828 results about "Surface oxide" patented technology

The invention discloses a casting detection method and system based on machine vision, and relates to the technical field of intersection of machine vision and material science, and the method comprises the steps: extracting the boundary coordinates of a region with a risk value exceeding a risk threshold according to a defect risk weight map, and forming a dynamic region of interest scanning frame; adjusting the incident angle of a polarized light source according to the track of the dynamic attention area scanning frame, collecting a local image, and obtaining a high-contrast image sequence for eliminating the interference of a surface oxide layer; extracting a defect edge feature map from the high-contrast image sequence through a deformable convolution kernel, and obtaining a defect candidate region mask; the defect candidate region mask is mapped to a von Mises stress field, and a crack germination probability is predicted in combination with a material fatigue limit parameter. According to the method, the accuracy and reliability of detection are improved, and the applicability under complex working conditions is remarkably improved, so that the casting quality control level is effectively improved, and the repair and quality control cost is reduced.

The invention relates to the technical field of metal pipe nondestructive testing, and discloses a method for detecting an oxide skin in a stainless steel pipe by an electromagnetic induction technology, which comprises the following steps: S1, generating multi-frequency excitation signals which comprise a high-frequency signal and a low-frequency signal which are used for respectively detecting the surface characteristics and deep distribution of the oxide skin in the stainless steel pipe; s2, applying the excitation signal to the stainless steel tube through an excitation coil, wherein the excitation coil adopts a multi-layer structure to ensure uniform distribution of a magnetic field; and S3, stainless steel pipe induction signals under the action of the excitation signals are collected, wherein the induction signals comprise response signals of the surface oxide skin and interference signals of the base body. According to the invention, the multi-frequency excitation technology is combined with signal decomposition and fusion processing, so that comprehensive detection of the thickness and distribution of the oxide skin is realized. Based on high sensitivity of high-frequency signals to surface characteristics and deep penetrability of low-frequency signals, detection results can accurately reflect characteristics and thickness distribution of the oxide skin at different depths.

The invention relates to the technical field of coatings, and discloses a product wear-resistant and corrosion-resistant remanufacturing process method based on laser deposition, which comprises the following steps: surface pretreatment: pretreating the substrate surface of a product to remove a surface oxide layer, oil stains and other impurities so as to improve the adhesive force of the coating; laser cladding coating preparation: a first wear-resistant coating is deposited on the surface of the pretreated matrix through a laser cladding process, and the wear-resistant coating is Fe-based or Co-based multi-component alloy powder; an ion deposition coating is prepared, specifically, a second corrosion-resistant coating is formed on the first coating through the ion deposition technology, and the corrosion-resistant coating is made of a ceramic material. Through the design of the functional gradient coating, the combination of the toughness of the inner layer and the hardness of the outer layer is realized, the wear resistance and the corrosion resistance are improved, the adhesive force is enhanced through metallurgical bonding, cracking and peeling are avoided, the residual stress is eliminated through low-temperature annealing and polishing, and the stability and the service life of the coating in a high-wear and high-corrosion environment are ensured.

The invention relates to a WE54 magnesium alloy CMT electric arc additive manufacturing process method, and belongs to the technical field of metal additive manufacturing. The method comprises the steps that 1, a CMT welding gun 1 is fixed to the front end of an automatic robot, printing parameters are set in 3DCAM software, a printing sample block is sliced through the 3DCAM software, and a printing path is planned; 2, surface oxides and impurities of a WE54 magnesium alloy substrate 12 are removed, the WE54 magnesium alloy substrate 12 is fixed to a working table top, the center and coordinate system of the WE54 magnesium alloy substrate 12 are determined through a welding wire 2 in a CMT welding gun 1, preheating treatment is conducted on the WE54 magnesium alloy substrate 12 through induction heating equipment, and the temperature is increased to 200 DEG C; and 3, a first cladding layer 10 is printed on the WE54 magnesium alloy substrate 12 through an electric arc 3 below the CMT welding gun 1, the surface is cleaned after printing is completed, and reciprocating printing of four-layer path planning is conducted in a reciprocating mode till a final printing sample block is formed. By means of the method, WE54 magnesium alloy CMT electric arc additive manufacturing is achieved, and the additive efficiency is effectively improved.

