19 results about "Methallyl chloride" patented technology

The application belongs to the technical field of oil and gas field development, and provides a phase permeability improver, a fracturing fluid system containing the same, and respective preparation methods and applications. The phase permeability improver is obtained by copolymerization and hydrolysis of acrylamide AM, a functional monomer 2-acrylamido-2-methylpropanesulfonic acid AMPS, and cationic hydrophobic monomers A and B; the cationic hydrophobic monomer A is at least one of tetradecyl dimethyl allyl ammonium chloride, hexadecyl dimethyl allyl ammonium chloride, and octadecyl dimethyl allyl ammonium chloride; the cationic hydrophobic monomer B is at least one of methacryloyloxyethyl trimethyl ammonium chloride, acryloyloxyethyl trimethyl ammonium chloride, and acryloyloxyethyldimethyl benzyl ammonium chloride; the phase permeability improver and the fracturing fluid system containing the same can significantly reduce the water phase permeability after fracturing operation, while having a smaller influence on the oil phase permeability, and have a significant effect of stabilizing oil and controlling water, and can significantly improve the stable production effect of fracturing operation in a low-permeability oil reservoir.

The application provides a carbon nanotube grafted polymer nano plugging agent, a preparation method thereof and a prepared drilling fluid, and the preparation method comprises the following steps: S1, reacting acrylic acid and amino functionalized multi-walled carbon nanotubes in a mass ratio of 1:0.1-0.2 to generate acrylic acid modified carbon nanotubes; and S2, performing a copolymerization reaction on acrylamide, the acrylic acid modified carbon nanotubes and octadecyl dimethyl allyl ammonium chloride in a mass ratio of 25:0.2-0.8:1.2-2.0 to obtain the carbon nanotube grafted polymer nano plugging agent. The carbon nanotube grafted polymer nano plugging agent comprises an amide group, a quaternary ammonium salt structure and an amino group, enhances the micro-nano plugging capacity of the plugging agent, enhances the inhibition capacity of the plugging agent to the hydration expansion and dispersion of formation mud shale, and has good temperature resistance, salt resistance and dispersion stability.

The invention relates to the technical field of polyacrylamide preparation, in particular to a preparation method of a temperature response type polyacrylamide water-in-water emulsion. The preparation method comprises the following steps: S1, mixing ammonium sulfate and a dispersion stabilizer, adding deionized water, and stirring to obtain a solution A; s2, mixing acrylamide, 2-acrylamide-2-methylpropanesulfonic acid, 2-methacryloyloxyethyl trimethyl ammonium chloride, N-vinyl pyrrolidone, octadecyl dimethyl allyl ammonium chloride and a modifier, and then adding water for dissolving, so as to obtain a solution B; and S3, mixing the solution A and the solution B, adjusting the pH value to 6.5-7.5, adding an initiator, and reacting to obtain the temperature-responsive polyacrylamide water-in-water emulsion. The invention provides a preparation method of a temperature response type polyacrylamide water-in-water emulsion, and aims to solve the problems of injection difficulty and insufficient high temperature resistance caused by poor solubility, poor rheological property and high injection viscosity of traditional PAM in related technologies.

The application discloses a kind of tetrapolymer type acidizing retarder and its preparation method and application, it is related to oil and gas exploitation technical field.The retarder is polymerized by acrylamide, sulfonate monomer, allyl polyoxyethylene ether and octadecyl dimethyl allyl ammonium chloride four monomers, other quaternary ammonium salt monomers except octadecyl dimethyl allyl ammonium chloride are not included in the system.By excluding the second quaternary ammonium salt monomer, electrostatic crosslinking caused by polyvalent cation center is cut off, and the viscosity of acid system is reduced to below 4 mPa·s.At the same time, the single quaternary ammonium salt structure unit produces adsorption isolation effect at rock interface, so that the retardation rate under the condition of 110 DEG C is maintained above 82%.The retarder provided by the application has low viscosity, high temperature resistance and salt resistance, and is suitable for high temperature deep well acidizing and fracturing operation.

