569 results about "High molecular mass" patented technology

A method for forming a cobalt-containing thin film by a vapor deposition process is provided. The method comprises using at least one precursor corresponding in structure to Formula (I); wherein R¹ and R² are independently C₂-C₈-alkyl; x is zero, 1 or 2; and y is zero or 1; wherein both x and y can not be zero simultaneously.

A robust process for the continuous preparation of solutions of high molecular weight UHMW PO that is capable of producing strong materials at high production capacity, is conservative of capital and energy requirements, and the articles made therefrom.

High molecular weight associative amphoteric polymers for increasing the viscosity of aqueous solutions, comprise: at lease one cationic monomer derived from acrylamide bearing at least one hydrophobic chain of 8 to 30 carbon atoms; 1 to 99.9 mole % of at least one anionic monomer; and 1 to 99 mole % of one or several non-ionic water-soluble monomers. Aqueous solutions containing said polymers find uses in industry, in particular the oil, paper, water treatment, mining, cosmetics, textile, detergency industries and generally in all industrial techniques using thickened solutions.

A new ionization source named Surface Activated Chemical Ionization (SACI) has been discovered and used to improve the sensitivity of the mass spectrometer. According to this invention the ionization chamber of a mass spectrometer is heated and contains a physical new surface to improve the ionization process. The analyte neutral molecules that are present in gas phase are ionized on this surface. The surface can be made of various materials and may also chemically modified so to bind different molecules. This new ionization source is able to generate ions with high molecular weight and low charge, an essential new key feature of the invention so to improve sensitivity and reduce noise. The new device can be especially used for the analysis of proteins, peptides and other macromolecules. The new invention overcomes some of the well known and critical limitations of the Electrospray (ESI) and Matrix Assisted Laser Desorption Ionization (MALDI) mass spectrometric techniques.

An antioxidant combined with UHMWPE prior to subjecting the UHMWPE to crosslinking irradiation. In one exemplary embodiment, the antioxidant is tocopherol. After the antioxidant is combined with the UHMWPE, the resulting blend may be formed into slabs, bar stock, and/or incorporated into a substrate, such as a metal, for example. The resulting product may then be subjected to crosslinking irradiation. In one exemplary embodiment, the UHMWPE blend is preheated prior to subjecting the same to crosslinking irradiation. Once irradiated, the UHMWPE blended product may be machined, packaged, and sterilized in accordance with conventional techniques.

Methods for producing high molecular weight poly-gamma-glutamic acid (PGA). The PGA is produced by fermentation, and purified by use of tangential flow filtration, followed by diafiltration, as necessary, to yield a product of the desired purity. Product obtained may be of very high purity using all the prescribed purification steps. Product of this purity is suitable for in vivo medical applications. Other applications, such as food or agricultural, may utilize lower purity levels, and hence do not require all the purification steps specified.

A composite material composed of continuous high strength fibers such as carbon, aramid or glass, and ultra high molecular weight polyethylene (UHMW PE), wherein the UHMW PE comprises a continuous matrix among and surrounding the fibers. The resultant composite material exhibits extraordinarily high strength, stiffness and other fiber dominated properties in the directions parallel to the fibers and exhibits its lowest strength and stiffness in directions perpendicular to the fibers. It also exhibits superb abrasion resistance, good impact strength, excellent chemical resistance, a low coefficient of friction and other beneficial properties of UHMW PE.

A gel-spinning ultrahigh-molecular-weight composite polyethene (UHMWPE)/carbon nanotube fibre is composed of UHMWPE and carbon nanotubes (0.01-5 wt.%) as modifier. It is prepared through purifying and organizing carbon nanotubes, preparing gel, and spinning. Its advantages are simple preparing process and high refractory and anticreep performance.

A system achieving a high density of transported natural gas by compressing it to high pressures typically above 5 MPa to transport the gas in a modified composition that permits a very low compressibility factor at near ambient temperature either above or below. This reduces greatly the size of the cooling systems that are required. In some cases cooling of the compressed gas may be achieved in a simple heat exchanger cooled by air or water. The transport of the gas takes place in self propelled ships or non-self propelled barges fitted with a cargo containment system capable of storing the cargo at high pressures, typically above 5 MPa and usually not above 25 MPa. The transport vessel may carry a store of higher molecular weight gases (c2 through c7) that when mixed with the incoming cargo results in a molecular weight of the mixture of at least 22 and possibly as high as 28 or higher. The store of higher molecular weight cargo may be gained from gases that condense during discharge of the vessel at its destination due to the adiabatic cooling of the cargo during discharge. These liquids may be retained aboard and transported back to the origin. If insufficient quantities of heavy gases are available at the origin they may be loaded at the destination. If required, the composition of the heavy gases transported back to the origin may be changed through partial discharge or partial receipt of additional hydrocarbons or a combination thereof at the destination point.

