495 results about "Perfluoropolyether" patented technology

The invention discloses a forming device and a forming method of a high-temperature-resistant low-temperature-resistant high-toughness cable. According to the invention, based on a double-substrate synergistic system of hydrogenated nitrile rubber and polyether type thermoplastic polyurethane, and in combination with a dynamic vulcanization crosslinking technology, the cable keeps excellent flexibility and tear resistance in a wide temperature range of-60 DEG C to 125 DEG C. A three-dimensional reinforced network of nano silicon dioxide and carbon nanotubes is directionally dispersed in a matrix, and mechanical support of aramid short fibers is matched, so that the cable is endowed with bending fatigue resistance, the durability of the drag chain cable in a high-frequency torsion scene of an oil platform exceeds 30 million cycles is realized, and the service life of the drag chain cable is prolonged. The problem of breakage caused by low-temperature embrittlement and high-temperature softening of a traditional cable is fundamentally solved, the synergistic effect of the perfluoropolyether surface modifier and the composite anti-aging system enables the cable to form a stable protective layer in strong acid, strong alkali, salt mist and oil stain environments, and chemical corrosion and ultraviolet irradiation are effectively resisted.

The invention belongs to the technical field of polymer composite materials, and particularly relates to an oil-resistant interior material. The material comprises a porous base material layer, a fluorine-containing polymer and organic silicon resin blended oil-resistant functional layer and a micro-nano structure layer with a periodic micro-bulge array, surface modified nanoparticles are distributed in the functional layer in a gradient manner, and the micro-bulge surface is covered with a perfluoropolyether / fluorinated silicon dioxide composite coating; through a synergistic effect of a low-surface-energy oleophobic interface formed through chemical bonding and curing and a micro-structure capillary lifting effect, anti-permeation barrier of high-viscosity grease is realized, and meanwhile, mechanical wear resistance and thermal stability are improved by virtue of a nano-particle enhanced cross-linked network; and continuous imprinting and an ultraviolet-thermal dual-curing process are combined to achieve high-efficiency manufacturing with zero solvent residue, and finally the interior material with long-acting oil resistance, high environmental tolerance and industrial mass production feasibility is obtained.

The invention discloses a perfluoropolyether blended PEGDE-based solid electrolyte and a preparation method thereof, and belongs to the technical field of lithium metal battery solid electrolyte materials. Adding SnCl4 and TAA into the nanocellulose precursor solution, stirring, carrying out suction filtration, and drying to obtain a SnS2 (at) NC support layer; and mixing and stirring PEGDE, LiDFOB, LiTFSI and PFPE to obtain PEGDE-based solid electrolyte slurry, coating the SnS < 2 > (at) NC supporting layer with the PEGDE-based solid electrolyte slurry, and performing in-situ polymerization in a drying oven to obtain the PEGDE-based solid electrolyte. The ultrathin perfluoropolyether blended PEGDE-based solid electrolyte prepared based on PEGDE in-situ polymerization and perfluoropolyether blending and in combination with nanocellulose enhancement has the advantages of stable anode interface, high mechanical strength, high decomposition voltage and high ion transference number.

The invention relates to an insulating material, in particular to a voltage-breakdown-resistant high-insulation EPDM material and application thereof, and the voltage-breakdown-resistant high-insulation EPDM material comprises the following components: modified silicone rubber, 4, 4 '-thiobis (6-tert-butyl o-cresol), a composite filler, a cross-linking agent, 4-isopropoxybenzoic acid and an EPDM matrix; according to the voltage-breakdown-resistant high-insulation EPDM material disclosed by the invention, the comprehensive performance of the material is greatly improved and the application field of the EPDM material is widened through the matching of all the components and the specific dosage ratio of the components. The modified silicone rubber is introduced, the modified silicone rubber is obtained by modifying vinyl-containing perfluoropolyether-b-polysiloxane, in the vinyl-containing perfluoropolyether-b-polysiloxane, a perfluoropolyether chain segment has extremely low surface energy and good chemical stability, and a polysiloxane chain segment endows the vinyl-containing perfluoropolyether-b-polysiloxane with excellent flexibility and electrical insulating property.

