680 results about "Surface oxide" patented technology

The invention discloses a casting detection method and system based on machine vision, and relates to the technical field of intersection of machine vision and material science, and the method comprises the steps: extracting the boundary coordinates of a region with a risk value exceeding a risk threshold according to a defect risk weight map, and forming a dynamic region of interest scanning frame; adjusting the incident angle of a polarized light source according to the track of the dynamic attention area scanning frame, collecting a local image, and obtaining a high-contrast image sequence for eliminating the interference of a surface oxide layer; extracting a defect edge feature map from the high-contrast image sequence through a deformable convolution kernel, and obtaining a defect candidate region mask; the defect candidate region mask is mapped to a von Mises stress field, and a crack germination probability is predicted in combination with a material fatigue limit parameter. According to the method, the accuracy and reliability of detection are improved, and the applicability under complex working conditions is remarkably improved, so that the casting quality control level is effectively improved, and the repair and quality control cost is reduced.

The invention provides a method for automatically measuring the thickness of an oxide layer on the surface of an aluminum profile, and the method comprises the steps: scanning a hanging tool contact region on the surface of the aluminum profile, obtaining an aluminum profile surface image, carrying out the edge contour recognition of the aluminum profile surface image, determining the coordinate position of a hanging tool contact point, and obtaining a contact point region range; dynamically adjusting a measurement probe avoidance path according to the boundary coordinates of the uncertain measurement area, generating a measurement track bypassing the uncertain measurement area, and determining a compensation measurement point position sequence according to the boundary of the effective measurement area and the uncertain measurement area; the measuring probe is guided to execute thickness scanning in the effective measuring area through the compensation measuring point position sequence, the oxide layer thickness value of each measuring point is obtained through scanning, and an oxide layer thickness data set is formed; and generating a final oxide layer thickness evaluation report according to the corrected thickness value and the effective measurement area range, and fusing the boundary coordinates of the uncertain measurement area and the oxide layer thickness distribution characteristics to determine the surface oxide layer thickness of the aluminum profile.

The invention discloses a manufacturing method of a semiconductor device, and belongs to the technical field of semiconductors. The manufacturing method comprises the following steps: providing a substrate, forming a dummy gate on the substrate, and forming a hard mask layer on the dummy gate; forming side wall structures on two sides of the dummy gate; forming a contact hole etching stop layer on the substrate, the side wall structure and the pseudo gate, wherein the material of the contact hole etching stop layer is the same as that of the hard mask layer; forming an interlayer dielectric layer on the contact hole etching stop layer, and planarizing the interlayer dielectric layer to the residual preset thickness of the hard mask layer; oxidizing the hard mask layer, a part of the contact hole etching stop layer and a part of the side wall structure to form a surface oxide layer; synchronously removing the surface oxide layer and a part of the interlayer dielectric layer, wherein the surface of the dummy gate is flush with the surfaces of the interlayer dielectric layers on the two sides; and removing the dummy gate to form a metal gate. According to the manufacturing method of the semiconductor device provided by the invention, the height of the formed metal gate can be ensured, the manufacturing process is simple, and the controllability is high.

The invention relates to the field of battery materials, in particular to a preparation method and application of a high-rate silicon-carbon negative electrode material. The preparation method of the high-rate silicon-carbon negative electrode material comprises the steps of silicon powder pretreatment, silicon-carbon powder composite ball milling, phosphoric acid treatment, high-temperature carbonization and the like. The preparation method of the high-magnification silicon-carbon negative electrode material is simple in process and high in success rate, the cycle stability of a negative electrode is effectively improved, the silicon-carbon negative electrode material has the characteristics of low expansion volume and long cycle life, the phenomenon that a surface oxide layer hinders lithium ion diffusion is avoided, and the service life of the silicon-carbon negative electrode material is prolonged. The comprehensive performance requirement of the existing lithium ion battery on the negative electrode material is met, and the application potential is very wide.