The present invention provides a preparation method of anionic polyacrylamide with a high molecular weight by ultra-low-temperature initiation, a polynary initiator and a plurality of additives are added in the acrylamide water solution, and high-purity nitrogen is introduced for water solution polymerization. The colloids are carried out the hydrolysis by granulation, adding the hydrolytic agents, mixing and heating after a period of polymerization and aging, after that, the anionic polyacrylamide with a molecular weight of more than 25 million can be generated by granulation, drying, smashing and screening, the present invention has the advantages of smooth polymerization reaction, being conductive to the growth of a chain and the formation of the products with the high molecular weight, overcoming the shortcoming of slow temperature increase or uneven speed of temperature increase of a single azo initiator, low initiation temperature and so on.

A process for preparing parenteral iron-saccharidic complexes, and the complexes produced, comprising: (1) providing an aqueous solution or dispersion including (i) Fe(III) and (OH)⁻ ions and (ii) at least one saccharide, to form a reaction mixture, where the molar ratio of (i): (ii) is about 30:1 to about 1:30; and the mixture temperature and pH are at or above the complex assembly point (CAP); and (2) maintaining temperature and pH at or above the CAP for a time sufficient to form an iron-saccharidic complex having a molecular weight of about 25,000 Daltons or more. Control of the temperature and pH efficiently produces a high molecular weight complex. The complex can be separated by precipitation, dialysis and/or column fractionation and, if desired, dried, e.g., lyophilized or spray dried. The process can controllably synthesize complexes of varying molecular weight and/or chemical composition, particularly sodium ferric gluconate and ferric hydroxide-sucrose.

Disclosed is a perfluoropolyether (PFPE) lubricant comprising less than about 10 percent PFPE molecules having a molecular weight lower than about 2000 Daltons, and wherein the average molecular weight of the lubricant is greater than about 5000 Daltons. Such a lubricant comprises less than about 15 percent PFPE molecules having a moleuclar weight greater than about 10,000 Daltons. Also disclosed is a thin film magnetic disc comprising a recording surface and a PFPE lubricant in contact with the recording surface. The recording surface of such a thin film magnetic disc can be adapted to magnetically record information via an air bearing read/write head. The recording surface can be smooth. The disc can further comprise a rough-surfaced landing zone inward of the recording surface, wherein the PFPE lubricant is in contact with the landing zone. Also disclosed is a method of lubricating a thin film magnetic disc. The method can comprise applying a narrow, high molecular weight fractionated PFPE lubricant to the disc. In addition, a method of preparing a PFPE lubricant for use with a thin film magnetic disc is disclosed. The method can comprise fractionating a PFPE lubricant to include less than about 10 percent PFPE molecules having a molecular weight lower than about 2000 Daltons. The average molecular weight of such a lubricant after fractionation is greater than about 5000 Daltons.

A method for generating a multihydrated hydronium ion including the steps: agitating water to reduce cluster size, mixing sulfuric acid in the water, adding a solution containing Ca3+ ions, removing precipitated Ca sulfate, cooling the resultant liquid to a form a slush, filterin out ice from the slush, distilling free water from the remaining liquid wherein the remaining liquid is H₉O₄⁺.

A water-soluble, high molecular weight cationic polymer is prepared with polyphyletic composite oxidation-reduction triggering system by: adding multiple aid reagent, triggering methylpropyleneacyloxyethyltrimethyl ammonium chloride, or propyleneamide- propyleneacyloxyethyltrimethyl ammonium chloride, together with propyleneamide water solution to copolymer. The obtained products are water-soluble cationic polymer powder state, viscidity number 13.4-23.4dl/g, METMACS or AETMAC in polymer mol percent content is 0.5% -99.5%, residual monomers content is is less than or equal to 0.1 wt%. This invention has the features of that it adopts domestic industrial grade monomers as raw materials directly, without refine, the obtained products' cationic value is 50-99.5. The products can be used as clay stabilizer, reverse emulsion breaker, slow corrosion agent in petroleum engineering, intensifier, treating agent for wastewater in paper-making industry, water-treating agent and silt dewatering agent in environment protection etc.

A capacitor material including a thermosetting resin (e.g., epoxy resin), a high molecular mass flexibilizer (e.g., phenoxy resin), and a quantity of nano-particles of a ferroelectric ceramic material (e.g., barium titanate), the capacitor material not including continuous or semi-continuous fibers (e.g., fiberglass) as part thereof. The material is adapted for being positioned in layer form on a first conductor member and heated to a predetermined temperature whereupon the material will not possess any substantial flaking characteristics. A second conductor member may then be positioned on the material to form a capacitor member, which then may be incorporated within a substrate to form a capacitive substrate. Electrical components may be positioned on the substrate and capacitively coupled to the internal capacitor.