The invention provides a method for automatically measuring the thickness of an oxide layer on the surface of an aluminum profile, and the method comprises the steps: scanning a hanging tool contact region on the surface of the aluminum profile, obtaining an aluminum profile surface image, carrying out the edge contour recognition of the aluminum profile surface image, determining the coordinate position of a hanging tool contact point, and obtaining a contact point region range; dynamically adjusting a measurement probe avoidance path according to the boundary coordinates of the uncertain measurement area, generating a measurement track bypassing the uncertain measurement area, and determining a compensation measurement point position sequence according to the boundary of the effective measurement area and the uncertain measurement area; the measuring probe is guided to execute thickness scanning in the effective measuring area through the compensation measuring point position sequence, the oxide layer thickness value of each measuring point is obtained through scanning, and an oxide layer thickness data set is formed; and generating a final oxide layer thickness evaluation report according to the corrected thickness value and the effective measurement area range, and fusing the boundary coordinates of the uncertain measurement area and the oxide layer thickness distribution characteristics to determine the surface oxide layer thickness of the aluminum profile.

The invention discloses a manufacturing method of a semiconductor device, and belongs to the technical field of semiconductors. The manufacturing method comprises the following steps: providing a substrate, forming a dummy gate on the substrate, and forming a hard mask layer on the dummy gate; forming side wall structures on two sides of the dummy gate; forming a contact hole etching stop layer on the substrate, the side wall structure and the pseudo gate, wherein the material of the contact hole etching stop layer is the same as that of the hard mask layer; forming an interlayer dielectric layer on the contact hole etching stop layer, and planarizing the interlayer dielectric layer to the residual preset thickness of the hard mask layer; oxidizing the hard mask layer, a part of the contact hole etching stop layer and a part of the side wall structure to form a surface oxide layer; synchronously removing the surface oxide layer and a part of the interlayer dielectric layer, wherein the surface of the dummy gate is flush with the surfaces of the interlayer dielectric layers on the two sides; and removing the dummy gate to form a metal gate. According to the manufacturing method of the semiconductor device provided by the invention, the height of the formed metal gate can be ensured, the manufacturing process is simple, and the controllability is high.

The invention relates to the field of battery materials, in particular to a preparation method and application of a high-rate silicon-carbon negative electrode material. The preparation method of the high-rate silicon-carbon negative electrode material comprises the steps of silicon powder pretreatment, silicon-carbon powder composite ball milling, phosphoric acid treatment, high-temperature carbonization and the like. The preparation method of the high-magnification silicon-carbon negative electrode material is simple in process and high in success rate, the cycle stability of a negative electrode is effectively improved, the silicon-carbon negative electrode material has the characteristics of low expansion volume and long cycle life, the phenomenon that a surface oxide layer hinders lithium ion diffusion is avoided, and the service life of the silicon-carbon negative electrode material is prolonged. The comprehensive performance requirement of the existing lithium ion battery on the negative electrode material is met, and the application potential is very wide.

The invention relates to the technical field of grain refinement processing, and discloses a grain refinement processing method of a titanium alloy pipe blank for spinning, which comprises the following specific process steps: S1, precise blank selection and pretreatment: selecting a titanium alloy cast ingot with low impurities and uniform components, deeply removing surface oxide skin and inclusions through a mechanical polishing and acid pickling composite means, and carrying out fine grinding on the titanium alloy cast ingot; the purity of the blank is ensured; s2, intelligently regulating and controlling multi-pass hot forging, specifically, an intelligent temperature control system is introduced, the temperature of a heating furnace is monitored in real time and precisely regulated and controlled, and it is ensured that the pipe blank is rapidly transferred to forging equipment when the pipe blank is heated to 1000 DEG C; s3, efficient channel extrusion co-processing is conducted, specifically, advanced equipment integrating heating and extrusion is adopted, and the pipe blank is seamlessly connected with the extrusion process under the precise heat preservation condition at the temperature of 925 DEG C; the corner of the die is optimized to 105 degrees, and the metal bears uniform and high-strength shearing force when flowing through the channel in cooperation with the parameter setting of the extrusion ratio of 5; s4, performing ultrasonic-rolling integrated processing; and S5, performing precise circulating heat treatment strengthening.