The invention relates to the technical field of grain refinement processing, and discloses a grain refinement processing method of a titanium alloy pipe blank for spinning, which comprises the following specific process steps: S1, precise blank selection and pretreatment: selecting a titanium alloy cast ingot with low impurities and uniform components, deeply removing surface oxide skin and inclusions through a mechanical polishing and acid pickling composite means, and carrying out fine grinding on the titanium alloy cast ingot; the purity of the blank is ensured; s2, intelligently regulating and controlling multi-pass hot forging, specifically, an intelligent temperature control system is introduced, the temperature of a heating furnace is monitored in real time and precisely regulated and controlled, and it is ensured that the pipe blank is rapidly transferred to forging equipment when the pipe blank is heated to 1000 DEG C; s3, efficient channel extrusion co-processing is conducted, specifically, advanced equipment integrating heating and extrusion is adopted, and the pipe blank is seamlessly connected with the extrusion process under the precise heat preservation condition at the temperature of 925 DEG C; the corner of the die is optimized to 105 degrees, and the metal bears uniform and high-strength shearing force when flowing through the channel in cooperation with the parameter setting of the extrusion ratio of 5; s4, performing ultrasonic-rolling integrated processing; and S5, performing precise circulating heat treatment strengthening.

The invention relates to the field of composite material ultrathin laminated plates, in particular to a preparation method of a SiC fiber reinforced Ti-based composite material ultrathin laminated plate. The method comprises the following steps: plating Ti alloy on the surface of SiC fiber by using a physical vapor deposition method; the titanium alloy foil is subjected to acid pickling to remove a surface oxide layer and impurities; the plated fibers are tightly arranged to form a SiCf / Ti alloy plate, the upper surface and the lower surface of the SiCf / Ti alloy plate are bonded to a titanium alloy foil through an adhesive, and a foil-plate-foil prefabricated body is manufactured; sealing the periphery of the prefabricated body, covering gaskets on the upper surface and the lower surface of the prefabricated body, removing the adhesive from the prefabricated body, and placing the prefabricated body in a vacuum hot-pressing mold; and a hot-pressing process is adopted to realize densification composite molding of the laminated plate. According to the method, uniform distribution of SiC fibers is achieved, the mechanical property of the material is effectively improved, the surface flatness is good after the laminated plate is prepared, and the method is suitable for weight reduction application of aerospace structural parts such as skins and reinforcing ribs.

The invention discloses a novel tin-plated copper-clad aluminum alloy wire coating process and a preparation method, and the novel tin-plated copper-clad aluminum alloy wire coating process comprises the following steps: rolling an aluminum alloy material into an aluminum alloy rod through a continuous casting and rolling process in a smelting process; removing an oxide layer on the surface of the aluminum alloy rod; the surface of the aluminum alloy rod with the surface oxide layer removed is coated with a copper strip; drawing and exhausting after coating the copper strip to form a copper-coated aluminum alloy wire blank; the copper-clad aluminum alloy wire blank is subjected to drawing, medium wire drawing, fine wire drawing and annealing treatment to form a copper-clad aluminum alloy wire; and the copper-clad aluminum alloy wire enters a tinning machine and is coated with a tinning layer on the surface to form the tinned copper-clad aluminum alloy wire. The core wire of the tin-plated copper-clad aluminum alloy wire is the copper-clad aluminum alloy wire, the outer layer of the copper-clad aluminum alloy wire is copper, the interior of the copper-clad aluminum alloy wire is made of a high-strength and high-conductivity aluminum alloy material, and the mechanical property and the electrical property of the tin-plated copper-clad aluminum alloy wire are superior to those of a copper-clad aluminum wire, a copper-clad aluminum alloy wire and an aluminum-magnesium wire which are used at present.

