531 results about "Surface oxide" patented technology

The invention provides a method for automatically measuring the thickness of an oxide layer on the surface of an aluminum profile, and the method comprises the steps: scanning a hanging tool contact region on the surface of the aluminum profile, obtaining an aluminum profile surface image, carrying out the edge contour recognition of the aluminum profile surface image, determining the coordinate position of a hanging tool contact point, and obtaining a contact point region range; dynamically adjusting a measurement probe avoidance path according to the boundary coordinates of the uncertain measurement area, generating a measurement track bypassing the uncertain measurement area, and determining a compensation measurement point position sequence according to the boundary of the effective measurement area and the uncertain measurement area; the measuring probe is guided to execute thickness scanning in the effective measuring area through the compensation measuring point position sequence, the oxide layer thickness value of each measuring point is obtained through scanning, and an oxide layer thickness data set is formed; and generating a final oxide layer thickness evaluation report according to the corrected thickness value and the effective measurement area range, and fusing the boundary coordinates of the uncertain measurement area and the oxide layer thickness distribution characteristics to determine the surface oxide layer thickness of the aluminum profile.

The invention discloses a manufacturing method of a semiconductor device, and belongs to the technical field of semiconductors. The manufacturing method comprises the following steps: providing a substrate, forming a dummy gate on the substrate, and forming a hard mask layer on the dummy gate; forming side wall structures on two sides of the dummy gate; forming a contact hole etching stop layer on the substrate, the side wall structure and the pseudo gate, wherein the material of the contact hole etching stop layer is the same as that of the hard mask layer; forming an interlayer dielectric layer on the contact hole etching stop layer, and planarizing the interlayer dielectric layer to the residual preset thickness of the hard mask layer; oxidizing the hard mask layer, a part of the contact hole etching stop layer and a part of the side wall structure to form a surface oxide layer; synchronously removing the surface oxide layer and a part of the interlayer dielectric layer, wherein the surface of the dummy gate is flush with the surfaces of the interlayer dielectric layers on the two sides; and removing the dummy gate to form a metal gate. According to the manufacturing method of the semiconductor device provided by the invention, the height of the formed metal gate can be ensured, the manufacturing process is simple, and the controllability is high.

The invention relates to the field of battery materials, in particular to a preparation method and application of a high-rate silicon-carbon negative electrode material. The preparation method of the high-rate silicon-carbon negative electrode material comprises the steps of silicon powder pretreatment, silicon-carbon powder composite ball milling, phosphoric acid treatment, high-temperature carbonization and the like. The preparation method of the high-magnification silicon-carbon negative electrode material is simple in process and high in success rate, the cycle stability of a negative electrode is effectively improved, the silicon-carbon negative electrode material has the characteristics of low expansion volume and long cycle life, the phenomenon that a surface oxide layer hinders lithium ion diffusion is avoided, and the service life of the silicon-carbon negative electrode material is prolonged. The comprehensive performance requirement of the existing lithium ion battery on the negative electrode material is met, and the application potential is very wide.

The invention relates to the field of composite material ultrathin laminated plates, in particular to a preparation method of a SiC fiber reinforced Ti-based composite material ultrathin laminated plate. The method comprises the following steps: plating Ti alloy on the surface of SiC fiber by using a physical vapor deposition method; the titanium alloy foil is subjected to acid pickling to remove a surface oxide layer and impurities; the plated fibers are tightly arranged to form a SiCf / Ti alloy plate, the upper surface and the lower surface of the SiCf / Ti alloy plate are bonded to a titanium alloy foil through an adhesive, and a foil-plate-foil prefabricated body is manufactured; sealing the periphery of the prefabricated body, covering gaskets on the upper surface and the lower surface of the prefabricated body, removing the adhesive from the prefabricated body, and placing the prefabricated body in a vacuum hot-pressing mold; and a hot-pressing process is adopted to realize densification composite molding of the laminated plate. According to the method, uniform distribution of SiC fibers is achieved, the mechanical property of the material is effectively improved, the surface flatness is good after the laminated plate is prepared, and the method is suitable for weight reduction application of aerospace structural parts such as skins and reinforcing ribs.

