219 results about "Hydrophilization" patented technology

The invention belongs to the technical field of membrane separation, and particularly relates to a low-pressure high-flux polyamide / polysulfone hollow fiber composite nanofiltration membrane and a preparation method thereof. The preparation method of the composite nanofiltration membrane comprises the following steps: dissolving sulfonated polysulfone, poly (1-vinyl-3-butylimidazole) bromide and polyvinylpyrrolidone to prepare a spinning solution, and spinning to obtain a base membrane; carrying out hydrophilic modification on the base membrane by using 1, 3-propane sultone; then, an aqueous phase solution containing poly (gamma-glutamic acid) and triethylene tetramine and an organic phase solution containing trimesoyl chloride and 3, 5-diaminobenzoic acid are subjected to interfacial polymerization in the inner cavity of the modified base membrane to form a polyamide separation layer; and finally, carrying out heat treatment to obtain the composite nanofiltration membrane. Through the synergistic effect of zwitterionic ionization of the base membrane and biomacromolecule construction of the separation layer, the mass transfer resistance of water is remarkably reduced, unification of high flux and high selectivity is achieved, and good structural stability is achieved.

The present invention provides a lightweight and thin thermal insulating / flame barrier sheet that is used between cells within a battery pack where battery cells are connected and stacked in series or parallel. This thermal insulating / flame barrier sheet has a thickness of 3 mm or less, and is obtained by papermaking process using a suspension containing 25 to 70% by weight of a silica-based inorganic fiber having a hydroxyl group; 2 to 25% by weight of a glass fiber; 5 to 40% by weight of a fibrous mineral; 3 to 20% by weight of a binder; and 0 to 45% by weight of a thermal insulating inorganic particle. The thermal insulating inorganic particle includes a hydrophilized aerogel particle obtained by treating the surfaces of hydrophobic aerogel particle having a porosity of 80% or more and an average particle size of 5 to 200 μm, with a hydrophilizing agent.

The invention discloses a high-flux anti-pollution nanofiber membrane modified by a nanoparticle reinforced coating and a preparation method of the high-flux anti-pollution nanofiber membrane. The nanofiber membrane is prepared by doping hydrophilic nanoparticles into a spinning solution and coupling an electrostatic spinning process with a functional coating for modification. The hydrophilic nano-particles are selected from hydrophilic modified inorganic nano-particles, organic nano-particles, carbon-based nano-materials or metal organic framework materials. Nanoparticles, a membrane base material and a solvent are blended to form a uniform spinning solution, and functional coating deposition is performed after electrostatic spinning forming. The method is simple and efficient in preparation process, and the obtained nanofiber membrane has excellent hydrophilicity and anti-pollution performance. The introduction of the nanoparticles not only realizes hydrophilic modification of the membrane surface, but also significantly enhances the bonding strength of the coating and the matrix, so that the membrane material has excellent selective separation performance on oil substances (the rejection rate is greater than or equal to 99%) and macromolecular impurities while maintaining high flux (pure water flux is 3000-4000 L.m <-2 >. H <-1 >), and the transmittance on protein can reach 99%. The membrane material also has outstanding flux recovery rate (greater than or equal to 90%) and long-term operation stability, and has wide application prospects in the fields of sewage treatment, food processing and the like.

The invention belongs to the field of spinning, and particularly relates to a preparation method of a high-breathability fabric, which mainly comprises the following steps: S1, plasma treatment: putting a polyester fabric into plasma treatment equipment, and carrying out plasma treatment by using a mixed gas of argon and oxygen under the condition that the vacuum degree is 10-50Pa; s2, surface grafting modification: taking the polyester fabric subjected to plasma treatment, adding the polyester fabric into a modification solvent composed of triallyl isocyanurate, vinyl acetate, azodiisobutyronitrile and n-heptane for grafting reaction, alternately cleaning the polyester fabric with an organic solvent and deionized water for 3-5 times, and drying the polyester fabric to realize surface grafting of the polyester fabric; s3, preparing hydroxyl groups on the surfaces of the fibers, namely treating the polyester fabric subjected to surface grafting in a hydrolytic agent, and then performing post-treatment on the polyester fabric to obtain the high-air-permeability fabric. According to the invention, hydrophilic modification treatment is carried out on the polyester fabric, so that the fabric can be endowed with certain moisture absorption and air permeability and certain washing resistance at the same time.

