PEDOT:PSS/chitosan/silver nano-wire functionalized cotton fiber

A technology of silver nanowires and chitosan, used in fiber processing, plant fibers, textiles and papermaking, etc., can solve the problems of weak washing fastness, decreased strength of cotton fibers, canceration, etc., and achieve excellent electrical conductivity.

Inactive Publication Date: 2018-01-05
赵兵
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example: (1) Cotton fiber has the characteristics of large specific surface area and strong moisture absorption capacity, so it is easy to attach, reproduce and spread microorganisms during consumption, which will cause the strength of cotton fiber to decrease, produce stains, fade and smell, and even spread diseases and affect the human body healthy
(2) Excessive ultraviolet radiation can cause skin damage, aging, and even cancer
However, the interaction between AgNWs and cotton fibers in the above literature is mainly based on physical adsorption in the form of van der Waals force and hydrogen bonds, lacking a firm force combination, and its wash fastness is weak (Chemical Progress, 2017, 29(8 ): 892-901)

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] (1) Put the cotton fabric in a sodium hydroxide solution with a mass fraction of 20%, with a bath ratio of 1:50, react at 90°C for 120 minutes, wash repeatedly with deionized water until neutral, and obtain sodium hydroxide modified after drying Cotton fabric; then redisperse the sodium hydroxide modified cotton fabric in deionized water, liquor ratio 1:50, add trimethylallyl ammonium chloride, wherein trimethylallyl ammonium chloride and sodium hydroxide The mass ratio of the modified cotton fabric was 1:5, reacted at 60°C for 1h, washed repeatedly with deionized water, and dried to obtain trimethylallyl ammonium chloride modified cotton fabric; trimethylallyl chloride The ammonium chloride modified cotton fabric is redispersed in deionized water, the bath ratio is 1:50, slowly add 10g / L polyamide-amine PAMAM aqueous solution, wherein the PAMAM aqueous solution and the trimethylallyl ammonium chloride modified cotton fabric aqueous solution The volume ratio is 1:5, rea...

Embodiment 2

[0014](1) Put the cotton fabric in a sodium hydroxide solution with a mass fraction of 20%, with a bath ratio of 1:50, react at 90°C for 120 minutes, wash repeatedly with deionized water until neutral, and obtain sodium hydroxide modified after drying Cotton fabric; then redisperse the sodium hydroxide modified cotton fabric in deionized water, liquor ratio 1:50, add trimethylallyl ammonium chloride, wherein trimethylallyl ammonium chloride and sodium hydroxide The mass ratio of the modified cotton fabric was 1:7, reacted at 70°C for 6 hours, washed repeatedly with deionized water, and dried to obtain trimethylallyl ammonium chloride modified cotton fabric; the trimethylallyl chloride The ammonium chloride modified cotton fabric is redispersed in deionized water, the bath ratio is 1:50, slowly add 50g / L polyamide-amine PAMAM aqueous solution, wherein the PAMAM aqueous solution and the trimethylallyl ammonium chloride modified cotton fabric aqueous solution The volume ratio is ...

Embodiment 3

[0016] (1) Put the cotton fabric in a sodium hydroxide solution with a mass fraction of 20%, with a bath ratio of 1:50, react at 90°C for 120 minutes, wash repeatedly with deionized water until neutral, and obtain sodium hydroxide modified after drying Cotton fabric; then redisperse the sodium hydroxide modified cotton fabric in deionized water, liquor ratio 1:50, add trimethylallyl ammonium chloride, wherein trimethylallyl ammonium chloride and sodium hydroxide The mass ratio of the modified cotton fabric was 1:10, reacted at 80°C for 24 hours, washed repeatedly with deionized water, and dried to obtain trimethylallyl ammonium chloride modified cotton fabric; trimethylallyl chloride The ammonium chloride modified cotton fabric is redispersed in deionized water, the bath ratio is 1:50, slowly add 100g / L polyamide-amine PAMAM aqueous solution, wherein the PAMAM aqueous solution and the trimethylallyl ammonium chloride modified cotton fabric aqueous solution The volume ratio is ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention discloses PEDOT:PSS / chitosan / silver nano-wire functionalized cotton fiber and a preparation method thereof. The preparation method comprises the following steps: modifying cotton fabricwith sodium hydroxide, trimethylallylammonium chloride and PAMAM to obtain cationized cotton fabric, dipping the cationized cotton fabric into a silver nano-wire solution modified with a hyperbranchedpolymer with terminal hydroxyl and a PEDOT:PSS-chitosan mixed solution sequentially, and performing layer-by-layer self-assembling to finally obtain the PEDOT:PSS / chitosan / silver nano-wire functionalized cotton fiber. The PEDOT:PSS-chitosan and the silver nano-wire are firmly combined through electrostatic attraction layer-by-layer self-assembling, the cotton fiber is endowed with excellent electroconductive, antibacterial and anti-ultraviolet properties, and important application value is achieved in the fields of textile, clothes, wearable equipment, flexible electroconductive devices and the like.

Description

technical field [0001] The invention relates to PEDOT:PSS / chitosan / silver nanowire functionalized cotton fiber, which belongs to the field of nanocomposite materials. Background technique [0002] Cotton fiber is loved by consumers for its excellent properties such as moisture absorption, breathability, comfort, softness, warmth retention, renewable and degradable. However, compared with synthetic fibers, the functionality of cotton fibers is still insufficient. For example: (1) Cotton fiber has the characteristics of large specific surface area and strong moisture absorption capacity, so it is easy to attach, reproduce and spread microorganisms during consumption, which will cause the strength of cotton fiber to decrease, produce stains, fade and smell, and even spread diseases and affect the human body healthy. (2) Excessive ultraviolet radiation can cause skin damage, aging, and even canceration. (3) In recent years, conductive textiles have gradually become a research...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M15/63D06M15/356D06M15/03D06M11/83D06M11/38D06M13/463D06M15/59D06M101/06
Inventor 赵兵
Owner 赵兵
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