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134 results about "Photoexcitation" patented technology

Photoexcitation is the production of an excited state of a quantum system by photon absorption. On the atomic and molecular scale photoexcitation is the photoelectrochemical process of electron excitation by photon absorption, when the energy of the photon is too low to cause photoionization. The absorption of the photon takes place in accordance with Planck's quantum theory.

Method for Specifically Detecting Analyte Using Photocurrent, and Electrode, Measuring Cell and Measuring Device for Use Therein

A method, an electrode, a measuring cell, and a measuring device are disclosed which can detect and quantitatively determine an analyte having specific bonding properties, in a highly sensitive, simple and accurate manner using photocurrent. This method comprises contacting a working electrode and a counter electrode with an electrolyte medium, wherein the working electrode has an analyte immobilized thereon through a probe substance and wherein the analyte is bonded to a sensitizing dye; irradiating the working electrode with light to photoexcite the sensitizing dye; and detecting photocurrent flowing between the working electrode and the counter electrode, wherein the photocurrent is generated by transfer of electrons from the photoexcited sensitizing dye to the working electrode. The working electrode comprises an electron accepting layer comprising an electron accepting substance capable of accepting electrons released from the sensitizing dye in response to photoexcitation, wherein the probe substance is supported on a surface of the electron accepting layer. The electron accepting substance is an oxide semiconductor having an energy level lower than that of a lowest unoccupied molecular orbit (LUMO) of the sensitizing dye. The electrolyte medium comprises an electrolyte and at least one solvent selected from an aprotic solvent and a protic solvent, wherein the electrolyte comprises a salt capable of providing an oxidized sensitizing dye with electrons.
Owner:TOTO LTD

Stimulated radiation loss micro imaging system

The invention provides a stimulated radiation loss micro imaging system which comprises an exciting light laser, a first dichroscope, a fluorescent light activating and imaging unit, a loss photoexcitation light, a vector beam modulation unit and a control unit, wherein the fluorescent light activating and imaging unit comprises a second dichroscope, an XY vibrating mirror scanning part, a scanning lens, a cylinder mirror, an objective lens, a probe hole and a photomultiplier tube. The stimulated radiation loss micro imaging system provided by the invention adopts the vector beam modulation unit to modulate the incident loss light laser beam amplitude, a phase and a polarization state, the loss light wave amplitude, the phase and the polarization state of the pupil of an objective lens are utilized to form loss light focal spots, and meanwhile, the loss light focal spots are reshaped in a fine and complicated manner under the action of the multiple physical quantities, so that the generated loss light focal spots are exactly matched with the exciting light focal spot distribution, meanwhile, the diameter of a centre dark region of the loss light focal spots is minimal under the condition of a certain signal-to-noise ratio, and the stimulated radiation loss micro imaging system has high optical resolution.
Owner:SUZHOU INST OF BIOMEDICAL ENG & TECH CHINESE ACADEMY OF SCI

Delay time modulation femtosecond time-resolved scanning probe microscope apparatus

Disclosed is a measuring apparatus for a physical phenomenon by photoexcitation, in particular a delay time modulated and time-resolved, scanning probe microscope apparatus providing an ultimate resolution both temporal and spatial. The apparatus comprises an ultrashort laser pulse generator (2); a delay time modulating circuit (6) which splits an ultrashort laser pulse (3) produced by the ultrashort laser pulse generator (2) into two and which also modulates a delay time td between the two ultrashort laser pulses (4 and 5) with a frequency (ω); a scanning probe microscope (7); and a lock-in detection unit (8) which performs lock-in detection with the delay time modulation frequency (ω) of a probe signal (11) from the scanning probe microscope (7). It can detect the delay time dependency of the probe signal (11) as its differential coefficient to the delay time, with no substantial influence from fluctuations in the intensity of ultrashort laser pulses (3) while preventing the probe apex (19) from thermal expansion and shrinkage by repeated irradiation with ultrashort laser pulses (3). A photoexcited physical phenomenon dependent on a delay time between ultrashort laser pulses can thus be measured at a temporal resolution in the order of femtoseconds and at a spatial resolution in the order of angstroms.
Owner:JAPAN SCI & TECH CORP

Device and method for treating high-concentration and degradation-resistant organic waste water