The invention provides a production process for stably controlling adhesive force of a DP steel zinc layer. The production process comprises the following steps: step 1, setting a heating section 1, a heating section 2 and a furnace nose section in a total radiation heating annealing furnace; 2, according to the model and thickness of DP steel, target dew points of a first heating section, a second heating section and a furnace nose section are set; 3, according to the target dew points set in the first heating section, the second heating section and the furnace nose section in the step 2, water vapor is put into the protective gas for humidification, and the water vapor reacts with Si, Mn and Cr elements enriched on the surface of the steel plate to generate volatile oxides; the dew point of the annealing furnace is precisely controlled in a segmented mode, different humidification modes are adopted, and the surface state is controlled, so that surface oxide residues are reduced, cleanliness of a steel substrate is guaranteed, and the binding force of a zinc layer is improved; the iron oxide layer formed on the surface of the steel plate enters a reducing atmosphere annealing furnace containing hydrogen, the hydrogen can reduce the iron oxide layer on the surface of the steel plate to form a reduced iron layer, and the adhesive force of a zinc layer is improved.

The invention discloses an injection molding aluminum alloy feed and a preparation process thereof, the feed is composed of aluminum alloy powder and a compound binder, and the aluminum alloy powder is composed of Si, Fe, Cu, Mn, Mg, Zn, Cr, Ti, Co and Al; according to the technical scheme, aiming at the technical problems that a brittle phase is easy to form due to high magnesium and silicon content of the 6013 aluminum alloy, the interface bonding force is poor, the sintering shrinkage is difficult to control and the like due to a stable surface oxide film, and through collaborative optimization of a formula and a process, the high-magnesium-silicon-content high-magnesium-silicon-content high-brittleness aluminum alloy is obtained; the feeding and finished product performance is obviously improved; and the prepared aluminum alloy part has the advantages of high sintering density, high hardness, high tensile strength, high elongation and the like, and can meet the manufacturing requirements of high-end fields such as aerospace and traffic transportation on complex precision parts.

The invention relates to the technical field of copper-aluminum composite welding, in particular to a thin aluminum bar lap welding method. The method comprises the following steps: firstly, carrying out microstructure regulation and control on a welding surface by adopting a mechanical directional polishing technology, effectively removing a surface oxide layer and forming a uniform rough surface; secondly, accurate management of heat input is achieved through a gradient temperature control strategy, and heat damage to the thin-wall material is avoided; and meanwhile, mutual diffusion of copper atoms and aluminum atoms is promoted by combining a metallurgical transition layer technology, and stable metallurgical bonding is formed. In terms of structural design, a unique positioning system ensures the assembly precision, and the process stability is remarkably improved in cooperation with an optimized welding process. According to the method, the welding quality of the thin aluminum row is improved in a breakthrough mode, meanwhile, the good industrial production adaptability is achieved, and a reliable solution is provided for the connection technology in the fields of power batteries, energy storage equipment and the like.

The present invention provides a method for preparing tin or tin alloy-coated copper powder and a low-temperature conductive paste, wherein the method comprises the following steps: S10, pretreating the surface of the copper powder to remove oxides and impurities on the copper powder surface; S20, placing the pretreated copper powder in an electroplating solution containing an organic phosphine compound additive; electroplating the copper powder using tin metal or tin alloy as an anode and copper powder as a cathode, wherein the copper powder is dispersed during the electroplating process; S30, after the electroplating is completed, filtering, washing, and drying to obtain the tin or tin alloy-coated copper powder. The addition of the organic phosphine compound in the present invention greatly improves the compactness of the tin or tin alloy coating formed on the surface of the copper powder, thereby making the prepared tin-coated copper powder or tin alloy-coated copper powder have the advantage of better oxidation resistance.