The invention provides chlorotrifluoroethylene continuously prepared based on a microchannel reactor and a preparation method of the chlorotrifluoroethylene, and the chlorotrifluoroethylene comprises the following raw materials in parts by weight: 1, 1, 2-trifluoro-1, 2, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3, 3 The low-temperature refrigerant refrigerant is prepared from the following components in parts by weight: 90 to 100 parts of 1, 2-trichloroethane, 1 to 5 parts of a zinc fluoride induced palladium-copper bimetallic catalyst, 8 to 15 parts of a cyclohexyl dimethyl ether-formic acid composite hydrogen donor, 0.5 to 2 parts of trifluoroacetic anhydride, 0.1 to 0.5 part of a perfluoropolyether lubricant, a proper amount of a low-temperature mixed refrigerant and 15 to 20 percent by weight of diluted hydrochloric acid. According to the invention, the preparation efficiency and product purity of chlorotrifluoroethylene can be improved, and stable operation of the preparation system and reasonable treatment of byproducts can be guaranteed.

The invention provides energy storage battery immersed cooling liquid based on fluorinated nanofluid and a preparation method, and belongs to the technical field of heat management of energy storage equipment, the energy storage battery immersed cooling liquid comprises 74-84% of perfluoropolyether base liquid, 10-15% of surface modified boron nitride nanosheets, 5-8% of microencapsulated perfluorohexanone and 1-3% of polydimethylsiloxane modified silicon dioxide. Microencapsulated perfluorohexanone is integrated into the cooling liquid to achieve the dual functions of heat dissipation and fire extinguishment, and synergistic effects are generated in the aspects of heat conduction, insulation, fire extinguishment and the like through combined use of the perfluoropolyether base liquid, the surface modified boron nitride nanosheets, the microencapsulated perfluorohexanone and polydimethylsiloxane modified silicon dioxide and specific modification performance of the perfluoropolyether base liquid, the surface modified boron nitride nanosheets, the microencapsulated perfluorohexanone and the polydimethylsiloxane modified silicon dioxide. And experimental data can prove that the comprehensive performance of the material has substantive features and remarkable progress in the aspects of heat conductivity coefficient improvement, fire extinguishing time and the like.

The invention relates to the technical field of optical films, and discloses a PET-based composite optical film and a preparation method thereof.The optical film is prepared from 100 parts of PET master batch, 5-10 parts of anti-blue-light nanofiller and 1-3 parts of interfacial compatibilizer through melt extrusion, asynchronous two-way stretching, online anti-fingerprint coating liquid coating and cooling and rolling; the blue-light-resistant nano filler is a core-shell structure filler prepared by taking KH570 silanized nano cerium oxide as a core, polymerizing by grafting glycidyl methacrylate to form a shell layer, and then reacting with 1H-benzotriazole-1-methanol. The anti-fingerprint coating liquid is prepared from perfluoropolyether modified siloxane acrylate and nano silicon dioxide sol. Through core-shell filler design and functional coating online coating, the technical problems that inorganic nanoparticles are easy to agglomerate and organic small molecule auxiliary agents are easy to migrate are synergistically solved, and the obtained optical film has excellent properties of high light transmittance, low haze, efficient blue light resistance and lasting fingerprint resistance and is good in durability.

The application discloses an aluminum alloy surface fine polishing polishing composition, polishing liquid and application thereof, and particularly belongs to the technical field of metal surface treatment. The polishing composition comprises the following components in mass fraction: 70-80 parts of silica sol, 1-4 parts of dispersing agent, 5-7 parts of surfactant, 5-10 parts of corrosion inhibitor, and 0.5-2 parts of water-retaining agent; and the surfactant is composed of perfluoropolyether, coconut oil alkylolamide and sodium dodecyl benzene sulfonate. The polishing composition provided by the application has high polishing efficiency, can reduce polishing cost, improve product quality, has low material surface roughness and few scratches after polishing treatment, effectively improves the polishing surface quality, improves the overall appearance and durability of the material, and the polishing liquid does not contain toxic substances such as chromium / phosphorus, and is environment-friendly.