The invention discloses biodegradable artificial leather and a preparation method thereof, and belongs to the technical field of artificial leather materials. According to the method, a porous structure is formed by rapidly vaporizing moisture in the modified starch composition through the steps of preparing a main body mixture containing the modified starch composition, coating, rapidly heating and forming pores and the like, and a foaming agent does not need to be additionally added. The modified starch composition is subjected to hydrophilic treatment, so that the compatibility with waterborne polyurethane is improved, and the problem of starch agglomeration is solved. The prepared artificial leather has good biodegradability, air permeability and mechanical properties, is suitable for the fields of clothes, bags and the like, and has environmental protection and practical values.

The invention provides a sodium ion specific fluorescence labeled transparent soil sample as well as a preparation method and application thereof, and belongs to the technical field of rock soil and geological engineering. The method comprises the following steps: firstly, sequentially carrying out hydrophilization treatment, solvent evaporation and dissolution on a sodion combined benzofuran isophthalate probe to obtain a probe mother solution; mixing the probe mother solution, a buffer solution, an inorganic sodium salt solution and a solvent to prepare a fluorescence labeling pore solution; and finally, mixing the sodium polyacrylate particles and the fluorescence labeled pore liquid, and performing vacuum saturation treatment to obtain the transparent soil sample. The transparent soil sample provided by the invention still keeps excellent optical transparency while having sodium ion specific response capability, so that a stable and reliable experimental medium is provided for in-situ, real-time and full-field observation of sodium ion migration.

The invention discloses porous carbon with a gradient structure, a preparation method of the porous carbon and application of the porous carbon in a negative electrode of a lithium ion battery. The porous carbon has a gradient structure with compact micropores on the surface and loose macropores inside. The preparation method of the porous carbon comprises the following steps: carrying out oleophylic modification on SiO2 to obtain hydrophobic SiO2; carrying out hydrophilic coating on NH4Cl to obtain PVP (Polyvinyl Pyrrolidone) coated NH4Cl; the preparation method comprises the following steps: mixing coal pitch, methylbenzene, oleic acid, hydrophobic SiO2 and PVP (at) NH4Cl to form a suspension; preparing a spherical precursor by a micro-fluidic emulsification method; and carbonizing, sequentially carrying out oxygen plasma treatment and HF solution etching, and removing the template to obtain the porous carbon with the gradient structure. The gradient distribution of the template and the pore-forming agent is realized through surface modification difference and a microfluidic technology, the pore structure and the particle size can be accurately regulated and controlled, the process is simple, the compatibility is high, the prepared porous carbon can be used as a substrate for a silicon-carbon composite negative electrode material, the volume expansion of silicon can be effectively buffered, and the service life of the silicon-carbon composite negative electrode material is prolonged. And the first coulombic efficiency, the specific capacity and the cycling stability of the lithium ion battery are improved.

There are provided a die surface treatment apparatus capable of sequentially performing reduction and activation processes on dies in a dual zone and a die bonding system including the die surface treatment apparatus. The die surface treatment apparatus includes: a stage supporting dies, a first plasma generator installed on a moving path of the dies, the first plasma generator performing a reduction process on surfaces of the dies, in a first plasma area; and a second plasma generator installed on the moving path of the dies, the second plasma generator performing a hydrophilization process on the surfaces of the dies, in a second plasma area.