The invention relates to the technical field of powder metallurgy materials, and discloses rare earth microalloyed ultrahigh-strength high-toughness hot work die steel and a preparation method thereof.The die steel is prepared from 4Cr5MoSiV1 pre-alloyed powder, rare earth hydride, boron carbide and porous amorphous carbon powder loaded with a nickel catalyst. The preparation method comprises the steps of material mixing, sheath packaging, graded dynamic reaction thermal devolatilization, hot isostatic pressing densification and heat treatment, in the graded dynamic reaction thermal devolatilization, active hydrogen generated by decomposition of rare earth hydride is used for reducing oxide on the surface of powder, and nickel catalyzed carbon powder is used for capturing water vapor at low temperature to generate CO to be discharged. An oxide film on the surface of the powder is thoroughly removed through in-situ chemical reaction, original particle boundaries are eliminated, meanwhile, a nano strengthening phase with high thermal stability is generated in situ, and the high-temperature strength, impact toughness and tissue compactness of the die steel are remarkably improved.

The invention relates to the field of screw forming, and discloses a screw cold heading forming process which is characterized by comprising the following steps: step 1, wire preparation and surface pretreatment: based on the requirement of screw forming on the surface quality of raw materials, a metal wire is treated by adopting a mechanical wiredrawing and chemical phosphating and saponifying composite process, and the surface of the metal wire is treated; surface oxide skin is removed, a lubricating film layer is formed, and the forming flowability and the service life of the die in the subsequent cold heading process are effectively improved. A raw material is subjected to spheroidizing annealing treatment in a continuous spheroidizing annealing furnace, internal pearlite is converted into spherical cementite, the ductility and deformation uniformity of the material are improved, then a continuous wire drawing machine is adopted for multi-stage drawing diameter reduction, a three-stage chemical phosphating-saponification treatment process is matched, a low-friction and high-adhesion lubricating film layer is formed, and the service life of the lubricating film layer is prolonged. And a stable material basis and a lubricating environment are provided for the subsequent cold heading process, so that the problems that the friction resistance generated in the forming process of a screw material is large, and a mold is quickly worn are solved.

The invention discloses a laser cleaning method for a magnesium-based foil, and belongs to the technical field of magnesium ion battery manufacturing. According to the laser cleaning method for the magnesium-based foil, the magnesium-based foil is magnesium foil or magnesium alloy foil, and the method comprises the following steps that laser cleaning is conducted on the magnesium-based foil through a laser device, and a laser beam conducts 45-degree cross filling path scanning on the surface of the magnesium-based foil; monitoring a plasma spectral line of laser ablation in real time by using a plasma spectrometer; based on the dynamic change of the magnesium characteristic plasma spectral line intensity, the cleaning parameters of the laser are adjusted; and after cleaning is completed, an oxide layer on the surface of the magnesium-based foil is removed. 45-degree cross filling path scanning is adopted, heat accumulation of a repeated scanning area can be reduced, during 45-degree cross filling, adjacent scanning lines cover in a cross mode, heat distribution is more uniform, heat of the scanning area can be reduced, and therefore the problems of local overheating and negative plate perforation or structural damage caused by too high energy are avoided.

The invention discloses a high-heat-conductivity leakproof liquid metal phase change heat-conducting gasket and a preparation method thereof, and relates to the technical field of heat-conducting gaskets. The preparation method comprises the following steps: alloying high-heat-conductivity low-melting-point liquid metal gallium with high-heat-conductivity metal silver and copper, mixing with a polymer containing a specific functional group, adding a modified heat-conducting filler, and carrying out UV curing to form the heat-conducting gasket. Liquid metal is easily alloyed to form eutectic alloy, the melting point can be increased, a chemical cross-linked network formed by the modified heat conduction filler and UV curing can make up heat conduction loss, a heat conduction path is established, the interface thermal resistance is reduced, and the heat conduction efficiency is remarkably improved. The surface oxide layer interacts with the polar group of the polymer, and the steric hindrance effect of the cross-linked network is combined to synergistically realize the leak-proof effect. The high-heat-conductivity leakproof liquid metal phase change heat-conducting gasket prepared by the invention has the effects of high heat conductivity and leakproof.