An aerogel interfacial photothermal evaporation material, and a preparation method therefor and the use thereof. The aerogel interfacial photothermal evaporation material comprises graphene, a carbonized ternary precursor and oxide nanoparticles, wherein the graphene coats the surface of the carbonized ternary precursor, and the oxide nanoparticles are loaded on the surface of the carbonized ternary precursor coated with the graphene.

The invention relates to the field of composite material ultrathin laminated plates, in particular to a preparation method of a SiC fiber reinforced Ti-based composite material ultrathin laminated plate. The method comprises the following steps: plating Ti alloy on the surface of SiC fiber by using a physical vapor deposition method; the titanium alloy foil is subjected to acid pickling to remove a surface oxide layer and impurities; the plated fibers are tightly arranged to form a SiCf / Ti alloy plate, the upper surface and the lower surface of the SiCf / Ti alloy plate are bonded to a titanium alloy foil through an adhesive, and a foil-plate-foil prefabricated body is manufactured; sealing the periphery of the prefabricated body, covering gaskets on the upper surface and the lower surface of the prefabricated body, removing the adhesive from the prefabricated body, and placing the prefabricated body in a vacuum hot-pressing mold; and a hot-pressing process is adopted to realize densification composite molding of the laminated plate. According to the method, uniform distribution of SiC fibers is achieved, the mechanical property of the material is effectively improved, the surface flatness is good after the laminated plate is prepared, and the method is suitable for weight reduction application of aerospace structural parts such as skins and reinforcing ribs.

The invention discloses a novel tin-plated copper-clad aluminum alloy wire coating process and a preparation method, and the novel tin-plated copper-clad aluminum alloy wire coating process comprises the following steps: rolling an aluminum alloy material into an aluminum alloy rod through a continuous casting and rolling process in a smelting process; removing an oxide layer on the surface of the aluminum alloy rod; the surface of the aluminum alloy rod with the surface oxide layer removed is coated with a copper strip; drawing and exhausting after coating the copper strip to form a copper-coated aluminum alloy wire blank; the copper-clad aluminum alloy wire blank is subjected to drawing, medium wire drawing, fine wire drawing and annealing treatment to form a copper-clad aluminum alloy wire; and the copper-clad aluminum alloy wire enters a tinning machine and is coated with a tinning layer on the surface to form the tinned copper-clad aluminum alloy wire. The core wire of the tin-plated copper-clad aluminum alloy wire is the copper-clad aluminum alloy wire, the outer layer of the copper-clad aluminum alloy wire is copper, the interior of the copper-clad aluminum alloy wire is made of a high-strength and high-conductivity aluminum alloy material, and the mechanical property and the electrical property of the tin-plated copper-clad aluminum alloy wire are superior to those of a copper-clad aluminum wire, a copper-clad aluminum alloy wire and an aluminum-magnesium wire which are used at present.

The invention provides a production process for stably controlling adhesive force of a DP steel zinc layer. The production process comprises the following steps: step 1, setting a heating section 1, a heating section 2 and a furnace nose section in a total radiation heating annealing furnace; 2, according to the model and thickness of DP steel, target dew points of a first heating section, a second heating section and a furnace nose section are set; 3, according to the target dew points set in the first heating section, the second heating section and the furnace nose section in the step 2, water vapor is put into the protective gas for humidification, and the water vapor reacts with Si, Mn and Cr elements enriched on the surface of the steel plate to generate volatile oxides; the dew point of the annealing furnace is precisely controlled in a segmented mode, different humidification modes are adopted, and the surface state is controlled, so that surface oxide residues are reduced, cleanliness of a steel substrate is guaranteed, and the binding force of a zinc layer is improved; the iron oxide layer formed on the surface of the steel plate enters a reducing atmosphere annealing furnace containing hydrogen, the hydrogen can reduce the iron oxide layer on the surface of the steel plate to form a reduced iron layer, and the adhesive force of a zinc layer is improved.

