144 results about "Allyl alcohol" patented technology

The invention relates to the field of chemical synthesis, in particular to a production process of allyl diethylene glycol dicarbonate, which comprises the following steps: by taking allyl alcohol and dimethyl carbonate as raw materials, carrying out transesterification under the action of a core-shell catalyst to generate dipropylene carbonate; carrying out solid-liquid separation, carrying out reduced pressure distillation to recover methanol and dimethyl carbonate, and then carrying out second-step ester exchange reaction with diethylene glycol under the action of the same catalyst to generate allyl diethylene glycol dicarbonate; and finally, performing multi-stage reduced pressure distillation purification to obtain a high-purity product. According to the core-shell type catalyst, an MCM-41 molecular sieve is used as a carrier, an inner core is formed after amino modification and zirconium ion coordination, then an interface layer and a phenyl modified silicon dioxide shell are used for packaging, and the core-shell type catalyst has high activity, high selectivity and excellent structural stability. The method has the advantages of mild process conditions, recyclable catalyst, high product yield and excellent purity, and is suitable for industrial production.

Acrolein is produced by selectively oxidizing allyl alcohol over a first mixed metal oxide catalyst in the presence of oxygen in the vapor phase. The first mixed metal oxide catalyst comprises oxides of molybdenum and bismuth. Acrylic acid is produced by selectively oxidizing the acrolein over a second mixed metal oxide catalyst in the presence of oxygen in the vapor phase. The second mixed metal oxide catalyst has a different composition from the first mixed metal oxide catalyst.

The invention discloses a temperature-resistant and salt-resistant tackifier and a preparation method thereof, and relates to the technical field of fracturing fluids. The preparation method of the temperature-resistant and salt-resistant tackifier comprises the following steps: taking a first monomer and diethanol amine to carry out epoxy ring-opening reaction, and after the reaction is finished, separating and purifying to obtain an intermediate; taking the intermediate, adding a quaternization reagent for quaternization reaction, and then separating and purifying to obtain an active monomer; the first monomer is one of allyl alcohol glycidyl ether, acrylic acid glycidyl ether and methacrylic acid glycidyl ether, and the quaternization reagent is one of halogenated carboxylate or halogenated sulfonate; the preparation method comprises the following steps: dissolving acrylamide, an active monomer and unsaturated phosphate, and carrying out free radical polymerization under the action of an initiator. The tackifier provided by the invention has good temperature-resistant and salt-resistant effects, and can tolerate salt water with mineralization degree of 120,000 mg / L and high temperature of 150 DEG C.

The invention relates to a preparation technology of a multifunctional plastic clothes hanger through cooperation of degradable color master batches and nitrogen filling injection molding, and belongs to the technical field of plastic products. Adding the polylactic acid, the styrene-acrylonitrile copolymer, the modified stone powder, the degradable color master batch and the compound additive into a horizontal helical ribbon mixer, stirring and drying to obtain a mixture; the dried mixture is added into an injection molding machine to be melted and plasticized, a screw pushes melt to be injected into a mold, high-pressure nitrogen is injected into the melt, and the melt is pushed to completely fill a cavity; the plastic clothes hanger is obtained through pressure maintaining, cooling and demolding; the compound additive is prepared from allyl alcohol polyoxyethylene ether, 2-octenyl succinic anhydride, 14-mercaptotetradecanoic acid, anhydrous tetrahydrofuran, 2-hydroxy-4 '-(2-hydroxyethoxy)-2-methyl propiophenone and triethylamine. The preparation method comprises the following steps: preparing the compound additive; the degradable material is adopted, the biodegradation rate is high, the mechanical property is stable, the coloring effect is good, fading is not prone to occurring, and the service life is long.

The invention belongs to an allyl alcohol copolymer, and particularly relates to a method for preparing an allyl alcohol copolymer based on an intermediate conversion method, the allyl alcohol copolymer and application of the allyl alcohol copolymer. The method comprises the following steps: reacting allyl alcohol with a hydroxyl conversion reagent to convert hydroxyl into other groups so as to obtain a new allyl monomer; carrying out copolymerization on the monomer and other comonomers under the action of an initiator to obtain a copolymer; the hydroxyl is recovered by removing a conversion group, so that efficient and green preparation of the allyl alcohol copolymer is realized. The hydroxyl is converted into other groups, so that the reactivity rate of copolymerized monomers is closer during copolymerization, and the regulation and control of molecular weight and molecular composition are easy to realize; the high-temperature and high-pressure reaction conditions are avoided, and the safety risk caused by the fact that the highly toxic allyl alcohol raw material is greatly excessive is avoided; the polymerization reaction can be performed under normal pressure, the reaction condition is mild, and the equipment investment and maintenance cost are reduced; and the amount of residual allyl alcohol in the product is greatly reduced.