The invention provides a production process for stably controlling adhesive force of a DP steel zinc layer. The production process comprises the following steps: step 1, setting a heating section 1, a heating section 2 and a furnace nose section in a total radiation heating annealing furnace; 2, according to the model and thickness of DP steel, target dew points of a first heating section, a second heating section and a furnace nose section are set; 3, according to the target dew points set in the first heating section, the second heating section and the furnace nose section in the step 2, water vapor is put into the protective gas for humidification, and the water vapor reacts with Si, Mn and Cr elements enriched on the surface of the steel plate to generate volatile oxides; the dew point of the annealing furnace is precisely controlled in a segmented mode, different humidification modes are adopted, and the surface state is controlled, so that surface oxide residues are reduced, cleanliness of a steel substrate is guaranteed, and the binding force of a zinc layer is improved; the iron oxide layer formed on the surface of the steel plate enters a reducing atmosphere annealing furnace containing hydrogen, the hydrogen can reduce the iron oxide layer on the surface of the steel plate to form a reduced iron layer, and the adhesive force of a zinc layer is improved.

The invention discloses an injection molding aluminum alloy feed and a preparation process thereof, the feed is composed of aluminum alloy powder and a compound binder, and the aluminum alloy powder is composed of Si, Fe, Cu, Mn, Mg, Zn, Cr, Ti, Co and Al; according to the technical scheme, aiming at the technical problems that a brittle phase is easy to form due to high magnesium and silicon content of the 6013 aluminum alloy, the interface bonding force is poor, the sintering shrinkage is difficult to control and the like due to a stable surface oxide film, and through collaborative optimization of a formula and a process, the high-magnesium-silicon-content high-magnesium-silicon-content high-brittleness aluminum alloy is obtained; the feeding and finished product performance is obviously improved; and the prepared aluminum alloy part has the advantages of high sintering density, high hardness, high tensile strength, high elongation and the like, and can meet the manufacturing requirements of high-end fields such as aerospace and traffic transportation on complex precision parts.

The invention relates to the technical field of copper-aluminum composite welding, in particular to a thin aluminum bar lap welding method. The method comprises the following steps: firstly, carrying out microstructure regulation and control on a welding surface by adopting a mechanical directional polishing technology, effectively removing a surface oxide layer and forming a uniform rough surface; secondly, accurate management of heat input is achieved through a gradient temperature control strategy, and heat damage to the thin-wall material is avoided; and meanwhile, mutual diffusion of copper atoms and aluminum atoms is promoted by combining a metallurgical transition layer technology, and stable metallurgical bonding is formed. In terms of structural design, a unique positioning system ensures the assembly precision, and the process stability is remarkably improved in cooperation with an optimized welding process. According to the method, the welding quality of the thin aluminum row is improved in a breakthrough mode, meanwhile, the good industrial production adaptability is achieved, and a reliable solution is provided for the connection technology in the fields of power batteries, energy storage equipment and the like.

The invention relates to the technical field of powder metallurgy materials, and discloses rare earth microalloyed ultrahigh-strength high-toughness hot work die steel and a preparation method thereof.The die steel is prepared from 4Cr5MoSiV1 pre-alloyed powder, rare earth hydride, boron carbide and porous amorphous carbon powder loaded with a nickel catalyst. The preparation method comprises the steps of material mixing, sheath packaging, graded dynamic reaction thermal devolatilization, hot isostatic pressing densification and heat treatment, in the graded dynamic reaction thermal devolatilization, active hydrogen generated by decomposition of rare earth hydride is used for reducing oxide on the surface of powder, and nickel catalyzed carbon powder is used for capturing water vapor at low temperature to generate CO to be discharged. An oxide film on the surface of the powder is thoroughly removed through in-situ chemical reaction, original particle boundaries are eliminated, meanwhile, a nano strengthening phase with high thermal stability is generated in situ, and the high-temperature strength, impact toughness and tissue compactness of the die steel are remarkably improved.

The invention relates to the field of screw forming, and discloses a screw cold heading forming process which is characterized by comprising the following steps: step 1, wire preparation and surface pretreatment: based on the requirement of screw forming on the surface quality of raw materials, a metal wire is treated by adopting a mechanical wiredrawing and chemical phosphating and saponifying composite process, and the surface of the metal wire is treated; surface oxide skin is removed, a lubricating film layer is formed, and the forming flowability and the service life of the die in the subsequent cold heading process are effectively improved. A raw material is subjected to spheroidizing annealing treatment in a continuous spheroidizing annealing furnace, internal pearlite is converted into spherical cementite, the ductility and deformation uniformity of the material are improved, then a continuous wire drawing machine is adopted for multi-stage drawing diameter reduction, a three-stage chemical phosphating-saponification treatment process is matched, a low-friction and high-adhesion lubricating film layer is formed, and the service life of the lubricating film layer is prolonged. And a stable material basis and a lubricating environment are provided for the subsequent cold heading process, so that the problems that the friction resistance generated in the forming process of a screw material is large, and a mold is quickly worn are solved.