The invention relates to the technical field of soldering tin, in particular to a low-splashing lead-free tin wire coated with rosin, which comprises the following alloy components: Sn, Sb, Cu, Ge, P, Ga, In and Ni. The solder wire is manufactured through extrusion forming and is coated with scaling powder composed of rosin resin, maleic anhydride, polyoxypropylene glycerol ether, composite ammonium salt, a solvent, sodium carboxymethyl cellulose and polyvinyl butyral. By optimizing the alloy components and the formula of the soldering flux and adding antimony, copper, germanium, phosphorus, gallium, indium and nickel elements, the fluidity and wettability of a solder wire are improved, soldering tin is easier to spread in the welding process, the outer covering rosin is decomposed in the welding process to generate active substances, oxides on the surface of metal can be removed, and the welding quality is improved. Good contact between the soldering tin and the metal surface is promoted, the surface tension of the soldering tin is further reduced, the fluidity of the soldering tin is improved, and therefore the splashing rate is remarkably reduced.

The invention relates to a laser surface remelting method for improving corrosion resistance of a low-alloy steel weld joint, and belongs to the technical field of metal surface treatment and protection. The method comprises the following steps: (1) preparing a low-alloy steel welding seam by adopting gas metal arc welding; (2) polishing the low-alloy steel welding seam, immersing the welding seam in a treating fluid, and carrying out ultrasonic treatment, cleaning and drying to obtain the treated low-alloy steel welding seam; and (3) carrying out laser surface remelting treatment on the surface of the treated low-alloy steel welding seam by adopting an optical fiber laser. The laser surface remelting technology is simple in process, the influence of oxides and impurities on the surface of the welding seam on the quality of the welding seam is reduced through layer-by-layer treatment, efficiency is high, pollution is avoided, and the corrosion resistance of the low-alloy steel welding seam obtained through treatment is effectively improved.

The invention relates to the technical field of brazing, in particular to a metal wetting behavior regulation and control system and method in the vacuum brazing process. The pretreated hard alloy, the pretreated base body and the pretreated mixed brazing filler metal are loaded into a vacuum brazing furnace, a heating and temperature control system is started, and heating is conducted according to a preset heating curve; in the heating process, according to a feedback result monitored in real time, the wetting behavior of the brazing filler metal is regulated and controlled; and the heating system is closed, so that the brazed part is naturally cooled in the vacuum environment. The hard alloy and the substrate are subjected to surface pretreatment, so that surface oxides, oil stains and other impurities are effectively removed, the wettability of the surface of the substrate is improved, and favorable conditions are provided for uniform wetting of the brazing filler metal. And a proper amount of active elements are added into the prepared mixed brazing filler metal, so that the wettability of the brazing filler metal on the hard alloy is improved. Therefore, the problem that metal wetting is not uniform in the traditional vacuum brazing process is solved.

The invention discloses an injection molding aluminum alloy feed and a preparation process thereof, the feed is composed of aluminum alloy powder and a compound binder, and the aluminum alloy powder is composed of Si, Fe, Cu, Mn, Mg, Zn, Cr, Ti, Co and Al; according to the technical scheme, aiming at the technical problems that a brittle phase is easy to form due to high magnesium and silicon content of the 6013 aluminum alloy, the interface bonding force is poor, the sintering shrinkage is difficult to control and the like due to a stable surface oxide film, and through collaborative optimization of a formula and a process, the high-magnesium-silicon-content high-magnesium-silicon-content high-brittleness aluminum alloy is obtained; the feeding and finished product performance is obviously improved; and the prepared aluminum alloy part has the advantages of high sintering density, high hardness, high tensile strength, high elongation and the like, and can meet the manufacturing requirements of high-end fields such as aerospace and traffic transportation on complex precision parts.

The invention relates to the technical field of copper-aluminum composite welding, in particular to a thin aluminum bar lap welding method. The method comprises the following steps: firstly, carrying out microstructure regulation and control on a welding surface by adopting a mechanical directional polishing technology, effectively removing a surface oxide layer and forming a uniform rough surface; secondly, accurate management of heat input is achieved through a gradient temperature control strategy, and heat damage to the thin-wall material is avoided; and meanwhile, mutual diffusion of copper atoms and aluminum atoms is promoted by combining a metallurgical transition layer technology, and stable metallurgical bonding is formed. In terms of structural design, a unique positioning system ensures the assembly precision, and the process stability is remarkably improved in cooperation with an optimized welding process. According to the method, the welding quality of the thin aluminum row is improved in a breakthrough mode, meanwhile, the good industrial production adaptability is achieved, and a reliable solution is provided for the connection technology in the fields of power batteries, energy storage equipment and the like.