The invention discloses a high-temperature wear-resistant crack-free high-entropy alloy and a preparation method and application thereof, the molecular formula of the alloy is as follows: Fe < 11.9 > Co < 23.8 > Cr < 23.8 > Ni < 35.7 > Nb < 4.8 >, and a Laves phase exists in the microstructure of the alloy. The preparation method comprises the following steps: putting weighed powder into a ball milling tank for ball milling, uniformly mixing the powder, and then drying, sieving and drying for storage; 304L stainless steel is selected as a base material, a sand mill is used for polishing the surface of the base material so as to remove surface oxide skin until a bright surface is exposed, and oil stains on the surface are cleaned; and the dried powder is placed in a powder feeding tank in a laser system, high-purity Ar gas is used for feeding the powder to a round spot laser head for melting and stacking, and the high-temperature wear-resistant crack-free high-entropy alloy without cracks is formed through layer-by-layer continuous deposition. By adding the Nb element, a Laves phase capable of improving the high-temperature performance is formed in a matrix, a high-entropy alloy sample is prepared through the laser directional energy deposition technology, subsequent heat treatment does not need to be conducted on the high-entropy alloy sample, and the deposited alloy has the excellent wear resistance at the high temperature.

The invention relates to a liquid metal tilt angle sensor with wettability regulated and controlled by graphite, which comprises a flexible polymer matrix, a liquid metal layer and a graphite layer, the graphite coating covers part of the surface of the inner wall of the micro-channel and is used for regulating and controlling the wettability of the inner wall; and the liquid metal is filled in the micro-channel and forms an axially continuous gradient section fluid. According to the method, the wettability of the inner wall to the liquid metal is regulated and controlled by coating the inner wall of the smooth flexible polymer micro-channel with graphite (and regulating the proportion of the coating area) by utilizing the characteristic that a graphite material is not wetted to the liquid metal. And by utilizing the surface oxidation film characteristic and high fluidity of the liquid metal, a liquid metal gradient section with instability can be formed in the pipeline. When the pipeline is inclined, the state (such as contact area or form) of the liquid metal surface can be changed under the action of gravity, so that the resistance of the liquid metal surface is influenced, and accurate angle detection can be realized.

The invention discloses a burning metal particle three-dimensional surface panoramic microscopic imaging measurement method. The method comprises the following steps: collecting a dynamic panoramic microscopic image of burning metal particles; the collected panoramic microscopic image is preprocessed, the combustion metal particles are cut out independently from the panoramic microscopic image, and a binary image of the combustion metal particles and a binary image of surface oxides of the combustion metal particles are obtained; modeling combustion metal particles by using a long ellipsoid geometric model to obtain a mapping relation between the three-dimensional surface of the combustion metal particles and the two-dimensional information of the collected panoramic microscopic image; and calculating the three-dimensional surface areas of the combustion metal particles and the surface oxides thereof according to the binary image of the combustion metal particles, the binary image of the surface oxides thereof and the mapping relation. According to the measurement method, the three-dimensional surface reconstruction of the combustion metal particles can be realized, the areas of the combustion metal particles and oxides thereof can be quantitatively obtained, and the dynamic process of oxide fragments on the surfaces of the combustion metal particles can be visualized.

The invention discloses a copper wire tinning method for tinned copper stranded wire production, which relates to the technical field of metal surface treatment, and comprises the following steps: releasing a copper wire to an ionic liquid electrophoresis tank, applying an electric field to strip surface oxides, and then carrying out three-stage countercurrent rinsing to generate a clean copper wire; putting the clean copper wire into a composite plating tank, monitoring the tin liquid viscosity and the copper wire linear speed in real time, calculating the magnetic field gradient, and controlling tin crystal oriented growth according to the magnetic field gradient to generate an oriented crystallization tinned copper wire; the surface temperature of the directionally crystallized tinned copper wire is monitored in real time and compared with a preset temperature threshold value, a temperature permission trigger signal is generated, the annular array spray gun is triggered to work according to the temperature permission trigger signal, and a densified tinned copper wire is generated; and the densified tinned copper wire is scanned through a micro-focus CT scanner, a gap three-dimensional point cloud picture is generated, the gap size and the normal angle of the gap three-dimensional point cloud picture are analyzed, the optimal spraying parameters are recognized, and the passivation film tinned copper wire is generated.