The invention relates to a preparation method of a polysiloxane defoaming composition. The polysiloxane defoaming composition is prepared from silicone grease, a polyether-polysiloxane copolymer, a surfactant and polyether. The silicone grease is prepared from the following raw materials: branched polysiloxane, hydrogen-containing polysiloxane, silicon dioxide, a TQ polymer, an addition catalyst and an inhibitor; the polyether-polysiloxane copolymer is prepared from hydrogen-containing silicon resin with a spatial structure, diallyl alcohol polyether and allyl polyether through a reaction. The polysiloxane defoaming agent composition obtained by the invention has the characteristics of excellent foam control and easiness in cleaning.

The present invention relates to the field of organic synthesis, and more particularly to a method for the oxidation of allylic alcohols to α,β-unsaturated carbonyl compounds in the presence of a zirconium catalyst and a hydrogen acceptor.

Provided is a binder including a polymer having a hydroxyl group, wherein the polymer includes a structural unit derived from an unsaturated carboxylic acid-based monomer, and a structural unit derived from at least one hydroxyl group-containing monomer selected from the group consisting of 2-hydroxyethyl acrylate, allyl alcohol, and isoprenol, the content of the structural unit derived from the hydroxyl group-containing monomer is 5 mol % to 50 mol % based on the total amount of the polymer, the weight average molecular weight of the polymer is 1000 to 5000, and the pH is 6.5 or lower.

The invention relates to a synthesis method of a branched chain type allyl alcohol compound, which comprises the following steps: under the protection of nitrogen, taking different substituted terminal alkyne and formalin as raw materials, taking metal cobalt salt and an organic ligand as catalysts, taking Hanus ester as a reducing agent, and carrying out a reaction in the presence of an organic solvent and a photosensitizer to obtain the branched chain type allyl alcohol compound. And carrying out illumination reaction to obtain the branched chain type allyl alcohol compound. According to the method, reaction raw materials and reagents are simple and easy to obtain, conditions are mild and easy to control, atom economy is high, precious metal catalysis is not needed, the substrate application range is wide, regioselectivity is high, and wide application prospects are achieved.

The invention belongs to the technical field of organic synthesis, and discloses a preparation method of a 3-alkylindole compound, which comprises the following steps: in an inert atmosphere, reacting a reaction solution mixed with an indole compound, an allyl alcohol compound, a catalyst Mn-1 and alkali at 110-150 DEG C for 12-24 hours to obtain the 3-alkylindole compound. Mn (CO) 5Br is used as a transition metal and complexed with a PNP pincerlike manganese complex to obtain the Mn-1 catalyst, the 3-alkylindole compound is obtained under the catalysis of the catalyst, allyl alcohol can be aryl allyl alcohol or aliphatic allyl alcohol, a substituent group on an indole ring can be an electron withdrawing group, the application range of a substrate is wide, meanwhile, the selection range of alkali or a solvent is wide, and the 3-alkylindole compound is suitable for industrial production. The method has the advantages of high atom economy, environment friendliness, high safety and the like.

The invention discloses a method for synthesizing a polysubstituted trifluoromethyl olefin compound from gem-difluoroallyl alcohol. The preparation method comprises the following steps: in a nitrogen (N2) atmosphere, sequentially adding a gem-difluoroallyl alcohol (R1R2OHCR3C = CF2) compound, acetic anhydride (Ac2O), a solvent dichloromethane (DCM) and a fluorine source pyridine hydrofluoride (Py.9HF) reagent into a 10mL Schlenk tube to obtain a mixture, stirring the mixture at room temperature (rt) until the reaction is finished, filtering, washing and drying to obtain the compound. A crude product obtained by the reaction is subjected to silica gel column chromatography separation to obtain the high-selectivity polysubstituted trifluoromethyl olefin compound. The preparation method disclosed by the invention can be carried out under mild conditions and is simple and convenient to operate, most of the adopted raw materials are simple and easily available or commercialized reagents, the reaction raw materials are easily available, the yield of the target product is high, the functional group compatibility of the product is good, and the application range of a substrate is relatively wide; the obtained polysubstituted trifluoromethyl olefin compound contains a plurality of functional groups such as trifluoromethyl, olefin and the like. The method provides a more efficient and safer new strategy for synthesizing the polysubstituted trifluoromethyl olefin under mild conditions, particularly, metal participation is avoided, a new opportunity is provided for green medicine synthesis, and the method is predicted to have wide application prospects in the fields of medicine research and development, natural product derivative synthesis, life science and the like.