The application relates to a film-forming fluid loss additive, a preparation method thereof, a workover fluid and a workover method, and relates to the workover field. The film-forming fluid loss additive comprises an oil phase, an emulsifier, acrylamide, N-vinyl pyrrolidone, 2-acrylamido-2-methylpropanesulfonic acid, hexadecyl dimethyl allyl ammonium chloride, water and an initiator. The workover fluid comprises water, a viscosity increasing agent, a plugging agent, an acid-soluble temporary plugging agent, an interface modifier, an anti-corrosion agent, a weighting agent and the aforementioned film-forming fluid loss additive. The film-forming fluid loss additive is provided, a polymer obtained through reverse emulsion polymerization of specific acrylamide, N-vinyl pyrrolidone, 2-acrylamido-2-methylpropanesulfonic acid and hexadecyl dimethyl allyl ammonium chloride is massively adsorbed on the surface of a filter cake under the action of high temperature and high pressure to form a high-molecular polymer film with high toughness, and the reduction of the fluid loss is realized. The temperature resistance of the workover fluid is greater than or equal to 180 DEG C, the pressure plugging capacity of the workover fluid to a fractured core is greater than 10 MPa, and the permeability recovery value of the workover fluid is greater than or equal to 92%.

The invention relates to the technical field of preparation of 2-methylallyl magnesium chloride, in particular to a preparation method of 2-methylallyl magnesium chloride, which comprises the following steps: pretreatment and initial feeding, reaction initiation, continuous reaction and heat preservation, end point judgment and product transfer. Magnesium is activated through a zinc stearate ethanol solution, zinc stearate can form an ultra-thin selective adsorption layer on the surface of magnesium particles, the layer cannot completely isolate the reaction, the reaction rate can be regulated and controlled, the risks of bumping and material flushing caused by too violent local reaction are avoided, and meanwhile, the service life of magnesium particles is prolonged. Ethanol is used as a solvent to assist zinc stearate to be uniformly attached to the surface of magnesium, and the dispersity of magnesium particles can be improved when the ethanol is subsequently mixed with tetrahydrofuran; tert-butyl p-hydroxyanisole is added into 2-methylallyl chloride to serve as a stabilizer, free radicals possibly generated in a reaction system can be captured, and side reactions such as polymerization and oxidation of 2-methylallyl chloride are inhibited.

The invention belongs to the technical field of synthesis of organic compounds, and relates to a synthesis method of drometrisiloxane, which comprises the following steps: carrying out Williamson etherification reaction on an ultraviolet light absorber UV-P and methyl allyl chloride to obtain an intermediate I; carrying out Claisen rearrangement reaction on the intermediate I to obtain an intermediate II; and carrying out hydrosilylation reaction on the intermediate II and heptamethyltrisiloxane to obtain dromethicone, the Williamson etherification reaction comprises the following steps: dissolving an ultraviolet light absorber UV-P in an alcohol ether solvent, and reacting with methyl allyl chloride under the condition of an acid-binding agent. According to the synthesis method of the drometrisiloxane, the etherification reaction is efficient, simple and convenient, the hydrosilylation reaction catalyst is high in efficiency, the solvent system is green and economical, the overall process is high in yield and purity, and the product quality is excellent.

The invention belongs to the technical field of synthesis of epoxy compounds, and discloses a preparation method of (methyl) epichlorohydrin. The preparation method comprises the following steps: (1) after tungstic acid reacts with hydrogen peroxide A, adding phosphoric acid for continuous reaction to prepare peroxyphosphotungstic acid; and (2) mixing the peroxy phosphotungstic acid prepared in the step (1) with allyl chloride or methyl allyl chloride dissolved with quaternary ammonium salt and a pH regulator, and adding hydrogen peroxide B for reaction to prepare epoxy chloropropane or methyl epoxy chloropropane. By adopting the preparation method provided by the invention to prepare the (methyl) epichlorohydrin, the procedures of liquid separation, drying and the like in the catalyst preparation process are omitted, the process steps are few, and hydrogen peroxide and a large amount of solvent can be saved while the process is simplified; and the prepared catalyst is high in selectivity, good in reuse effect and convenient to recycle and reuse.

The invention discloses a preparation method of methylallyl alcohol, which comprises the following steps: adding tricarboxylate into a reaction kettle, adding water for dissolving, heating and refluxing; dropwise adding methyl allyl chloride, and controlling the reaction temperature; cooling and filtering to obtain tricarboxylate solid and filtrate for later use; adding the tricarboxylate solid into a sodium hydroxide aqueous solution for reflux hydrolysis, cooling and layering to obtain methylallyl alcohol and tricarboxylate, and after separation, combining the tricarboxylate with the filtrate for recycling. The polycarboxylate obtained after esterification of the ternary carboxylate has small solubility in a solution, and an esterification product is a precipitate and can be naturally separated out; the esterification reaction can be carried out even under the condition of no catalyst, and the reaction is simple and rapid; then, the polybasic carboxylic ester can be separated through simple filtration, so that the emulsification phenomenon of the carboxylic ester in a water layer is overcome; and hydrolyzing the polybasic carboxylic ester to obtain corresponding alcohol and tricarboxylate, rectifying the alcohol to obtain the product methylallyl alcohol, and recycling the tricarboxylate.