The invention discloses an amino-modified graphene oxide hydrophilic membrane as well as a preparation method and application thereof, and belongs to the technical field of membrane material preparation. The preparation method comprises the following steps: carrying out hydrophilic modification on graphene oxide by using an amino group modified substance through a blending method to obtain a membrane casting solution, and defoaming to prepare the hydrophilic membrane. The preparation method of the hydrophilic film is simple, amino groups and groups such as hydroxyl groups on the surface of the graphene oxide are strongly adsorbed through hydrogen bonds, and the hydrophilic film is relatively stable in property. According to the preparation method, the graphene oxide is directly subjected to surface hydrophilic modification, the graphene oxide hydrophilic film is prepared by adopting a blending method, a base film does not need to be used, and the production cost of the hydrophilic film is reduced; compared with an existing common commodity microfiltration membrane, the hydrophilic performance of the hydrophilic membrane is greatly improved, meanwhile, compared with a microfiltration membrane which is subjected to amino modified graphene oxide graft modification by taking a commercial microfiltration membrane as a base membrane, the hydrophilic performance of the hydrophilic membrane is equivalent to that of the commercial microfiltration membrane, and the hydrophilic membrane has higher cost performance.

The present invention provides a method for producing hydrophilic quantum dots, which is characterized by adding a metal halide, two or more phosphorus compounds, an organic acid having a mercapto group or an alcohol having a mercapto group, and an aprotic polar solvent to hydrophobic quantum dots dispersed in a non-polar solvent and heating the mixture to thereby produce the hydrophilic quantum dots. Therefore, hydrophilic treatment of the hydrophobic quantum dots is carried out. As a result, provided is a method for producing hydrophilic quantum dots that can be hydrophilized during a hydrophilization treatment without deteriorating the characteristics of the quantum dots.

The application discloses a kind of hydrophilic polyvinylidene fluoride oil-water separation membranes and preparation method thereof, belong to oil-water separation membrane technical field.The preparation method steps include: with 2,2-dimethoxy-2-phenyl acetophenone as photo initiator, 3,6-dioxane-1,8-octane dithiol and polyethylene glycol diacrylate as modifier, by photo initiation mercapto-olefin gradually polymerization method is modified to alkali treated PVDF membrane, and hydrophilic polyvinylidene fluoride oil-water separation membrane is prepared.The application is grafted to PVDF separation membrane surface by photo initiation mercapto-olefin gradually polymerization method, and hydrophilic separation membrane is obtained.The preparation method provided by the application has the characteristics of simple process, low cost and the like, and the prepared hydrophilic membrane can be further developed and utilized as sewage treatment separation membrane, hemodialysis membrane.

This bonding method includes: a first hydrophilization treatment step for hydrophilizing a temporary bonding surface of a temporary substrate (WTD), to said temporary bonding surface a chip (CP) being to be temporarily bonded; a second hydrophilization treatment step for hydrophilizing a surface of the chip (CP), the surface being on the reverse side of a bonding surface (CPf) that is to be bonded to a substrate (W1); a first temporary bonding step for temporarily bonding the surface on the reverse side of the bonding surface (CPf) of the chip (CP) to the temporary bonding surface (WTDf) of the temporary substrate (WTD) after the first hydrophilization treatment step and the second hydrophilization treatment step; a first bonding step for bonding the chip (CP) to the substrate (W1) by bringing the temporary substrate (WTD) close to the substrate (W1) and bringing the bonding surface (CPf) of the chip (CP) into contact with the bonding surface of the substrate (W1) in a state in which the temporary bonding surface (WTDf) side of the temporary substrate (WTD) faces the substrate (W1) after the first temporary bonding step; and a first temporary substrate separation step for separating the temporary substrate (WTD) from the chip (CP) while maintaining the state in which the chip (CP) is bonded to the substrate (W1).