The invention discloses a laser cleaning method for a magnesium-based foil, and belongs to the technical field of magnesium ion battery manufacturing. According to the laser cleaning method for the magnesium-based foil, the magnesium-based foil is magnesium foil or magnesium alloy foil, and the method comprises the following steps that laser cleaning is conducted on the magnesium-based foil through a laser device, and a laser beam conducts 45-degree cross filling path scanning on the surface of the magnesium-based foil; monitoring a plasma spectral line of laser ablation in real time by using a plasma spectrometer; based on the dynamic change of the magnesium characteristic plasma spectral line intensity, the cleaning parameters of the laser are adjusted; and after cleaning is completed, an oxide layer on the surface of the magnesium-based foil is removed. 45-degree cross filling path scanning is adopted, heat accumulation of a repeated scanning area can be reduced, during 45-degree cross filling, adjacent scanning lines cover in a cross mode, heat distribution is more uniform, heat of the scanning area can be reduced, and therefore the problems of local overheating and negative plate perforation or structural damage caused by too high energy are avoided.

The invention discloses a high-heat-conductivity leakproof liquid metal phase change heat-conducting gasket and a preparation method thereof, and relates to the technical field of heat-conducting gaskets. The preparation method comprises the following steps: alloying high-heat-conductivity low-melting-point liquid metal gallium with high-heat-conductivity metal silver and copper, mixing with a polymer containing a specific functional group, adding a modified heat-conducting filler, and carrying out UV curing to form the heat-conducting gasket. Liquid metal is easily alloyed to form eutectic alloy, the melting point can be increased, a chemical cross-linked network formed by the modified heat conduction filler and UV curing can make up heat conduction loss, a heat conduction path is established, the interface thermal resistance is reduced, and the heat conduction efficiency is remarkably improved. The surface oxide layer interacts with the polar group of the polymer, and the steric hindrance effect of the cross-linked network is combined to synergistically realize the leak-proof effect. The high-heat-conductivity leakproof liquid metal phase change heat-conducting gasket prepared by the invention has the effects of high heat conductivity and leakproof.

The invention relates to a liquid metal tilt angle sensor with wettability regulated and controlled by graphite, which comprises a flexible polymer matrix, a liquid metal layer and a graphite layer, the graphite coating covers part of the surface of the inner wall of the micro-channel and is used for regulating and controlling the wettability of the inner wall; and the liquid metal is filled in the micro-channel and forms an axially continuous gradient section fluid. According to the method, the wettability of the inner wall to the liquid metal is regulated and controlled by coating the inner wall of the smooth flexible polymer micro-channel with graphite (and regulating the proportion of the coating area) by utilizing the characteristic that a graphite material is not wetted to the liquid metal. And by utilizing the surface oxidation film characteristic and high fluidity of the liquid metal, a liquid metal gradient section with instability can be formed in the pipeline. When the pipeline is inclined, the state (such as contact area or form) of the liquid metal surface can be changed under the action of gravity, so that the resistance of the liquid metal surface is influenced, and accurate angle detection can be realized.

The invention discloses a copper wire tinning method for tinned copper stranded wire production, which relates to the technical field of metal surface treatment, and comprises the following steps: releasing a copper wire to an ionic liquid electrophoresis tank, applying an electric field to strip surface oxides, and then carrying out three-stage countercurrent rinsing to generate a clean copper wire; putting the clean copper wire into a composite plating tank, monitoring the tin liquid viscosity and the copper wire linear speed in real time, calculating the magnetic field gradient, and controlling tin crystal oriented growth according to the magnetic field gradient to generate an oriented crystallization tinned copper wire; the surface temperature of the directionally crystallized tinned copper wire is monitored in real time and compared with a preset temperature threshold value, a temperature permission trigger signal is generated, the annular array spray gun is triggered to work according to the temperature permission trigger signal, and a densified tinned copper wire is generated; and the densified tinned copper wire is scanned through a micro-focus CT scanner, a gap three-dimensional point cloud picture is generated, the gap size and the normal angle of the gap three-dimensional point cloud picture are analyzed, the optimal spraying parameters are recognized, and the passivation film tinned copper wire is generated.