The invention relates to a synthesis method of 2-methylallyl chloride, which comprises the following steps: by taking isobutylene chloride as a raw material, carrying out transposition rearrangement of free radical chlorine under the condition of ultraviolet irradiation to obtain the 2-methylallyl chloride. The method has the advantages that the process is simple, the conversion yield is high, the byproduct isobutenyl chloride in the process of preparing 2-methylallyl chloride through isobutene chlorination can be turned into wealth, and the additional value of the byproduct is improved.

The present application relates to the technical field of oilfield treatment agent, and is an oilfield sewage treatment oil removal agent and a preparation method thereof.The former is obtained by the following method: 1-ethyl-4-vinylbenzene, methacrylate, long-chain alkyl dimethyl allyl ammonium chloride, urea, anhydrous ethanol and water are stirred and uniformly mixed to obtain a mixed solution, and then acrylamide and a catalyst are added to the mixed solution to react and obtain the oil removal agent.The raw materials are easy to obtain, and the process is simple.The oil removal agent obtained by the preparation method has strong oil removal capacity, high oil removal rate, and is suitable for oil-water separation of oilfield sewage.The oil removal agent is effective in a wide pH range, does not contain metal ions, avoids secondary pollution, and also has the functions of demulsification, sterilization, flocculation and slow release.

This invention provides a thickener for fracturing, its preparation method, and its application. The preparation method includes: reacting monomers in an aqueous environment using an azo initiator and a redox initiator; the resulting product is then granulated, hydrolyzed, dried, and powdered to obtain the thickener for fracturing; wherein, based on the total monomer mass of 100%, the monomers include 64.5%-70.5% hydrophilic monomers, 5.5%-7% cationic monomers, 18%-24.5% anionic monomers, and 4.5%-7.0% composite supramolecular interaction monomers; the hydrophilic monomer is acrylamide; the cationic monomer is dimethyl diallyl ammonium chloride and / or acryloyloxyethyltrimethylammonium chloride; the anionic monomer is sodium acrylate; the composite supramolecular interaction monomers include a mixture of hexadecyl dimethyl allyl ammonium chloride, octadecyl dimethyl allyl ammonium chloride, and silane monomers in a mass ratio of 4.1-4.5:1:0.3-0.7.

The application discloses a self-degradation temporary plugging agent and a preparation method and application thereof. The raw materials of the self-degradation temporary plugging agent are composed of the following components in parts by weight and the total mass is 100 parts: 19.4-20 parts of hydrophilic polymer monomer, 10.5-1 parts of modified nano-particle NP-1, 0.1-0.5 parts of hydrophobic monomer, 0.12-0.2 parts of crosslinking agent, 0.8-1 parts of initiator, and the balance of water; the hydrophilic polymer monomer is acrylamide and / or acrylic acid; the hydrophobic monomer is selected from one or more of cetyl dimethyl allyl ammonium chloride, dimethyl diallyl ammonium chloride and methacryloyloxyethyl trimethyl ammonium chloride; the crosslinking agent is polyethylene glycol diacrylate; and the modified nano-particle NP-1 is nano-SiO2 which is hydrophobically modified by a silane coupling agent. The temporary plugging agent has a certain plugging strength under high pressure difference conditions and can be self-degraded into a low-viscosity solution in a wide temperature range (40-120 DEG C).

This invention provides a method for preparing a scale inhibitor for well control fluid. The preparation method includes the following steps: S1, maleic anhydride, sodium hypophosphite, and deionized water are mixed evenly and reacted at 60-70℃ for 1-1.5 hours, then cooled to room temperature; S2, acrylic acid, 2-acrylamide-2-methylpropanesulfonic acid, allyl polyethylene glycol, and octadecyl dimethyl allyl ammonium chloride are added sequentially to the cooled solution obtained in step S1. After complete dissolution, a reaction system is formed, and the pH of the reaction system is adjusted to 6-8 with NaOH; S3, the reaction system is placed in a 60-75℃ water bath, ammonium persulfate is added as an initiator, and the reaction is carried out at a constant temperature for 6-7 hours, then cooled to room temperature to obtain the scale inhibitor for well control fluid. The scale inhibitor for well control fluid obtained by the preparation method provided by this invention has the advantages of being environmentally friendly, non-corrosive, and not causing damage to the environment. Furthermore, it has a good scale inhibition effect on CaCO3, with a scale inhibition rate of over 91%, and can be used as a scale inhibitor for well control fluids without solid phase brine.