The invention provides a method for recycling valuable metal from germanium-antimony-tellurium alloy waste. The method comprises the three steps of surface treatment, chlorine reaction and compartment condensation and discharging. Oxidation films on the surfaces of the waste materials are removed through surface treatment, and the subsequent chlorine reaction efficiency is improved; then a self-made chlorination-step condensation integrated device is utilized, germanium, antimony and tellurium react with chlorine at the high temperature to generate gaseous chloride, step-by-step condensation separation is achieved through partition temperature control based on the boiling point difference of tellurium tetrachloride, antimony pentachloride and germanium tetrachloride, and target products are collected respectively; and finally, introducing inert gas to purge residual chlorine, and discharging safely. The method has the advantages of short process flow, no need of complex wet process steps and low equipment investment; metal chlorides are efficiently separated through the integrated device, and recovery is thorough; and the pyrogenic process is mainly adopted, no wastewater is generated, only tail gas is treated in a compliance manner, and the method is environment-friendly. Compared with a traditional wet process, the method has the remarkable advantages of high efficiency, low cost, environment friendliness and the like.

The invention discloses a plasma cleaning device and method. The plasma cleaning device comprises a base, a workpiece carrying plate and a protective cover, a positive electrode plate is arranged on the upper end face of the base, a ceramic plate is arranged on the upper end face of the positive electrode plate, a positioning piece is arranged on the upper end face of the ceramic plate, and a vacuumizing pipeline is arranged on the base; the workpiece carrier plate is provided with a plurality of positioning grooves for loading substrates to be cleaned, and the distance between the workpiece carrier plate and the ceramic plate is smaller than or equal to 0.05 mm; the protective cover is connected with a lifting mechanism and provided with a negative electrode plate, the negative electrode plate is located above the positive electrode plate, and the positive electrode plate and the negative electrode plate are located in the closed space. A ceramic plate is arranged on the positive electrode plate for covering, and a discharge mode is changed into a dielectric discharge mode, so that a golden finger of the substrate is prevented from being polluted by a tin element; according to the method, oxygen is input firstly to clean the surface of the substrate in a high-efficiency chemical reaction mode, then argon is introduced, the surface of the substrate is physically impacted, and surface oxides are thoroughly removed, so that the cleaning effect is better.

The invention discloses a low-temperature connecting method for glass and a C / C composite material, and relates to a connecting method for the glass and the C / C composite material. The problems that the performance of a base material is reduced and interface bonding is poor due to the fact that the connection temperature of an existing C / C composite material and glass is too high are solved. According to the method, firstly, a metal modified layer is prepared on the surface of the C / C composite material through magnetron sputtering, a carbide reaction layer is generated at the interface of the composite material, then connection of the C / C composite material and microcrystalline glass is achieved at the temperature of 580-660 DEG C through Bi2O3-B2O3-ZnO glass brazing filler metal, a microstructure mainly comprising a glass phase is formed in a welding seam, and the welding seam is formed. A continuous reaction layer is generated at the interface of the glass brazing filler metal and a glass base material, the glass brazing filler metal and the C / C composite material are connected through direct combination of oxides on the surface of a metal modified layer, and formed welding seams are compact and free of defects such as air holes and cracks. And the shear strength of the obtained joint can reach 13MPa.

