The invention belongs to the field of
biogas treatment, and relates to plastic-based
nitrogen-doped porous
activated carbon, a preparation method and application thereof, and a method for removing
carbon dioxide in
biogas. The preparation method of the plastic-based
nitrogen-doped porous
activated carbon comprises the following steps: mixing PET plastic
pyrolytic carbon with
urea, carrying out high-temperature
nitrogen-doped reaction on the obtained
urea-
carbon black mixture under the protection of
inert gas, cooling, mixing the obtained nitrogen-
doped carbon material with
potassium hydroxide, and
drying to obtain the plastic-based nitrogen-doped porous
activated carbon. And
grinding the obtained modified nitrogen-
doped carbon material, and performing high-temperature activation treatment under the protection of
inert gas to obtain the plastic-based nitrogen-doped porous activated carbon. The preparation method is characterized in that
solid carbon obtained after
pyrolysis of PET plastic is taken as a
raw material,
urea is taken as a
nitrogen source, and
potassium hydroxide is adopted for pore forming, so that the obtained plastic-based nitrogen-doped porous activated carbon has relatively high CO2 adsorption capacity, CO2 in
biogas can be removed at
room temperature, the influence of repeated use of the porous activated carbon on the
adsorption effect of CO2 is relatively small, and the adsorption efficiency is relatively high. The cycle performance is excellent.