The invention belongs to the technical field of materials and in particular relates to a 
graphene coating as well as a preparation method and a 
coating method thereof. The 
graphene coating is prepared from the components by weight: 5-95wt percent of less layer of 
grapheme, 5-95wt percent of 
adhesive, 0.01-50wt percent of dispersant and surfactant, 0.01-10wt percent of 
defoamer and the balance of 
solvent. With the adoption of the 
graphene coating, the thickness of an 
electricity and heat 
conductive coating can be controlled to be 100nm-20 microns; when the 
graphene coating is used on a plastic matrix, the volume resistivity can reach a range from 10<-2>
ohm.cm to 10<-4>
ohm.cm; while the 
graphene coating is used on a 
metal matrix, the volume resistivity can reach 10<-6>
ohm.cm. The 
graphene coating can be applied to the 
metal surface so as to improve the cohesiveness, the 
electricity / heat conduction performance and the 
corrosion and 
oxidation resistance. When the graphene coating is coated on the plastic surface, the 
frictional resistance, the 
electricity and heat conduction performances and the static resistance can be lowered, and the graphene coating can be applied to the fields of printed circuits, electronic devices, 
radio frequency devices, touch screens, thin film 
solar energy, LEDs, magnetic shielding, 
radio frequency shielding and the like.