The tin wire surface oxide layer removing device comprises a machine shell and two rotating columns, the two rotating columns are rotationally installed in the machine shell, a first motor is fixedly installed at one end of the machine shell, the outer surface of an output shaft of the first motor is sleeved with a first transmission belt, and the other end of the first transmission belt is arranged on the outer surface of a first transmission wheel in a sleeving mode; the first transmission wheel is fixedly installed on the outer surface of one set of rotating columns, the other ends of the two sets of rotating columns rotationally penetrate out of the other end of the machine shell, a grinding disc is fixedly installed on the outer surfaces, rotationally penetrating out, of the rotating columns, and pushing and unfolding mechanisms are oppositely rotationally installed at the two ends of the machine shell. Traction mechanisms are fixedly mounted on the upper surface of one of the two groups of pushing and unfolding mechanisms and the lower surface of the other group of pushing and unfolding mechanisms. Through the design of the pushing and unfolding mechanism and the traction mechanism, the polishing stroke of the tin wire by the polishing disc can be shortened or increased, so that the device can adapt to tin wires with different oxidation degrees, and it is ensured that an oxidation layer is thoroughly removed.

The invention discloses a preparation method of surface metallized ceramic particles and a ceramic wear-resistant accessory, and mainly solves the technical problems of high cost, poor product performance, low yield and the like in the existing ceramic composite material preparation method. The preparation method of the surface metallized ceramic particles comprises the steps that wrapping alloy and ceramic particles with the volume ratio being (0.5-1.5): (8.5-9.5) are prepared, and the wrapping alloy comprises active metal, auxiliary welding metal and melting metal with the mass ratio being (15-40): (60-80): (0-10); the method comprises the following steps: mixing ceramic particles and a coating alloy, filling the mixture into a coating reaction tube, vacuumizing, heating, injecting reducing gas and / or protective gas, vacuumizing again, heating, completely reducing surface oxides of auxiliary welding metal and melting metal, vacuumizing again, heating to 900-1250 DEG C, melting the coating alloy, preserving heat, keeping the temperature at normal temperature, and cooling to room temperature. And surface metallization ceramic particles are obtained. The method is short in time, low in energy consumption and higher in production efficiency.

The invention provides improved techniques for bonding devices using copper-to-copper or other types of bonds. A substrate is cleaned to remove surface oxides and contaminants and then rinsed. The rinsed substrate is provided to coating unit where a protective coating is applied to the substrate. The protective coating may be applied by immersing the substrate in a bath or via chemical vapor deposition. In an aspect, the protective coating may be copper selective so that the protective coating is only applied to copper features of the substrate. The protective coating minimizes formation of oxides and other bond weakening forces that may form during bonding processes, such as bonding a copper wire to a copper bond pad of the substrate. In an aspect, an annealing process is used to cure the protective coating and remove small imperfections and other abnormalities in the protective coating prior to the bonding process.

The invention discloses a method for preparing a non-polymer coating of a pure magnesium intravascular stent, and relates to the technical field of medical instruments, and the method comprises the following steps: pretreatment: immersing the pure magnesium intravascular stent into a diluted hydrochloric acid solution for ultrasonic cleaning, removing a surface oxidation film and impurities, then washing the pure magnesium intravascular stent with deionized water until the pure magnesium intravascular stent is neutral, and drying the pure magnesium intravascular stent for later use; micro-arc oxidation: taking the pretreated bracket as an anode, taking a stainless steel plate as a cathode, putting the bracket and the stainless steel plate in electrolyte, applying pulse voltage for treatment, and generating a ceramic oxide layer with the thickness of 5-20 microns on the surface of the bracket; and bioactive coating: immersing the stent subjected to micro-arc oxidation into the suspension, and depositing by adopting an electrophoretic deposition method to form a hydroxyapatite coating with the thickness of 1-5 microns. According to the non-polymer coating method for the pure magnesium intravascular stent, no polymer is used in the whole coating process, inflammatory reaction possibly caused by the polymer and degradation products of the polymer is avoided, and the biological safety of the stent is improved.

