light stabilizer and 0.1-0.5 part of antioxidant, and preparing power to obtain the composite material, wherein the average particle size of the composite material powder is 10-100 mu m. The product can be prepared by a 3D printing technique, such as selective laser sintering. The polyurethane has favorable flexibility; and the introduced inorganic filler improves the 3D printing performance of the polyurethane, so that the product has excellent mechanical properties. The tensile strength of the product prepared from the material by laser sintering can reach 20.12 MPa, and the elongation at break can reach 511.12%.

The invention provides a cement slurry with long-term-integrity cement sheath for a heavy-oil thermal-recovery well. The cement slurry comprises, by weight, 100 parts of thermally responsive cement, 25 to 65 parts of water and 0.2 to 8 parts of a cement slurry aid. The thermally responsive cement comprises 30 to 60 parts of oil well cement, 10 to 20 parts of active silicon powder, 0 to 10 parts of hollow glass beads and 10 to 50 parts of a thermally responsive composite material. The thermally responsive composite material comprises 20 to 30 parts of clay mineral, 10 to 20 parts of fly ash and/or vulcanic ash, 5 to 20 parts of rubber powder and/or latex powder, 3 to 10 parts of carbon fiber, 10 to 15 parts of nanometer silicon dioxide, 5 to 10 parts of calcined magnesia, 10 to 20 parts of ultrafine superfine slag powder and 5 to 10 parts of inorganic whiskers. The cement slurry provided by the invention can solidify at normal temperature; and set cement can resist long-term high temperature, and the mechanical properties and thermal properties of the set cement in a high temperature environment are integrally adaptive to strata and casing pipes.

The invention relates to a dual-interlayer symmetrical multi-pyramid configuration three-dimensional integrally-braid lattice composite material and a preparation method thereof. The composite material comprises an upper panel layer, a middle panel layer, a lower panel layer and lattice core layers arranged between the upper panel layer and the middle panel layer as well as between the middle panel layer and the lower panel layer. The composite material is characterized in that the upper panel layer, the middle panel layer and the lower panel layer form a dual-interlayer structure, the lattice core layers are of a space network truss structure consisting of symmetrical multi-pyramid configuration unit cells arranged periodically and communicated through holes, and the lattice core layers, the upper panel layer, the middle panel layer and the lower panel layer are weaved, alternated, wound and sutured into a whole according to the design rule and are subjected to once resin injection forming by adopting a resin transfer process. The preparation method in the invention comprises the steps of: 1, preparing the upper panel layer, the middle panel layer and the lower panel layer; 2, drilling a needle hole; 3, preparing the lattice core layers; and 4, curing and forming resins. The composite material prepared by the method has better integrity, more excellent mechanical property, lighter mass, higher bearing efficiency and better functionality in comparison with the traditional interlayer structure composite material.

The invention relates to radiation shield concrete and a preparation method thereof. The radiation shield concrete is characterized by comprising a cementing material, coarse aggregates, fine aggregates, steel fibre, a high-efficiency slushing agent and water; the cementing material is composed of ordinary portland cement and inorganic mineral admixtures; the inorganic mineral admixtures are siliceous dust and coal ash; the fine aggregates are natural sand, boron glass powder and steel slag powder; the coarse aggregates are steel sections or a mixture of the steel sections and steel slag; the proportions of various types of components are as follows: 500 kg/m<3> of cementing material, 1400-2215 kg/m<3> of coarse aggregates, 750-950 kg/m<3> of fine aggregates, and 155-200 kg/m<3> of water; the high-efficiency slushing agent is 0.5-1.0% of the total weight of the cementing material by weight; and the steel fibre is 1.0-1.5% of the total volume of the concrete by volume. The radiation shield concrete has good mechanical property and lasting quality, good shielding effect on gamma rays, good effect on shielding neutron rays, can be used or comprehensively recycling wastes and has low cost.

The invention discloses a macromolecule heat conduction and dissipation blended composite material. The macromolecule heat conduction and dissipation blended composite material is prepared from, by mass, 35-75 parts of matrix resin, 0-10 parts of flexibilizer, 20-50 parts of heat conduction filler, 0.2-1.0 part of antioxidant 1010, 0.2-1.0 part of phosphite ester antioxidant 168, 0.5-1.5 parts of powder surface activation treating agents and 0.5-1.5 parts of lubricant. An automatic preparation method of the macromolecule heat conduction and dissipation blended composite material includes the steps of firstly, conducting surface treating on heat conduction filler for 20 min through powder surface activation treating agents in a high-speed stirring machine; secondly, making the heat conduction filler enter another high-speed stirring machine through an automatic conveying device to be evenly mixed with other materials; thirdly, automatically conveying the mixture obtained in the second step to an internal mixer to be mixed and kneaded for 15 min; fourthly, making the obtained mixture directly enter a double-screw extruder to be extruded and granulated. The prepared heat conduction and dissipation material has the high mechanical property and heat conduction performance, automatic and continuous production is achieved, a large amount of labor is saved, the production period is greatly shortened, the production cost is greatly reduced, and the macromolecule heat conduction and dissipation blended composite material can be widely applied to the fields of LED illumination, electronic electrical appliances, automobiles and the like where good heat conduction and dissipation performance is required.