The invention relates to the technical field of composite materials, in particular to a composite material for a waterproof breathable film and a preparation method of the composite material. The composite material for the waterproof breathable film comprises the following raw materials: PTFE resin, zinc oxide, a surfactant, a compatibilizer and a waterproof filler, the waterproof filler is a porous inorganic carrier material treated by a silane modified waterproof agent; the silane modified waterproof agent is a compound containing a perfluoropolyether chain segment and a siloxane chain segment. According to the prepared composite material for the waterproof and breathable film, the porous filler is subjected to surface modification through the perfluoropolyether-silane coupling agent, and the waterproofness, breathability and mechanical property of the PTFE composite material can be synchronously and synergistically improved.

The invention relates to the technical field of grinding fluid, in particular to efficient grinding fluid for an MPO connector, a preparation method and application of the efficient grinding fluid for the MPO connector. 27%-44% of alpha-aluminum oxide; 8%-15% of a styrene-maleic anhydride copolymer; 2%-5% of a modified polyurea solution; 0.05% to 0.3% of perfluoropolyether; 0.5%-2% of citric acid; 0.5%-1.5% of a polyether modified polysiloxane defoaming agent; by adopting a composite abrasive material system of the nano-diamond and the alpha-aluminum oxide, the grinding efficiency and the surface quality are improved in a breakthrough manner.

The invention relates to the technical field of high-end packaging and printing, and discloses a base material back coating and a preparation method thereof, and the base material back coating comprises the following components in parts by weight: 55-70 parts of mixed matrix resin formed by polar modified epoxy acrylate and perfluoropolyether acrylate according to a weight ratio of 4 / 1-9 / 1, according to the invention, self-stratification power generated by viscosity reduction in a heat leveling stage is utilized to drive the components to migrate directionally and construct a gradient interpenetrating network structure, so that the self-stratification effect is improved, and the self-stratification effect is improved; the coating is subjected to continuous chemical transition from the bottom anchoring layer to the surface shielding layer, interface stress concentration generated by physical layering is eliminated, and the interface bonding stability is improved on the premise that the protection strength of the ultrathin coating is guaranteed.

The invention discloses a preparation method of a double-response self-repairing super-hydrophobic coating on the surface of an aluminum alloy. The preparation method is specifically implemented according to the following steps: step 1, preparing sea urchin-shaped photo-thermal particles Fe3O4-at-TiO2; step 2, preparing self-repairing porous boron nitride; 3, preparing thermal response particles by an emulsion method; step 4, carrying out photocuring and dynamic disulfide bond crosslinking modification; and 5, preparing the double-response self-repairing super-hydrophobic coating. The invention also discloses the coating prepared by the method, the light absorption area is increased by preparing the sea urchin-shaped Fe3O4-coated TiO2, and after the two materials form a heterojunction, absorption spectrums complement each other, so that the energy of sunlight can be more efficiently utilized, and the photothermal conversion efficiency is improved. Porous boron nitride (PBN) increases the specific surface area, loads more perfluoropolyether and forms a continuous heat conduction channel through a porous framework to improve the heat conductivity, it is guaranteed that heat can be transmitted to the thermal response shell to the maximum extent, and the thermal response efficiency is improved.

The invention relates to the technical field of organic-inorganic hybrid materials, in particular to an antifouling organic-inorganic hybrid material, a preparation method, a photocuring antifouling material and a product. The organic-inorganic hybrid material is prepared by carrying out a ring-opening addition reaction on an epoxy group of epoxy polyhedral oligomeric silsesquioxane and polydimethylsiloxane with an amino group or perfluoropolyether with a carboxyl group. According to the scheme provided by the invention, the coating has high thermal stability and structural rigidity endowed by epoxy polyhedral oligomeric silsesquioxane and excellent low surface energy antifouling property endowed by amino-containing polydimethylsiloxane or carboxyl-containing perfluoropolyether, and the defect that a pure epoxy polyhedral oligomeric silsesquioxane coating does not have antifouling property is effectively overcome.