The invention provides cooling leather and a treatment process, and belongs to the technical field of cooling leathes.The cooling leather treatment process comprises the following steps that S1, modified boron nitride is prepared, specifically, S1, modified boron nitride is prepared; s2, polyurethane synthetic leather is selected as a base material and subjected to plasma cleaning, surface impurities are removed, and the surface is activated; s3, the surface of the base material is coated with waterborne polyurethane slurry containing 3%-8% of modified boron nitride; s4, after the heat conduction bottom layer is cured, embossing is conducted at the temperature of 160-170 DEG C; s5, plasma cleaning or short-time infrared heating is conducted on the embossed layer; s6, spraying a microcapsule phase change material on the surface of the activated embossing layer; s7, covering a fluorocarbon resin surface layer containing 1-3% of modified boron nitride; s8, carrying out secondary echelon cooling after the surface layer is cured; the h-BN is subjected to double-layer modification through polydopamine-hyperbranched polyethyleneimine (HPEI), and hydrophilic modification of the surface of the filler is realized at low temperature, so that the heat conductivity coefficient is increased, and meanwhile, the mechanical property of the material is kept stable.

A composite film for a current collector, a preparation method therefor, and the use thereof. The composite film comprises a base film (B) and a polyimide layer (A) provided on at least one surface of the base film (B). The base film (B) comprises a base film (B) hydrophilically modified by a modification compound, the molecular structure of the modification compound containing a carbon-carbon double bond and a functional group, and the functional group comprising at least one of an anhydride group, a carboxyl group, a hydroxyl group, an amide group, or an ester group; the polyimide layer is prepared by an aqueous phase monomer and an organic phase monomer undergoing an interfacial polymerization reaction on the surface of the base film. The composite film has excellent heat resistance and mechanical properties, exhibits high adhesion to metal conductive layers, so as to prevent metal conductive layers in composite current collectors from peeling off, and in addition, is not prone to film breakage during the preparation process , thus achieving high yield and low cost.

To provide a simple method for hydrophilizing a surface of a dental implant body.SOLUTION: A method for hydrophilizing a surface of a dental implant body includes drying the implant body after immersing it in ozone nanobubble water. Even when the implant body is exposed to atmosphere before being immersed in the ozone nano-bubble water and a surface thereof becomes contaminated and hydrophobized by organic substances such as hydrocarbons in the atmosphere, the surface contaminants are decomposed by drying the implant body after immersion in the ozone nano-bubble water, to clean the surface as well as making the surface hydrophilic, thereby facilitating acquisition of osteointegration.SELECTED DRAWING: Figure 1

The present application relates to a kind of monodisperse core-shell type hybrid silica microspheres containing vinyl shell and its preparation and application. Specifically, using "two-phase method" strategy, monodisperse solid silica microspheres are used as matrix, vinyl triethoxysilane and tetraethyl orthosilicate are used as raw materials, lauryl amide propyl betaine and sodium subtiliporin are used as double-template pore-forming agent, under the catalysis of urea, sol-gel reaction occurs, a layer of porous hybrid shell containing vinyl functional group is constructed on the surface of solid silica microspheres, and core-shell type silica hybrid microspheres are formed. Because the shell contains a large number of vinyl functional groups, after hydrophilic modification with captopril, it is used as the adsorbent of hydrophilic interaction chromatography, and is applied to the selective enrichment of biological samples. The core-shell type silica hybrid microspheres prepared in the present application have uniform morphology, good monodispersity, and rich vinyl functional groups on the surface, which are easy to modify and apply subsequently.

According to one embodiment of the present disclosure, a substrate cleaning apparatus includes a hydrophilization chamber connected to a polishing apparatus and that accommodates a substrate having a polished surface polished by the polishing apparatus; a support provided in the hydrophilization chamber; a liquid supply unit that supplies a cleaning liquid to the polished surface of the substrate to hydrophilize the polished surface; an imaging unit that captures an image of the polished surface supplied with the cleaning liquid; a determination unit that determines whether hydrophilization is achieved on a basis of the image; an adjustment unit that adjusts the supply of the cleaning solution by the liquid supply unit depending on a determination result obtained by the determination unit; and a cleaning chamber connected to the hydrophilization chamber and that cleans the polished surface hydrophilized by the cleaning liquid.

