The application provides a
biomass-based hard carbon composite negative
electrode material with high capacity and high initial efficiency, and a preparation method and application thereof. The
biomass-based hard carbon composite negative
electrode material has high capacity and high initial efficiency, and also has excellent cycle performance. AlCl3 and SnCl4 are added into molten
pitch, and AlCl3 and SnCl4 react with water in the
pitch to generate nano Al2O3 particles and nano SnO2 particles, thereby obtaining modified
pitch. After the modified pitch is prepared into a solution, the modified pitch can be filled into pores of a hard carbon precursor and form a
coating layer on a surface of the hard carbon precursor in the process of impregnation of the hard carbon precursor. In a high-temperature
carbonization process, the hard carbon precursor is converted into hard carbon, nano SnO2 is reduced into nano Sn particles by carbon, and pitch is converted into
amorphous carbon. The nano Sn particles, the
amorphous carbon and the nano Al2O3 particles are uniformly distributed in pores and on a surface of the hard carbon, and synchronous modification of the inside and the surface of the hard carbon is realized.