The present invention provides a
passivation film structure capable of achieving both
passivation and surface
doping, and a preparation method therefor and the use thereof. The
passivation film structure comprises a nano-
dielectric layer, a
silicide layer and a
hydrogen-rich
dielectric layer, which are sequentially stacked on a surface of a
silicon substrate, wherein the nano-
dielectric layer is made of a hydrogenated
silicon oxide thin film or a hydrogenated
silicon oxynitride thin film, the
silicide layer is made of a carbon-containing and / or
nitrogen-containing
boron /
phosphorus-doped hydrogenated
silicon thin film, and the
hydrogen-rich
dielectric layer is made of one or more of a laminated thin film selected from a hydrogenated aluminum
oxide thin film, a hydrogenated
silicon nitride thin film, a hydrogenated
silicon oxide thin film and a hydrogenated
silicon oxynitride thin film. The passivation
film structure of the present invention has good passivation performance, and can achieve a good passivation effect on polished and textured silicon wafers or
boron /
phosphorus diffused emitters; moreover, the passivation film structure contains
boron /
phosphorus, and can achieve surface
doping on silicon wafers during the preparation process of the passivation film, without requiring an additional
doping process.