The invention discloses a polyurethane or polyurea aqueous dispersion with high humidity and heat resistance as well as a preparation method and application thereof. The aqueous dispersion is prepared by reacting the following components: a) polyester diol and / or polyol, b) di-and / or polyisocyanate which at least contains more than 50% by mass of toluene diisocynate, c) a monofunctional or polyfunctional polyethoxy chain segment-containing component which is synthesized by taking sodium methoxide as a catalyst and has reaction activity to isocyanate, and d) a polyethoxy chain segment-containing component which has reaction activity to isocyanate. D) a sulfonic acid type hydrophilic compound; e) a low molecular compound containing hydroxyl and containing at least two NCO reactive amino groups; wherein the ratio of the sodium ions in the component c) to the toluene diisocynate in the component b) is 10 ppm to 100 ppm. Sodium ions can catalyze a small amount of isocyanate groups to react with carbamate bonds to generate allophanate bonds in a polyurethane synthesis process, so that a trace cross-linked structure is introduced into a polyurethane chain segment, and the heat resistance / damp heat resistance of a product is improved.

An electrochemical system with an electrochemical stack (1) comprising a first reaction chamber (2) and a second reaction chamber (3), separated by a semipermeable barrier (4), between which an electrical potential difference can be applied. At least one of the reaction chambers (2; 3) is filled with water during operation and connected to a drain line (10) through which water or the aqueous solution can flow out. The inner surface (110) of the drain line (10) is hydrophilized and has a wetting angle (α) of 0° to 90°.

This invention discloses a high-strength, hydrophilic PVDF hollow fiber porous membrane with a through-cell honeycomb structure and its preparation method, belonging to the field of membrane separation technology. The technical solution includes: a) preparing a homogeneous spinning solution composed of a fluoropolymer and a diluent; b) simultaneously extruding the spinning solution and core solution through a spinning device, and then introducing the extruded nascent hollow fiber membrane containing the core solution into an external coagulation bath system to complete phase separation, solidification, and stretching; the core solution and / or the external coagulation bath system in step b is a solution containing a hydrophilic agent. This invention proposes a simple, controllable, and effective method to achieve uniform, durable, and non-damaging hydrophilic modification of the inner and outer surfaces of the fiber while preserving the excellent mechanical properties of the PVDF bulk.

The invention discloses a high-performance waterborne polyurethane primer applied to an optical-grade biaxially oriented polyester film and a preparation method of the high-performance waterborne polyurethane primer, and belongs to the field of waterborne polyurethane primer. The primer is prepared from the following raw materials in parts by weight: 52 to 68 parts of polyester polyol, 4 to 7 parts of sulfonate polyester polyol, 1 to 3 parts of polyether polyol, 1 to 6 parts of carboxylic acid type hydrophilic compound, 16 to 38 parts of isocyanate, 0.1 to 0.5 part of alcohol chain extender, 1 to 5 parts of amine chain extender, 0.02 to 0.06 part of catalyst, 1 to 6 parts of neutralizer, 160 to 280 parts of acetone, 1340 to 1740 parts of deionized water, 0.3 to 2 parts of silane coupling agent, 0.3 to 1 part of defoaming agent, 1 to 5 parts of wetting agent and 260 to 300 parts of isopropanol. And 4-7 parts of a closed curing agent. The primer prepared by the invention has good high-temperature yellowing resistance on an optical-grade biaxially oriented polyester film, is free of stripes after being coated, has the adhesive force of grade 0, and also has the advantages of flame retardance, environment friendliness, no toxicity, low VOC (Volatile Organic Compounds), low odor and the like.

