The invention provides a
system for hydrogenation conversion of
coal-fired
flue gas CO2 into
methanol under normal pressure and a catalyst preparation method. High-temperature
flue gas led out from an outlet of a
hearth of the
coal-fired boiler is subjected to
oxygen removal through the
oxygen removal reactor and then returns to a boiler
flue for continuous heat exchange, then the high-temperature
flue gas is led out from the position between the first-stage air pre-heater and the second-stage air pre-heater and mixed with H2 according to a certain proportion to be led into the thermal catalytic reactor, CO2 and H2 are reduced into methyl
alcohol through the Ni-Ga-Zr catalyst, and the methyl
alcohol is recycled. And then the
flue gas returns to the air pre-heater to continuously release heat, passes through a dust removal device and then is introduced into a low-temperature
coal economizer, and the temperature of the
flue gas is cooled to 70 DEG C or below, so that
methanol is condensed. The used Ni-Ga-Zr catalyst is prepared through a
coprecipitation method, and the used steps comprise stirring and dipping, adding of an alkaline solution for
coprecipitation, ultrasonic aging, centrifugal washing,
drying and calcining, H2 reduction and the like. According to the method, CO2 in the coal-fired flue gas can be reduced into
methanol under normal pressure, a carbon capture and
separation process is not needed, and the
energy consumption is low.