The application discloses an indoor moisture-proof and water-resistant gypsum board and a preparation method thereof, and belongs to the technical field of gypsum board preparation. The preparation method of the indoor moisture-proof and water-resistant gypsum board comprises the following steps: S1, uniformly mixing building gypsum, modified fluorite gypsum, deionized water, a polyester adhesive, a composite water reducing agent, blast furnace slag powder and the like to obtain a gypsum slurry; S2, paving the gypsum slurry on a first layer of cover paper, paving a second layer of cover paper on the gypsum slurry, and performing compaction, final setting, drying and solidification to obtain the indoor moisture-proof and water-resistant gypsum board. The composite water reducing agent is obtained by the reaction of ethyl vinyl ether, trichlorofluoroethylene and allyltrimethoxysilane. The polyester adhesive is obtained by the reaction of allyl alcohol, phthalic anhydride and triallyl cyanurate. The prepared gypsum board not only has good moisture-proof and water-resistant performance, but also has good mechanical properties, thereby prolonging the service life and ensuring the quality of the gypsum board to a certain extent.

The present application relates to the technical field of organic synthesis, and particularly relates to a method for preparing (+)-crispine A by means of biological enzyme resolution. First, 6,7-dimethoxy-3,4-dihydroisoquinoline-2-oxide is subjected to 1,3-dipolar cycloaddition with allyl alcohol to obtain a first compound; then the first compound is added into a sulfonylation reagent and zinc powder to obtain a racemate second compound through a three-step continuous series reaction of primary alcohol sulfonylation, nitrogen-oxygen bond cleavage and ring formation; then the second compound is mixed with vinyl acetate and biological enzyme, and chiral resolution is carried out under the action of the biological enzyme to obtain a third compound with right-handed optical rotation and a fourth compound with left-handed optical rotation; finally, the third compound is mixed with an alkaline reagent and a sulfonylation reagent, and then secondary alcohol sulfonylation is carried out to obtain a fifth compound with right-handed optical rotation; the fifth compound is mixed with a deoxidizing reagent to carry out deoxidation reaction, and (+)-crispine A is prepared. The method is simple, green and environmentally friendly, and can be produced in large quantities.

The present invention relates to the technical field of organic synthesis. Disclosed is a method for synthesizing allyl alcohol. The synthesis method comprises the following steps: adding a water-soluble acid-resistant high-boiling-point organic solvent to an aqueous allyl acetate solution and stirring the mixture to form a homogeneous solution; then heating the homogeneous solution, and performing a hydrolysis reaction under the action of a solid acid catalyst to obtain a mixture solution containing allyl alcohol; and then distilling the mixture solution to separate out the high-boiling-point organic solvent to obtain a crude allyl alcohol product. The synthesis method provided by the present invention can significantly improve the single-pass hydrolysis conversion rate of allyl acetate at low costs and achieve efficient and continuous industrial production of allyl alcohol. Moreover, the method can realize the separation of allyl alcohol from the high-boiling-point organic solvent simply by means of a simple distillation separation process. The separated organic solvent has high purity and light color and can be reused. The method has no waste liquid and waste residue generated.

The invention discloses a preparation method of a cyanoborate lithium salt derivative, which comprises the following steps: 1, mixing an alcohol compound, a lithium source compound, a boron source compound and trimethylsilyl cyanide in a polar organic solvent, and filtering after complete reaction to obtain a cyanoborate crude product filtrate; the alcohol compound is selected from one of 2, 2, 2-trifluoroethanol, 2, 2-difluoroethanol, 2-fluoroethanol, 3-hydroxypropionitrile, allyl alcohol and propargyl alcohol; the lithium source compound is selected from one of lithium carbonate and lithium hydroxide; the boron source compound is selected from one of boric acid, diboron trioxide and boron tribromide; the reaction temperature is controlled to be 0-120 DEG C; and 2, adding an inert organic solvent into the cyanoborate crude product filtrate for crystallization, and performing vacuum drying to obtain a finished product of the cyanoborate lithium salt. The method has the advantages of high yield and purity, simple process, convenience in operation and low cost, and is extremely suitable for industrial production.