The invention discloses a method for solid-phase regeneration of a high-homogeneity intermediate alloy from dissimilar metal chips. The method comprises the following steps that firstly, metal elementary substance chips and intermediate alloy chips are subjected to ultrasonic cleaning and drying; step 2, mixing; step 3, crushing processing; step 4, pressing; 5, pulse current assisted vacuum sintering is carried out under the pressurization condition; step 6, performing hot extrusion deformation; step 7, carrying out homogenization treatment; 8, surface oxide skin is removed; and ninthly, machining is conducted, and the granular or scrap-shaped high-homogeneity intermediate alloy is obtained. According to the method, the cost of raw materials for preparing the intermediate alloy is reduced through solid-phase recycling of the metal filing, after the metal filing is crushed and pressed, pulse current is used for assisting vacuum sintering and hot extrusion deformation, local heating and rapid pre-compounding of the filing interface are achieved, an oxidation film is crushed, and the mechanical occlusal force of the filing interface is improved; and the defect healing capacity is improved through the homogenization treatment process, and the solid-phase regenerated high-homogenization intermediate alloy with uniform components is obtained.

The present invention provides a method for preparing tin or tin alloy-coated copper powder and a low-temperature conductive paste, wherein the method comprises the following steps: S10, pretreating the surface of the copper powder to remove oxides and impurities on the copper powder surface; S20, placing the pretreated copper powder in an electroplating solution containing an organic phosphine compound additive; electroplating the copper powder using tin metal or tin alloy as an anode and copper powder as a cathode, wherein the copper powder is dispersed during the electroplating process; S30, after the electroplating is completed, filtering, washing, and drying to obtain the tin or tin alloy-coated copper powder. The addition of the organic phosphine compound in the present invention greatly improves the compactness of the tin or tin alloy coating formed on the surface of the copper powder, thereby making the prepared tin-coated copper powder or tin alloy-coated copper powder have the advantage of better oxidation resistance.

The invention relates to the technical field of powder metallurgy materials, and discloses rare earth microalloyed ultrahigh-strength high-toughness hot work die steel and a preparation method thereof.The die steel is prepared from 4Cr5MoSiV1 pre-alloyed powder, rare earth hydride, boron carbide and porous amorphous carbon powder loaded with a nickel catalyst. The preparation method comprises the steps of material mixing, sheath packaging, graded dynamic reaction thermal devolatilization, hot isostatic pressing densification and heat treatment, in the graded dynamic reaction thermal devolatilization, active hydrogen generated by decomposition of rare earth hydride is used for reducing oxide on the surface of powder, and nickel catalyzed carbon powder is used for capturing water vapor at low temperature to generate CO to be discharged. An oxide film on the surface of the powder is thoroughly removed through in-situ chemical reaction, original particle boundaries are eliminated, meanwhile, a nano strengthening phase with high thermal stability is generated in situ, and the high-temperature strength, impact toughness and tissue compactness of the die steel are remarkably improved.

The invention relates to the field of screw forming, and discloses a screw cold heading forming process which is characterized by comprising the following steps: step 1, wire preparation and surface pretreatment: based on the requirement of screw forming on the surface quality of raw materials, a metal wire is treated by adopting a mechanical wiredrawing and chemical phosphating and saponifying composite process, and the surface of the metal wire is treated; surface oxide skin is removed, a lubricating film layer is formed, and the forming flowability and the service life of the die in the subsequent cold heading process are effectively improved. A raw material is subjected to spheroidizing annealing treatment in a continuous spheroidizing annealing furnace, internal pearlite is converted into spherical cementite, the ductility and deformation uniformity of the material are improved, then a continuous wire drawing machine is adopted for multi-stage drawing diameter reduction, a three-stage chemical phosphating-saponification treatment process is matched, a low-friction and high-adhesion lubricating film layer is formed, and the service life of the lubricating film layer is prolonged. And a stable material basis and a lubricating environment are provided for the subsequent cold heading process, so that the problems that the friction resistance generated in the forming process of a screw material is large, and a mold is quickly worn are solved.