The invention provides a method for recycling valuable metal from germanium-antimony-tellurium alloy waste. The method comprises the three steps of surface treatment, chlorine reaction and compartment condensation and discharging. Oxidation films on the surfaces of the waste materials are removed through surface treatment, and the subsequent chlorine reaction efficiency is improved; then a self-made chlorination-step condensation integrated device is utilized, germanium, antimony and tellurium react with chlorine at the high temperature to generate gaseous chloride, step-by-step condensation separation is achieved through partition temperature control based on the boiling point difference of tellurium tetrachloride, antimony pentachloride and germanium tetrachloride, and target products are collected respectively; and finally, introducing inert gas to purge residual chlorine, and discharging safely. The method has the advantages of short process flow, no need of complex wet process steps and low equipment investment; metal chlorides are efficiently separated through the integrated device, and recovery is thorough; and the pyrogenic process is mainly adopted, no wastewater is generated, only tail gas is treated in a compliance manner, and the method is environment-friendly. Compared with a traditional wet process, the method has the remarkable advantages of high efficiency, low cost, environment friendliness and the like.

The invention provides improved techniques for bonding devices using copper-to-copper or other types of bonds. A substrate is cleaned to remove surface oxides and contaminants and then rinsed. The rinsed substrate is provided to coating unit where a protective coating is applied to the substrate. The protective coating may be applied by immersing the substrate in a bath or via chemical vapor deposition. In an aspect, the protective coating may be copper selective so that the protective coating is only applied to copper features of the substrate. The protective coating minimizes formation of oxides and other bond weakening forces that may form during bonding processes, such as bonding a copper wire to a copper bond pad of the substrate. In an aspect, an annealing process is used to cure the protective coating and remove small imperfections and other abnormalities in the protective coating prior to the bonding process.

The invention discloses a chemically enhanced shear thickening polishing solution suitable for a WC-Co alloy and a polishing method, and aims to solve the problem of loss of a Co phase on the surface of the WC-Co alloy in a traditional polishing method. The polishing solution comprises K3 [Fe (CN) 6], KOH, diamond abrasive particles, dispersed phase particles and deionized water, a WC phase and a Co phase of a WC-Co alloy react with [Fe (CN) 6] 3 <-> and OH <-> in the polishing solution respectively, and a soft oxidation film WO3-x and a stable Co3O4 oxidation film are generated on the surface of the alloy. Through the shear thickening effect, the polishing solution forms a particle cluster wrapping the abrasive particles when the relative speed reaches a threshold value, a surface oxidation film is removed through the micro-cutting effect of the diamond abrasive particles, and efficient, high-quality and Co-loss-free WC-Co alloy surface polishing is achieved. The method obviously inhibits the loss of the Co phase at the same time, maintains the hardness and the use performance of the alloy surface, and is especially suitable for precision machining of the hard alloy blade.

The invention discloses a method for reducing impurity element sulfur in cast high-temperature alloy return scraps, and belongs to the technical field of metal material smelting. The method comprises the following steps: carrying out vacuum induction melting on pretreated cast high-temperature alloy return scraps of the same mark to obtain a return scrap alloy induction ingot; surface oxide skin of the obtained return scrap alloy induction ingot is removed, a primary shrinkage cavity in the upper end is cut off, then the return scrap alloy induction ingot and an auxiliary electrode are coaxially welded, and a consumable electrode is obtained; and after the consumable electrode is baked, electroslag remelting is conducted under the protective atmosphere, and an electroslag ingot is obtained. On the basis of vacuum induction melting, the protective atmosphere electroslag remelting technology is further adopted for conducting deep purification melting treatment on the return scrap alloy ingot, the content of the impurity element S in the return scrap alloy ingot can be reduced to 0.5 ppm or below, and the content of the impurity element S in the return scrap alloy ingot reaches the level lower than the content of the element S in a new material; and the high-temperature oxidation resistance and corrosion resistance of the alloy can be obviously improved, and the fatigue, durability and other mechanical properties of the alloy are improved.

