The invention relates to luminescent photocatalytic coating and a preparation method thereof. The luminescent photocatalytic coating is novel coating capable of removing the lampblack and the odor. The luminescent photocatalytic coating comprises inorganic coating base basically with dispersed nanoscale photocatalytic titanium dioxide nanotube and rare-earth long-acting noctilucence powder. The luminescent photocatalytic coating comprises the following components: 25 to 65 percent of photocatalytic titanium dioxide nanotube, 5 to 10 percent of long-acting rare-earth noctilucence powder, 15 to 25 percent of pigments, 3 to 5 percent of self-dissolving agent, 2 to 15 percent of dispersing agent, 2 to 5 percent of anti-foaming agent, 1 to 3 percent of sterilizing agent and 3 to 5 percent of calcium carbonate. The photocatalytic titanium dioxide nanotube is prepared in a novel hydrothermal synthesis method, the diameter of the photocatalytic titanium dioxide nanotube is about 5nm to 15nm, the length of the photocatalytic titanium dioxide nanotube is about 100nm, and by adopting the coating, pollutants such as lampblack and harmful gas of NOX compound in the air of a kitchen and a toilet can be resisted. The luminescent photocatalytic coating not only can work at daytime, but also can react at night, and the efficiency of the nano material for purifying the air can be improved.