The invention discloses a needle bed for testing an integrated circuit, and relates to the technical field of test needle beds. The device comprises a transverse plate, the top of the transverse plate is in sliding fit with a storage plate, the transverse plate is in sliding fit with a mounting plate, a plurality of elastic probes are mounted on the mounting plate, and each elastic probe comprises a fixed section and a pointed-cone-shaped movable section. During cleaning, the cleaning plate can be driven to be far away from the mounting plate, the driving mechanism synchronously drives the movable plates to be close to each other, and finally the driving part synchronously drives the movable section to rotate, so that the surface oxide layer of the test probe can be cleaned on the premise of not dismounting the test probe, and the test probe cleaning device is relatively convenient and easy to use.

The invention discloses an oxide skin detection method and device, electronic equipment and a storage medium, and relates to the technical field of nondestructive detection.The oxide skin detection method comprises the steps that oxide skin phase composition information of all sampling points on the surface of hot-rolled strip steel is obtained, and the oxide skin phase composition information comprises oxide skin components and component mass proportions; and for each sampling point, calculating optical parameters according to the oxide skin phase composition information of the sampling point, and calculating the oxide skin thickness of the sampling point according to the terahertz echo signal of the oxide skin on the surface of the hot-rolled strip steel and the optical parameters. The method can guarantee the nondestructive high-precision measurement of the surface oxide skin of the hot-rolled strip steel.

The invention discloses a laser cleaning method for a magnesium-based foil, and belongs to the technical field of magnesium ion battery manufacturing. According to the laser cleaning method for the magnesium-based foil, the magnesium-based foil is magnesium foil or magnesium alloy foil, and the method comprises the following steps that laser cleaning is conducted on the magnesium-based foil through a laser device, and a laser beam conducts 45-degree cross filling path scanning on the surface of the magnesium-based foil; monitoring a plasma spectral line of laser ablation in real time by using a plasma spectrometer; based on the dynamic change of the magnesium characteristic plasma spectral line intensity, the cleaning parameters of the laser are adjusted; and after cleaning is completed, an oxide layer on the surface of the magnesium-based foil is removed. 45-degree cross filling path scanning is adopted, heat accumulation of a repeated scanning area can be reduced, during 45-degree cross filling, adjacent scanning lines cover in a cross mode, heat distribution is more uniform, heat of the scanning area can be reduced, and therefore the problems of local overheating and negative plate perforation or structural damage caused by too high energy are avoided.

The invention discloses a high-heat-conductivity leakproof liquid metal phase change heat-conducting gasket and a preparation method thereof, and relates to the technical field of heat-conducting gaskets. The preparation method comprises the following steps: alloying high-heat-conductivity low-melting-point liquid metal gallium with high-heat-conductivity metal silver and copper, mixing with a polymer containing a specific functional group, adding a modified heat-conducting filler, and carrying out UV curing to form the heat-conducting gasket. Liquid metal is easily alloyed to form eutectic alloy, the melting point can be increased, a chemical cross-linked network formed by the modified heat conduction filler and UV curing can make up heat conduction loss, a heat conduction path is established, the interface thermal resistance is reduced, and the heat conduction efficiency is remarkably improved. The surface oxide layer interacts with the polar group of the polymer, and the steric hindrance effect of the cross-linked network is combined to synergistically realize the leak-proof effect. The high-heat-conductivity leakproof liquid metal phase change heat-conducting gasket prepared by the invention has the effects of high heat conductivity and leakproof.

The invention discloses a high-temperature wear-resistant crack-free high-entropy alloy and a preparation method and application thereof, the molecular formula of the alloy is as follows: Fe < 11.9 > Co < 23.8 > Cr < 23.8 > Ni < 35.7 > Nb < 4.8 >, and a Laves phase exists in the microstructure of the alloy. The preparation method comprises the following steps: putting weighed powder into a ball milling tank for ball milling, uniformly mixing the powder, and then drying, sieving and drying for storage; 304L stainless steel is selected as a base material, a sand mill is used for polishing the surface of the base material so as to remove surface oxide skin until a bright surface is exposed, and oil stains on the surface are cleaned; and the dried powder is placed in a powder feeding tank in a laser system, high-purity Ar gas is used for feeding the powder to a round spot laser head for melting and stacking, and the high-temperature wear-resistant crack-free high-entropy alloy without cracks is formed through layer-by-layer continuous deposition. By adding the Nb element, a Laves phase capable of improving the high-temperature performance is formed in a matrix, a high-entropy alloy sample is prepared through the laser directional energy deposition technology, subsequent heat treatment does not need to be conducted on the high-entropy alloy sample, and the deposited alloy has the excellent wear resistance at the high temperature.