The present invention includes a multimodal polyethylene composition has (1) a density of at least about 0.940 g/cm³ as measured by ASTM Method D-1505; (2) a melt flow index (I₅) of from about 0.2 to about 1.5 g/10 min (as measured by ASTM D-1238, measured at 190° C. and 5 kilograms); (3) a melt flow index ratio (I₂₁/I₅) of from about 20 to about 50; (4) a molecular weight distribution, Mw/Mn, of from about 20 to about 40; (5) a bubble stability measured on specified equipment according to specified conditions for a film of about 6×10⁻⁶ m thickness of at least about 1.22 m/s line speed, at least about 45 kg/hr (0.013 kg/sec) output rate, or at least about 0.5 lb/hr/rpm (0.0000011 kg/s/rps) specific output rate or a combination thereof; the composition comprising; and (6) a dart impact on 12.5 micron (1.25×10⁻⁵ m) film of at least 300 g; measured according to ASTM 1709, Method A; (A) a high molecular weight fraction which; (a) is present in an amount of from about 30 to about 70 weight percent (based on the total weight of the composition); (b) has a density of at least about 0.860 g/cm³ as measured by ASTM D-1505; (c) has a melt flow index (I₂₁) of from about 0.01 to about 50 g/10 min (as measured by ASTM D-1238, measured at 190° C. and 21.6 kilograms); and (d) a melt flow index ratio (I₂₁/I₅) of from about 6 to about 12; and (B) a low molecular weight fraction which; (a) is present in an amount of from about 30 to about 70 weight percent (based on the total weight of the composition); (b) has a density of at least about 0.900 g/cm³ as measured by ASTM D-1505; (c) has a melt flow index (I₂) of from about 0.5 to about 3000 g/10 min (as measured by ASTM D-1238, measured at 190° C. and 2.16 kilograms); (d) a melt flow index ratio (I₂₁/I₅) of from about 5 to about 15; and (e) is prepared using a mole ratio of alpha olefin to ethylene of less than or equal to about 0.001:1. The invention also include a process for producing a multimodal ethylene polymer, which process comprises the following steps: (1) contacting in a first gas phase fluidized bed reactor under polymerization conditions and at a temperature of from about 70° C. to about 110° C., a titanium magnesium catalyst precursor, cocatalyst, and a gaseous composition, the gaseous composition having; (i) a mole ratio of alpha-olefin to ethylene of from about 0.01:1 to about 0.8:1; and optionally (ii) a mole ratio of hydrogen to ethylene of from about 0.001:1 to about 0.3:1, to produce a high molecular weight polymer(HMW); and (2) transferring the HMW polymer from step 1 to a second gas phase fluidized bed reactor under polymerization conditions and at a temperature of from about 70° C. to about 110° C., with a gaseous composition having; (i) a mole ratio of alpha-olefin to ethylene of from about 0.0005:1 to about 0.01:1; and (ii) a mole ratio of hydrogen (if present) to ethylene of from about 0.01:1 to about 3:1 to form a polymer blend

An activated sludge process for the clarification of wastewater comprising introducing the wastewater into a reactor where microorganisms consume organic material in the wastewater to form a mixed liquor comprising water, the microorganisms and an activated sludge; separating clarified water from the mixed liquor by filtration through a microfiltration or ultrafiltration membrane; separating the activated sludge from the mixed liquor; adding to the activated sludge at least one high molecular weight water soluble polymer to form a mixture of water and coagulated and flocculated solids; dewatering the coagulated and flocculated solids to form a mixture of dewatered solids and filtrate water; and recycling the filtrate water into the mixed liquor and a method of controlling polymer dosage, preferably using fluorescence emission spectroscopy.

The invention provides enzymatic methods for direct determination of percentage of glycated hemoglobin in blood samples without the need of a separated measurement of total hemoglobin content in blood samples. The methods utilizes one or two different types of oxidizing agents which selectively oxidize low-molecular weight reducing substances and high-molecular weight (mainly hemoglobin) reducing substances in blood samples, coupled with enzymatic reactions catalyzed by proteases, fructosyl amino acid oxidase, and peroxidase. The invention provides kits for performing the methods of the invention.

In the method, prepolymer of polylactic is obtained by direct melt polycondensation, then chain extender containing two active functional groups in which one is easy to react with hydroxyl and another is easy to react with carboxy is added. The viscosity of polylactic prepared by the chain extendor can be increased up to 1.0-1.5 dl/g.