The invention discloses a mirror finished stainless steel bearing and a process technology thereof, which comprise molding of an inner ring and an outer ring of a bar stock, turning operation, heat treatment, plane centerless grinding, coarsely grinding the channels of the inner and the outer rings, heat treatment, finely grinding the channels of the inner and the outer rings, heat treatment, grinding the channels of the inner and the outer rings, assembly and pressing fit a dust cap. The mirror finished stainless steel bearing and the process technology thereof are characterized in that: 9Cr18 stainless steel is adopted as the bar stock; liquid casting passivation is carried out before fine grinding of the channels of the inner and the outer rings; uniform burnishing treatment with a waxing machine is carried out to the inner ring surface, the two end surfaces and the two chamfers of the inner ring and the outer ring surface, the two end surfaces and the two chamfers of the outer ring after grinding the channels of the inner and the outer rings; the dust cap and a retainer adopt material of stainless steel 304, coated with a vacuum ion coating and colored into golden. The mirror finished stainless steel bearing of the invention has strong corrosion resistance and long service life and can be widely used in special environment, such as food machinery, chemical dyeing, marine equipment, pharmaceutical industry, assembly line of IT industry, etc.