The invention provides a method for preparing allyl alcohol through epoxypropane isomerization, and relates to the technical field of chemical synthesis. According to the method, propylene oxide is subjected to an isomerization reaction in the presence of a polymerization inhibitor to prepare allyl alcohol; wherein the polymerization inhibitor is a phenol polymerization inhibitor and / or a quinone polymerization inhibitor. The technical scheme of the invention can effectively reduce the deactivation rate of the catalyst and prolong the service life of the catalyst. The method for preparing allyl alcohol through epoxypropane isomerization is high in production efficiency and low in production cost, and has important industrial application value.

The invention relates to the technical field of preparation of allyl alcohol polyether, in particular to a preparation method of allyl alcohol random polyether. According to the method, allyl alcohol is used as an initiator and is subjected to a polymerization reaction with ethylene oxide and epoxypropane in the presence of a non-metal organic catalyst. The method comprises the following steps: firstly, activating a mixed solution of part of ethylene oxide and propylene oxide, an initiator and a catalyst, then continuously dropwise adding the residual mixed solution into a sealed reaction system for growth polymerization, and finally recovering the catalyst through reduced pressure distillation to directly obtain a high-purity product. The method is simple in process route, avoids complex post-treatment steps such as neutralization and adsorption required by using a noble metal or sodium alcoholate catalyst, is high in catalyst recovery rate, extremely low in potassium and sodium ion content (less than or equal to 3ppm) in the product, and capable of accurately regulating and controlling the molecular weight in a range of 1400-3100, remarkably reduces the production cost, and is suitable for industrial production.

The invention discloses a preparation method of a low-pore-number composite lining, and belongs to the technical field of textiles. The preparation method of the low-hole-number composite lining comprises the following steps: (1) weaving polyester yarns into gray fabric; (2) shaping and preshrinking the gray fabric; (3) dyeing the set and pre-shrunk gray fabric; (4) shaping and finishing the dyed gray fabric to obtain a composite lining; wherein the dye for dyeing is obtained by reacting N-amino-4-N, N-dimethyl-1, 8-naphthalimide with ferrocene dicarboxaldehyde, and the dye for dyeing is obtained by reacting N-amino-4-N, N-dimethyl-1, 8-naphthalimide with ferrocene The setting agent for setting and finishing contains a hydrophilic softening agent, the hydrophilic softening agent is obtained by mixing polyether phenyl silicone oil with a compound emulsifier and deionized water, and the polyether phenyl silicone oil is obtained by reacting side chain hydrogen-containing silicone oil, allyl alcohol polyoxyalkyl ether, vinyltriethoxysilane and 1-(4-vinyl-phenyl)-ethanone; the prepared low-hole-number composite lining is good in hydrophilicity, color fastness and softness.

An organic silicon resin toughening agent, a single-component high-strength epoxy structural adhesive, and the preparation method thereof. The organic silicon resin toughening agent is prepared by reacting epoxy modified hydrogen-containing silicone oil with vinyl six-membered cyclic oligomeric silsesquioxane; The epoxy modified hydrogen-containing silicone oil is prepared by reacting allyl alcohol glycidyl ether with dihydrogen-terminated hydrogen-containing silicone oil. The organic silicon resin toughening agent with a circular network structure unit synthesized by the present disclosure has better high and low temperature resistance compared to toughening agents such as nitrile rubber and core-shell structure rubber. While improving the toughness of single-component high-strength epoxy structural adhesive, it can significantly enhance the high and low temperature resistance of single-component high-strength epoxy structural adhesive.

A process for co-feeding gaseous ethylene and liquid allyl alcohol in the presence of a catalyst to produce 1,4-butanediol and n-propanol may comprise: introducing a gaseous mixture of ethylene, carbon monoxide, and hydrogen in a solvent into a reactor in the presence of a hydroformylation catalyst; introducing liquid allyl alcohol (AA) into the reactor; and conducting a hydroformylation reaction at a temperature between 50° C. and 100° C. to obtain a hydroformylation product.