The invention relates to the technical field of quartz glass surface treatment, in particular to a manufacturing method of a quartz glass surface high-temperature-resistant coating with high infrared reflectivity, and the method comprises the following steps: (1) preparing a water-based dispersion liquid: mixing deionized water, ethylene glycol, polyethylene glycol and a water reducing agent; (2) preparing coating slurry: mixing quartz glass micro powder, hydrophilic fumed silica particles, a non-metal sintering aid and a water-based dispersion liquid, and carrying out ball milling treatment; (3) carrying out hydrophilization treatment on the quartz glass substrate; (4) coating of a slurry layer: coating the slurry obtained in the step (2) on the surface of the quartz glass substrate treated in the step (3); and (5) sintering the slurry layer: performing high-temperature heat treatment on the quartz glass treated in the step (4) to form the high-temperature-resistant coating. According to the preparation method, the high-temperature-resistant coating with the infrared relative reflectivity of 90% or above can be prepared, and the heating performance and the temperature uniformity of the quartz glass-based reaction cavity are effectively improved.

A method for producing a hydrophilized product according to one aspect of the present invention comprises a step for hydrophilizing an inorganic oxide by subjecting an alkaline reaction solution containing water and an object to be treated having the inorganic oxide on the surface thereof to a hydrothermal treatment.

The present invention relates to a toughened ceramic-based composite material and a preparation method thereof. The method comprises the following steps: providing a porous carbon / carbon composite material and performing a hydrophilization treatment to obtain a hydrophilized porous carbon / carbon composite material; immersing the hydrophilized porous carbon / carbon composite material in a fullerene aqueous solution and subjecting the hydrophilized porous carbon / carbon composite material to a high-temperature treatment to obtain a porous carbon / carbon composite material compounded with fullerene; using a zirconium carbide-silicon carbide composite ceramic precursor as a reactant, depositing a zirconium carbide-silicon carbide composite interface layer by chemical vapor deposition to obtain a carbon / carbon composite material having a zirconium carbide-silicon carbide composite interface layer; reacting the zirconium carbide-silicon carbide composite ceramic precursor with a carbon / carbon composite material having a zirconium carbide-silicon carbide composite interface layer by an impregnation cracking method to obtain a toughened ceramic-based composite material. The present invention can significantly improve the toughness of a ceramic matrix and enhance the mechanical properties of the composite material under a high-temperature aerobic environment.

The present technology relates to: a hydrophilic film used for, for example, a hydrophilic coating of an optical component; an antireflective film; a camera; and a film formation method. The purpose of the present technology is to provide: a hydrophilic film that has excellent optical transparency and abrasion resistance and that can be reversibly hydrophilized; an antireflective film; a camera; and a film formation method. A hydrophilic film according to the present technology comprises a substance in which a silicon oxide and a metal oxide having a structure represented by M2O3 are compounded, wherein M is a metal element. In the hydrophilic film according to the present technology, polarization occurs between oxygen atoms and atoms of the metal element, and the atoms of the metal element are negatively charged.

The present application relates to a fiber with hydrophilic and hydrophobic alternating structure, a preparation method thereof and a fog water capturing application, the fiber is a skin-core structure with a static water absorption layer coated on a cellulose fiber, and the outer surface of the static water absorption layer has hydrophilic regions and hydrophobic regions arranged alternately along the fiber axis. The preparation method comprises: coating a modifiable polymer layer on the surface of the cellulose fiber by a solution immersion method, then performing heat stretching treatment to obtain a skin-core structure fiber; performing polarity modification on the skin-core structure fiber, converting part of the groups in the modifiable polymer layer into static water absorption groups, thereby converting the modifiable polymer layer into a static water absorption layer, to obtain a modified fiber; performing hydrophilization treatment and hydrophobization treatment on the modified fiber, to form a structure with hydrophilic regions and hydrophobic regions arranged alternately along the fiber axis. The present application takes the cellulose fiber rich in hydrophilic functional groups as the core layer, and constructs a hydrophilic and hydrophobic alternating structure in the skin layer, to realize active capture of fog water droplets, thereby improving the fog water collection efficiency.