The invention relates to a device for treating high-concentration and degradation-resistant organic waste water. The device for treating the high-concentration and degradation-resistant organic waste water mainly comprises an anaerobic bio-membrane reactor, an aerobic bio-membrane reactor, an artificial wetland system, a turbine sieve filter and a sand setting tank. The invention also discloses a method for removing high-concentration organic pollutants in sewage by utilizing the device provided by the invention. The device and method for treating the high-concentration and degradation-resistant organic waste water have the advantages that a nano aeration technology is adopted, two methods, namely photoexcitation and photocatalysis, are combined, hydroxyl free radicals are produced at high efficiency, biologically treated sewage effluent is subjected to deep treatment in a lasting and effective manner by utilizing strong oxidizing property of the hydroxyl free radicals, the pollutants with poor biodegradability and relative high molecular weight can be completely oxidized and degraded, and bacteria and pathogenic bacteria in sewage are killed, so that the sterilization and disinfection effects are realized.
Owner:CHINESE RES ACAD OF ENVIRONMENTAL SCI

Measurement device used for specifically detecting substance to be examined using photocurrent, sensor unit used for same, and method for specifically detecting substance to be examined using photocurrent

In utilizing photocurrent generated in the photoexcitation of a dye in specific detection of an analyte, highly accurate detection can be realized by discharging charged current generated in the formation of a sensor unit and, in the detection of photocurrent of a plurality of detection spots provided on a working electrode, discharging photocurrent which is derived from a detection spot subjected to the latest photocurrent measurement and becomes noise current. The present invention provides a measuring apparatus comprising a sensor unit comprising a working electrode, a counter electrode, and an electrolyte-containing substance, a single or plurality of light sources that apply light to the working electrode, an XY moving device provided when the light source is moved relatively in an XY direction relative to the working electrode, an ammeter that measures current which flows across the working electrode and the counter electrode, and a discharge device that discharges charged current and photocurrent derived from a detection spot subjected to the latest photocurrent measurement. The specific detection method using the measuring apparatus is carried out by controlling the timing of light irradiation and the timing of connection to the ammeter and the discharge device.
Owner:TOTO LTD

Catalyst for producing ethylene through photocatalytic reduction of carbon dioxide and preparation method of catalyst

The invention belongs to the technical field of catalytic materials and preparation thereof, and particularly relates to a catalyst for producing ethylene through photocatalytic reduction of carbon dioxide and a preparation method of the catalyst, and the catalyst is formed by loading atomic-scale dispersed Cu on the surface of a CeO2-TiO2 heterostructure; the preparation method comprises the following steps: impregnating and adsorbing a proper amount of Ce 3+ and Cu2+ by using MIL-125-NH2, and performing pyrolyzing in air at a certain temperature. In the catalyst, TiO2 generates electron-hole pairs under optical excitation, the separation efficiency of the photo-generated electron-hole pairs is improved by a CeO2-TiO2 heterostructure, and multiple active sites of Cu and Ce on the surface of the catalyst are beneficial to formation and stabilization of CO intermediates and promote formation of COCO dimers, so that the efficiency and selectivity of generating C2H4 through photocatalytic reduction of CO2 are remarkably improved. The preparation method of the catalyst is simple and easy to implement, and the catalyst has wide application prospects in the aspects of preparing high-added-value chemicals through catalytic conversion of greenhouse gas CO2, efficiently utilizing solar energy and the like.
Owner:ZHEJIANG SCI-TECH UNIV

Delay time modulation femtosecond time-resolved scanning probe microscope apparatus

Disclosed is a measuring apparatus for a physical phenomenon by photoexcitation, in particular a delay time modulated and time-resolved, scanning probe microscope apparatus providing an ultimate resolution both temporal and spatial. The apparatus comprises an ultrashort laser pulse generator (2); a delay time modulating circuit (6) which splits an ultrashort laser pulse (3) produced by the ultrashort laser pulse generator (2) into two and which also modulates a delay time td between the two ultrashort laser pulses (4 and 5) with a frequency (ω); a scanning probe microscope (17); and a lock-in detection unit (8) which performs lock-in detection with the delay time modulation frequency (ω) of a probe signal (11) from the scanning probe microscope (17). It can detect the delay time dependency of the probe signal (11) as its differential coefficient to the delay time, with no substantial influence from fluctuations in the intensity of ultrashort laser pulses (3) while preventing the probe apex (19) from thermal expansion and shrinkage by repeated irradiation with ultrashort laser pulses (3). A photoexcited physical phenomenon dependent on a delay time between ultrashort laser pulses can thus be measured at a temporal resolution in the order of femtoseconds and at a spatial resolution in the order of angstroms.
Owner:JAPAN SCI & TECH CORP
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