The invention discloses a method for recycling high-value components of a solder strip in a decommissioned crystalline silicon photovoltaic module, belongs to the field of decommissioned photovoltaic material treatment and resource recycling, and the novel method for recycling the solder strip is efficient and has large-scale application potential. The recovery method comprises the steps that firstly, the surface of the welding strip is cleaned through alkali solution pretreatment, then a lead-tin coating on the surface of the welding strip is oxidized through a method of heat treatment in air, then the welding strip is soaked in an acid solution to remove surface oxides, then recovered solid products are washed with water and dried, and high-value components in the waste welding strip can be obtained. And further purifying and recycling. The method solves the problems of tedious operation method, low efficiency and the like during treatment of a traditional method. And meanwhile, the recovery route has a simple and convenient operation process, has large-scale application potential, and provides a large-scale application technical route and feasibility for recovery of the welding strip in the waste crystalline silicon photovoltaic module.

The invention discloses a preparation method of a corrosion-resistant and impact-resistant high manganese steel wear-resistant lining plate, and relates to the technical field of wear-resistant materials, the preparation method comprises the following steps: S1, weighing raw materials according to the mass percentage; s2, raw material smelting; s3, rare earth purification is conducted, specifically, rare earth elements are added into the molten-state raw materials, and the molten-state raw materials are subjected to deoxidation and desulfurization treatment; s4, casting molding is conducted, the temperature from the bottom end of a casting to a riser is controlled to be decreased stage by stage, and directional solidification is achieved; s5, heat treatment is conducted, specifically, the casting is subjected to solution treatment and then subjected to water quenching to the room temperature; and S6, surface treatment is conducted, specifically, shot blasting treatment is adopted, surface oxide skin is removed, and a surface compressive stress layer is formed. The strength, hardness and high toughness of the high-manganese steel are guaranteed by controlling the content of carbon and manganese, meanwhile, single-phase austenite is obtained through solution treatment, the hardness is improved through carbon atom segregation through low-temperature aging, and the strength, hardness, toughness and corrosion resistance of the high-manganese steel lining plate are improved.

The invention discloses a preparation method of a TiAl alloy casting containing return scraps, the TiAl alloy return scraps used in the preparation method are casting sprues, patches and skull which are cut off in subsequent processing, and the preparation method comprises the following specific implementation steps: carrying out ultrasonic cleaning and surface treatment on the return scraps to remove a surface oxide layer; a new material with the target weight of 50% is used for smelting during primary smelting to obtain a primary ingot, a return material is placed below the turned primary ingot before secondary smelting, and then the primary ingot is smelted and poured into a preheated mold to form a casting, so that recycling of a TiAl alloy raw material is realized, the raw material cost is reduced by 50%, the preparation cost is reduced by 33%, and the production efficiency is improved. And the power consumption and the equipment loss are reduced, so that the purposes of energy conservation and emission reduction are achieved. The impurity element control of the cast ingot produced by the method is equivalent to that of alloy produced by conventional raw materials, and is convenient and fast compared with a preparation process by directly utilizing the raw materials. And the poured casting is uniform in component, compact in structure and high in purity.

The invention relates to the field of solar cell manufacturing, and particularly discloses a polishing additive for solving the black core problem in the BC cell pre-rough polishing process and a use method of the polishing additive. 0.1-5% of a defoaming agent; 0.1 to 0.5 percent of pH (Potential of Hydrogen) regulator; and the balance of deionized water. According to the method, the accelerant, the defoaming agent and the pH regulator in a specific ratio are combined, so that the oxidation reaction on the surface of the silicon wafer is more uniform and controllable; the accelerant accelerates formation and dissolution of a surface oxide layer, and generation of black cores is effectively avoided; the synergistic effect of the defoaming agent ensures that bubbles generated by the reaction can be quickly desorbed, the problem of uneven local corrosion caused by bubble retention is prevented, the surface of the polished silicon wafer is completely free of black nuclei, and ideal surface conditions are provided for subsequent processes.