The invention discloses a chemically enhanced shear thickening polishing solution suitable for a WC-Co alloy and a polishing method, and aims to solve the problem of loss of a Co phase on the surface of the WC-Co alloy in a traditional polishing method. The polishing solution comprises K3 [Fe (CN) 6], KOH, diamond abrasive particles, dispersed phase particles and deionized water, a WC phase and a Co phase of a WC-Co alloy react with [Fe (CN) 6] 3 <-> and OH <-> in the polishing solution respectively, and a soft oxidation film WO3-x and a stable Co3O4 oxidation film are generated on the surface of the alloy. Through the shear thickening effect, the polishing solution forms a particle cluster wrapping the abrasive particles when the relative speed reaches a threshold value, a surface oxidation film is removed through the micro-cutting effect of the diamond abrasive particles, and efficient, high-quality and Co-loss-free WC-Co alloy surface polishing is achieved. The method obviously inhibits the loss of the Co phase at the same time, maintains the hardness and the use performance of the alloy surface, and is especially suitable for precision machining of the hard alloy blade.

The invention discloses a recyclable porous copper / cuprous oxide filamentous catalytic material and also discloses a preparation method of the catalytic material, and the preparation method comprises the following steps: taking a copper wire and pre-treating the copper wire to remove surface oxides; performing zinc electrodeposition treatment on the copper wire to obtain a galvanized copper wire; carrying out solution treatment on the galvanized copper wire to obtain a porous copper precursor; then, the porous copper precursor is subjected to corrosion treatment, zinc in a plating layer is removed, and a porous copper catalyst carrier is obtained; and putting the porous copper catalyst carrier into a tubular furnace for high-temperature oxidation to obtain the Cu / Cu2O filamentous catalytic material. The catalytic material provided by the invention has the characteristics of recoverability and good catalytic performance. According to the method, cuprous oxide is generated by adopting a one-step high-temperature thermal oxidation method, and regulation and control parameters are few and easy to control in the process.

The invention relates to a device for removing an oxide layer on the surface of tin-phosphor bronze before hot rolling treatment, and belongs to the technical field of tin-phosphor bronze surface treatment.The device comprises a supporting structure used for supporting a grinding mechanism, and the supporting structure is provided with a chuck and a driving mechanism which are used in cooperation with the grinding mechanism; a knocking mechanism and a limiting plate which are used for treating tin-phosphor bronze are arranged on one side of the grinding mechanism, and a liquid conveying mechanism used in cooperation with the grinding mechanism is further arranged on the supporting structure. The knocking mechanism comprises a knocking block and a connecting frame arranged above the knocking block, and a mounting shaft for mounting the knocking block is fixed to the bottom side of the connecting frame. After the device for removing the surface oxide layer of the tin-phosphor bronze before hot rolling treatment is used in cooperation with a knocking function, the device for removing the surface oxide layer of the tin-phosphor bronze has remarkable advantages in the aspects of removal efficiency, surface quality, treatment stability, equipment service life, production efficiency and flexibility, environmental protection, energy conservation and the like.

The invention discloses a method for reducing impurity element sulfur in cast high-temperature alloy return scraps, and belongs to the technical field of metal material smelting. The method comprises the following steps: carrying out vacuum induction melting on pretreated cast high-temperature alloy return scraps of the same mark to obtain a return scrap alloy induction ingot; surface oxide skin of the obtained return scrap alloy induction ingot is removed, a primary shrinkage cavity in the upper end is cut off, then the return scrap alloy induction ingot and an auxiliary electrode are coaxially welded, and a consumable electrode is obtained; and after the consumable electrode is baked, electroslag remelting is conducted under the protective atmosphere, and an electroslag ingot is obtained. On the basis of vacuum induction melting, the protective atmosphere electroslag remelting technology is further adopted for conducting deep purification melting treatment on the return scrap alloy ingot, the content of the impurity element S in the return scrap alloy ingot can be reduced to 0.5 ppm or below, and the content of the impurity element S in the return scrap alloy ingot reaches the level lower than the content of the element S in a new material; and the high-temperature oxidation resistance and corrosion resistance of the alloy can be obviously improved, and the fatigue, durability and other mechanical properties of the alloy are improved.