The invention relates to the field of medical materials, and particularly discloses a collagen microsphere preparation method based on a micro-fluidic technology, and the preparation method comprises the following steps: preparing a micro-fluidic device which comprises a chip with a coaxial flow channel, a fluid control system and an ultraviolet crosslinking module integrated at the outlet of the chip; preparing an inner phase fluid, an intermediate phase fluid and an outer phase fluid, wherein the inner phase is a modified collagen solution containing a photoinitiator, the intermediate phase is a perfluoropolyether oil phase and contains a surfactant, and the outer phase is a water phase and contains a nonionic surfactant; the three-phase flow velocity is adjusted, and monodisperse W / O / W liquid drops are generated in the micro-fluidic chip; sequentially carrying out low-temperature physical crosslinking and ultraviolet-initiated crosslinking on the W / O / W liquid drops to form cured microspheres; collecting and post-processing the microspheres to obtain the collagen microspheres. According to the preparation method provided by the invention, the natural activity of collagen is reserved, meanwhile, the size of the microspheres is accurately controlled, multiple functions are integrated, and the preparation method is environment-friendly and safe.

In a secondary battery including an electrolyte layer containing a sulfide solid electrolyte, the electrolyte layer has both high voltage resistance and high ionic conductivity. The secondary battery of the present disclosure includes a positive electrode, an electrolyte layer, and a negative electrode, wherein the electrolyte layer contains a sulfide solid electrolyte and a perfluoropolyether represented by formula (1) below:where Rf1 and Rf2 are each independently a C1-16 divalent alkylene group which may be substituted with one or more fluorine atoms, E1 and E2 are each independently a monovalent group selected from the group consisting of a fluorine group, a hydrogen group, a hydroxyl group, an aldehyde group, a carboxylic acid group, a C1-10 alkyl ester group, an amide group which may have one or more substituents, and an amino group which may have one or more substituents, and RF is a divalent fluoropolyether group.

The invention discloses a perfluoropolyether-terminated polymer, an electrolyte, a battery, a preparation method and an application, and belongs to the technical field of solid-state batteries, and the structure of the perfluoropolyether-terminated polymer is shown as a formula I. Through the structure of the multi-arm polyether, the crystallinity is obviously reduced, and the ionic conductivity is effectively improved. In addition, by grafting the perfluoropolyether chain segment, the dissolving property of the lithium salt can be further improved, the ion transference number can be increased, and meanwhile, the generation of LiF is facilitated, so that a good SEI interface is provided, and the generation of dendritic crystals is inhibited. Meanwhile, the oxidation resistance and the thermal stability of the polymer can be remarkably improved.

This fluoropolyether-based curable composition contains(A) a perfluoropolyether compound having two or more alkenyl groups per molecule,(B) a fluorine-containing organo hydrogen silane compound having two or more hydrosilyl groups having a specific structure,(C) a platinum group metal-based catalyst, and(D) a specific amount of at least one filler selected from organic resin powders and carbon black powders.Such a fluoropolyether-based curable composition can provide a cured product that has endurance against fluoric acid and electrolytic solutions for lithium ion batteries, has fine mechanical properties, and has excellent releasability because of not having uncured portions resulting from low compatibility between structural ingredients.

