Antibacterial thermoplastic plastic composition and preparation method thereof

A thermoplastic and composition technology, applied in the field of plastic processing, can solve the problems of poor compatibility, antibacterial delay, and poor hydrophilicity, so as to prolong the antibacterial timeliness and water resistance, improve antibacterial efficiency, and The effect of large surface area

Active Publication Date: 2013-05-01
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Inorganic antibacterial agents are characterized by good safety, heat resistance, and durability. The disadvantages are high price and slow antibacterial effect, and they cannot kill bacteria as quickly as organic antibacterial agents.
[0005] Organic antibacterial agents are usually compounds with a certain molecular structure, and there are many types, for example, thiabendazole, chlorothalonil, carbendazim, zinc pyrithione, 2-n-octyl-4-isothiazol-3 ketone (OIT ), 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one (DCOIT), 10,10′-oxybisphenoxine (OBPA), n-butylbenzisothiazoline Ketone (BBIT), 3-iodo-2-propargyl butyl carbamate (IPBC), etc., most of the organic antibacterial agents have the characte

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-1

[0079] Weigh 100 g of fully vulcanized styrene-butadiene powder rubber (VP101) and 30 g of 2-n-octyl-4-isothiazol-3-ketone (OIT), stir it in a mixer until it is evenly mixed, and take it out after standing for 2 hours to obtain powder butyl rubber. Styrene rubber loaded OIT antibacterial agent (VP101KJ-1).

Embodiment 1-2

[0081] Weigh 95g of fully vulcanized styrene-butadiene powder rubber (VP101) and 5g of n-butylbenzisothiazolinone (BBIT), stir them in a mixer until they are evenly mixed, take them out after standing for 3 hours, and obtain powdered styrene-butadiene rubber loaded BBIT antibacterial agent (VP101KJ-2).

Embodiment 1-3

[0083] Take by weighing 4,5-dichloro-2-n-octyl-4-isothiazolin-3-one (DCOIT) 10g, it is dissolved in plasticizer dioctyl phthalate (DOP) 90g, fully Stir to make it a clear and transparent solution, called DCOIT / DOP-1#.

[0084] Weigh DCOIT / DOP-1#40g, fully vulcanized styrene-butadiene powder rubber (VP101) 100g, stir it evenly in a mixer, take it out after standing for 3h, and obtain the antibacterial agent (VP101KJ-3) of powdered styrene-butadiene rubber loaded with DCOIT .

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PUM

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Abstract

The invention provides an antibacterial thermoplastic plastic composition comprising blended materials of thermoplastic plastic and a load-type antibacterial agent. Calculated with the weight of the thermoplastic plastic as 100 parts, the composition comprises 0.1-30 parts of the load-type antibacterial agent. The load-type antibacterial agent is an antibacterial agent loaded by powder rubber. The load-type antibacterial agent comprises an organic antibacterial agent and power rubber. The antibacterial agent is loaded on the powder rubber. An organic antibacterial agent which is in a liquid state in normal temperature or an organic antibacterial agent solution is well mixed with the powder rubber, and the mixture is subjected to standing, until the powder rubber absorbs the organic antibacterial agent which is in a liquid state in normal temperature or the organic antibacterial agent solution, such that the load-type antibacterial agent is obtained. With the method, the obtained antibacterial thermoplastic plastic composition has the advantages such as good antibacterial effect, good color, low cost, high safety, and the like. The preparation process is simple and is easy to operate. The method is suitable for industrialized application.

Description

technical field [0001] The invention relates to the field of plastic processing, in particular to an antibacterial thermoplastic composition and a preparation method thereof. Background technique [0002] In recent years, with the improvement of people's living standards and the enhancement of hygiene awareness, the demand for various antibacterial material products has been increasing, of which antibacterial plastic products account for a large proportion, various daily products, including refrigerators, air conditioners, various Food containers, packaging bags, washing machines, toy products, vacuum cleaners, etc., all use a variety of thermoplastic antibacterial plastics, including antibacterial polypropylene (PP), antibacterial polyethylene (PE), antibacterial polystyrene (PS), Antibacterial polyvinyl chloride (PVC), antibacterial polyacrylonitrile-butadiene-styrene (ABS), antibacterial nylon (PA), antibacterial polyethylene terephthalate (PET), antibacterial polyoxymeth...

Claims

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Application Information

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IPC IPC(8): C08L101/00C08K13/06C08K9/12
Inventor 乔金樑李杰张师军刘涛张丽英邹浩邵静波杨庆泉王小兰吕明福
Owner CHINA PETROLEUM & CHEM CORP
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