The invention belongs to the technical field of oil exploitation, and particularly relates to an anti-swelling clay stabilizer as well as a preparation method and application thereof. The preparation method comprises the following steps: adding 2-allyloxymethyl-2-methylolpropane-1, 3-diol into a reactor, adding sulfamic acid, and carrying out heat preservation reaction; distilled water, N-acryloyl (trihydroxymethyl) aminomethane, octadecyl dimethyl allyl ammonium chloride, allyl tributyl phosphonium chloride and buffer salt are sequentially added into the reactor, and the pH value is adjusted; dropwise adding an initiator, after dropwise adding is completed, carrying out heat preservation reaction, adding ethanol, precipitating, centrifuging, and drying overnight to obtain the clay stabilizer. The clay stabilizer disclosed by the invention has the advantages of high anti-swelling rate and washing resistance.

This invention relates to the field of organic synthesis and industrial by-product resource utilization technology, specifically to a method for synthesizing n-butane chloride using HCl, a by-product of methyl allyl chloride. This invention directly utilizes HCl, a by-product of the methyl allyl chloride production process, eliminating the need for purchased chlorination reagents and reducing the raw material cost of n-butane chloride by more than 40%, while simultaneously solving the pollution problem caused by HCl emissions. The composite catalyst (ionic liquid-zinc chloride / γ-Al₂O₃) works synergistically, achieving a n-butanol conversion rate ≥98% and a n-butane chloride selectivity ≥99%, avoiding heavy metal pollution from traditional catalysts. After two-stage distillation, the purity of n-butane chloride is ≥99.8%, meeting the requirements of high-end applications such as butyllithium synthesis. The process is continuous and stable: the fixed-bed continuous reaction mode ensures that the catalyst retains ≥92% activity after 15 cycles, suitable for industrial scale-up. Unreacted n-butanol is recycled, reducing wastewater discharge by 80% and eliminating waste gas emissions, meeting green chemical requirements.

The present application relates to the technical field of textile fabric, and discloses a multifunctional composite acrylic fabric and a preparation method thereof, the multifunctional composite acrylic fabric is obtained by treating acrylic fabric with sodium hydroxide solution and finishing liquid in sequence; the finishing liquid is prepared from deionized water, a crosslinking agent, nano silicon dioxide, perfluorohexyl ethyl acrylate, butyl acrylate, polyvinyl pyrrolidone, fatty alcohol polyoxyethylene ether, quaternary ammonium salt modified nano zinc oxide and ammonium persulfate aqueous solution; the quaternary ammonium salt modified nano zinc oxide is prepared from ethanol aqueous solution, nano zinc oxide, gamma-methacryloxypropyl trimethoxysilane, hexadecyl dimethyl allyl ammonium chloride aqueous solution and ammonium persulfate; and the crosslinking agent is prepared from hydroxyl silicone oil, isophorone diisocyanate, dibutyl tin dilaurate catalyst and methanol; the present application has good wear resistance, waterproofness and antibacterial property.

The invention discloses a shear-resistant high-temperature-resistant salt-resistant drag reducer for a fracturing fluid, which is prepared from the following components: 14 to 19.5 percent of acrylamide, 3.5 to 4.8 percent of 2-acrylamide-2-methylpropanesulfonic acid, 3.5 to 4.8 percent of sodium p-styrenesulfonate, 1.5 to 2.5 percent of hexadecyl dimethyl allyl ammonium chloride, 1.5 to 2.5 percent of acryloylmorpholine, 0.05 to 0.14 percent of cosolvent urea, 0.025 to 0.07 percent of chelating agent ethylene diamine tetraacetic acid tetrasodium salt, 0.05 to 0.18 percent of initiator azobis (isobutylamidine hydrochloride) and the balance of water. And the balance of water. The invention further discloses a preparation method and application of the drag reducer for the shear-resistant high-temperature-resistant salt-resistant fracturing fluid. The drag reducer for the shear-resistant, high-temperature-resistant and salt-resistant fracturing fluid provided by the invention solves the problem that the drag reduction capability of the existing drag reducer is reduced under the conditions of high temperature, high salinity and on-site high shear rate.