The invention discloses a high-stability magnetic liquid and a preparation method thereof, and belongs to the field of magnetic fluid nano functional materials related to ships. The magnetic liquid comprises a metal-doped iron oxide nano-particle core, a double-layer surface modification layer composed of oleic acid and a silane coupling agent, and a composite carrier liquid formed by compounding poly-alpha olefin synthetic oil and perfluoropolyether and adding nano-diamond. The preparation method comprises the following steps: firstly, coprecipitating and calcining to obtain metal-doped iron oxide nanoparticles, then carrying out double-layer coating modification, and finally carrying out mixed ball milling, ultrasonic treatment and magnetic separation purification on the metal-doped iron oxide nanoparticles and the composite carrier liquid. The saturation magnetization intensity of the magnetic liquid reaches 92-95 emu / g, the magnetic liquid can work for a long time under the high-temperature working condition, the heat conductivity coefficient is increased by 2-3 times, and the redispersibility is excellent. The problems that a traditional magnetic fluid is low in magnetic performance, prone to failure at high temperature, poor in dispersion stability and the like are solved, and the magnetic fluid is suitable for aerospace, high-end manufacturing, ship propulsion and other extreme scenes.

The invention belongs to the technical field of anti-reflection coatings, and particularly relates to an anti-reflection coating for photoresist and a preparation method of the anti-reflection coating. The coating comprises perfluoropolyether-polyhedral oligomeric silsesquioxane, the structural formula of the coating is # imgabs0 #, R is CH2CH (CH3) 2, and n is equal to (3-6). The preparation method of the coating comprises the following steps: dissolving perfluoropolyether-polyhedral oligomeric silsesquioxane in a solvent to prepare a solution, stirring at room temperature for 24 hours, filtering, coating, removing the solvent, crosslinking and curing to form the coating. By introducing an inorganic-organic hybrid skeleton and a rigid cage structure in a POSS structure and a fluorocarbon chain of perfluoropolyether, the thermal stability, hydrophobicity and etching resistance of the coating are improved.

The invention discloses a perfluoropolyether-based polymer solid electrolyte film regulated and controlled by a mixed solvent as well as a preparation method and application of the perfluoropolyether-based polymer solid electrolyte film, and belongs to the field of organic polymer solid electrolyte preparation. Reacting under the action of an initiator and an RAFT (reversible addition-fragmentation chain transfer) reagent to obtain a perfluoropolyether-based copolymer; the method comprises the following steps: adding a perfluoropolyether-based copolymer into a polyvinylidene fluoride-hexafluoropropylene copolymer solution in which lithium salt is dissolved, the mass of the polyvinylidene fluoride-hexafluoropropylene copolymer accounts for 10%-30% of the mass of the polyvinylidene fluoride-hexafluoropropylene copolymer, the mass of the N, N '-dimethylformamide, the mass of the trifluorotoluene and the mass of the perfluoropolyether-based copolymer account for 10%-30% of the mass of the polyvinylidene fluoride-hexafluoropropylene copolymer, and the perfluoropolyether-based polymer solid-state electrolyte film is obtained by uniformly mixing and then preparing a film. And the comprehensive performance of the composite solid electrolyte serving as the film is improved.

The invention discloses a polyurethane modified low-temperature adaptive protective earplug material and a preparation process thereof, and belongs to the technical field of earplug materials. The earplug material comprises a component A, a component B, a component C and a component D, wherein the component A is prepared from isocyanate, 2-hydroxyethyl disulfide and octafluoro-1, 6-hexanediol; the component B comprises polyether polyol, perfluoropolyether glycol, polysiloxane, a foaming agent, a foam stabilizer, a dynamic cross-linking agent and a catalyst. 2-hydroxyethyl disulfide and octafluoro-1, 6-hexanediol are used for partially modifying a hard section of a polyurethane material, and perfluoropolyether glycol, polysiloxane and polyether polyol are grafted, so that the hardness of the earplug material at a low temperature is reduced through synergism of all the components, and the earplug material has low-temperature flexibility, tear resistance, hydrophobicity and pollution resistance; and low-temperature embrittlement can be avoided.