The invention relates to a double-phase powder slurry composition and application thereof, an oil-in-water sunscreen system and a preparation method thereof, and the double-phase powder slurry composition comprises the following components in parts by weight: 4-6.5 parts of hydrophilic nano titanium dioxide powder slurry; and 1.5-4 parts by weight of a lipophilic micron titanium dioxide powder slurry, wherein nanoscale titanium dioxide in the hydrophilic nanometer titanium dioxide powder is subjected to hydrophilic surface treatment of hydrated silica and lecithin, and the average primary particle size is 10-100 nm; micron-sized titanium dioxide in the lipophilic micron-sized titanium dioxide powder slurry is subjected to hydrophobization surface treatment of triethoxyoctyl silane, and the average primary particle size is 1-10 [mu] m; the solid mass ratio of the nanoscale titanium dioxide to the micron-sized titanium dioxide is (1: 0.5)-(1: 1). Through the synergistic effect of the hydrophilic nano-scale titanium dioxide and the oleophylic micron-scale titanium dioxide in the two-phase powder slurry composition, the oil-in-water sunscreen emulsion which has a high SPF value, high water resistance, natural optical brightening, refreshing skin feeling and long-term stability is obtained.

The invention relates to the field of new chemical materials, and discloses a polyacrylamide / polyurethane dual-network hydrogel based on a sacrificial bond energy dissipation mechanism and a preparation method thereof. The preparation method comprises the following steps: S1, preparing an acrylamide precursor, adjusting the pH value, carrying out polymerization to obtain polyacrylamide colloid, and carrying out crushing granulation, alkaline post-hydrolysis, drying and secondary crushing to obtain powder; s2, enabling polyethylene glycol and hexamethylene diisocyanate to react under the catalysis of dibutyltin dilaurate by adopting a prepolymer method, adding a chain extender, and performing neutralization hydrophilization, high-speed shearing emulsification and ethanediamine post-chain extension to obtain a waterborne polyurethane emulsion; s3, performing in-situ polymerization on the powder and the emulsion by a one-pot method to form an interpenetrating double-network structure; the hydrogel obtained in the invention takes a waterborne polyurethane network as a sacrifice bond to consume energy, and a polyacrylamide network maintains matrix integrity, so that the hydrogel has better mechanical properties and can be used in different fields such as biomedical engineering.

The present application provides a semiconductor wafer surface hydrophilization treatment liquid capable of imparting hydrophilicity to the surface of a semiconductor wafer. The semiconductor wafer surface hydrophilization treatment liquid of the present application contains water and a compound represented by the following formula (1), and the total content of water and the compound represented by the following formula (1) is 95% by weight or more, R 1 O-(C3H6O2) n -H (1) (in the formula, R 1 represents a hydrogen atom, a hydrocarbon group having 1 to 24 carbon atoms which optionally has a hydroxyl group, or R 2 CO represents a group, the aforementioned R 2 represents a hydrocarbon group having 1 to 24 carbon atoms, and n represents the average polymerization degree of the glycerol unit shown in the parentheses and is 2 to 60).

The invention relates to novel biocompatible hybrid nanoparticles of very small size, useful in particular for diagnostics and / or therapy.The purpose of the invention is to offer novel nanoparticles which are useful in particular as contrast agents in imaging (e.g. MRD and / or in other diagnostic techniques and / or as therapeutic agents, which give better performance than the known nanoparticles of the same type and which combine both a small size (for example less than 20 nm) and a high loading with metals (e.g. rare earths), in particular so as to have, in imaging (e.g. MRI), strong intensification and a correct response (increased relaxivity) at high frequencies.Thus, the nanoparticles according to the invention, with diameter d1 between 1 and 20 nm, each comprise a polyorganosiloxane (POS) matrix including gadolinium cations optionally associated with doping cations; a chelating graft C1 DTPABA (diethylenetriaminepentaacetic acid bisanhydride) bound to the POS matrix by an —Si—C— covalent bond, and present in sufficient quantity to be able to complex all the gadolinium cations; and optionally another functionalizing graft Gf* bound to the POS matrix by an —Si—C— covalent bond (where Gf* can be derived from a hydrophilic compound (PEG); from a compound having an active ingredient PA1; from a targeting compound; from a luminescent compound (fluorescein).The method for the production of these nanoparticles and the applications thereof in imaging and in therapy also form part of the invention.