The invention relates to a novel method of SAPO-34 
molecular sieve membrane for selectively separating 
methane gas by 
crystal guidance and secondary synthesis. The method includes three steps, namely synthesizing 
crystal seed, preparing 
basement membrane of 
crystal seed and synthesizing SAPO-34 
molecular sieve membrane, in particular to the following steps: 
phosphoric acid, TEAOH and silica 
sol are added into adequately hydrolyzed 
aluminium isopropoxide to prepare a crystal seed solution of the 
molecular sieve and the molecular 
sieve composite mother solution; the crystal seed solution of the molecular 
sieve is prepared to be suspension after 
crystallization and rinsing for dripping onto a treated carrier; a 
basement membrane of crystal seed acquired is placed in a reaction kettle and is added with the molecular 
sieve composite mother solution for 
crystallization at a temperature 
ranging from 150 DEG C to 180 DEG C for 3 through 20 days, which is taken out for cleaning and 
drying and then is followed with actively removing a template agent at a temperature 
ranging from 400 DEG C to 600 DEG C. Synthesizing the molecular sieve membrane with the method of the invention is suitable for various porous supports with 
smooth surface, which is of high repetitiveness, good orientation, excellent separating property and ultrahigh gas permeability and is suitable for industrial application.