The invention provides a preparation method of a hydrophobic silver nanoparticle doped coating, which comprises the following specific steps: preparing silicon shell silver chloride nanoparticles (AgCl (at) SiO2NPs) by taking cetyltrimethylammonium chloride (CTAC), silver nitrate, sodium chloride and tetraethyl orthosilicate (TEOS) as raw materials through a one-pot method, and introducing carbon-carbon double bonds by 3-(methacryloyloxy) propyltrimethoxysilane (MPS) under an acidic condition. In the subsequent distillation-precipitation polymerization process, 4-chloromethyl styrene (VBC) is grafted with chloromethyl, and finally, perfluoropolyether methyl acrylate (PFPEMA) is introduced through atom transfer radical polymerization (ATRP) to form AgCl (at) SiO2-F NPs. Nanoparticles are added into polydimethylsiloxane (PDMS) to be evenly mixed, a silica gel catheter is used for pulling and curing to form the hydrophobic nanoparticle coating SR-F. The hydrophobic nanoparticle coating SR-F is mature in step, firm in film and good in hydrophobicity, and experimental results show that the coating has long-acting antibacterial ability.

The invention provides an ultraviolet-cured low-refractive-index UV resin and a preparation method thereof, and the preparation method comprises the following steps: A) mixing epoxy resin, fluorine-modified binary acid, a first catalyst, an antioxidant and a polymerization inhibitor, and carrying out a reaction to obtain a first product; b) mixing the first product, modified acrylate and a coupling agent, and reacting to obtain a second product; and C) mixing the second product with a modified acrylate monomer to obtain the UV-cured low-refractive-index UV resin. The perfluoropolyether and the silicon-containing hydroxyl acrylate are modified, so that the problems of poor compatibility, non-transparent paint film and the like caused by directly grafting the perfluoropolyether and the silicon-containing hydroxyl acrylate into a structural system are greatly improved, and the perfluoropolyether and the silicon-containing hydroxyl acrylate have obvious advantages in the application direction with requirements on the transparency of the paint film. The stability of the resin can be improved, so that the resin is not prone to gelling during production, and the problems of layering and the like are not prone to occurring during use.

Provided is a fluoropolyether-based curable composition which can be used for a longer time than in the prior art, can be cured at room temperature or heat-cured, and can form a cured product having reduced hardness and good mechanical and physical properties. The fluoropolyether-based curable composition contains (A) a fluorine-containing compound having at least two secondary amino groups in one molecule and having a divalent perfluoropolyether group in the main chain, and (B) a fluorine-containing compound having at least two epoxy groups in one molecule and having a monovalent or divalent perfluoropolyether group in the main chain in an amount such that the amount of the fluorine-containing compound is less than or equal to 1 mol per secondary amino group in the component (A), and the amount of the fluorine-containing compound is less than or equal to 1 mol per secondary amino group in the component (A). And the epoxy group in the component (B) is 0.5-5 mol.

The present invention pertains to a curable perfluoropolyether adhesive composition that contains: (A) 100 parts by mass of a straight-chain perfluoropolyether compound that has at least two alkenyl groups in one molecule, and that has, in the main chain, a perfluoropolyether structure including a repeating unit represented by —CaF2aO— (where a is an integer from 1-6); (B) in an amount effective for curing, a fluorine-containing organohydrogenpolysiloxane having, in one molecule, at least two hydrogen atoms to which a silicon atom is bonded; and (C) a catalyzing quantity of a hydrosilylation reaction catalyst. The composition does not contain an organic solvent. This configuration makes it possible to provide: a curable perfluoropolyether adhesive composition with which can be achieved a cured product that has excellent heat resistance, weather resistance, water repellency, oil repellency, chemical resistance, solvent resistance, etc., and that is characterized in particular in that voids are not generated on the surface of a coating film in a heating step; and an adhesive and adhesive tape that include said cured product.

The invention relates to a transfer printing template and a preparation method thereof. The transfer printing template comprises a base body, at least one part of the surface of the base body is provided with a texture layer, the surface of the side, away from the base body, of the texture layer is provided with a middle layer, and the surface of the side, away from the base body, of the middle layer is provided with a surface layer; the material of the middle layer comprises silicon dioxide, and the material of the surface layer comprises perfluoropolyether siloxane. According to the transfer printing template, the middle layer and the surface layer which are good in synergy are sequentially arranged on the surface of the texture layer, so that the demolding performance and the durability of the transfer printing template are remarkably improved.