The invention relates to a negative pole piece, which comprises a negative pole current collector and a negative pole film layer, wherein the negative pole film layer is arranged on the negative pole current collector and comprises at least two negative pole active material layers; and the at least two negative pole active material layers are sequentially arranged on the negative pole current collector from the inside to the outside according to the lithium-ion dynamic property decreasing order of the negative pole active material layers. The invention particularly relates to the negative pole film layer of which the negative pole active material is a graphite/hard carbon and/or silicon material composite material. The graphite is compounded with the hard carbon and/or silicon material, and a multi-layer gradient of which the lithium-ion dynamic property is sequentially increased from the outside to the inside is formed, so that the negative pole piece has the effects of simultaneously improving the charging capability and increasing the energy density.

The invention discloses a method for improving thermal conductivity of thermal conductive polymer. The method comprises the following steps of: adding a polymer substrate into a high speed mixer, adding a thermal conductive filler and other additives into the high speed mixer, continuously mixing uniformly, and feeding into a main feeding port of a double-screw extruder; controlling the ratio of a reinforcing component to the nanometer thermal conductive filler to be 20:1-5:1, adding the reinforcing component into the high speed mixer, adding the nanometer thermal conductive filler and a surface modifier, continuously mixing to ensure that the thermal conductive filler is adhered to the surface of the reinforcing component, uniformly mixing, and feeding into a side feeding port of the double-screw extruder; and performing melt blending on raw material components by using the double-screw extruder, extruding, performing water cooling, pelletizing, sieving, packaging and the like to obtain the thermal conductive polymer with improved thermal conductivity. The thermal conductive polymer prepared by the method has the improved thermal conductivity and keeps high mechanical properties.

The invention belongs to the technical field of high-temperature alloy near net shape forming and discloses a method for preparing oxide dispersion strengthened alloy by rapid forming. The method includes: using the mechanical alloying process to obtain oxide dispersion strengthened alloy powder, using CAD (computer-aided design) software to design a three-dimensional solid model of an ODS (oxide dispersion strengthened) alloy part, subjecting the three-dimensional model to layering and slicing to disperse the three-dimensional model into a series of two-dimensional layers, smelting the ODS alloy powder layer by layer according to slicing information to obtain a laser rapidly formed blank in a needed shape, eliminating residue pores in the laser rapidly formed blank by means of hot isostatic pressing, and optimizing structure property by means of subsequent annealing or solid solution and aging heat treatment to obtain an ODS alloy part in a complex shape. Wrap packaging or fixture moulds are not needed, the complexity of shapes of parts is unlimited, and alloy components and structures are easy to control. The prepared ODS alloy is small in oxide dispersed phase, and products are high in compactness and excellent in comprehensive mechanical property.

The invention discloses high-strength high-thermal-insulation silica aerogel and a preparation method thereof. The preparation method comprises the following steps: modifying halloysite with amino-terminated polysiloxane; adding ethyl orthosilicate, absolute ethyl alcohol, hydrochloric acid, dimethyl formamide and ammonium hydroxide to ensure a reaction and obtain gel; finally, carrying out carbon dioxide supercritical extraction to obtain the silica aerogel. As hollow natural clay fiber halloysite which is high in mechanical strength, low in thermal conductivity and high in thermal stability is taken as a reinforcing phase, the silica aerogel prepared according to the preparation method is relatively high in porosity, relatively low in density, excellent in mechanical property, favorable in heat-insulating property and relatively high in heat resistance.

The invention relates to a tissue engineering material and a preparation method thereof, in particular to a nano fiber tissue engineering blood vessel and a preparation method thereof. The invention consists of a three-dimensional reticular non-woven film formed by an inner layer of nano fiber and an outer layer of nano fiber; the inner layer of the blood vessel is natural polymer, wherein, calculated by weight, 40 percent to 80 percent is fibroin, 20 percent to 50 percent is gelatine, 0 percent to 20 percent is extracellular matrix protein; while the outer layer of the blood vessel is synthetic polymer. The preparation method is that the natural polymer is dissolved in trifluroroethyl and other solution, while the synthetic polymer is dissolved in hexafluoroisopropanol and other solution, which are respectively prepared into spinning solution; the static electricity spinning technique is adopted to subsequently form the inner and the outer layers on a gather roller; cross-linked treatment is conducted after the inner and the outer layers are taken down, to prepare the nano fiber tissue engineering vessel. The inner layer can simulate the structure of the extracellular matrix, provide good environment for endothelial cells to grow, support adhesion, proliferation and differentiation of the cells, and is good for endothelization of the blood vessel; and the outer layer has good mechanical performance.