The invention discloses a production method of stable liquid aluminum isopropoxide, and belongs to the field of organic metal compound preparation. According to the method, an oxidation film on the surface of aluminum and water in isopropanol are removed through raw material pretreatment, and initial liquid aluminum isopropoxide is prepared in an inert atmosphere; the composite solvent is prepared by mixing a functional main solvent and a high-boiling-point auxiliary solvent in proportion, the addition amount of the composite solvent is 15-30% of that of the initial product, and the finished product is obtained through step-by-step stirring and mixing and precise filtration. Through double mechanisms of chemical coordination stabilization and physical volatilization inhibition, the problems of short shelf life and poor stability of the existing product are solved, the shelf life reaches 6-12 months, the purity is greater than or equal to 99.0%, the batch difference is less than or equal to + / -10%, and the preparation method has a good application prospect.

The invention discloses a modification method for improving oxidation resistance of a high-entropy alloy. The modification method comprises the following steps: S1, carrying out solution treatment and oil cooling on an as-cast high-entropy alloy; s2, the high-entropy alloy subjected to oil cooling is cut, surface oxide skin is removed, and a metal sample is obtained; and S3, the metal sample is subjected to large-deformation cold rolling treatment. According to the method, dendritic structures in the as-cast alloy are eliminated through solution treatment, then the solid-solution-state high-entropy alloy is subjected to multi-pass rolling, the total deformation is 60%-90%, and the oxidation resistance of the high-entropy alloy can be greatly improved. The method is reasonable in design and easy to operate, and the oxidation resistance of the high-entropy alloy is well improved.

The invention relates to a low-cost high-strength corrosion-resistant magnesium alloy and a preparation method thereof. The magnesium alloy comprises the following components in percentage by mass: 6-11% of Al, 0.4-0.6% of Zn, 0.2-0.6% of Mn, 0.2-0.4% of Y, 0.2-0.6% of Ca and the balance of Mg and inevitable impurities. A small amount of Ca and Y elements are added, on one hand, an alpha-Mg matrix structure can be refined, beta phase distribution is more uniform, and the mechanical property is improved; and on the other hand, the solid solubility of the alloy element Y in an alpha-Mg matrix can be improved by adding the Ca element, the compactness of a surface oxidation film and a corrosion product film is promoted, compared with other rare earth elements, the potential difference between Al-Ca and Al-Y phases formed by Ca, Y and Al and the magnesium matrix is smaller, micro galvanic corrosion is smaller, and the corrosion resistance of the alloy is remarkably improved.

The invention discloses a preparation method of a nickel-iron alloy composite electrode suitable for electrocatalytic cracking of alkaline seawater and a product. The preparation method comprises the steps of surface treatment of a nickel-iron alloy sheet and preparation of a boronized nickel-iron alloy sheet composite electrode. According to the method, the marketed NiFe alloy sheet is directly subjected to thermal boronizing treatment and is directly subjected to electrochemical oxidation to prepare the multi-chromatography oxygen electrode, and various requirements of an anode material for seawater decomposition can be met. The prepared multi-layer oxygen electrode is mainly composed of a surface oxide layer, an alloy middle layer and an alloy substrate layer. The NiFeB alloy layer on the surface plays a role of a catalytic active layer, the NiFeB alloy layer in the middle plays a role of a corrosion-resistant layer, the NiFe alloy layer on the substrate plays a role of supporting, and the electrode material is efficiently supported by multiple layers together, so that the electrode material has a rapid electron transfer process, and the electrode material can show relatively high catalytic activity. The electrode material is cheap in raw material source and simple in preparation process, and has a relatively strong commercial application prospect.

The invention relates to a preparation method of a high-hardness composite coating on a titanium alloy surface, which comprises the following steps: pretreating a titanium alloy base material to remove a surface oxide layer to obtain the treated titanium alloy base material; prepared high-entropy alloy powder is dried and evenly laid on the surface of the treated titanium alloy base material, and the titanium alloy base material with the powder laid is obtained; performing laser cladding treatment on the titanium alloy base material subjected to powder laying in a protective gas atmosphere to obtain a high-entropy alloy strengthened coating; the particle size of the powder is controlled to be 65-90 microns. The Al powder, the Co powder, the Ni powder, the Ti powder and the B powder with the purity higher than 99.5 wt% are selected as raw materials, the high-entropy alloy powder and the high-strength titanium alloy matrix are molten on the surface of the high-strength titanium alloy through a laser high-energy heat source, the metallurgical bonding effect is achieved, high-entropy phase strengthening is achieved, grains can be fine, and the hardness and abrasion resistance of a surface coating can be improved. The surface hardness of the coating prepared by laser cladding of the high-entropy alloy powder on the surface of the titanium alloy is not lower than 677 HV, and the wear resistance is not lower than 1.128 hmm.