The present invention relates to the field of photoresist technology, and more particularly to an aqueous liquid photosensitive photoresist and a preparation method thereof. The aqueous liquid photosensitive photoresist comprises the following raw materials, in parts by weight: 50-70 parts of an acrylic resin emulsion, 2-5 parts of a monomer composition, 8-12 parts of ethoxylated trimethylolpropane triacrylate, 3-6 parts of a photoacid generator, 0.5-1.5 parts of a thickener, 1-3 parts of a modified perfluoropolyether carboxylic acid ammonium, 0.2-0.4 parts of an anti-cratering agent, and 20-24 parts of deionized water. The aqueous liquid photosensitive photoresist prepared by the present invention has excellent etching resistance and high resolution, and the preparation method is simple.

The invention relates to the field of dielectric energy storage materials, and discloses a polyimide-based composite dielectric film material and a preparation method thereof.The dielectric film is prepared from, by mass, 4-20 parts of modified barium strontium titanate and 100 parts of fluorinated polyamide acid solution, the modified barium strontium titanate is prepared from the following raw materials: hydroxylated barium strontium titanate, 3-glycidyl ether oxypropyl trimethoxy silane, perfluoropolyether alcohol and a catalyst, and the fluorinated polyamide acid solution is prepared from the following raw materials: a fluorine-containing diamine monomer and a fluorine-containing dianhydride monomer; according to the technical scheme, the polyimide film dielectric film is prepared from fluorinated polyamide and modified silane barium strontium titanate, the dispersity of barium strontium titanate in a polyimide matrix is remarkably improved, the compatibility of barium strontium titanate and fluorinated polyimide is remarkably improved, and the dielectric energy storage performance of the dielectric film is remarkably improved; the hydroxylated barium strontium titanate is modified through the 3-glycidyl ether oxypropyl trimethoxy silane and the perfluoropolyether alcohol, so that the dielectric loss of the dielectric film is remarkably reduced.

The invention discloses a preparation method of sulfide solid electrolyte slurry, a preparation method of a positive plate, an all-solid-state battery and a preparation method of the all-solid-state battery. The method comprises the following steps: preparing modified perfluoropolyether oil by taking perfluoropolyether carboxylic acid as a raw material, and mixing the modified perfluoropolyether oil with lithium salt, a suspension stabilizing additive and sulfide electrolyte to prepare the slurry. The modified perfluoropolyether oil adopts asymmetric end group design, one end is an epoxypropyl ether group, and the other end is a cyano group. The modified perfluoropolyether oil is introduced as a protective medium and an ionic conduction enhancer of the sulfide electrolyte, so that the problems of air stability, space charge layer and high-voltage operation of the sulfide electrolyte are solved, the process is simple, the cost is low, and the method has a good industrial application prospect. According to the all-solid-state battery disclosed by the invention, the gel-state ion conduction layer is formed between the positive plate and the electrolyte layer, and the gel-state ion conduction layer has high viscoelasticity and can keep good solid-solid interface contact under a relatively low external pressure condition.

A fluorine-containing ether compound represented by formula (1). R < 1 >-O-CH < 2 >-R < 2 >-CH < 2 >-O-R < 3 > (R < 2 > is a perfluoropolyether chain. R1 is a formula (2-1) or a formula (2-2). And R3 is an organic group having at least one polar group and having 2-65 carbon atoms. In formula (2-1), X1 is a divalent linking group having 1-40 carbon atoms. Y1 and Z1 are organic groups with 1-12 carbon atoms or hydrogen atoms. At least one of X1, Y1, and Z1 contains a primary hydroxyl group. In the formula (2-2), X2 is a divalent linking group having 1-40 carbon atoms. And Y2 is an organic group with 1-12 carbon atoms or a hydrogen atom. And Z2 is an organic group with a carbon atom number of 1-12. And at least one of X2, Y2, and Z2 contains a primary hydroxyl group. )