The invention relates to a liquid metal tilt angle sensor with wettability regulated and controlled by graphite, which comprises a flexible polymer matrix, a liquid metal layer and a graphite layer, the graphite coating covers part of the surface of the inner wall of the micro-channel and is used for regulating and controlling the wettability of the inner wall; and the liquid metal is filled in the micro-channel and forms an axially continuous gradient section fluid. According to the method, the wettability of the inner wall to the liquid metal is regulated and controlled by coating the inner wall of the smooth flexible polymer micro-channel with graphite (and regulating the proportion of the coating area) by utilizing the characteristic that a graphite material is not wetted to the liquid metal. And by utilizing the surface oxidation film characteristic and high fluidity of the liquid metal, a liquid metal gradient section with instability can be formed in the pipeline. When the pipeline is inclined, the state (such as contact area or form) of the liquid metal surface can be changed under the action of gravity, so that the resistance of the liquid metal surface is influenced, and accurate angle detection can be realized.

The invention discloses a burning metal particle three-dimensional surface panoramic microscopic imaging measurement method. The method comprises the following steps: collecting a dynamic panoramic microscopic image of burning metal particles; the collected panoramic microscopic image is preprocessed, the combustion metal particles are cut out independently from the panoramic microscopic image, and a binary image of the combustion metal particles and a binary image of surface oxides of the combustion metal particles are obtained; modeling combustion metal particles by using a long ellipsoid geometric model to obtain a mapping relation between the three-dimensional surface of the combustion metal particles and the two-dimensional information of the collected panoramic microscopic image; and calculating the three-dimensional surface areas of the combustion metal particles and the surface oxides thereof according to the binary image of the combustion metal particles, the binary image of the surface oxides thereof and the mapping relation. According to the measurement method, the three-dimensional surface reconstruction of the combustion metal particles can be realized, the areas of the combustion metal particles and oxides thereof can be quantitatively obtained, and the dynamic process of oxide fragments on the surfaces of the combustion metal particles can be visualized.

The invention discloses a copper wire tinning method for tinned copper stranded wire production, which relates to the technical field of metal surface treatment, and comprises the following steps: releasing a copper wire to an ionic liquid electrophoresis tank, applying an electric field to strip surface oxides, and then carrying out three-stage countercurrent rinsing to generate a clean copper wire; putting the clean copper wire into a composite plating tank, monitoring the tin liquid viscosity and the copper wire linear speed in real time, calculating the magnetic field gradient, and controlling tin crystal oriented growth according to the magnetic field gradient to generate an oriented crystallization tinned copper wire; the surface temperature of the directionally crystallized tinned copper wire is monitored in real time and compared with a preset temperature threshold value, a temperature permission trigger signal is generated, the annular array spray gun is triggered to work according to the temperature permission trigger signal, and a densified tinned copper wire is generated; and the densified tinned copper wire is scanned through a micro-focus CT scanner, a gap three-dimensional point cloud picture is generated, the gap size and the normal angle of the gap three-dimensional point cloud picture are analyzed, the optimal spraying parameters are recognized, and the passivation film tinned copper wire is generated.

The invention provides a method for recycling valuable metal from germanium-antimony-tellurium alloy waste. The method comprises the three steps of surface treatment, chlorine reaction and compartment condensation and discharging. Oxidation films on the surfaces of the waste materials are removed through surface treatment, and the subsequent chlorine reaction efficiency is improved; then a self-made chlorination-step condensation integrated device is utilized, germanium, antimony and tellurium react with chlorine at the high temperature to generate gaseous chloride, step-by-step condensation separation is achieved through partition temperature control based on the boiling point difference of tellurium tetrachloride, antimony pentachloride and germanium tetrachloride, and target products are collected respectively; and finally, introducing inert gas to purge residual chlorine, and discharging safely. The method has the advantages of short process flow, no need of complex wet process steps and low equipment investment; metal chlorides are efficiently separated through the integrated device, and recovery is thorough; and the pyrogenic process is mainly adopted, no wastewater is generated, only tail gas is treated in a compliance manner, and the method is environment-friendly. Compared with a traditional wet process, the method has the remarkable advantages of high efficiency, low cost, environment friendliness and the like.