The invention discloses a preparation method of a silicone oil modified polyether defoaming agent, which is characterized in that alkynol (EO / PO type) block polyether and allyl alcohol (PO / EO type) block polyether are subjected to addition reaction under the action of a catalyst to generate the silicone oil modified polyether defoaming agent. The silicone oil modified polyether defoaming agent disclosed by the invention has the characteristics of high foam breaking speed and long foam inhibition period; the defoaming agent provided by the invention has the advantages of high temperature resistance, excellent chemical stability and excellent compatibility, and compared with a traditional polyether defoaming agent, the defoaming agent provided by the invention can achieve a better defoaming effect under the condition of a relatively low addition amount.

Provided is a method for producing 4-hydroxybutyramide represented by formula (1), which comprises a reaction step in which allyl alcohol, a primary amine represented by R-NH2 (R is a hydrocarbon group having 1-20 carbon atoms), and carbon monoxide are reacted in the presence of a rhodium or cobalt-containing catalyst. (In formula 1, R represents a hydrocarbon group having 1-20 carbon atoms. > # imgabs0 #

The application discloses a continuous Saucy-Marbet ketonization reaction process of allyl alcohol compounds. Specifically provided is a preparation method of compound II, which comprises the following steps: reacting compound I and 2-methoxy propylene in the presence of an acid in a tubular reactor to generate compound II; and the acid is added in the following manner: in the first stage, the molar ratio of the acid to the compound I is 0.005-0.015; in the second stage, the molar ratio of the acid to the compound I is 0.006-0.020; and in the third stage, the molar ratio of the acid to the compound I is 0.009-0.025. The preparation method disclosed by the application has one or more of the following advantages: (1) high yield, (2) high purity, (3) few side reactions, (4) simple operation and (5) low cost.

The invention provides a high-stability defoaming agent and a preparation method thereof, and belongs to the technical field of defoaming agents. The defoaming agent is prepared from 40 to 60 parts of polyether modified organic silicon, 130 to 170 parts of branched polyether ester, 270 to 330 parts of silicon factice, 14 to 18 parts of other auxiliary agents and 430 to 530 parts of water; the polyether modified organic silicon is obtained by carrying out hydrosilylation reaction on allyl polyoxyalkyl ether and hydrogen-containing silicone oil under the catalysis of chloroplatinic acid; the allyl polyoxyalkyl ether is prepared by carrying out polymerization reaction on allyl alcohol and alkylene oxide; the branched polyether ester is obtained by carrying out esterification reaction on branched polyoxyalkyl ether and fatty acid under the action of an acid catalyst; and the branched polyoxyalkyl ether is prepared by carrying out polymerization reaction on polyfunctional polyol and alkylene oxide. The defoaming agent disclosed by the invention is stable in storage at a high temperature, can maintain a good defoaming speed in a strong acid and alkali environment, and can maintain relatively strong foam inhibition activity.

The invention discloses a polyether type defoaming agent as well as a preparation method and application thereof, and the polyether type defoaming agent is obtained by carrying out second polymerization on 35%-65% of allyl polyoxyethylene ether, 20%-65% of allyl polyoxypropylene ether and 0%-15% of allyl polyoxybutylene ether; the allyl polyoxyethylene ether is formed by first polymerization of allyl alcohol and ethylene oxide, the allyl polyoxypropylene ether is formed by first polymerization of allyl alcohol and epoxypropane, and the allyl polyoxybutylene ether is formed by first polymerization of allyl alcohol and epoxybutane. When the polyether type defoaming agent is used in papermaking white water, the foam inhibition and defoaming properties are obviously improved, and the quality of paper products is not influenced.

The application discloses a Schiff base catalyst, a preparation method thereof and a preparation method of allyl glycidyl ether. The Schiff base catalyst comprises a Schiff base ligand and a central metal ion, wherein the Schiff base ligand is a condensate of ethylenediamine, one molecule of 3,5-di-tert-butyl salicylaldehyde and one molecule of 5-tert-butyl salicylaldehyde, and the central metal ion is selected from any one of Sn, Al and Fe. The Schiff base catalyst can efficiently catalyze the ring opening of allyl alcohol and epichlorohydrin, and the reaction period can be compressed to 3 hours. Meanwhile, the asymmetric structure of the Schiff base complex can effectively control the ring opening position of epichlorohydrin, improve the ring opening selectivity, and the methylene ring opening selectivity can be up to 99%.