The invention relates to a low-smell polypropylene composite material and a preparation method thereof. The low-smell polypropylene composite material comprises the following components in percentage by weight: 54 to 90 percent of polypropylene, 10 to 40 percent of talcpowder, 0.5 to 5 percent of plant fibers and 0.1 to 1.0 percent of heat stabilizer disteaxyl thiodipropionate (DSTP). The preparation method comprises the following steps of: weighing the raw materials in a weight ratio; performing dry mixing in a high-speed mixer for 3 to 5 minutes; and putting the mixed raw materials into a twin-screw machine, and melting, extruding and granulating to prepare granules of the polypropylene composite material. The polypropylene composite material has a simple preparation process, is low in cost, good in smell, low in organic volatile matter content and high in other fundamental characteristics such as mechanical properties and thermal oxidization stability.

The invention belongs to the technical field of friction material, and in particular relates to a graphene-nano polytetrafluoroethylene composite filler with a function of reducing friction, as well as a preparation method and the application of the composite filler. The composite filler comprises the following main components in parts by weight: 1 part of modified graphene and 1-20 parts of modified nano polytetrafluoroethylene; the preparation method of the composite filler comprises the following steps: separately reacting graphene and nano polytetrafluoroethylene with amination reagent and carboxylation reagent to obtain the modified graphene and the modified nano polytetrafluoroethylene; carrying condensation reaction so that the modified graphene and the modified nano polytetrafluoroethylene are connected with each other by a covalent bond to obtain the graphene-nano polytetrafluoroethylene composite filler. The function of friction reduction of the graphene and the function of lubrication of the nano polytetrafluoroethylene are utilized at the same time; after the composite filler is added to a polymer material, the friction coefficient and the wear rate of the material can be reduced, and the mechanical property of the material can be improved.

The invention relates to a self-emulsifying polyurethanes epoxy sizing agent for carbon fibers and a preparation method thereof. The sizing agent comprises the following components in part by weight: 10 to 15 parts of self-emulsifying polyurethanes epoxy emulsion, 0.2 to 0.3 part of aid, and 84.7 to 89.8 parts of deionized water. The method for preparing the sizing agent comprises the following steps of: (1) preparing hydrophilic polyurethane prepolymer of the self-emulsifying polyurethanes epoxy emulsion; (2) preparing a prepolymer of which the end group is an epoxy group; (3) adding 6 to 20 parts of neutralizer into the prepolymer of which the end group is an epoxy group for neutralization, pouring the neutralized solution into water for dispersing, and removing the solvent through reduced pressure distillation to obtain the self-emulsifying polyurethanes epoxy emulsion; and (4) adding the aid and the deionized water into the polyurethanes epoxy emulsion in the ratio, and uniformly mixing to obtain the self-emulsifying polyurethanes epoxy sizing agent for the carbon fibers. The self-emulsifying polyurethanes epoxy sizing agent for the carbon fibers and the preparation method thereof have reasonable design. The sizing agent can improve the mechanical property of carbon fiber composite materials, and has excellent dilution stability.

The invention belongs to the technical field of structural composite materials, and relates to an electric conductive continuous fiber-reinforced fabric or prepreg and an electric conductive treatment method. A continuous fiber-reinforced fabric and/or a prepreg thereof is used as a mechanical carrier and nano electric conductive components are directly loaded on the surface of the continuous fiber-reinforced fabric and/or the prepreg thereof, so that electric conductive functionalized continuous fiber-reinforced fabric or prepreg is obtained; then, a prefabricated structure including a sandwich structure is formed by spreading one layer or multi layers of the fabric or the prepreg mingled with unprocessed fabric or prepreg or all the fabric or the prepreg in different manners; and then, an electric conductive continuous fiber-reinforced structural composite material or sandwich composite material with adjustable electric conductivity and heat conductivity is prepared by a preparation process of a conventional composite material. The electric conductive and heat conductive composite material can fully keep structural mechanical performances of an original composite material.

The invention relates to a method for preparing a nanocomposite and particularly relates to a method for modifying a halloysite nanotube with a silane coupling agent and an epoxy resin nanocomposite prepared by mixing the modified halloysite nanotube obtained by the method and epoxy resin. The surface modification treatment method of the halloysite nanotube, which is disclosed by the invention comprises the following steps of adding the silane coupling agent into a suspension containing the acidified halloysite nanotube and carrying out condensation reaction on a hydrolyzable X group on the silane coupling agent and a hydroxy group on the lamella on the surface of the halloysite nanotube to obtain the halloysite nanotube which is modified by the silane coupling agent and of which an inner cavity and the outer surface are grafted by the silane coupling agent, and mixing the modified halloysite nanotube and epoxy resin to prepare the epoxy resin nanocomposite. The epoxy resin nanocomposite can obtain the desired mechanical properties and thermal properties.