The application discloses a method for testing diffusion depth by voltage method, which comprises the following steps: firstly, oxidizing the upper part of a silicon substrate; secondly, performing photoetching on the oxide layer according to a designed layout, wherein the shape of the photoetching pattern is square and the photoetching patterns are distributed in an array, the interval between two adjacent photoetching patterns in each row is increased in turn, and the interval between two adjacent rows is greater than the maximum value of the interval between any two adjacent photoetching patterns in the two rows; thirdly, removing the oxide layer in the photoetching area and photoresist used in the photoetching; fourthly, injecting or doping impurities into the photoetching area of the silicon substrate, and then removing the surface oxide layer; fifthly, connecting two probes with a graphic instrument, and testing the two adjacent photoetching patterns on the sample in the order of the interval from small to large; sixthly, continuing to test the next two adjacent photoetching patterns when the sample is broken down; and seventhly, recording the interval of the last two adjacent photoetching patterns when the sample cannot be broken down, and then obtaining the diffusion depth by combining the ratio of the lateral diffusion distance of the impurities to the diffusion depth, so that the method has low cost and wide application range.

The invention discloses a surface cleaning method for a large complex magnesium alloy structural part formed through electric arc additive manufacturing, and belongs to the field of post-treatment of formed structural parts after electric arc additive manufacturing. The method comprises the following steps that a mechanical arm is adopted to drive a special wire brush to conduct preliminary mechanical cleaning, and flexible contact is achieved through a mechanical sensor and a floating clamp; acidic cleaning liquid is sprayed to the surface of the workpiece through an ultrasonic spraying system, the surface color change is monitored in real time through a high-speed camera so as to control the reaction endpoint, and flushing and drying are conducted in time; and finally, carrying out fine cleaning under the protection of argon by adopting large-light-spot laser with low power density, and monitoring in real time through a spectrograph to ensure the cleaning effect. According to the method, the oxide layer and the pollutants on the surface of the large complex component can be efficiently, losslessly and automatically removed, the problem that the magnesium alloy WAAM component is difficult to clean due to high chemical activity and complex structure is solved, and the whole process is environmentally friendly and controllable.

The application relates to a method for improving a tungsten-copper connecting interface based on internal oxidation and hydrogen reduction process, and relates to the technical field of tungsten-copper composite material preparation. First, an oxide (Cu2O, CuO) or oxygen is added to the surface of a tungsten block for internal oxidation treatment, a nano-oxide porous structure is generated on the surface, the surface roughness is increased, then hydrogen reduction is performed to remove surface oxide impurities, the surface pores are reserved, finally, the tungsten block with the treated surface is combined with copper powder through discharge plasma sintering to realize effective combination between tungsten and copper. Through the internal oxidation process, the influence of a metal alloy layer formed by a heterogeneous element brazing filler on the tungsten-copper interface compatibility and stability under radiation can be effectively avoided, and through the reduction treatment of high-purity hydrogen, the high-purity of the matrix is maintained, and the combination performance of the porous structure reinforced connecting layer is generated.

The invention relates to the field of removal of oxide layers on the surfaces of metal materials, in particular to an acid pickling process for removing oxide layers on the surfaces of high-purity nickel particles. High-purity nickel particles with oxide layers on the surfaces are placed in a beaker to be decontaminated, the nickel particles are washed three times with pure water and washed once with alcohol, and then the nickel particles are blow-dried through a blow gun; an acid solution is prepared according to the proportion of nitric acid to concentrated sulfuric acid to water being 1: 1: 4; soaking the nickel sheet and the nickel particles in the mixed acid solution, and finally, flatly laying the nickel sheet and the nickel particles on purification cloth, simply wiping and drying; according to the method, oxide skin on the surfaces of high-purity nickel particles is directly removed through soaking; the pickling method is simple, the high-purity nickel particles with good surface brightness are obtained by controlling parameters such as the pickling solution ratio, the pickling temperature and the pickling time of the pickling process, the problems of poor surface smoothness and size precision caused by mechanical pretreatment can be effectively solved, and metal loss caused by mechanical treatment can be reduced.