The invention belongs to the field of fine chemical technology, discloses a kind of preparation method of allyl glycidyl ether.The preparation method is:Using allyl alcohol and epichlorohydrin as reaction raw materials, ring-opening reaction is carried out under the effect of strongly acidic cation exchange resin, after reaction terminates, filtrate is filtered to obtain;Then filtrate is mixed with strong base, ring-closed reaction is carried out under the effect of phase-transfer catalyst, after reaction terminates, through refinement, allyl glycidyl ether is obtained;The mol ratio of allyl alcohol and epichlorohydrin is 1:(0.95 1.2).The present invention uses open loop, closed loop two-step method to synthesize allyl glycidyl ether, using strongly acidic cation exchange resin as the catalyst of ring-opening reaction, it is possible to prepare the allyl glycidyl ether of high content, high yield without adding excessive allyl alcohol.

The invention discloses an indoor moisture-proof and water-resistant gypsum board and a preparation method thereof, and belongs to the technical field of gypsum board preparation. The preparation method of the indoor moisture-proof and water-resistant gypsum board comprises the following steps: S1, uniformly mixing building gypsum, modified fluorgypsum, deionized water, a polyester adhesive, a composite water reducing agent, blast furnace slag powder and the like to obtain gypsum slurry; s2, the gypsum slurry is flatly laid on the first layer of surface protection paper, the second layer of surface protection paper is flatly laid on the gypsum slurry, compaction, final setting and drying curing are conducted, and the indoor damp-proof and water-resistant gypsum board is prepared; wherein the composite water reducing agent is obtained by carrying out a reaction on ethyl vinyl ether, trichlorofluoroethylene and allyl trimethoxy silane; the polyester adhesive is obtained by reaction of allyl alcohol, phthalic anhydride and triallyl cyanurate; the prepared gypsum board not only has good moisture-proof and water-resistant performance, but also has good mechanical performance, the service life of the gypsum board is prolonged to a certain extent, and meanwhile the quality of the gypsum board is guaranteed.

The application provides a method for preparing normal aldehyde by one-step method, in which a raw material non-conjugated allyl alcohol is contacted with a catalyst under the condition of 0-2.0 bar in a hydrogen atmosphere containing carbon monoxide, and a normal aldehyde is generated by reaction; wherein the catalyst is a supported catalyst, including an active component main metal and an active assistant; the active component main metal includes at least one of rhodium, ruthenium and platinum elements, and the active assistant includes at least one of sulfur, selenium, tellurium, phosphorus, arsenic, antimony, bismuth, tin, cadmium, cerium and praseodymium elements. By controlling the synergistic effect of the reaction condition and the catalyst component, the double bond migration and saturated hydrogenation in the raw material are jointly regulated, the raw material conversion rate and the selectivity of the normal aldehyde are improved, and the generation of by-products is significantly reduced. The process flow of the application is simple and efficient, and is beneficial to large-scale production and application.

This invention provides a phosphorus-silicon synergistic flame-retardant coolant for immersion liquid cooling and its preparation method, belonging to the field of thermal safety technology for energy storage batteries. The preparation method of the phosphorus-silicon synergistic flame-retardant coolant for immersion liquid cooling includes adding diphenyl phosphate, allyl alcohol, a condensing agent, and an esterification catalyst to a reaction vessel under an inert atmosphere to carry out an esterification reaction, obtaining the intermediate allyl diphenyl phosphate; subsequently, adding 1,1,3,3-tetramethyldisiloxane and a platinum catalyst to the reaction system to carry out a hydrosilylation reaction; after the reaction, purification treatment is performed to obtain a siloxane-bridged phosphate; the obtained siloxane-bridged phosphate is added to a base mineral insulating oil, and a high-efficiency antioxidant is added, followed by uniform mixing to obtain the phosphorus-silicon synergistic flame-retardant coolant. This method can solve the problems of insufficient oxidation stability, easy increase in acid value, and difficulty in simultaneously achieving flame-retardant efficiency and long-term stability in existing coolants under long-term high-temperature operation.